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    • 1. 发明授权
    • N-Phenylsulfonyl-N-triazinylureas
    • N-苯基磺酰基-N-三嗪基脲
    • US4443243A
    • 1984-04-17
    • US396959
    • 1982-07-09
    • Werner ForyKarl GassWilly MeyerRolf Schurter
    • Werner ForyKarl GassWilly MeyerRolf Schurter
    • A01N47/24A01N47/08A01N47/22A01N47/36C07C303/36C07C311/16C07C311/53C07C323/67C07D239/42C07D239/46C07D239/47C07D239/48C07D239/52C07D239/56C07D251/16C07D251/22C07D251/40C07D251/46C07D251/52C07D521/00C07D251/44A01N43/66C07D251/42
    • C07C311/65A01N47/36C07D239/47C07D239/48C07D521/00
    • N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.
    • 具有通式(I)的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后 芽后选择性,除草和生长调节性质。 该式中的符号如下:A是C 3 -C 6炔基,E是次甲基或氮,X是氧,硫或亚磺酰基或磺酰基桥,Z是氧或硫,m是第一个 或两个,R 1是氢,卤素,C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5,R 2是氢,卤素,C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5,-COOR 6,-NO 2或-CO-NR 7 -R 8,R 3和R 4彼此独立地为氢,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷基,C 1 -C 4卤代烷氧基,卤素或至多4个碳原子的烷氧基烷基,R 5和R 6各自为C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 2 -C 6炔基,R 7和R 8 各自独立地为氢,C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 2 -C 6 - 炔基,Y为氧,硫或亚磺酰基或磺酰基桥。
    • 2. 发明授权
    • N-Phenylsulfonyl-N'-pyrimidinylureas
    • N-苯基磺酰基-N'-嘧啶基脲
    • US4523944A
    • 1985-06-18
    • US571985
    • 1984-01-19
    • Werner ForyKarl GassWilly MeyerRolf Schurter
    • Werner ForyKarl GassWilly MeyerRolf Schurter
    • A01N43/54A01N47/36C07D239/42C07D239/48C07D251/22C07D521/00
    • C07D239/48A01N47/36C07C317/00C07D521/00
    • N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.
    • 具有通式(I)的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后 芽后选择性,除草和生长调节性质。 该式中的符号如下:A是C 3 -C 6炔基,E是次甲基或氮,X是氧,硫或亚磺酰基或磺酰基桥,Z是氧或硫,m是第一个 或两个,R 1是氢,卤素,C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5,R 2是氢,卤素,C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5,-COOR 6,-NO 2或-CO-NR 7 -R 8,R 3和R 4彼此独立地为氢,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷基,C 1 -C 4卤代烷氧基,卤素或至多4个碳原子的烷氧基烷基,R 5和R 6各自为C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 2 -C 6炔基,R 7和R 8 各自独立地为氢,C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 2 -C 6 - 炔基,Y为氧,硫或亚磺酰基或磺酰基桥。
    • 3. 发明授权
    • N-Phenylsulfonamides
    • N-苯基磺酰胺
    • US4565887A
    • 1986-01-21
    • US571986
    • 1984-01-19
    • Werner ForyKarl GassWilly MeyerRolf Schurter
    • Werner ForyKarl GassWilly MeyerRolf Schurter
    • A01N47/24A01N47/08A01N47/22A01N47/36C07C303/36C07C311/16C07C311/53C07C323/67C07D239/42C07D239/46C07D239/47C07D239/48C07D239/52C07D239/56C07D251/16C07D251/22C07D251/40C07D251/46C07D251/52C07D521/00C07C143/78C07C149/447
    • C07C311/65A01N47/36C07D239/47C07D239/48C07D521/00
    • N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.
    • 具有通式(I)的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后 芽后选择性,除草和生长调节性质。 该式中的符号如下:A是C 3 -C 6炔基,E是次甲基或氮,X是氧,硫或亚磺酰基或磺酰基桥,Z是氧或硫,m是第一个 或两个,R 1是氢,卤素,C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5,R 2是氢,卤素,C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5,-COOR 6,-NO 2或-CO-NR 7 -R 8,R 3和R 4彼此独立地为氢,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷基,C 1 -C 4卤代烷氧基,卤素或至多4个碳原子的烷氧基烷基,R 5和R 6各自为C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 2 -C 6炔基,R 7和R 8 各自独立地为氢,C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 2 -C 6 - 炔基,Y为氧,硫或亚磺酰基或磺酰基桥。
    • 4. 发明授权
    • N-Phenylsulfonylcarbamates
    • N-苯基磺酰基氨基甲酸酯
    • US4487951A
    • 1984-12-11
    • US571976
    • 1984-01-19
    • Werner F/o/ ryKarl GassWilly MeyerRolf Schurter
    • Werner F/o/ ryKarl GassWilly MeyerRolf Schurter
    • A01N47/24A01N47/08A01N47/22A01N47/36C07C303/36C07C311/16C07C311/53C07C323/67C07D239/42C07D239/46C07D239/47C07D239/48C07D239/52C07D239/56C07D251/16C07D251/22C07D251/40C07D251/46C07D251/52C07D521/00C07C143/83
    • C07C311/65A01N47/36C07D239/47C07D239/48C07D521/00
    • N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.
    • 具有通式(I)的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后 芽后选择性,除草和生长调节性质。 该式中的符号如下:A是C 3 -C 6炔基,E是次甲基或氮,X是氧,硫或亚磺酰基或磺酰基桥,Z是氧或硫,m是第一个 或两个,R 1是氢,卤素,C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5,R 2是氢,卤素,C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5,-COOR 6,-NO 2或-CO-NR 7 -R 8,R 3和R 4彼此独立地为氢,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷基,C 1 -C 4卤代烷氧基,卤素或至多4个碳原子的烷氧基烷基,R 5和R 6各自为C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 2 -C 6炔基,R 7和R 8独立地为 各自为氢,C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 2 -C 6 - 炔基,Y为氧,硫或亚磺酰基或磺酰基桥。
    • 7. 发明授权
    • N-Heterocyclosulfonyl-N'-pyrimidinylureas and
N-heterocyclosulfonyl-N'-triazinylureas
    • US4549898A
    • 1985-10-29
    • US501459
    • 1983-06-06
    • Beat BohnerWerner ForyKarl GassWilly Meyer
    • Beat BohnerWerner ForyKarl GassWilly Meyer
    • A01N47/36C07D401/12C07D403/12C07D407/12C07D409/12C07D521/00
    • C07D521/00A01N47/36
    • N-heterocyclosulfonyl-N'-pyrimidinylureas and N-heterocyclosulfonyl-N'-triazinylureas of the general formula I ##STR1## wherein X is oxygen, sulfur, ##STR2## Y is oxygen or sulfur, Z is oxygen or sulfur,E is nitrogen or --CH.dbd.,R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxy, halogen, C.sub.1 -C.sub.4 alkylthio, --NR.sub.6 R.sub.7 or alkoxyalkyl containing not more than 4 carbon atoms,R.sub.2 is hydrogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, halogen, nitro, C.sub.1 -C.sub.3 alkoxy, ##STR3## --SO.sub.2 --NR.sub.6 R.sub.7, --SO.sub.n --C.sub.1 -C.sub.3 alkyl or --CO--R.sub.9,R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.3 alkyl, methoxy, nitro or trifluoromethyl,R.sub.4 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 cyanoalkyl, C.sub.3 14 C.sub.6 cycloalkyl, benzyl, --CO--C.sub.1 -C.sub.4 alkoxy, --CO--NR.sub.6 R.sub.7 or --CO--C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.5 is hydrogen, nitro, fluorine, chlorine, bromine, methyl, trifluoromethyl, --SO.sub.n --C.sub.1 -C.sub.3 alkyl, --CO--C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.3 alkoxy,R.sub.6 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.4 cyanoalkyl, methoxy or ethoxy,R.sub.7 is hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.3 -C.sub.6 alkenyl, orR.sub.6 and R.sub.7, together with the nitrogen atom to which they are attached, form a 5- or 6-membered saturated heterocyclic ring which may contain an oxygen or a sulfur atom as ring member,R.sub.8 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.4 -Chd 7cycloalkylalkyl or alkoxyalkyl containing not more than 4 carbon atoms,R.sub.9 is C.sub.1 -C.sub.6 alkoxy, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 alkynyloxy, C.sub.2 -C.sub.6 haloalkoxy, C.sub.1 -C.sub.4 cyanoalkoxy, C.sub.1 -C.sub.6 alkylthio, C.sub.3 -C.sub.6 alkenylthio, C.sub.3 -C.sub.6 alkynylthio, C.sub.5 -C.sub.6 cycloalkoxy, C.sub.4 -C.sub.7 cycloalkylalkoxy, --NR.sub.6 R.sub.7 or alkoxyalkoxy containing not more than 6 carbon atoms,W is oxygen or .dbd.N--O--R.sub.10, wherein R.sub.10 is hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.3 -C.sub.6 alkenyl, andn is a value from 0 to 2and the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases, have good preemergence and postemergence selective herbicidal and growth regulating properties.
    • 9. 发明授权
    • N-phenylsulfonyl-N'-pyrimidinyl- and -N'-triazinylureas
    • N-苯基磺酰基-N'-嘧啶基和-N'-三嗪基脲
    • US4835311A
    • 1989-05-30
    • US141820
    • 1988-01-11
    • Karl GassWerner ForyWilly MeyerWerner Topfl
    • Karl GassWerner ForyWilly MeyerWerner Topfl
    • C07D251/16A01N47/36C07D211/22C07D213/30C07D213/64C07D213/643C07D239/42C07D251/46C07D251/52C07D301/14C07D303/22C07D307/12C07D309/06C07D317/22C07D333/16C07D401/12C07D405/12C07D409/12C07D521/00
    • C07D213/30C07D213/643C07D301/14C07D303/22C07D307/12C07D309/06C07D317/22C07D333/16C07D521/00
    • N-Phenylsulfonyl-N'-pyrimidinylureas and -N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms of C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl,m is 0 or 1,E is nitrogen or the methine group,X is oxygen, sulfur, --SO-- or --SO.sub.2 --, andQ is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.
    • 具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基脲和-N'-三嗪基脲以及这些化合物与胺,碱金属碱和碱土金属碱或季铵碱的盐具有良好的选择性除草和植物 应用芽前和芽后的生长调节性质。 式中R 1为氢,卤素,硝基,C 1 -C 4卤代烷基,C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 5烯基或C 1 -C 4烷氧基羰基,R 2为C 1 -C 3烷基或C 1 -C 3烷氧基,各自未被取代或被1至3个卤素 原子,R3是卤素,氢,-NR4R5,C1-C3烷基,未取代或被C1-C4烷氧基的1至3个卤素原子取代,或是未被取代或被甲氧基,乙氧基或1至3个卤素原子取代的C1-C3烷氧基, R4是氢或甲基,R5是氢,C1-C2烷基或甲氧基,A是C1-C4亚烷基或C2-C4亚烯基,各自未被取代或被C1-C4烷基取代,m是0或1,E是氮或次甲基,X 是氧,硫,-SO-或-SO 2 - ,Q是羟基,氰基或选自5-或6-元杂环和稠合同系物,胺,缩醛,酯,酮,苯基,磺酸的基团 酸和羧酸,该基团可以进一步被取代并具有官能结构。
    • 10. 发明授权
    • N-phenylsulfonyl-N'-triazinylureas
    • N-苯基磺酰基-N'-三嗪基脲
    • US4648899A
    • 1987-03-10
    • US855060
    • 1986-04-23
    • Karl GassWerner ForyWilly MeyerWerner Topfl
    • Karl GassWerner ForyWilly MeyerWerner Topfl
    • C07D251/16A01N47/36C07D211/22C07D213/30C07D213/64C07D213/643C07D239/42C07D251/46C07D251/52C07D301/14C07D303/22C07D307/12C07D309/06C07D317/22C07D333/16C07D401/12C07D405/12C07D409/12C07D521/00A01N43/70C07D251/42
    • C07D213/30C07D213/643C07D301/14C07D303/22C07D307/12C07D309/06C07D317/22C07D333/16C07D521/00
    • N-Phenylsulfonyl-N'-pyrimidinylureas and -N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl,m is 0 or 1,E is nitrogen or the methine group,X is oxygen, sulfur, --SO--, or --SO.sub.2 --, andQ is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.
    • 具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基脲和-N'-三嗪基脲和这些化合物与胺,碱金属碱和碱土金属碱或季铵碱的盐具有良好的选择性除草和植物 应用芽前和芽后的生长调节性质。 式中R 1为氢,卤素,硝基,C 1 -C 4卤代烷基,C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 5烯基或C 1 -C 4烷氧基羰基,R 2为C 1 -C 3烷基或C 1 -C 3烷氧基,各自未被取代或被1至3个卤素 原子,R 3是卤素,氢,-NR 4 R 5,未被取代或被1至3个卤素原子或C 1 -C 4烷氧基取代的C 1 -C 3烷基,或是未被取代或被甲氧基,乙氧基或1至3个卤素原子取代的C 1 -C 3烷氧基, R4是氢或甲基,R5是氢,C1-C2烷基或甲氧基,A是C1-C4亚烷基或C2-C4亚烯基,各自未被取代或被C1-C4烷基取代,m是0或1,E是氮或次甲基,X 是氧,硫,-SO-或-SO 2 - ,Q是羟基,氰基或选自5-或6-元杂环和稠合同系物,胺,缩醛,酯,酮,苯基, 磺酸和羧酸,该基团可进一步被取代并具有官能结构。