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11. 发明申请

WO2018219762A1 IMPROVED ADHESIVE POLYMER COMPOSITION 审中-公开
公开(公告)号：WO2018219762A1
公开(公告)日：2018-12-06
申请号：PCT/EP2018/063599
申请日：2018-05-24
申请人： BOREALIS AG
发明人： SUNDHOLM, Tua , HARTIKAINEN, Juha , PURMONEN, Jouni , TUPE, Ravindra , KUOSA, Juha , NIKIFOROVA, Liubov
IPC分类号： C09J151/06 , F16L9/12 , F16L13/02 , B32B27/30
摘要： An adhesive polymer composition comprising a non-elastomeric copolymer of ethylene and one or more comonomers having 3 to 10 carbon atoms, and an elastomer is disclosed herein. The non-elastomeric copolymer is present in an amount of 60 to 95 % by weight, based on the adhesive polymer composition, has a weight average molecular weight Mw of from 50 000 to 80 000 g/mol, molecular weight distribution Mw/Mn of 2.0 to 5.5, density of from 0.925 to 0.945 g/cm 3 , and at most 0.1 vinyl groups/ 1000 carbon atoms. The non- elastomeric copolymer or the non-elastomeric copolymer and the elastomer have been grafted with an acid grafting agent.

12. 发明申请

WO2016207270A1 PROCESS FOR PRODUCING LLDPE RESINS 审中-公开
标题翻译：生产LLDPE树脂的方法
公开(公告)号：WO2016207270A1
公开(公告)日：2016-12-29
申请号：PCT/EP2016/064511
申请日：2016-06-23
申请人： BOREALIS AG
发明人： ALBUNIA, Alexandra Romina , TUPE, Ravindra , SUMERIN, Victor , JAMIESON, John , AHO, Jani , VAHTERI, Markku , KELA, Jarmo , ECKMAYR, Renate
IPC分类号： C08F2/00 , C08L23/08
CPC分类号： C08F2/001 , C08L23/06 , C08L23/0815
摘要： The present invention is directed to a process for producing copolymers of ethylene and at least one alpha-olefin having from 4 to 10 carbon atoms in the presence of a solid Ziegler-Natta catalyst comprising of magnesium, titanium, halogen and an internal organic compound, the copolymer having a density of from 906 to 937 kg/m 3 and a melt flow rate MFR 21 measured at 190 °C under 21.6 kg load of from 3 to 150 g/10 min comprising the steps of (A) homopolymerising ethylene or copolymerising ethylene and a first alpha-olefin having from 4 to 10 carbon atoms in a first polymerisation stage in the presence of the polymerisation catalyst, hydrogen and optionally the first alpha-olefin wherein the molar ratio of hydrogen to ethylene in the fluid reaction mixture of the first polymerisation stage is from 200 to 50000 mol/kmol and the molar ratio of the first alpha-olefin to ethylene in the fluid reaction mixture of the first polymerisation stage is from 0 to 1500 mol/kmol, to produce a first homo- or copolymer of ethylene; (B) copolymerising ethylene and a second alpha-olefin having from 4 to 10 carbon atoms in a second polymerisation stage in the presence of the first homo- or copolymer of ethylene and the solid Ziegler-Natta catalyst to produce a polymer mixture comprising the first homo- or copolymer of ethylene and a second copolymer of ethylene, the polymer mixture having a density of from 906 to 937 kg/m 3 and a melt flow rate MFR 21 of from 3 to 150 g/10 min; (C) recovering the polymer mixture, characterised in that the polymerisation catalyst comprises an internal organic compound having the formula (I): wherein in the formula (I) R 1 to R 5 are the same or different and can be hydrogen, a linear or branched C1 to C8-alkyl group, or a C3-C8-alkylene group, or two or more of R 1 to R 5 can form a ring, and the two oxygen-containing rings are individually saturated or partially unsaturated or unsaturated.
摘要翻译：本发明涉及一种在含有镁，钛，卤素和内部有机化合物的固体齐格勒 - 纳塔催化剂存在下制备乙烯和至少一种具有4-10个碳原子的α-烯烃的共聚物的方法，共聚物的密度为906至937kg / m 3，熔体流动速率MFR21在190℃，21.6kg负载下测量为3至150g / 10min，包括以下步骤：（A）乙烯均聚或乙烯共聚，和在聚合催化剂存在下的第一聚合阶段中具有4-10个碳原子的第一个α-烯烃，氢和任选的第一个α-烯烃，其中第一次聚合的流体反应混合物中氢与乙烯的摩尔比阶段为200至50000mol / kmol，第一聚合阶段的流体反应混合物中第一个α-烯烃与乙烯的摩尔比为0至1500mol / kmol，以产生第一个h 乙烯或乙烯的共聚物; （B）在乙烯和固体齐格勒 - 纳塔催化剂的第一均聚物或共聚物的存在下，在第二聚合阶段中使乙烯和具有4至10个碳原子的第二α-烯烃共聚以制备包含第一乙烯的均聚物或共聚物和乙烯的第二共聚物，所述聚合物混合物的密度为906至937kg / m 3，熔体流动速率MFR 21为3至150g / 10min; （C）回收聚合物混合物，其特征在于聚合催化剂包含具有式（I）的内部有机化合物：其中在式（I）中，R 1至R 5相同或不同并且可以是氢，直链或支链 C1至C8-烷基或C3-C8-亚烷基，或两个或更多个R 1至R 5可以形成环，并且所述两个含氧环分别为饱和或部分不饱和或不饱和的。

13. 发明申请

WO2016198273A1 MULTIMODAL COPOLYMER OF ETHYLENE AND AT LEAST TWO ALPHA-OLEFIN COMONOMERS AND FINAL ARTICLES MADE THEREOF 审中-公开
标题翻译：乙二醇的多官能共聚物和至少两种α-烯烃共聚物及其最终文章
公开(公告)号：WO2016198273A1
公开(公告)日：2016-12-15
申请号：PCT/EP2016/062128
申请日：2016-05-30
申请人： BOREALIS AG
发明人： TUPE, Ravindra , JAMIESON, John , KELA, Jarmo , ALBUNIA, Alexandra, Romina , GODOY-LOPEZ, Ricardo , VAHTERI, Markku
IPC分类号： C08J5/18 , C08L23/08
CPC分类号： C08L23/0815 , B32B27/32 , C08F2/001 , C08F210/16 , C08F2500/05 , C08F2500/26 , C08J5/18 , C08J2323/08 , C08L2203/16 , C08L2205/025 , C08F4/6555 , C08F4/025 , C08F210/08 , C08F2500/12 , C08F2500/08 , C08F210/14
摘要： The present invention is directed to a multimodal polyethylene copolymer comprising a first and a second copolymer of ethylene and at least two alpha-olefin comonomers. Such multimodal copolymers are highly suitable for conversion processes that require a high Draw Down Ratio, like the production of thin films. Such multimodal polyethylene copolymers provide a good impact strength in the sense of a high Dart drop impact strength (DDI) and good isotropy of the films produces thereof. The invention further presents final articles such as films made therefrom.
摘要翻译：本发明涉及包含乙烯和至少两种α-烯烃共聚单体的第一和第二共聚物的多峰聚乙烯共聚物。这种多峰共聚物非常适用于需要高拉伸比的转化方法，如薄膜的生产。这种多峰聚乙烯共聚物在高镖落下冲击强度（DDI）的意义上提供良好的冲击强度，并且其膜产生的良好的各向同性。本发明还提供最终制品，例如由其制成的薄膜。

14. 发明申请

WO2016198271A1 MULTIMODAL POLYETHYLENE COPOLYMER 审中-公开
标题翻译：多模聚乙烯共聚物
公开(公告)号：WO2016198271A1
公开(公告)日：2016-12-15
申请号：PCT/EP2016/062121
申请日：2016-05-30
申请人： BOREALIS AG
发明人： TUPE, Ravindra , JAMIESON, John , KELA, Jarmo , ALBUNIA, Alexandra, Romina , VAHTERI, Markku , GODOY-LOPEZ, Ricardo
IPC分类号： C08J5/18 , C08L23/08
CPC分类号： C08L23/0815 , B32B27/32 , C08J5/18 , C08J2323/08 , C08J2423/08 , C08L2203/16 , C08L2205/025
摘要： The present invention is directed to a multimodal polyethylene copolymer comprising a first and a second copolymer of ethylene and at least two alpha-olefin comonomers. The multimodal polyethylene copolymer is highly suitable for the production of films providing high impact strength in the sense of high Dart drop impact strength (DDI) and low extractables. The invention further presents final articles such as films made therefrom.
摘要翻译：本发明涉及包含乙烯和至少两种α-烯烃共聚单体的第一和第二共聚物的多峰聚乙烯共聚物。多峰聚乙烯共聚物非常适合于在高Dart滴落冲击强度（DDI）和低可提取物的意义上生产提供高冲击强度的膜。本发明还提供最终制品，例如由其制成的薄膜。

15. 发明申请

WO2021234040A1 POLYMER FOR CABLE JACKET 审中-公开
公开(公告)号：WO2021234040A1
公开(公告)日：2021-11-25
申请号：PCT/EP2021/063367
申请日：2021-05-19
申请人： BOREALIS AG
发明人： HJÄRTFORS, Anna , JAMIESON, John , TUPE, Ravindra , LESKINEN, Pauli
IPC分类号： C08L23/08 , C08F210/02 , H01B3/44 , C08F210/16
摘要： A multimodal polyethylene composition having a lower molecular weight (LMW) ethylene homo or copolymer component (A) and a higher molecular weight ethylene copolymer component (B); wherein the LMW component comprises two fractions (ai) and (aii); wherein the polymer composition has a density of 930 kg/m3 or more (ISO1183), such as 938 to 955 kg/m3, an MFR2 (ISO1133 at 190ºC and 2.16 kg load) in the range of 0.05 to 10 g/10min, a flex modulus of up to 800 MPa (ISO 178:2010), such as 300 to 800 MPa (ISO 178:2010) and a taber abrasion resistance of 8.0 to 13.0 mg/1000 cycle (ASTM D 4060: 2014).

16. 发明申请

WO2020244834A1 PROCESS AND REACTOR ASSEMBLY FOR THE ENHANCEMENT OF HYDRODYNAMICS IN A GAS-SOLIDS FLUIDIZED BED REACTOR 审中-公开
公开(公告)号：WO2020244834A1
公开(公告)日：2020-12-10
申请号：PCT/EP2020/059811
申请日：2020-04-06
申请人： BOREALIS AG
发明人： WEICKERT, Gunter , KANELLOPOULOS, Vasileios , PRINSEN, Eric-Jan , AGUAYO ARELLANO, Pablo Ivan , VAHTERI, Markku , SALMINEN, Juha , RUSKEENIEMI, Jari-Jussi , TUPE, Ravindra , ELOVAINIO, Erno , NYFORS, Klaus
IPC分类号： B01J19/18 , B01J8/24 , B01J8/38 , B01J8/44
摘要： A process for polymerizing olefin monomer(s) in a gas-solids olefin polymerization reactor comprising a top zone; a middle zone, which comprises a top end in direct contact with said top zone and which is located below said top zone, the middle zone having a generally cylindrical shape; and a bottom zone, which is in direct contact with a bottom end of the middle zone and which is located below the middle zone; comprising the following steps: introducing a fluidization gas stream into the bottom zone; polymerizing olefin monomer(s) in the presence of a polymerization catalyst in a dense phase formed by particles of a polymer of the olefin monomer(s) suspended in an upwards flowing stream of the fluidization gas in the middle zone; introducing a jet gas stream through one or more jet gas feeding ports in a jet gas feeding area of the middle zone at the dense phase in the middle zone of the gas-solids olefin polymerization reactor; wherein the kinetic energy (E JG ) input in the reactor by the jet stream is between 1.5 and 50 times higher than the kinetic energy (E FG ) input in the reactor by the fluidization gas stream (FG).

17. 发明申请

WO2015086813A1 MULTISTAGE PROCESS FOR PRODUCING POLYETHYLENE COMPOSITIONS 审中-公开
标题翻译：用于生产聚乙烯组合物的多级方法
公开(公告)号：WO2015086813A1
公开(公告)日：2015-06-18
申请号：PCT/EP2014/077547
申请日：2014-12-12
申请人： BOREALIS AG
发明人： TUPE, Ravindra , AHO, Jani , VAHTERI, Markku , NOOPILA, Tuomas , KELA, Jarmo
IPC分类号： C08F2/00
CPC分类号： C08L23/0815 , C08F4/025 , C08F210/16 , C08L2205/025 , C08F210/08 , C08F2500/12 , C08F2500/26 , C08F2/001 , C08F4/6546 , C08F4/6565
摘要： The present invention is a process for producing low density copolymers of ethylene and alpha-olefins having from 4 to 10 carbon atoms in three polymerization stages in the presence of an olefin polymerization catalyst where a low molecular weight copolymer of ethylene is produced in two of the stages and a high molecular weight copolymer in one of the stages. The resulting copolymers have a low density of not more than 920 kg/m 3 .
摘要翻译：本发明是在烯烃聚合催化剂存在下在三个聚合阶段中生产具有4-10个碳原子的乙烯和α-烯烃的低密度共聚物的方法，其中乙烯的低分子量共聚物在阶段和高分子量共聚物。得到的共聚物具有不大于920kg / m 3的低密度。

18. 发明申请

WO2015086812A1 MULTISTAGE PROCESS FOR PRODUCING POLYETHYLENE COMPOSITIONS 审中-公开
标题翻译：用于生产聚乙烯组合物的多级方法
公开(公告)号：WO2015086812A1
公开(公告)日：2015-06-18
申请号：PCT/EP2014/077546
申请日：2014-12-12
申请人： BOREALIS AG
发明人： LIU, Yi , JAMIESON, John , TUPE, Ravindra , KELA, Jarmo
IPC分类号： C08F210/02 , C08F2/00 , C08F10/02
CPC分类号： C08F210/16 , C08F2/001 , C08J5/18 , C08J2323/08 , C08L23/0815 , C08L2205/025 , C08L2205/03 , C08F210/08 , C08F2500/07 , C08F2500/12 , C08F2500/26 , C08F2500/08 , C08F4/025 , C08F4/6492 , C08F4/6555
摘要： The present invention is a process for producing copolymers of ethylene and alpha-olefins having from 4 to 10 carbon atoms in three polymerization stages where a low molecular weight copolymer of ethylene is produced in two of the stages and a high molecular weight copolymer in one of the stages. The resulting copolymers have a low content of extractable material and can be extruded to films which can be used in food contact applications.
摘要翻译：本发明是在三个聚合阶段中制备乙烯和具有4-10个碳原子的α-烯烃的共聚物的方法，其中在两个阶段中制备低分子量共聚物的乙烯和一种高分子量共聚物阶段所得共聚物的可萃取材料含量低，可以挤出成可用于食品接触应用的薄膜。

19. 发明申请

WO2015051878A1 MULTISTAGE PROCESS FOR PRODUCING POLYETHYLENE COMPOSITIONS 审中-公开
标题翻译：用于生产聚乙烯组合物的多级方法
公开(公告)号：WO2015051878A1
公开(公告)日：2015-04-16
申请号：PCT/EP2014/002587
申请日：2014-09-24
申请人： BOREALIS AG
发明人： HJERTBERG, Thomas , TUPE, Ravindra , WAHNER, Udo , PIEL, Tanja , LIU, Yi , ALBUNIA, Alexandra Romina , PRADES, Floran , THORMAN, Joseph , JEREMIC, Dusan
IPC分类号： C08F2/00
CPC分类号： C08L23/0815 , C08F2/001 , C08L2205/02 , C08L2205/03 , C08F210/16 , C08F210/14 , C08F2500/07 , C08F2500/12
摘要： A process for polymerizing ethylene in the presence of a polymerization catalyst by copolymerizing ethylene with a comonomer selected from the group of C4-C10 alpha-olefins in three polymerization stages. The polymers produced in the three stages have different melt flow rates. The polymer composition produced by the process has good mechanical properties and can be used for making pipes. The process has a good productivity and provides a stable and economic operation.
摘要翻译：在聚合催化剂存在下，通过在三个聚合阶段使乙烯与选自C 4 -C 10α-烯烃的共聚单体共聚来制备乙烯的方法。在三个阶段中生产的聚合物具有不同的熔体流动速率。该方法生产的聚合物组合物具有良好的机械性能，可用于制造管材。该过程具有良好的生产力，并提供稳定和经济的运作。

20. 发明公开

EP4153677A1 POLYMER FOR CABLE JACKET 审中-实审
公开(公告)号：EP4153677A1
公开(公告)日：2023-03-29
申请号：EP21726654.3
申请日：2021-05-19
申请人： Borealis AG
发明人： HJÄRTFORS, Anna , JAMIESON, John , TUPE, Ravindra , LESKINEN, Pauli
IPC分类号： C08L23/08 , C08F210/02 , H01B3/44 , C08F210/16

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