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    • 15. 发明授权
    • N-phenylsulfonyl-N'-triazinylureas
    • N-苯基磺酰基-N'-三嗪基脲
    • US4594097A
    • 1986-06-10
    • US745749
    • 1985-06-17
    • Rolf SchurterWerner ForyWilly Meyer
    • Rolf SchurterWerner ForyWilly Meyer
    • C07D251/16A01N47/36C07C67/00C07C301/00C07D239/42C07D239/47C07D239/48C07D239/52C07D239/56C07D251/42C07D401/12C07D409/12C07D521/00C07D251/50A01N43/70C07D251/52
    • C07D521/00A01N47/36
    • N-Phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'-triazinylureas of the general formula I ##STR1## wherein A is a radical of the formula --C.tbd.C--R,m is 1 or 2,Z is oxygen or sulfur,R is hydrogen; unsubstituted or substituted, branched or unbranched C.sub.1 -C.sub.9 alkyl; unsubstituted or substituted C.sub.3 -C.sub.9 cycloalkyl; unsubstituted or substituted phenyl; or an unsubstituted or substituted 5- or 6-membered aromatic heterocyclic ring,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or a radical --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, halogen, C.sub.2 -C.sub.5 alkoxyalkyl, --NR.sub.9 R.sub.10 or --O--CH.sub.2 --CH.sub.2 --NR.sub.9 R.sub.10,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl, C.sub.1 -C.sub.5 haloalkyl, C.sub.2 -C.sub.5 haloalkenyl or C.sub.2 -C.sub.6 alkoxyalkyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl,R.sub.9 is hydrogen, methyl or ethyl,R.sub.10 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, methoxymethyl, cyanomethyl, cyanoethyl, C.sub.3 -C.sub.5 alkenyl or C.sub.3 -C.sub.6 alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridgeand the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases, have good preemergence and postemergence selective herbicidal and growth regulating properties.
    • N-苯基磺酰基-N'-嘧啶基脲和通式I的N-苯基磺酰基-N'-三嗪基脲其中A是式-CB 3 CR的基团,m是1或2,Z是氧 或硫,R是氢; 未取代或取代的支链或非支链C 1 -C 9烷基; 未取代或取代的C 3 -C 9环烷基; 未取代或取代的苯基; 或未取代或取代的5元或6元芳族杂环,R 1为氢,卤素,C 1 -C 5烷基,C 2 -C 5烯基或自由基-Y-R 5,R 2为氢,卤素,C 1 -C 5烷基,C 2 -C 5链烯基, C1-C4卤代烷基或自由基-Y-R5,-COOR6,-NO2或-CO-NR7-R8,R3和R4各自独立地为氢,C1-C4烷基,C1-C4烷氧基,C1-C4烷硫基, C1-C4卤代烷基,C1-C4卤代烷氧基,C1-C4卤代烷硫基,卤素,C2-C5烷氧基烷基,-NR9R10或-O-CH2-CH2-NR9R10,R5和R6各自独立地为C1-C5烷基,C2-C5链烯基或C2 C 1-6炔基,C 1 -C 5卤代烷基,C 2 -C 5卤代烯基或C 2 -C 6烷氧基烷基,R 7和R 8各自独立地为氢,C 1 -C 5烷基,C 2 -C 5烯基或C 2 -C 6炔基,R 9为氢,甲基或乙基,R 10为 氢,C1-C4烷基,C1-C4烷氧基,甲氧基甲基,氰基甲基,氰乙基,C3-C5链烯基或C3-C6炔基,Y是氧,硫,亚磺酰基或磺酰基桥,这些化合物与胺,碱金属碱或碱 地球 金属碱基或季铵碱基,具有良好的出芽前和出芽后选择性除草和生长调节性质。
    • 16. 发明授权
    • N-azidophenylsulfonyl-N'-triazinylureas
    • N-叠氮苯基磺酰基-N'-三嗪基脲
    • US4589912A
    • 1986-05-20
    • US763175
    • 1985-08-07
    • Rudolph C. ThummelWerner Fory
    • Rudolph C. ThummelWerner Fory
    • C07D251/16A01N47/36C07D239/47C07D239/52C07D521/00C07D251/18A01N43/70C07D251/46C07D251/52
    • C07D521/00A01N47/36
    • The invention relates to N-azidophenylsulfonyl-N'-pyrimidinyl- and -N'-triazinylureas of the general formula ##STR1## wherein E is nitrogen or the methine bridge,R.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl or C.sub.2 -C.sub.5 alkoxyalkoxy,R.sub.2 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy,R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkoxy, C.sub.2 -C.sub.5 alkoxyalkoxy or --NR.sub.4 R.sub.5, whereinR.sub.4 is hydrogen or methyl andR.sub.5 is hydrogen, methyl, ethyl or methoxyand to the salts thereof with amines, alkali metal hydroxides and alkaline earth metal hydroxides or with quaternary ammonium bases. These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.
    • 本发明涉及通式为“IMAGE”的N-叠氮苯基磺酰基-N'-嘧啶基和-N'-三嗪基脲,其中E为氮或次甲基桥,R1为氢,卤素,硝基,C1-C4烷基,C1-C4卤代烷基 ,C1-C4烷氧基,C1-C4卤代烷氧基,C1-C4烷氧基羰基,C1-C4烷硫基,C1-C4烷基亚磺酰基,C1-C4烷基磺酰基或C2-C5烷氧基烷氧基,R2是C1-C3烷基,C1-C3烷氧基或C1-C3卤代烷氧基,R3是氢, C 3烷基,C 1 -C 3卤代烷基,C 1 -C 3烷氧基,C 1 -C 3卤代烷氧基,C 2 -C 5烷氧基烷氧基或-NR 4 R 5,其中R 4是氢或甲基,R 5是氢,甲基,乙基或甲氧基,其盐与胺,碱金属氢氧化物和 碱土金属氢氧化物或季铵碱。 这些化合物具有良好的芽前和芽后选择性除草和生长调节性质。
    • 19. 发明授权
    • N-Phenylsulfonyl-N-triazinylureas
    • N-苯基磺酰基-N-三嗪基脲
    • US4443243A
    • 1984-04-17
    • US396959
    • 1982-07-09
    • Werner ForyKarl GassWilly MeyerRolf Schurter
    • Werner ForyKarl GassWilly MeyerRolf Schurter
    • A01N47/24A01N47/08A01N47/22A01N47/36C07C303/36C07C311/16C07C311/53C07C323/67C07D239/42C07D239/46C07D239/47C07D239/48C07D239/52C07D239/56C07D251/16C07D251/22C07D251/40C07D251/46C07D251/52C07D521/00C07D251/44A01N43/66C07D251/42
    • C07C311/65A01N47/36C07D239/47C07D239/48C07D521/00
    • N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.
    • 具有通式(I)的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后 芽后选择性,除草和生长调节性质。 该式中的符号如下:A是C 3 -C 6炔基,E是次甲基或氮,X是氧,硫或亚磺酰基或磺酰基桥,Z是氧或硫,m是第一个 或两个,R 1是氢,卤素,C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5,R 2是氢,卤素,C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5,-COOR 6,-NO 2或-CO-NR 7 -R 8,R 3和R 4彼此独立地为氢,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷基,C 1 -C 4卤代烷氧基,卤素或至多4个碳原子的烷氧基烷基,R 5和R 6各自为C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 2 -C 6炔基,R 7和R 8 各自独立地为氢,C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 2 -C 6 - 炔基,Y为氧,硫或亚磺酰基或磺酰基桥。