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1. 发明授权

US5135927A Microbicidal composition 失效
标题翻译：杀菌组合物
公开(公告)号：US5135927A
公开(公告)日：1992-08-04
申请号：US617702
申请日：1990-11-26
申请人： Werner Topfl , Robert Nyfeler , Werner Fory
发明人： Werner Topfl , Robert Nyfeler , Werner Fory
IPC分类号： A01N43/78 , C07D277/56 , C07D277/60 , C07D417/06 , C07D417/12 , C07D493/04 , C07F9/6539
CPC分类号： C07D277/60 , A01N43/78 , C07D277/56 , C07D417/06 , C07D417/12 , C07D493/04 , C07F9/6539
摘要： A microbicidal composition contains as active ingredient 2-chloro-4-trifluoromethylthiazol-5-carboxylic acid derivatives of the formula I ##STR1## R is an organic radical with up to 40 carbon atoms, which optionally contains nitrogen, oxygen or sulfur atoms and which can be transformed by hydrolosis or oxydation into the directly to the thiazol ring bound carboxyl rest.These compounds have good microbicidal activity and are used for the control and prevention of infestation of plants by phytophathogenic microorganismes.
摘要翻译：杀微生物组合物含有作为活性成分的式I的2-氯-4-三氟甲基噻唑-5-羧酸衍生物（I）R是具有至多40个碳原子的有机基团，其任选地含有氮，氧或硫原子，其可以通过水痘病毒或氧化反应直接转化成噻唑环结合的羧基。这些化合物具有良好的杀微生物活性，用于通过植物致病性微生物控制和预防植物侵染。

2. 发明授权

US4992434A Microbicidal composition 失效
标题翻译：杀菌组合物
公开(公告)号：US4992434A
公开(公告)日：1991-02-12
申请号：US336166
申请日：1989-04-11
申请人： Werner Topfl , Robert Nyfeler , Werner Fory
发明人： Werner Topfl , Robert Nyfeler , Werner Fory
IPC分类号： A01N43/78 , C07D277/56 , C07D277/60 , C07D417/06 , C07D417/12 , C07D493/04 , C07F9/6539
CPC分类号： C07D277/60 , A01N43/78 , C07D277/56 , C07D417/06 , C07D417/12 , C07D493/04 , C07F9/6539
摘要： A microbicidal compostion contains as active ingredient 2-chloro-4-trifluoromethylthiazol-5-carbonic acid derivatives of the formula I ##STR1## R is organic radical with up to 40 carbon atoms, which optionally contains nitrogen, oxygen or sulfur atoms and which can be transformed by hydrolosis or oxydation into the directly to the thiazol ring bound carboxyl rest. These compounds have good microbicidal activity and are used for the control and prevention of infestation of plants by phytophathogenic microorganisms.
摘要翻译：杀微生物组合物含有作为活性成分的式I的2-氯-4-三氟甲基噻唑-5-碳酸衍生物（I）R是具有多达40个碳原子的有机基团，其任选地含有氮，氧或硫原子并且其可以通过水痘病毒或氧化反应直接转化成噻唑环结合的羧基。这些化合物具有良好的杀菌活性，用于通过植物致病微生物控制和预防植物侵染。

3. 发明授权

US4518776A Process for producing sulfonylureas 失效
标题翻译：制备磺酰脲类的方法
公开(公告)号：US4518776A
公开(公告)日：1985-05-21
申请号：US511830
申请日：1983-07-08
申请人： Willy Meyer , Werner Fory , Werner Topfl
发明人： Willy Meyer , Werner Fory , Werner Topfl
IPC分类号： C07D251/16 , A01N47/36 , C07C67/00 , C07C301/00 , C07C303/36 , C07C311/53 , C07C325/00 , C07C333/12 , C07D239/42 , C07D239/47 , C07D333/38 , C07D521/00 , C07D251/46 , C07D239/69 , C07D251/18 , C07D401/12
CPC分类号： C07D521/00 , C07D333/38
摘要： There is described a process for producing sulfonylureas of the formula ##STR1## wherein G is an unsubstituted or substituted furanyl, thienyl, pyrrolyl, pyridinyl or phenyl radical,X is alkyl, haloalkyl, alkoxy, alkylthio, halogen, haloalkoxy, alkylamino or dialkylamino,Y is alkyl, alkoxy or haloalkoxy,Z is a nitrogen atom or the methyne group --CH.dbd..This novel process comprises reacting a sulfonamide of the formulaG--SO.sub.2 --NH.sub.2,in the presence of a base, with a chloroformic acid ester of the formulaCl--CO--Q--T,or a sulfonyl chloride of the formulaG--SO.sub.2 Cl,in the presence of a base, with a urethane of the formulaH.sub.2 N--CO--Q--T;and converting the formed carbamate of the formulaG--SO.sub.2 --NH--CO--Q--Tby reaction with an amine of the formula ##STR2## into the sulfonylurea of the above formula. There is also described novel sulfonylcarbamates of the above formula as intermediates.
摘要翻译：描述了一种制备式IMA的磺酰脲的方法，其中G是未取代或取代的呋喃基，噻吩基，吡咯基，吡啶基或苯基，X是烷基，卤代烷基，烷氧基，烷硫基，卤素，卤代烷氧基，烷基氨基或二烷基氨基， Y是烷基，烷氧基或卤代烷氧基，Z是氮原子或甲炔基-CH =。该新方法包括使式G-SO 2 -NH 2的磺酰胺在碱的存在下与式Cl-CO-QT的氯甲酸酯或式G-SO 2 Cl的磺酰氯反应，碱的存在与式H2N-CO-QT的氨基甲酸酯反应; 并且通过与下式的磺酰脲反应将式G-SO 2 -NH-CO-Q-T的所形成的氨基甲酸酯转化为式（I）所示的磺酰脲。还描述了上述式的新型磺酰基氨基甲酸酯作为中间体。

4. 发明授权

US4739068A O-substituted-phenylsulfonamides 失效
标题翻译： O-取代苯基磺酰胺
公开(公告)号：US4739068A
公开(公告)日：1988-04-19
申请号：US887762
申请日：1986-07-21
申请人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
发明人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
IPC分类号： C07D251/16 , A01N47/36 , C07D211/22 , C07D213/30 , C07D213/64 , C07D213/643 , C07D239/42 , C07D251/46 , C07D251/52 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D401/12 , C07D405/12 , C07D409/12 , C07D521/00 , C07D213/63 , C07D319/06
CPC分类号： C07D213/30 , C07D213/643 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinylureas and --N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl,m is 0 or 1,E is nitrogen or the methine group,X is oxygen, sulfur, --SO-- or --SO.sub.2 --, andQ is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.
摘要翻译：具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基脲和-N'-三嗪基脲和这些化合物与胺，碱金属碱和碱土金属碱或季铵碱的盐具有良好的选择性除草和植物应用芽前和芽后的生长调节性质。式中R 1为氢，卤素，硝基，C 1 -C 4卤代烷基，C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 5烯基或C 1 -C 4烷氧基羰基，R 2为C 1 -C 3烷基或C 1 -C 3烷氧基，各自未被取代或被1至3个卤素原子，R 3是卤素，氢，-NR 4 R 5，未被取代或被1至3个卤素原子或C 1 -C 4烷氧基取代的C 1 -C 3烷基，或是未被取代或被甲氧基，乙氧基或1至3个卤素原子取代的C 1 -C 3烷氧基， R4是氢或甲基，R5是氢，C1-C2烷基或甲氧基，A是C1-C4亚烷基或C2-C4亚烯基，各自是未取代的或被C1-C4烷基取代，m是0或1，E是氮或次甲基， X是氧，硫，-SO-或-SO 2 - ，Q是羟基，氰基或选自5-或6-元杂环和稠合同系物，胺，缩醛，酯，酮，苯基，磺酸和羧酸，该基团可进一步被取代并具有官能结构。

5. 发明授权

US4726836A N-phenylsulfonyl-N'-pyrimidinylureas 失效
标题翻译： N-苯基磺酰基-N'-嘧啶基脲
公开(公告)号：US4726836A
公开(公告)日：1988-02-23
申请号：US887759
申请日：1986-07-21
申请人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
发明人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
IPC分类号： C07D251/16 , A01N47/36 , C07D211/22 , C07D213/30 , C07D213/64 , C07D213/643 , C07D239/42 , C07D251/46 , C07D251/52 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D401/12 , C07D405/12 , C07D409/12 , C07D521/00 , A01N43/54 , C07D239/69
CPC分类号： C07D213/30 , C07D213/643 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinylureas and -N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.2 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl,m is 0 or 1,E is nitrogen or the methine group,X is oxygen, sulfur, --SO-- or --SO.sub.2 --, andQ is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.
摘要翻译：具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基脲和-N'-三嗪基脲和这些化合物与胺，碱金属碱和碱土金属碱或季铵碱的盐具有良好的选择性除草和植物应用芽前和芽后的生长调节性质。式中R 1为氢，卤素，硝基，C 1 -C 4卤代烷基，C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 5链烯基或C 1 -C 4烷氧基羰基，R 2为C 1 -C 2烷基或C 1 -C 3烷氧基，各自未被取代或被1至3个卤素原子，R 3是卤素，氢，-NR 4 R 5，未被取代或被1至3个卤素原子或C 1 -C 4烷氧基取代的C 1 -C 3烷基，或是未被取代或被甲氧基，乙氧基或1至3个卤素原子取代的C 1 -C 3烷氧基， R4是氢或甲基，R5是氢，C1-C2烷基或甲氧基，A是C1-C4亚烷基或C2-C4亚烯基，各自未被取代或被C1-C4烷基取代，m是0或1，E是氮或次甲基，X 是氧，硫，-SO-或-SO 2 - ，Q是羟基，氰基或选自5-或6-元杂环和稠合同系物，胺，缩醛，酯，酮，苯基，磺酸的基团酸和羧酸，该基团可以进一步被取代并具有官能结构。

6. 发明授权

US4677212A Intermediate 1,2-benzoxathiin derivatives 失效
标题翻译：中间体1,2-苯并恶嗪衍生物
公开(公告)号：US4677212A
公开(公告)日：1987-06-30
申请号：US658003
申请日：1984-10-04
申请人： Josef Ehrenfreund , Werner Fory , Willy Meyer , Werner Topfl
发明人： Josef Ehrenfreund , Werner Fory , Willy Meyer , Werner Topfl
IPC分类号： A01N47/36 , C07D209/08 , C07D215/00 , C07D215/36 , C07D239/00 , C07D251/00 , C07D307/00 , C07D307/79 , C07D307/82 , C07D307/83 , C07D307/88 , C07D311/00 , C07D311/18 , C07D311/20 , C07D311/22 , C07D311/58 , C07D311/70 , C07D311/76 , C07D317/00 , C07D317/46 , C07D317/62 , C07D319/00 , C07D319/18 , C07D327/00 , C07D327/04 , C07D327/06 , C07D333/00 , C07D333/54 , C07D333/62 , C07D335/00 , C07D335/06 , C07D401/12 , C07D403/12 , C07D405/12 , C07D409/12 , C07D411/12 , C07D417/12 , C07D521/00
CPC分类号： C07D307/79 , A01N47/36 , C07D209/08 , C07D215/36 , C07D307/83 , C07D307/88 , C07D311/18 , C07D311/22 , C07D311/58 , C07D311/70 , C07D311/76 , C07D317/46 , C07D317/62 , C07D319/18 , C07D327/06 , C07D333/54 , C07D335/06 , C07D521/00
摘要： The invention relates to N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N-triazinylureas of the general formula ##STR1## wherein Q is selected from a radical ##STR2## Z is oxygen or sulfur, E is nitrogen or .dbd.CH--,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.3 alkoxy, andR.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.1 -C.sub.4 alkylthio, halogen, C.sub.2 -C.sub.5 alkoxyalkyl, C.sub.2 -C.sub.5 alkoxyalkoxy or --NR.sub.5 R.sub.6, wherein R.sub.5 and R.sub.6 are hydrogen or C.sub.1 -C.sub.4 alkyl,and to the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases. These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.
摘要翻译：本发明涉及通式为（I）的N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N-三嗪基脲，其中Q选自基团Z是氧或硫，E是氮或= CH-，R 2是氢，C 1 -C 4烷基或C 1 -C 3烷氧基，R 3和R 4各自独立地是氢，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4 卤代烷氧基，C 1 -C 4卤代烷硫基，C 1 -C 4烷硫基，卤素，C 2 -C 5烷氧基烷基，C 2 -C 5烷氧基烷氧基或-NR 5 R 6，其中R 5和R 6是氢或C 1 -C 4烷基，以及这些化合物与胺，碱金属碱或碱土金属碱或季铵碱。这些化合物具有良好的芽前和芽后选择性除草和生长调节性质。

7. 发明授权

US5342823A Sulfonylureas 失效
标题翻译：磺脲类
公开(公告)号：US5342823A
公开(公告)日：1994-08-30
申请号：US18603
申请日：1993-02-17
申请人： Rainer Kuhlmeyer , Werner Topfl , Werner Fory
发明人： Rainer Kuhlmeyer , Werner Topfl , Werner Fory
IPC分类号： A01N47/36 , C07D213/80 , C07D231/18 , C07D405/12 , C07D405/14 , C07D409/12 , C07D409/14 , C07D521/00 , F16N11/04 , F16N11/08 , C07D407/14 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36 , C07D405/12 , C07D409/12 , F16N11/04 , F16N11/08 , F16N2230/10
摘要： N-Arylsulfonyl-N'-pyrimidinyl-and N'-triazinylureas of formula I ##STR1## wherein Q is ##STR2## R is hydrogen or methyl; R.sub.1 is hydrogen, fluoro, chloro, C.sub.1 -C.sub.4 alkyl or methoxy;R.sub.2 is hydrogen, fluoro or chloro;R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are each independently of one another hydrogen or C.sub.1-C.sub.4 alkyl;R.sub.8, R.sub.9, R.sub.10, R.sub.11 and R.sub.12 are each independently of one another hydrogen or C.sub.1 -C.sub.4 alkyl;R.sub.13, R.sub.14, R.sub.15, R.sub.16 and R.sub.17 are each independently of one another hydrogen or C.sub.1 -C.sub.4 alkyl;Z is methyl or 2-pyridyl;E is methine or nitrogen;X is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.1 -C.sub.4 alkylthio,C.sub.2 -C.sub.5 alkoxyalkyl, C.sub.2 -C.sub.5 alkoxyalkoxy, C.sub.2 -C.sub.5 alkylthioalkyl or cyclopropyl;Y is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkylthio,C.sub.1 -C.sub.4 alkylthio, halogen, C.sub.2 -C.sub.5 alkoxyalkyl, C.sub.2 -C.sub.5 alkoxyalkoxy, amino, C.sub.1 -C.sub.3 alkylamino or di-(C.sub.1 -C.sub.3 alkyl)amino;and the salts of these compounds with amines, alkali metal or alkaline earth metal bases or with quaternary ammonium bases, have good pre-and postemergence selective herbicidal and growth regulating properties.
摘要翻译：（Q）（Q 3）（Q 3）（Q 3）R 3是氢或甲基; R 3是氢或甲基; R 3是氢或甲基。 R 1是氢，氟，氯，C 1 -C 4烷基或甲氧基; R2是氢，氟或氯; R3，R4，R5，R6和R7各自独立地为氢或C1-C4烷基; R8，R9，R10，R11和R12各自独立地为氢或C1-C4烷基; R 13，R 14，R 15，R 16和R 17各自独立地为氢或C 1 -C 4烷基; Z是甲基或2-吡啶基; E是次甲基或氮; X是C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4卤代烷硫基，C 1 -C 4烷硫基，C 2 -C 5烷氧基烷基，C 2 -C 5烷氧基烷氧基，C 2 -C 5烷硫基烷基或环丙基; Y是C1-C4烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4卤代烷基，C1-C4卤代烷硫基，C1-C4烷硫基，卤素，C2-C5烷氧基烷基，C2-C5烷氧基烷氧基，氨基，C1-C3烷基氨基或二 - （C1-C3烷基）氨基 ; 并且这些化合物与胺，碱金属或碱土金属碱或季铵碱的盐具有良好的芽前和芽后选择性除草和生长调节性质。

8. 发明授权

US4978383A N-phenylsulfonyl-N'-triazinylureas 失效
标题翻译： N-苯基磺酰基-N'-三嗪基脲
公开(公告)号：US4978383A
公开(公告)日：1990-12-18
申请号：US777502
申请日：1985-09-19
申请人： Erfinders K. Gass , Werner Fory , Willy Meyer , Werner Topfl
发明人： Erfinders K. Gass , Werner Fory , Willy Meyer , Werner Topfl
IPC分类号： C07D251/16 , A01N47/36 , C07D211/22 , C07D213/30 , C07D213/64 , C07D213/643 , C07D239/42 , C07D251/46 , C07D251/52 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D401/12 , C07D405/12 , C07D409/12 , C07D521/00
CPC分类号： C07D213/30 , C07D213/643 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D521/00
摘要： N-phenylsulfonyl-N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, andQ is cyano or --COB in which B is alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms; phenyl; phenyl substituted with cyano, nitro, halo, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, or haloalkyl of 1 to 3 carbon atoms; amino; alkylamino of 1 to 4 carbon atoms; or dialkylamino of 1 to 4 carbon atoms in each alkyl group.

9. 发明授权

US4835311A N-phenylsulfonyl-N'-pyrimidinyl- and -N'-triazinylureas 失效
标题翻译： N-苯基磺酰基-N'-嘧啶基和-N'-三嗪基脲
公开(公告)号：US4835311A
公开(公告)日：1989-05-30
申请号：US141820
申请日：1988-01-11
申请人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
发明人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
IPC分类号： C07D251/16 , A01N47/36 , C07D211/22 , C07D213/30 , C07D213/64 , C07D213/643 , C07D239/42 , C07D251/46 , C07D251/52 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D401/12 , C07D405/12 , C07D409/12 , C07D521/00
CPC分类号： C07D213/30 , C07D213/643 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinylureas and -N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms of C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl,m is 0 or 1,E is nitrogen or the methine group,X is oxygen, sulfur, --SO-- or --SO.sub.2 --, andQ is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.
摘要翻译：具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基脲和-N'-三嗪基脲以及这些化合物与胺，碱金属碱和碱土金属碱或季铵碱的盐具有良好的选择性除草和植物应用芽前和芽后的生长调节性质。式中R 1为氢，卤素，硝基，C 1 -C 4卤代烷基，C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 5烯基或C 1 -C 4烷氧基羰基，R 2为C 1 -C 3烷基或C 1 -C 3烷氧基，各自未被取代或被1至3个卤素原子，R3是卤素，氢，-NR4R5，C1-C3烷基，未取代或被C1-C4烷氧基的1至3个卤素原子取代，或是未被取代或被甲氧基，乙氧基或1至3个卤素原子取代的C1-C3烷氧基， R4是氢或甲基，R5是氢，C1-C2烷基或甲氧基，A是C1-C4亚烷基或C2-C4亚烯基，各自未被取代或被C1-C4烷基取代，m是0或1，E是氮或次甲基，X 是氧，硫，-SO-或-SO 2 - ，Q是羟基，氰基或选自5-或6-元杂环和稠合同系物，胺，缩醛，酯，酮，苯基，磺酸的基团酸和羧酸，该基团可以进一步被取代并具有官能结构。

10. 发明授权

US4648899A N-phenylsulfonyl-N'-triazinylureas 失效
标题翻译： N-苯基磺酰基-N'-三嗪基脲
公开(公告)号：US4648899A
公开(公告)日：1987-03-10
申请号：US855060
申请日：1986-04-23
申请人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
发明人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
IPC分类号： C07D251/16 , A01N47/36 , C07D211/22 , C07D213/30 , C07D213/64 , C07D213/643 , C07D239/42 , C07D251/46 , C07D251/52 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D401/12 , C07D405/12 , C07D409/12 , C07D521/00 , A01N43/70 , C07D251/42
CPC分类号： C07D213/30 , C07D213/643 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinylureas and -N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl,m is 0 or 1,E is nitrogen or the methine group,X is oxygen, sulfur, --SO--, or --SO.sub.2 --, andQ is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.
摘要翻译：具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基脲和-N'-三嗪基脲和这些化合物与胺，碱金属碱和碱土金属碱或季铵碱的盐具有良好的选择性除草和植物应用芽前和芽后的生长调节性质。式中R 1为氢，卤素，硝基，C 1 -C 4卤代烷基，C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 5烯基或C 1 -C 4烷氧基羰基，R 2为C 1 -C 3烷基或C 1 -C 3烷氧基，各自未被取代或被1至3个卤素原子，R 3是卤素，氢，-NR 4 R 5，未被取代或被1至3个卤素原子或C 1 -C 4烷氧基取代的C 1 -C 3烷基，或是未被取代或被甲氧基，乙氧基或1至3个卤素原子取代的C 1 -C 3烷氧基， R4是氢或甲基，R5是氢，C1-C2烷基或甲氧基，A是C1-C4亚烷基或C2-C4亚烯基，各自未被取代或被C1-C4烷基取代，m是0或1，E是氮或次甲基，X 是氧，硫，-SO-或-SO 2 - ，Q是羟基，氰基或选自5-或6-元杂环和稠合同系物，胺，缩醛，酯，酮，苯基，磺酸和羧酸，该基团可进一步被取代并具有官能结构。

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