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    • 1. 发明申请
    • PROCESS
    • WO2019166652A1
    • 2019-09-06
    • PCT/EP2019/055210
    • 2019-03-01
    • BOREALIS AG
    • GALGALI, Girish SureshJEREMIC, DusanALBRECHT, Andreas
    • C08F2/00C08L23/04C08F210/16
    • A process for preparing an ethylene terpolymer comprising the steps of: (a) pre-polymerizing ethylene and at least one C4-C12 comonomer to produce a copolymer component (i o ) having a MFR 2 in the range of 30 to 80 g/10min; (b) in the presence of component (i o ), copolymerizing ethylene with a C4- C12 comonomer to produce component (i) wherein the MFR 2 of component (i) is in the range of 30 to 80 g/10min; (c) in the presence of component (i), polymerizing ethylene and at least one C4-C12 comonomer to produce component (ii); wherein the MFR 2 ratio of (i)/(i o ) is in the range of 0.5 to 2.5; wherein the MFR 2 of the terpolymer is 1.5 to 10 g/10min, and wherein the density of the terpolymer is 905 to 940 kg/m 3 . An ethylene terpolymer, such as a multimodal ethylene terpolymer, comprising: (i o ) 0.5-5.0 wt.% of a copolymer of ethylene and at least one C4-C12 comonomer having an MFR 2 of 30 to 80 g/10min; (i a ) 25-69.5 wt.% of a copolymer of ethylene and at least one C4-C12 comonomer different from (i o ) wherein the MFR 2 of components (i o ) and (i a ) combined is 30 to 80 g/10 min and wherein the MFR 2 ratio of (i a + i o )/(i o ) is in the range of 0.5 to 2.5; and (ii) 30-70 wt.% of a copolymer of ethylene and at least one C4-C12 comonomer different from (i o ) and (i); wherein the MFR 2 of the terpolymer is 1.5 to 10 g/10min, and wherein the density of the terpolymer is 905 to 940 kg/m 3 .