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    • 1. 发明授权
    • N-azidophenylsulfonyl-N'-triazinylureas
    • N-叠氮苯基磺酰基-N'-三嗪基脲
    • US4589912A
    • 1986-05-20
    • US763175
    • 1985-08-07
    • Rudolph C. ThummelWerner Fory
    • Rudolph C. ThummelWerner Fory
    • C07D251/16A01N47/36C07D239/47C07D239/52C07D521/00C07D251/18A01N43/70C07D251/46C07D251/52
    • C07D521/00A01N47/36
    • The invention relates to N-azidophenylsulfonyl-N'-pyrimidinyl- and -N'-triazinylureas of the general formula ##STR1## wherein E is nitrogen or the methine bridge,R.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl or C.sub.2 -C.sub.5 alkoxyalkoxy,R.sub.2 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy,R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkoxy, C.sub.2 -C.sub.5 alkoxyalkoxy or --NR.sub.4 R.sub.5, whereinR.sub.4 is hydrogen or methyl andR.sub.5 is hydrogen, methyl, ethyl or methoxyand to the salts thereof with amines, alkali metal hydroxides and alkaline earth metal hydroxides or with quaternary ammonium bases. These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.
    • 本发明涉及通式为“IMAGE”的N-叠氮苯基磺酰基-N'-嘧啶基和-N'-三嗪基脲,其中E为氮或次甲基桥,R1为氢,卤素,硝基,C1-C4烷基,C1-C4卤代烷基 ,C1-C4烷氧基,C1-C4卤代烷氧基,C1-C4烷氧基羰基,C1-C4烷硫基,C1-C4烷基亚磺酰基,C1-C4烷基磺酰基或C2-C5烷氧基烷氧基,R2是C1-C3烷基,C1-C3烷氧基或C1-C3卤代烷氧基,R3是氢, C 3烷基,C 1 -C 3卤代烷基,C 1 -C 3烷氧基,C 1 -C 3卤代烷氧基,C 2 -C 5烷氧基烷氧基或-NR 4 R 5,其中R 4是氢或甲基,R 5是氢,甲基,乙基或甲氧基,其盐与胺,碱金属氢氧化物和 碱土金属氢氧化物或季铵碱。 这些化合物具有良好的芽前和芽后选择性除草和生长调节性质。
    • 2. 发明授权
    • N-Azidophenylsulfonyl-N'-pyrimidinyl ureas
    • N-叠氮苯基磺酰基-N'-嘧啶基脲
    • US4555262A
    • 1985-11-26
    • US525365
    • 1983-08-22
    • Rudolph C. ThummelWerner Fory
    • Rudolph C. ThummelWerner Fory
    • C07D251/16A01N47/36C07D239/47C07D239/52C07D521/00C07D239/46
    • C07D521/00A01N47/36
    • The invention relates to N-azidophenylsulfonyl-N'-pyrimidinyl- and -N'-triazinylureas of the general formula ##STR1## wherein E is nitrogen or the methine bridge,R.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl or C.sub.2 -C.sub.5 alkoxyalkoxy,R.sub.2 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy,R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkoxy, C.sub.2 -C.sub.5 alkoxyalkoxy or --NR.sub.4 R.sub.5, whereinR.sub.4 is hydrogen or methyl andR.sub.5 is hydrogen, methyl, ethyl or methoxyand to the salts thereof with amines, alkali metal hydroxides and alkaline earth metal hydroxides or with quaternary ammonium bases. These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.
    • 本发明涉及通式为“IMAGE”的N-叠氮苯基磺酰基-N'-嘧啶基和-N'-三嗪基脲,其中E为氮或次甲基桥,R1为氢,卤素,硝基,C1-C4烷基,C1-C4卤代烷基 ,C1-C4烷氧基,C1-C4卤代烷氧基,C1-C4烷氧基羰基,C1-C4烷硫基,C1-C4烷基亚磺酰基,C1-C4烷基磺酰基或C2-C5烷氧基烷氧基,R2是C1-C3烷基,C1-C3烷氧基或C1-C3卤代烷氧基,R3是氢, C 3烷基,C 1 -C 3卤代烷基,C 1 -C 3烷氧基,C 1 -C 3卤代烷氧基,C 2 -C 5烷氧基烷氧基或-NR 4 R 5,其中R 4是氢或甲基,R 5是氢,甲基,乙基或甲氧基,其盐与胺,碱金属氢氧化物和 碱土金属氢氧化物或季铵碱。 这些化合物具有良好的芽前和芽后选择性除草和生长调节性质。
    • 3. 发明授权
    • Sulfonylureas
    • SULFONYLUREAS
    • US5221315A
    • 1993-06-22
    • US705459
    • 1991-05-24
    • Werner ForyRolf Schurter
    • Werner ForyRolf Schurter
    • A01N47/36C07D213/71C07D213/73C07D213/74C07D401/12C07D521/00
    • C07D213/73A01N47/36C07D213/74C07D521/00
    • N-Pyridinesulfonyl-N'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen, C.sub.1 -C.sub.8 alkyl or C.sub.3 -C.sub.8 cycloalkyl; C.sub.2 -C.sub.8 alkyl or C.sub.3 -C.sub.8 cycloalkyl substituted by halogen; C.sub.1 -C.sub.8 alkyl or C.sub.3 -C.sub.8 cycloalkyl substituted by --NR.sub.5 R.sub.6, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkyl-S(O).sub.n --; C.sub.1 -C.sub.4 alkyl or C.sub.3 -C.sub.6 cycloalkyl substituted by C.sub.2 -C.sub.4 alkenyl, C.sub.5 -C.sub.6 cycloalkenyl, C.sub.2 -C.sub.6 alkynyl or C.sub.4 -C.sub.8 alkadienyl; or C.sub.2 -C.sub.4 alkenyl, C.sub.5 -C.sub.6 cycloalkenyl and C.sub.4 -C.sub.8 alkadienyl substituted by halogen; or R.sub.1 and R.sub.2 together are a 4-5-membered C.sub.4 -C.sub.10 alkylene chain which can be interrupted by oxygen, sulfur or N--R.sub.7 ; R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or C.sub.1 - C.sub.4 alkylthio; C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylthio substituted by halogen; R.sub.4, R.sub.5, R.sub.6 and R.sub.7 independently of one another are hydrogen or C.sub.1 -C.sub.4 alkyl; n is 0, 1 or 2; X is C.sub.1 -C.sub.3 alkyl, or C.sub.1 -C.sub.3 alkyl which is substituted by 1 to 3 halogens; C.sub.1 -C.sub.3 alkoxy, or C.sub.1 -C.sub.3 alkoxy which is substituted by 1 to 3 halogens; Y is halogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkyl which is substituted by 1 to 3 halogens; C.sub.1 -C.sub.3 alkoxy, or C.sub.1 -C.sub.3 alkoxy which is substituted by 1 to 3 halogens; cyclopropyl, methylamino or dimethylamino; and E is nitrogen or the methine group, and the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases have good selective herbicidal and growth-regulating properties when used pre- and post-emergence.
    • 其中R 1和R 2彼此独立地是氢,C 1 -C 8烷基或C 3 -C 8环烷基的式I(I)的N-吡啶磺酰基-N'-嘧啶基 - 和 - 三嗪基脲; C 2 -C 8烷基或被卤素取代的C 3 -C 8环烷基; 被-NR 5 R 6,C 1 -C 4烷氧基或C 1 -C 4烷基-S(O)n取代的C 1 -C 8烷基或C 3 -C 8环烷基; 被C 2 -C 4烯基,C 5 -C 6环烯基,C 2 -C 6炔基或C 4 -C 8链烯基取代的C 1 -C 4烷基或C 3 -C 6环烷基; 或C 2 -C 4烯基,C 5 -C 6环烯基和被卤素取代的C 4 -C 8链二烯基; 或R 1和R 2一起是可被氧,硫或N-R 7中断的4-5元C 4 -C 10亚烷基链; R 3是氢,卤素,C 1 -C 4烷基,C 1 -C 4烷氧基或C 1 -C 4烷硫基; C 1 -C 4烷基,C 1 -C 4烷氧基或被卤素取代的C 1 -C 4烷硫基; R 4,R 5,R 6和R 7彼此独立地是氢或C 1 -C 4烷基; n为0,1或2; X是C 1 -C 3烷基或被1至3个卤素取代的C 1 -C 3烷基; C1-C3烷氧基或被1〜3个卤素取代的C1-C3烷氧基; Y为卤素,C1-C3烷基或被1〜3个卤素取代的C1-C3烷基; C1-C3烷氧基或被1〜3个卤素取代的C1-C3烷氧基; 环丙基,甲基氨基或二甲基氨基; E是氮或次甲基,这些化合物与胺,碱金属碱或碱土金属碱或季铵碱的盐在出苗前和出苗后使用时具有很好的选择性除草和生长调节特性。
    • 8. 发明授权
    • N-phenylsulfonyl-N'-triazinylureas
    • N-苯基磺酰基-N'-三嗪基脲
    • US4594097A
    • 1986-06-10
    • US745749
    • 1985-06-17
    • Rolf SchurterWerner ForyWilly Meyer
    • Rolf SchurterWerner ForyWilly Meyer
    • C07D251/16A01N47/36C07C67/00C07C301/00C07D239/42C07D239/47C07D239/48C07D239/52C07D239/56C07D251/42C07D401/12C07D409/12C07D521/00C07D251/50A01N43/70C07D251/52
    • C07D521/00A01N47/36
    • N-Phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'-triazinylureas of the general formula I ##STR1## wherein A is a radical of the formula --C.tbd.C--R,m is 1 or 2,Z is oxygen or sulfur,R is hydrogen; unsubstituted or substituted, branched or unbranched C.sub.1 -C.sub.9 alkyl; unsubstituted or substituted C.sub.3 -C.sub.9 cycloalkyl; unsubstituted or substituted phenyl; or an unsubstituted or substituted 5- or 6-membered aromatic heterocyclic ring,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or a radical --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, halogen, C.sub.2 -C.sub.5 alkoxyalkyl, --NR.sub.9 R.sub.10 or --O--CH.sub.2 --CH.sub.2 --NR.sub.9 R.sub.10,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl, C.sub.1 -C.sub.5 haloalkyl, C.sub.2 -C.sub.5 haloalkenyl or C.sub.2 -C.sub.6 alkoxyalkyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl,R.sub.9 is hydrogen, methyl or ethyl,R.sub.10 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, methoxymethyl, cyanomethyl, cyanoethyl, C.sub.3 -C.sub.5 alkenyl or C.sub.3 -C.sub.6 alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridgeand the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases, have good preemergence and postemergence selective herbicidal and growth regulating properties.
    • N-苯基磺酰基-N'-嘧啶基脲和通式I的N-苯基磺酰基-N'-三嗪基脲其中A是式-CB 3 CR的基团,m是1或2,Z是氧 或硫,R是氢; 未取代或取代的支链或非支链C 1 -C 9烷基; 未取代或取代的C 3 -C 9环烷基; 未取代或取代的苯基; 或未取代或取代的5元或6元芳族杂环,R 1为氢,卤素,C 1 -C 5烷基,C 2 -C 5烯基或自由基-Y-R 5,R 2为氢,卤素,C 1 -C 5烷基,C 2 -C 5链烯基, C1-C4卤代烷基或自由基-Y-R5,-COOR6,-NO2或-CO-NR7-R8,R3和R4各自独立地为氢,C1-C4烷基,C1-C4烷氧基,C1-C4烷硫基, C1-C4卤代烷基,C1-C4卤代烷氧基,C1-C4卤代烷硫基,卤素,C2-C5烷氧基烷基,-NR9R10或-O-CH2-CH2-NR9R10,R5和R6各自独立地为C1-C5烷基,C2-C5链烯基或C2 C 1-6炔基,C 1 -C 5卤代烷基,C 2 -C 5卤代烯基或C 2 -C 6烷氧基烷基,R 7和R 8各自独立地为氢,C 1 -C 5烷基,C 2 -C 5烯基或C 2 -C 6炔基,R 9为氢,甲基或乙基,R 10为 氢,C1-C4烷基,C1-C4烷氧基,甲氧基甲基,氰基甲基,氰乙基,C3-C5链烯基或C3-C6炔基,Y是氧,硫,亚磺酰基或磺酰基桥,这些化合物与胺,碱金属碱或碱 地球 金属碱基或季铵碱基,具有良好的出芽前和出芽后选择性除草和生长调节性质。