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    • 13. 发明申请
    • Optical energy conversion apparatus
    • 光能转换装置
    • US20050092358A1
    • 2005-05-05
    • US10999049
    • 2004-11-29
    • Akio MachidaSetsuo UsuiKazumasa Nomoto
    • Akio MachidaSetsuo UsuiKazumasa Nomoto
    • H01L31/00H01L31/0368
    • H01L31/03682Y02E10/546
    • An optical energy conversion apparatus 10 includes a first impurity doped semiconductor layer 5, formed on a substrate, and which is of a semiconductor material admixed with a first impurity, an optically active layer 6, formed on the first impurity doped semiconductor layer 5, and which is of a hydrogen-containing amorphous semiconductor material, and a second impurity doped semiconductor layer 7, admixed with a second impurity and formed on the optically active semiconductor layer 6. The second impurity doped semiconductor layer is of a polycrystallized semiconductor material lower in hydrogen concentration than the material of the optically active semiconductor layer 6. The average crystal grain size in the depth-wise direction in an interfacing structure between the optically active semiconductor layer 6 and the second impurity doped semiconductor layer 7 is decreased stepwise in a direction proceeding from the surface of the second impurity doped semiconductor layer towards the substrate 1. By controlling the hydrogen concentration of the second impurity doped semiconductor layer 7, the number of dangling bonds in the second impurity doped semiconductor layer 7 is significantly decreased to exhibit superior crystallinity to improve the conversion efficiency of the apparatus 10.
    • 光能转换装置10包括形成在基板上的第一杂质掺杂半导体层5,其是与第一杂质混合的半导体材料,形成在第一杂质掺杂半导体层5上的光学活性层6,以及 其是含氢非晶半导体材料,和第二杂质掺杂半导体层7,与第二杂质混合并形成在光学活性半导体层6上。 第二杂质掺杂半导体层是多晶半导体材料,其氢浓度低于光学活性半导体层6的材料。 在光学活性半导体层6和第二杂质掺杂半导体层7之间的界面结构中的深度方向上的平均晶粒尺寸在从第二杂质掺杂半导体层的表面朝向衬底的方向上逐步降低 1。 通过控制第二杂质掺杂半导体层7的氢浓度,第二杂质掺杂半导体层7中的悬挂键数量显着降低,以显示出优异的结晶度,从而提高了装置10的转换效率。
    • 14. 发明授权
    • Optical energy conversion apparatus
    • 光能转换装置
    • US07199303B2
    • 2007-04-03
    • US10221719
    • 2001-03-13
    • Akio MachidaSetsuo UsuiKazumasa Nomoto
    • Akio MachidaSetsuo UsuiKazumasa Nomoto
    • H01N6/00
    • H01L31/03682Y02E10/546
    • An optical energy conversion apparatus 10 includes a first impurity doped semiconductor layer 5, formed on a substrate, and which is of a semiconductor material admixed with a first impurity, an optically active layer 6, formed on the first impurity doped semiconductor layer 5, and which is of a hydrogen-containing amorphous semiconductor material, and a second impurity doped semiconductor layer 7, admixed with a second impurity and formed on the optically active semiconductor layer 6. The second impurity doped semiconductor layer is of a polycrystallized semiconductor material lower in hydrogen concentration than the material of the optically active semiconductor layer 6. The average crystal grain size in the depth-wise direction in an interfacing structure between the optically active semiconductor layer 6 and the second impurity doped semiconductor layer 7 is decreased stepwise in a direction proceeding from the surface of the second impurity doped semiconductor layer towards the substrate 1. By controlling the hydrogen concentration of the second impurity doped semiconductor layer 7, the number of dangling bonds in the second impurity doped semiconductor layer 7 is significantly decreased to exhibit superior crystallinity to improve the conversion efficiency of the apparatus 10.
    • 光能转换装置10包括形成在基板上的第一杂质掺杂半导体层5,其是与第一杂质混合的半导体材料,形成在第一杂质掺杂半导体层5上的光学活性层6,以及 其是含氢非晶半导体材料,和第二杂质掺杂半导体层7,与第二杂质混合并形成在光学活性半导体层6上。 第二杂质掺杂半导体层是多晶半导体材料,其氢浓度低于光学活性半导体层6的材料。 在光学活性半导体层6和第二杂质掺杂半导体层7之间的界面结构中的深度方向上的平均晶粒尺寸在从第二杂质掺杂半导体层的表面朝向衬底的方向上逐步降低 1。 通过控制第二杂质掺杂半导体层7的氢浓度,第二杂质掺杂半导体层7中的悬挂键数量显着降低,以显示出优异的结晶度,从而提高了装置10的转换效率。