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    • 4. 发明授权
    • Organic crystal
    • 有机水晶
    • US07199237B2
    • 2007-04-03
    • US10930293
    • 2004-08-31
    • Hideo YamakadoToshiyuki KunikiyoAkito Ugawa
    • Hideo YamakadoToshiyuki KunikiyoAkito Ugawa
    • C09B47/04C09B62/00
    • C07D487/22
    • A flexible organic single crystal has a plurality of columns. The plurality of columns includes a plurality of planar organic compounds arranged so that molecular planes of molecules are respectively parallel to each other. As the organic compound, an organic compound is used that has a large molecular plane and a large area overlapping on an adjacent organic compound due to an intermolecular interaction. Further, energy changes in proportion to a strain. In this structure, when force along the direction of a stack axis is exerted, an angle formed by the stack axis and the normal of the molecular plane of the organic compound changes. Thus, the single crystal obtains flexibility.
    • 柔性有机单晶具有多个列。 多个列包括多个平面有机化合物,其被布置成使得分子的分子平面彼此平行。 作为有机化合物,由于分子间相互作用,使用具有大分子面和大面积重叠在相邻有机化合物上的有机化合物。 此外,能量与应变成比例地变化。 在这种结构中,当施加沿着堆叠轴线的方向的力时,由堆叠轴线形成的角度和有机化合物的分子平面的法线变化。 因此,单晶获得灵活性。
    • 6. 发明授权
    • Metal complexes of heterocyclic aromatic compounds
    • 杂环芳族化合物的金属络合物
    • US07038025B2
    • 2006-05-02
    • US10468982
    • 2002-12-18
    • Eriko MatsuiYuriko KainoToshiyuki KunikiyoYoshifumi MoriTatsushiro Hirata
    • Eriko MatsuiYuriko KainoToshiyuki KunikiyoYoshifumi MoriTatsushiro Hirata
    • C09B45/00C07D207/00
    • C07D207/32C07D207/323
    • A novel metal complex of a heterocyclic aromatic compound which shows a low activation energy, is stabilized structurally, is capable of modulation of the structure thereof, and capable of preferably functioning as a molecular device in technological fields. The metal complex of a heterocyclic aromatic compound comprises a transition metal (for example, silver ion) as a central atom, and basic ligands comprised of a 5-membered heterocyclic aromatic compound (for example, pyrrole rings), in which the position of the central atom can be changed by an internal factor such as transfer of an electric charge or by an external factor such as application of an electric field, a change in acidity of the surrounding environment, etc., whereby the number of atoms (or the number of electrons) relating to the coordination ability can be modulated, and, upon polymerization, the conformation can be modulated depending on the position of the central atom.
    • 显示低活化能的杂环芳族化合物的新型金属络合物在结构上是稳定的,能够调节其结构,并且能够优选在技术领域中用作分子装置。 杂环芳族化合物的金属络合物包含作为中心原子的过渡金属(例如银离子)和由5元杂环芳族化合物(例如吡咯环)构成的碱性配体,其中, 中心原子可以通过诸如电荷的转移或诸如施加电场的外部因素,周围环境的酸度变化等内部因素而改变,由此原子数(或数) 的电子)可以调节,并且在聚合时,可以根据中心原子的位置来调节构象。
    • 9. 发明授权
    • Organic crystal
    • 有机水晶
    • US07790879B2
    • 2010-09-07
    • US11152708
    • 2005-06-14
    • Hideo YamakadoToshiyuki KunikiyoAkito Ugawa
    • Hideo YamakadoToshiyuki KunikiyoAkito Ugawa
    • C07B47/00C07D487/22
    • C07D487/22
    • A flexible organic single crystal has a plurality of columns. The plurality of columns includes a plurality of planar organic compounds arranged so that molecular planes of molecules are respectively parallel to each other. As the organic compound, an organic compound is used that has a large molecular plane and a large area overlapping on an adjacent organic compound due to an intermolecular interaction. Further, energy changes in proportion to a strain. In this structure, when force along the direction of a stack axis is exerted, an angle formed by the stack axis and the normal of the molecular plane of the organic compound changes. Thus, the single crystal obtains flexibility.
    • 柔性有机单晶具有多个列。 多个列包括多个平面有机化合物,其被布置成使得分子的分子平面彼此平行。 作为有机化合物,由于分子间相互作用,使用具有大分子面和大面积重叠在相邻有机化合物上的有机化合物。 此外,能量与应变成比例地变化。 在这种结构中,当施加沿着堆叠轴线的方向的力时,由堆叠轴线形成的角度和有机化合物的分子平面的法线变化。 因此,单晶获得灵活性。
    • 10. 发明申请
    • Organic crystal
    • 有机水晶
    • US20060047111A1
    • 2006-03-02
    • US11152708
    • 2005-06-14
    • Hideo YamakadoToshiyuki KunikiyoAkito Ugawa
    • Hideo YamakadoToshiyuki KunikiyoAkito Ugawa
    • C07D487/22
    • C07D487/22
    • A flexible organic single crystal has a plurality of columns. The plurality of columns includes a plurality of planar organic compounds arranged so that molecular planes of molecules are respectively parallel to each other. As the organic compound, an organic compound is used that has a large molecular plane and a large area overlapping on an adjacent organic compound due to an intermolecular interaction. Further, energy changes in proportion to a strain. In this structure, when force along the direction of a stack axis is exerted, an angle formed by the stack axis and the normal of the molecular plane of the organic compound changes. Thus, the single crystal obtains flexibility
    • 柔性有机单晶具有多个列。 多个列包括多个平面有机化合物,其被布置成使得分子的分子平面彼此平行。 作为有机化合物,由于分子间相互作用,使用具有大分子面和大面积重叠在相邻有机化合物上的有机化合物。 此外,能量与应变成比例地变化。 在这种结构中,当施加沿着堆叠轴线的方向的力时,由堆叠轴线形成的角度和有机化合物的分子平面的法线变化。 因此,单晶获得灵活性