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    • 12. 发明授权
    • Morpholinones as light stabilizers
    • 吗啉酮作为光稳定剂
    • US06562815B1
    • 2003-05-13
    • US09639906
    • 2000-08-16
    • Dario LazzariThomas BolleMirko RossiHugh Stephen Laver
    • Dario LazzariThomas BolleMirko RossiHugh Stephen Laver
    • A61K315375
    • C07C229/12C07D265/32C08K5/357
    • The invention relates to new compounds containing 1-8 active groups of the type 3,3,6,6-polysubstituted 2-morpholinone and having the formula F (A′—Z)m—X  (F), wherein m is a number from 1 to 8; X is an organic anchor group of valency m and in case that m is not 1, X may also be a direct bond, SO2, P or PO; A′ is a monovalent group of the formula E  containing one linking group; Z is a direct bond, —O—, —S—, —SO—, —SO2— or —NR′14—; provided that Z is —O—, —S—, —SO—, —SO2— or —NR′14— if m is 1 and the linking group in formula E is G3 or G5; G1 is hydrogen; C1-C18alkyl; C2-C18alkyl substituted by OH and/or phenyl; oxyl; OH; C2-C12cyanoalkyl; C2-C12cyanoalkoxy; C1-C18alkoxy; C5-C12cycloalkoxy; C3-C8alkenyl; C3-C8alkynyl; C3-C8alkenyloxy; C7-C12phenylalkyl; C7-C12phenylalkyl substituted by hydroxy, C1-C4alkyl and/or C1-C4alkoxy; C7-C15phenylalkoxy; C7-C15phenylalkoxy, which is substituted by C1-C4alkyl and/or C1-C4alkoxy; or G1 is C1-C8alkanoyl; C3-C5alkenoyl; C1-C18alkanoyloxy; C3-C8epoxyalkyl; or G1 is the linking group —R10—; G2 and G4 are, independently of one another, C1-C18alkyl, C5-C12cycloalkenyl, C5-C12cycloalkyl, or an oligocyclic hydrocarbon residue of 6-12 carbon atoms; G3 is as defined for G2 or is C1-C8hydroxyalkyl; or G2 and G3 together are (CH2)e, where e is a number from 4 to 11; or G3 is the linking group —R5—; G5 is as defined for G4 or is C1-C8hydroxyalkyl; or G4 and G5 together are (CH2)e, where e is a number from 4 to 11; or G5 is the linking group —R5—; G6 is as defined for G4 or is hydrogen; or G6 is the linking group, which is a direct bond or —R5—; and other residues are as defined in claim 1. The new compounds are effective as stabilizers for organic material, especially coatings, against harmful effects of light, oxygen and/or heat.
    • 本发明涉及含有1,3,6,6-三取代的2-吗啉酮类型的1-8个活性基团并具有式F的新化合物,其中m为1至8的数; X为化合价m 并且在m不为1的情况下,X也可以是直接键合,SO 2,P或PO; A'是含有一个连接基团的式E的一价基团; Z是直接键,-O-,-S - , - SO - , - SO2-或-NR'14-; 条件是如果m是1,则Z是-O - , - S - , - SO - , - SO 2 - 或-NR'14-,式E中的连接基团是G 3或G 5; G 1是氢; C1-C18烷基; 由OH和/或苯基取代的C 2 -C 18烷基; 氧基 哦; C 2 -C 12氰基烷基; C2-C12氰基烷氧基; C1-C18烷氧基; C5-C12环烷氧基; C3-C8链烯基; C3-C8炔基; C3-C8链烯氧基; C7-C12苯基烷基; 被羟基,C 1 -C 4烷基和/或C 1 -C 4烷氧基取代的C 7 -C 12苯基烷基; C7-C15苯基烷氧基; 被C 1 -C 4烷基和/或C 1 -C 4烷氧基取代的C 7 -C 15苯基烷氧基; 或G1是C1-C8烷酰基; C3-C5链烯酰基; C1-C18烷酰氧基; C3-C8环氧烷基; 或G1是连接基团-R10-; G 2和G 4彼此独立地是C 1 -C 18烷基,C 5 -C 12环烯基,C 5 -C 12环烷基或6-12个碳原子的低聚烃残基; G3如对于G2 或是C 1 -C 8羟烷基; 或G2和G3一起为(CH 2)e,其中e为4至11的数; 或G3是连接基团-R5-; G5如G4所定义或是C 1 -C 8羟烷基; 或G4和G5一起为(CH 2)e,其中e为4至11的数; 或G5为连接基团-R5-; G6如G4所定义或是氢;或G6是连接基团,其是直接键或-R 5 - ;其它残基如权利要求1中所定义。该新化合物作为有机材料的稳定剂是有效的,特别是涂料 ,防止光,氧和/或热的有害影响。
    • 13. 发明授权
    • Triazine compounds containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials
    • 含有2,2,6,6-四甲基-4-哌啶基的三嗪化合物作为有机材料的稳定剂
    • US06221937B1
    • 2001-04-24
    • US09426025
    • 1999-10-25
    • Dario LazzariFabrizio Guizzardi
    • Dario LazzariFabrizio Guizzardi
    • C08J708
    • C07D401/14C08K5/34926
    • A product of the formula (I) in which n is a number from 2 to 14; the radicals R1 are for example hydrogen or C1-C8alkyl; R2 is for example C2-C12alkylene; the radicals A are for example C1-C8acyl; the radicals B are independently of one another —OR3, —N(R4)(R5) or a group of the formula R3, R4 and R5, which are identical or different, are for example hydrogen or C1-C18alkyl, or —N(R4)(R5) is additionally a group of the formula with Y being —O—, —CH2—, —CH2CH2— or >N—CH3; X is —O— or >N—R6; R6 is for example hydrogen or C1-C18alkyl; R is preferably a group of the formula with the proviso that in the individual recurrent units of the formula (I), each of the radicals B, R, R1 and R2 has the same or a different meaning. The indicated product is useful as light stabilizer, heat stabilizer and oxidation stabilizer for organic materials, in particular synthetic polymers.
    • 式(I)的产物,其中n为2至14的数; 基团R1是例如氢或C1-C8烷基; R2是例如C 2 -C 12亚烷基; 基团A是例如C 1 -C 8酰基; 基团B彼此独立地为-OR3,-N(R4)(R5)或相同或不同的式R3,R4和R5的基团为例如氢或C1-C18烷基,或-N(R4 )(R 5)另外是一个基团,Y是-O - , - CH 2 - , - CH 2 CH 2 - 或> N-CH 3; X是-O-或> N-R6; R6是例如氢或C1-C18烷基; R优选为一组公开的条件,即在式(I)的各个反复单元中,基团B,R,R 1和R 2各自具有相同或不同的含义。所指示的产物可用作光稳定剂 ,用于有机材料的热稳定剂和氧化稳定剂,特别是合成聚合物。
    • 15. 发明申请
    • NANO STRUCTURED UV ABSORBERS
    • 纳米结构紫外线吸收剂
    • US20110015297A1
    • 2011-01-20
    • US12747194
    • 2008-12-12
    • Mara DestroSamanta CimitanCesare LorenzettiDario Lazzari
    • Mara DestroSamanta CimitanCesare LorenzettiDario Lazzari
    • C08K5/3492C08K5/17F21V9/06
    • C08K3/22B82Y30/00C08K5/34C08K2201/011C08L21/00
    • The present invention relates to an UV absorbing polymer composition comprising effective amounts of (a1) a nanoparticulate oxide selected from oxides of the groups 4 and 12 of the periodic table, wherein the oxide is doped with In, Ga and/or Al, and (b1) a UV stabilizing/absorbing substance comprising a sterically hindered amine and/or a polymeric hydroxyphenyl-triazine; or (a2) a nanoparticulate oxide selected from oxides of the groups 4 and 12, and (b2) a UV light stabilizing substance comprising a N-oxygen-substituted sterically hindered amine. Furthermore, the present invention relates to a polymer comprising said composition and the use of said composition as a UV absorber in polymers, particularly in agricultural films or packaging films. Finally, the present invention relates to a process for producing doped nanoparticulate metal oxides.
    • 本发明涉及一种UV吸收聚合物组合物,其包含有效量的(a1)选自元素周期表第4和12族的氧化物的纳米颗粒氧化物,其中该氧化物掺杂有In,Ga和/或Al,和( b1)包含空间位阻胺和/或聚合羟基苯基 - 三嗪的UV稳定/吸收物质; 或(a2)选自组4和12的氧化物的纳米颗粒氧化物,和(b2)包含N-氧取代的空间位阻胺的UV光稳定物质。 此外,本发明涉及包含所述组合物的聚合物和所述组合物作为聚合物中的UV吸收剂的用途,特别是在农业膜或包装膜中。 最后,本发明涉及一种制备掺杂的纳米颗粒金属氧化物的方法。
    • 17. 发明申请
    • Imidazolidinone derivatives
    • 咪唑啉酮衍生物
    • US20050038236A1
    • 2005-02-17
    • US10921261
    • 2004-08-18
    • Dario LazzariGraziano Zagnoni
    • Dario LazzariGraziano Zagnoni
    • C07D233/38C07D233/32C07D403/04C07D403/14C08K5/3445C08K5/3492C08L101/12C09K15/30C09B62/16C09B62/24C07D43/14
    • C07D403/04C07D233/32C07D403/14C08K5/3445C08K5/34926
    • A compound of the formula (IA) or (IB) wherein G1, G2, G3 and G4 are independently of one another C1-C18alkyl or C5-C12cycloalkyl or the radicals G1 and G2 and the radicals G3 and G4 form independently of one another, together with the carbon atom they are attached to, C5-C12cycloalkyl; R is hydrogen C1-C18alkyl, C1-C18hydroxyalkyl, C2-C18alkenyl, C5-C12cycloalkyl, C7-C12phenylalkyl unsubstituted or substituted on the phenyl radical by C1-C4alkyl and/or C1-C4alkoxy; or C1-C18alkanoyl; R* is hydrogen, C1-C18alkyl, oxyl, —OH, —CH2CN, C3-C6alkenyl, C3-C8alkynyl, C7-C12phenylalkyl unsubstituted or substituted on the phenyl radical by C1-C4alkyl and/or C1-C4alkoxy; C1-C8acyl, C1-C18alkoxy, C1-C18hydroxyalkoxy, C2-C18alkenyloxy, C5-C12cycloalkoxy, C7-C12phenylalkoxy unsubstituted or substituted on the phenyl radical by C1-C4alkyl and/or C1-C4alkoxy; C1-C18alkanoyloxy, (C1-C18alkoxy)carbonyl, glycidyl or a group —CH2CH(OH)(G) with G being hydrogen, methyl or phenyl; n is 1, 2, 3 or 4; n* is 1, 2 or 3; X is an organic radical of a valency equal to n; and X* is a triazinic radical with a valency equal to n*; with the proviso that when n is 1, R is methyl, ethyl, propyl, C1-C18hydroxyalkyl, C2C18alkenyl, C5-C12cycloalkyl or C1-C18alkanoyl. The compounds described above are useful for stabilizing an organic material against degradation induced by light, heat or oxidation.
    • 式(IA)或(IB)的化合物,其中G1,G2,G3和G4彼此独立地为C1-C18烷基或C5-C12环烷基,或者基团G1和G2以及基团G3和G4彼此独立地形成, 与它们连接的碳原子一起,C5-C12环烷基; R是氢,C 1 -C 18烷基,C 1 -C 18羟烷基,C 2 -C 18烯基,C 5 -C 12环烷基,C 1 -C 4烷基和/或C 1 -C 4烷氧基在苯基上未取代或取代的C 7 -C 12苯基烷基; 或C 1 -C 18烷酰基; R *是未取代的或被C 1 -C 4烷基和/或C 1 -C 4烷氧基取代在苯基上的氢,C 1 -C 18烷基,氧基,-OH,-CH 2 CN,C 3 -C 6烯基,C 3 -C 8炔基,C 7 -C 12苯基烷基; C 1 -C 8酰基,C 1 -C 18烷氧基,C 1 -C 18羟基烷氧基,C 2 -C 18链烯氧基,C 5 -C 12环烷氧基,未被取代或被C 1 -C 4烷基和/或C 1 -C 4烷氧基取代在苯基上的C 7 -C 12苯基烷氧基; C 1 -C 18烷酰氧基,(C 1 -C 18烷氧基)羰基,缩水甘油基或基团-CH 2 CH(OH)(G),其中G为氢,甲基或苯基; n为1,2,3或4; n *为1,2或3; X是等价于n的化合价的有机基团; 并且X *是化合价等于n *的三嗪基;
    • 19. 发明授权
    • Oxopiperazinyl derivatives and light stabilized compositions
    • 氧哌嗪衍生物和光稳定组合物
    • US06642383B2
    • 2003-11-04
    • US09855905
    • 2001-05-15
    • Dario LazzariGraziano ZagnoniMirko RossiAlessandro ZeddaValerio BorzattaStephen Mark Andrews
    • Dario LazzariGraziano ZagnoniMirko RossiAlessandro ZeddaValerio BorzattaStephen Mark Andrews
    • C07D24106
    • G03C1/8155C07D241/08C07D403/14C07D405/12C07D409/14C08G63/6856C08G73/0633C08K5/3462
    • Compounds of the formula (I) wherein p is zero or 1; q and r, independently of each other, are an integer from 1 to 6; and s is a number ranging from 1 to 8; X is —O— or, when p is 1, X is also a group Rw, Rx, Ry and Rz are, independently of each other, C1-C18alkyl, C5-C12cycloalkyl or C1-C5hydroxyalkyl, especially methyl; R1 is hydrogen; C1-C18alkyl; oxyl; OH; CH2CN; C1-C18alkoxy; C5-C12cycloalkoxy; C3-C8alkenyl; C3-C8alkynyl; C7-C12phenylalkyl; C7-C15phenylalkyl, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; C7-C15phenylalkoxy; C7-C15phenylalkoxy, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; or R1 is C1-C8alkanoyl; C3-C5alkenoyl; C1-C18alkanoyloxy; glycidyl; or a group —CH2CH(OH)—G, in which G is hydrogen, methyl or phenyl; R2 is hydrogen, C1-C8alkyl, C5-C12cycloalkyl or C1-C4hydroxyalkyl; R3, R4, R5 independently of each other are hydrogen, C1-C8alkyl or C5-C12cycloalkyl; and W and other residues are as described in claim 1, are effective stabilizers for organic materials, for example thermoplastic organic polymers, coating compositions or photographic materials.
    • 式(I)的化合物,其中p为0或1; q和r彼此独立地是1至6的整数; 且为1至8的数; X为-O-或当p为1时,X为基团R w,R x,R y和R z彼此独立地为C 1 -C 18烷基,C 5 -C 12环烷基或C 1 -C 18烷基, C5羟烷基,特别是甲基; R1是氢; C1-C18烷基; 氧基 哦; CH2CN; C1-C18烷氧基; C5-C12环烷氧基; C3-C8链烯基; C3-C8炔基; C7-C12苯基烷基; C7-C15苯基烷基,其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; C7-C15苯基烷氧基; C7-C15苯基烷氧基,其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; 或R 1为C 1 -C 8烷酰基; C3-C5链烯酰基; C1-C18烷酰氧基; 缩水甘油基 或基团-CH 2 CH(OH)-G,其中G是氢,甲基或苯基; R 2是氢,C 1 -C 8烷基,C 5 -C 12环烷基或C 1 -C 4羟烷基; R 3,R 4,R 5彼此独立地是氢,C 1 -C 1-8烷基或C 5 -C 12环烷基; 和W和其它残余物如权利要求1所述,是有机材料的有效稳定剂,例如热塑性有机聚合物,涂料组合物或照相材料。