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1. 发明申请

US20060145151A1 Metal complex of heterocyclic aromatic compound 失效
公开(公告)号：US20060145151A1
公开(公告)日：2006-07-06
申请号：US11368793
申请日：2006-03-06
申请人： Eriko Matsui , Yuriko Kaino , Toshiyuki Kunikiyo , Tatsushiro Hirata , Yoshifumi Mori
发明人： Eriko Matsui , Yuriko Kaino , Toshiyuki Kunikiyo , Tatsushiro Hirata , Yoshifumi Mori
IPC分类号： C07F1/10 , H01L29/08
CPC分类号： C07D207/32 , C07D207/323
摘要： A novel metal complex of a heterocyclic aromatic compound which shows a low activation energy, is stabilized structurally, is capable of modulation of the structure thereof, and capable of preferably functioning as a molecular device in technological fields. The metal complex of a heterocyclic aromatic compound comprises a transition metal (for example, silver ion) as a central atom, and basic ligands comprised of a 5-membered heterocyclic aromatic compound (for example, pyrrole rings), in which the position of the central atom can be changed by an internal factor such as transfer of an electric charge or by an external factor such as application of an electric field, a change in acidity of the surrounding environment, etc., whereby the number of atoms (or the number of electrons) relating to the coordination ability can be modulated, and, upon polymerization, the conformation can be modulated depending on the position of the central atom.

2. 发明授权

US07038025B2 Metal complexes of heterocyclic aromatic compounds 失效
标题翻译：杂环芳族化合物的金属络合物
公开(公告)号：US07038025B2
公开(公告)日：2006-05-02
申请号：US10468982
申请日：2002-12-18
申请人： Eriko Matsui , Yuriko Kaino , Toshiyuki Kunikiyo , Yoshifumi Mori , Tatsushiro Hirata
发明人： Eriko Matsui , Yuriko Kaino , Toshiyuki Kunikiyo , Yoshifumi Mori , Tatsushiro Hirata
IPC分类号： C09B45/00 , C07D207/00
CPC分类号： C07D207/32 , C07D207/323
摘要： A novel metal complex of a heterocyclic aromatic compound which shows a low activation energy, is stabilized structurally, is capable of modulation of the structure thereof, and capable of preferably functioning as a molecular device in technological fields. The metal complex of a heterocyclic aromatic compound comprises a transition metal (for example, silver ion) as a central atom, and basic ligands comprised of a 5-membered heterocyclic aromatic compound (for example, pyrrole rings), in which the position of the central atom can be changed by an internal factor such as transfer of an electric charge or by an external factor such as application of an electric field, a change in acidity of the surrounding environment, etc., whereby the number of atoms (or the number of electrons) relating to the coordination ability can be modulated, and, upon polymerization, the conformation can be modulated depending on the position of the central atom.
摘要翻译：显示低活化能的杂环芳族化合物的新型金属络合物在结构上是稳定的，能够调节其结构，并且能够优选在技术领域中用作分子装置。杂环芳族化合物的金属络合物包含作为中心原子的过渡金属（例如银离子）和由5元杂环芳族化合物（例如吡咯环）构成的碱性配体，其中，中心原子可以通过诸如电荷的转移或诸如施加电场的外部因素，周围环境的酸度变化等内部因素而改变，由此原子数（或数）的电子）可以调节，并且在聚合时，可以根据中心原子的位置来调节构象。

3. 发明授权

US07598358B2 Metal complex of heterocyclic aromatic compound 失效
标题翻译：杂环芳族化合物的金属络合物
公开(公告)号：US07598358B2
公开(公告)日：2009-10-06
申请号：US11368793
申请日：2006-03-06
申请人： Eriko Matsui , Yuriko Kaino , Toshiyuki Kunikiyo , Tatsushiro Hirata , Yoshifumi Mori
发明人： Eriko Matsui , Yuriko Kaino , Toshiyuki Kunikiyo , Tatsushiro Hirata , Yoshifumi Mori
IPC分类号： C09B45/00
CPC分类号： C07D207/32 , C07D207/323
摘要： A novel metal complex of a heterocyclic aromatic compound which shows a low activation energy, is stabilized structurally, is capable of modulation of the structure thereof, and capable of preferably functioning as a molecular device in technological fields. The metal complex of a heterocyclic aromatic compound comprises a transition metal (for example, silver ion) as a central atom, and basic ligands comprised of a 5-membered heterocyclic aromatic compound (for example, pyrrole rings), in which the position of the central atom can be changed by an internal factor such as transfer of an electric charge or by an external factor such as application of an electric field, a change in acidity of the surrounding environment, etc., whereby the number of atoms (or the number of electrons) relating to the coordination ability can be modulated, and, upon polymerization, the conformation can be modulated depending on the position of the central atom.
摘要翻译：显示低活化能的杂环芳族化合物的新型金属络合物在结构上是稳定的，能够调节其结构，并且能够优选在技术领域中用作分子装置。杂环芳族化合物的金属络合物包含作为中心原子的过渡金属（例如银离子）和由5元杂环芳族化合物（例如吡咯环）构成的碱性配体，其中，中心原子可以通过诸如电荷的转移或诸如施加电场的外部因素，周围环境的酸度变化等内部因素而改变，由此原子数（或数）的电子）可以调节，并且在聚合时，可以根据中心原子的位置来调节构象。

4. 发明授权

US07816679B2 Organic compound crystal and field-effect transistor 失效
标题翻译：有机复合晶体和场效晶体管
公开(公告)号：US07816679B2
公开(公告)日：2010-10-19
申请号：US12182203
申请日：2008-07-30
申请人： Akito Ugawa , Yousuke Ohta , Toshiyuki Kunikiyo , Masayuki Murakami
发明人： Akito Ugawa , Yousuke Ohta , Toshiyuki Kunikiyo , Masayuki Murakami
IPC分类号： H01L51/30 , C07D339/00
CPC分类号： H01L51/0052 , H01L51/0051 , H01L51/0074 , H01L51/0545
摘要： A field-effect transistor includes a channel-forming region composed of an organic compound crystal including π-electron conjugated molecules each containing chalcogen atoms as a constituent, wherein the distance between chalcogen atoms of adjacent π-electron conjugated molecules is short, and the organic compound crystal has a periodic structure in which π-electron conjugated molecules are two-dimensionally or three-dimensionally linked together.
摘要翻译：场效应晶体管包括由包含以硫族元素原子为主成分的pgr电子共轭分子的有机化合物晶体构成的沟道形成区域，其中相邻＆pgr-电子共轭分子的硫属原子之间的距离短，有机化合物晶体具有其中＆pgr-电子共轭分子二维或三维连接在一起的周期性结构。

5. 发明申请

US20060047111A1 Organic crystal 有权
标题翻译：有机水晶
公开(公告)号：US20060047111A1
公开(公告)日：2006-03-02
申请号：US11152708
申请日：2005-06-14
申请人： Hideo Yamakado , Toshiyuki Kunikiyo , Akito Ugawa
发明人： Hideo Yamakado , Toshiyuki Kunikiyo , Akito Ugawa
IPC分类号： C07D487/22
CPC分类号： C07D487/22
摘要： A flexible organic single crystal has a plurality of columns. The plurality of columns includes a plurality of planar organic compounds arranged so that molecular planes of molecules are respectively parallel to each other. As the organic compound, an organic compound is used that has a large molecular plane and a large area overlapping on an adjacent organic compound due to an intermolecular interaction. Further, energy changes in proportion to a strain. In this structure, when force along the direction of a stack axis is exerted, an angle formed by the stack axis and the normal of the molecular plane of the organic compound changes. Thus, the single crystal obtains flexibility
摘要翻译：柔性有机单晶具有多个列。多个列包括多个平面有机化合物，其被布置成使得分子的分子平面彼此平行。作为有机化合物，由于分子间相互作用，使用具有大分子面和大面积重叠在相邻有机化合物上的有机化合物。此外，能量与应变成比例地变化。在这种结构中，当施加沿着堆叠轴线的方向的力时，由堆叠轴线形成的角度和有机化合物的分子平面的法线变化。因此，单晶获得灵活性

6. 发明申请

US20050285156A1 Organic compound crystal and field-effect transistor 失效
标题翻译：有机复合晶体和场效晶体管
公开(公告)号：US20050285156A1
公开(公告)日：2005-12-29
申请号：US11152709
申请日：2005-06-14
申请人： Akito Ugawa , Yousuke Ohta , Toshiyuki Kunikiyo , Masayuki Murakami
发明人： Akito Ugawa , Yousuke Ohta , Toshiyuki Kunikiyo , Masayuki Murakami
IPC分类号： G02B5/00 , H01L29/80 , H01L31/112 , H01L51/00 , H01L51/05
CPC分类号： H01L51/0052 , H01L51/0051 , H01L51/0074 , H01L51/0545
摘要： A field-effect transistor includes a channel-forming region composed of an organic compound crystal including π-electron conjugated molecules each containing chalcogen atoms as a constituent, wherein the distance between chalcogen atoms of adjacent π-electron conjugated molecules is short, and the organic compound crystal has a periodic structure in which π-electron conjugated molecules are two-dimensionally or three-dimensionally linked together.
摘要翻译：场效应晶体管包括由包含以硫属元素原子为主成分的π电子共轭分子的有机化合物晶体构成的沟道形成区域，其中相邻π-电子共轭分子的硫属原子之间的距离短，有机复合晶体具有其中π-电子共轭分子二维或三维连接在一起的周期结构。

7. 发明申请

US20120068146A1 MEMORY ELEMENT AND MEMORY DEVICE 有权
标题翻译：存储元件和存储器件
公开(公告)号：US20120068146A1
公开(公告)日：2012-03-22
申请号：US13227870
申请日：2011-09-08
申请人： Shinnosuke Hattori , Toshiyuki Kunikiyo , Mitsunori Nakamoto , Shuichiro Yasuda
发明人： Shinnosuke Hattori , Toshiyuki Kunikiyo , Mitsunori Nakamoto , Shuichiro Yasuda
IPC分类号： H01L47/00 , H01L27/24
CPC分类号： H01L27/2472 , G11C13/0002 , G11C13/0007 , G11C2213/55 , G11C2213/56 , H01L27/2436 , H01L45/085 , H01L45/1233 , H01L45/1266 , H01L45/144 , H01L45/146
摘要： There are provided a memory element and a memory device with a smaller range of element-to-element variation of electrical characteristics. The memory element includes a first electrode, a memory layer, and a second layer in this order. The memory layer includes a resistance change layer including a plurality of layers varying in diffusion coefficient of mobile atoms, and an ion source layer disposed between the resistance change layer and the second electrode.
摘要翻译：提供了具有较小范围的电特性元件间元件变化的存储元件和存储器件。存储元件依次包括第一电极，存储层和第二层。存储层包括电阻变化层，该电阻变化层包括以移动原子的扩散系数变化的多个层，以及设置在电阻变化层和第二电极之间的离子源层。

8. 发明申请

US20120061638A1 MEMORY ELEMENT AND MEMORY DEVICE 有权
标题翻译：存储元件和存储器件
公开(公告)号：US20120061638A1
公开(公告)日：2012-03-15
申请号：US13223391
申请日：2011-09-01
申请人： Toshiyuki Kunikiyo , Shinnosuke Hattori , Mitsunori Nakamoto
发明人： Toshiyuki Kunikiyo , Shinnosuke Hattori , Mitsunori Nakamoto
IPC分类号： H01L45/00
CPC分类号： H01L45/08 , G11C13/0011 , H01L27/2436 , H01L27/2463 , H01L27/2472 , H01L45/085 , H01L45/1233 , H01L45/1266 , H01L45/144 , H01L45/146
摘要： There are provided a memory element and a memory device in which the state of erasing remains stable by deactivation of a localized site(s) formed inside of a resistance change layer. The memory element includes a first electrode, a memory layer, and a second electrode in this order. The memory layer includes a resistance change layer including an n-type dopant or a p-type dopant, and disposed on the first electrode side, and an ion source layer disposed between the resistance change layer and the second electrode.
摘要翻译：提供了一种存储元件和存储器件，其中擦除状态通过在电阻变化层内部形成的局部位置的停用而保持稳定。存储元件依次包括第一电极，存储层和第二电极。存储层包括电阻变化层，其包括n型掺杂剂或p型掺杂剂，并且设置在第一电极侧，以及设置在电阻变化层和第二电极之间的离子源层。

9. 发明授权

US07790879B2 Organic crystal 有权
标题翻译：有机水晶
公开(公告)号：US07790879B2
公开(公告)日：2010-09-07
申请号：US11152708
申请日：2005-06-14
申请人： Hideo Yamakado , Toshiyuki Kunikiyo , Akito Ugawa
发明人： Hideo Yamakado , Toshiyuki Kunikiyo , Akito Ugawa
IPC分类号： C07B47/00 , C07D487/22
CPC分类号： C07D487/22
摘要： A flexible organic single crystal has a plurality of columns. The plurality of columns includes a plurality of planar organic compounds arranged so that molecular planes of molecules are respectively parallel to each other. As the organic compound, an organic compound is used that has a large molecular plane and a large area overlapping on an adjacent organic compound due to an intermolecular interaction. Further, energy changes in proportion to a strain. In this structure, when force along the direction of a stack axis is exerted, an angle formed by the stack axis and the normal of the molecular plane of the organic compound changes. Thus, the single crystal obtains flexibility.
摘要翻译：柔性有机单晶具有多个列。多个列包括多个平面有机化合物，其被布置成使得分子的分子平面彼此平行。作为有机化合物，由于分子间相互作用，使用具有大分子面和大面积重叠在相邻有机化合物上的有机化合物。此外，能量与应变成比例地变化。在这种结构中，当施加沿着堆叠轴线的方向的力时，由堆叠轴线形成的角度和有机化合物的分子平面的法线变化。因此，单晶获得灵活性。

10. 发明授权

US09159911B2 Memory element and memory device 有权
标题翻译：存储器元件和存储器件
公开(公告)号：US09159911B2
公开(公告)日：2015-10-13
申请号：US13223391
申请日：2011-09-01
申请人： Toshiyuki Kunikiyo , Shinnosuke Hattori , Mitsunori Nakamoto
发明人： Toshiyuki Kunikiyo , Shinnosuke Hattori , Mitsunori Nakamoto
IPC分类号： H01L45/00 , H01L27/24 , G11C13/00
CPC分类号： H01L45/08 , G11C13/0011 , H01L27/2436 , H01L27/2463 , H01L27/2472 , H01L45/085 , H01L45/1233 , H01L45/1266 , H01L45/144 , H01L45/146
摘要： There are provided a memory element and a memory device in which the state of erasing remains stable by deactivation of a localized site(s) formed inside of a resistance change layer. The memory element includes a first electrode, a memory layer, and a second electrode in this order. The memory layer includes a resistance change layer including an n-type dopant or a p-type dopant, and disposed on the first electrode side, and an ion source layer disposed between the resistance change layer and the second electrode.
摘要翻译：提供了一种存储元件和存储器件，其中擦除状态通过在电阻变化层内部形成的局部位置的停用而保持稳定。存储元件依次包括第一电极，存储层和第二电极。存储层包括电阻变化层，其包括n型掺杂剂或p型掺杂剂，并且设置在第一电极侧，以及设置在电阻变化层和第二电极之间的离子源层。

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