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1. 发明授权

US06518326B1 Open chain alkoxyamine compounds and their use as polymerization regulators 有权
标题翻译：开链烷氧基胺化合物及其作为聚合调节剂的用途
公开(公告)号：US06518326B1
公开(公告)日：2003-02-11
申请号：US09744731
申请日：2001-01-29
申请人： Peter Nesvadba , Andreas Kramer , Marie-Odile Zink , Dario Lazzari
发明人： Peter Nesvadba , Andreas Kramer , Marie-Odile Zink , Dario Lazzari
IPC分类号： C07C23918
CPC分类号： C08L53/00 , C07C219/06 , C07C219/14 , C07C237/06 , C07C237/24 , C07C239/12 , C07C239/18 , C07C239/20 , C07C255/16 , C07C255/46 , C07C291/04 , C07C2601/08 , C07C2601/14 , C07D309/12 , C08F291/00 , C08F293/005 , C08L51/003 , C09J151/00 , C09J153/00
摘要： The invention relates to open chain alkoxyamine compounds useful as polymerization regulators. The open chain alkoxyamine compounds are useful for the polymerization of ethylenically unsaturated monomers. The compounds of the present invention provide polymeric resin products having low polydispersity. The polymerization process proceeds with enhanced monomer to polymer conversion efficiency. In particular, this invention relates to stable free radical-mediated polymerization processes which provide homopolymers, random copolymer, block copolymers, multiblock copolymers, graft copolymers and the like, at enhanced rates of polymerization and enhanced monomer to polymer conversions.
摘要翻译：本发明涉及用作聚合调节剂的开链烷氧基胺化合物。开链烷氧基胺化合物可用于烯属不饱和单体的聚合。本发明的化合物提供了具有低多分散性的聚合物树脂产品。聚合过程由单体转化为聚合物转化效率提高。特别地，本发明涉及稳定的自由基介导的聚合方法，其提供均聚物，无规共聚物，嵌段共聚物，多嵌段共聚物，接枝共聚物等，以提高聚合速率和提高单体与聚合物的转化率。

2. 发明授权

US06841703B2 Open chain alkoxyamine compounds and their use as polymerization regulators 有权
标题翻译：开链烷氧基胺化合物及其作为聚合调节剂的用途
公开(公告)号：US06841703B2
公开(公告)日：2005-01-11
申请号：US10298977
申请日：2002-11-18
申请人： Peter Nesvadba , Andreas Kramer , Marie-Odile Zink , Dario Lazzari
发明人： Peter Nesvadba , Andreas Kramer , Marie-Odile Zink , Dario Lazzari
IPC分类号： C07D317/32 , C07C219/06 , C07C219/14 , C07C237/06 , C07C237/24 , C07C239/12 , C07C239/16 , C07C239/18 , C07C239/20 , C07C255/16 , C07C255/46 , C07C255/62 , C07C291/04 , C07D309/12 , C08F2/38 , C08F2/46 , C08F4/00 , C08F291/00 , C08F293/00 , C08L51/00 , C08L53/00 , C09J151/00 , C09J153/00 , C07C259/00
CPC分类号： C08L53/00 , C07C219/06 , C07C219/14 , C07C237/06 , C07C237/24 , C07C239/12 , C07C239/18 , C07C239/20 , C07C255/16 , C07C255/46 , C07C291/04 , C07C2601/08 , C07C2601/14 , C07D309/12 , C08F291/00 , C08F293/005 , C08L51/003 , C09J151/00 , C09J153/00
摘要： The invention relates to a compound of formula Ia, Ib or Ic The open chain alkoxyamine compounds are useful for the polymerization of ethylenically unsaturated monomers. The compounds of the present invention provide polymeric resin products having low polydispersity. The polymerization process proceeds with enhanced monomer to polymer conversion efficiency. In particular, this invention relates to stable free radical-mediated polymerization processes which provide homopolymers, random copolymers, block copolymers, multiblock copolymers, graft copolymers and the like, at enhanced rates of polymerization and enhanced monomer to polymer conversions.
摘要翻译：本发明涉及式Ia，Ib或Ic的化合物。开链烷氧基胺化合物可用于烯属不饱和单体的聚合。本发明的化合物提供了具有低多分散性的聚合物树脂产品。聚合过程由单体转化为聚合物转化效率提高。特别地，本发明涉及稳定的自由基介导的聚合方法，其提供均聚物，无规共聚物，嵌段共聚物，多嵌段共聚物，接枝共聚物等，以提高聚合速率和提高单体与聚合物的转化率。

3. 发明授权

US07160966B2 2,2,6,6 Diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides 失效
标题翻译： 2,2,6,6二乙基 - 二甲基-1-烷氧基 - 哌啶化合物及其相应的1-氧化物
公开(公告)号：US07160966B2
公开(公告)日：2007-01-09
申请号：US11048677
申请日：2005-02-01
申请人： Peter Nesvadba , Marie-Odile Zink , Andreas Kramer
发明人： Peter Nesvadba , Marie-Odile Zink , Andreas Kramer
IPC分类号： C08F2/38 , C08F2/50 , C08F4/00
CPC分类号： C07D401/04 , C07D211/94 , C08F2/38 , C08F255/00 , C08F265/04 , C08F291/00 , C08F293/005 , C08F2220/1825 , C08F2438/02 , C08F220/34
摘要： The present invention relates to selected 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 trimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom; a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,6 dimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.
摘要翻译：本发明涉及在4位被氧或氮取代的选择的1-烷氧基-2,2-二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-三甲基哌啶衍生物原子; 一种可聚合组合物，其包含a）至少一种烯属不饱和单体和b）所述哌啶衍生物。本发明的其它方面是使烯属不饱和单体聚合的方法，以及使用1-烷氧基-2,2-二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,6-二甲基哌啶衍生物，其中在4位被氧或氮原子取代用于受控聚合。中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的主题。

4. 发明授权

US06936670B2 Multifunctional alkoxyamines based on polyalkylpiperidines, polyalkylpiperazinones and polyalkylmorpholinones and their use as polymerization regulators/initiators 有权
标题翻译：基于聚烷基哌啶，聚烷基哌嗪酮和聚烷基吗啉酮的多官能烷氧基胺及其作为聚合调节剂/引发剂的用途
公开(公告)号：US06936670B2
公开(公告)日：2005-08-30
申请号：US10482546
申请日：2002-06-27
申请人： Andreas Kramer , Andreas Mühlebach , Peter Nesvadba , Marie-Odile Zink , Tobias Hintermann
发明人： Andreas Kramer , Andreas Mühlebach , Peter Nesvadba , Marie-Odile Zink , Tobias Hintermann
IPC分类号： C07D295/22 , C07D211/94 , C08F2/00 , C08F2/38 , C08F4/00 , C08F10/00 , C08F12/00 , C08F12/08 , C08F20/18 , C08F118/00 , C08F122/00 , C08F136/00 , C08F126/06
CPC分类号： C08F4/00 , C07D211/94
摘要： The instant invention relates to multifunctional alkoxyamines based on polyalkylpiperidines, polyalkylpiperazinones and polyalkylmorpholinones and their use as polymerization regulatros/initiators. Further subjects of the invention are a polymerizable composition comprising an ethylenically unsaturated monomer or oligomer and the alkoxyamine compound as well as a process for polymerization and a process for preparation of the compounds.
摘要翻译：本发明涉及基于聚烷基哌啶，聚烷基哌嗪酮和聚烷基吗啉酮的多官能烷氧基胺及其作为聚合调节剂/引发剂的用途。本发明的其它主题是包含烯键式不饱和单体或低聚物和烷氧基胺化合物的可聚合组合物以及聚合方法和化合物的制备方法。

5. 发明授权

US06891008B2 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides 失效
标题翻译： 2,2,6,6-二乙基 - 二甲基-1-烷氧基 - 哌啶化合物及其相应的1-氧化物
公开(公告)号：US06891008B2
公开(公告)日：2005-05-10
申请号：US10348088
申请日：2003-01-21
申请人： Peter Nesvadba , Marie-Odile Zink , Andreas Kramer
发明人： Peter Nesvadba , Marie-Odile Zink , Andreas Kramer
IPC分类号： C07D211/94 , C07D401/04 , C08F2/38 , C08F2/46 , C08F4/00 , C08F220/18 , C08F255/00 , C08F265/04 , C08F291/00 , C08F293/00 , C07F2/38
CPC分类号： C07D401/04 , C07D211/94 , C08F2/38 , C08F255/00 , C08F265/04 , C08F291/00 , C08F293/005 , C08F2220/1825 , C08F2438/02 , C08F220/34
摘要： The present invention relates to selected 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 trimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom; a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,6 dimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.
摘要翻译：本发明涉及在4位被氧或氮取代的选择的1-烷氧基-2,2-二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-三甲基哌啶衍生物原子; 一种可聚合组合物，其包含a）至少一种烯属不饱和单体和b）所述哌啶衍生物。本发明的其它方面是使烯属不饱和单体聚合的方法，以及使用1-烷氧基-2,2-二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,6-二甲基哌啶衍生物，其中在4位被氧或氮原子取代用于受控聚合。中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的主题。

6. 发明授权

US06479608B1 Heterocyclic alkoxyamines as regulators in controlled radical polymerization processes 有权
标题翻译：杂环烷氧基胺作为受控自由基聚合方法中的调节剂
公开(公告)号：US06479608B1
公开(公告)日：2002-11-12
申请号：US09417538
申请日：1999-10-14
申请人： Peter Nesvadba , Andreas Kramer , Marie-Odile Zink
发明人： Peter Nesvadba , Andreas Kramer , Marie-Odile Zink
IPC分类号： C08F22810
CPC分类号： C07D241/08 , C07D233/32 , C07D233/36 , C07D243/08 , C07D265/32
摘要： The present invention relates to the use of 6, 7 and 8 membered heterocyclic alkoxyamines or their nitroxyl precursors, which have a high steric hindrance in the &agr;-position to the alkoxyamine group, as regulators/initiators which allow for very efficient and fast polymerization at higher temperatures, but that also work at relatively low temperatures such as for example 100° C. The higher steric hindrance may be introduced by at least one higher alkyl substituent than methyl in the &agr;-position to the alkoxyamine group. In many cases even higher hindrance by two, three or four higher alkyl groups may be advantageous.
摘要翻译：本发明涉及在烷氧基胺基的α-位上具有高空间位阻的6,7和8元杂环烷氧基胺或其硝酰基前体作为调节剂/引发剂的用途，其允许非常有效和快速的聚合较高的温度，但也可以在比较低的温度例如100℃下工作。较高的空间位阻可以通过至少一个高于烷氧基胺基的α-位的甲基引入。在许多情况下，两个，三个或四个较高级烷基的更高的阻碍可能是有利的。

7. 发明申请

US20050143539A1 2,2,6,6 Diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides 失效
标题翻译： 2,2,6,6二乙基 - 二甲基-1-烷氧基 - 哌啶化合物及其相应的1-氧化物
公开(公告)号：US20050143539A1
公开(公告)日：2005-06-30
申请号：US11048677
申请日：2005-02-01
申请人： Peter Nesvadba , Marie-Odile Zink , Andreas Kramer
发明人： Peter Nesvadba , Marie-Odile Zink , Andreas Kramer
IPC分类号： C07D211/94 , C07D401/04 , C08F2/38 , C08F2/46 , C08F4/00 , C08F220/18 , C08F255/00 , C08F265/04 , C08F291/00 , C08F293/00 , C07D211/44 , C07D211/56
CPC分类号： C07D401/04 , C07D211/94 , C08F2/38 , C08F255/00 , C08F265/04 , C08F291/00 , C08F293/005 , C08F2220/1825 , C08F2438/02 , C08F220/34
摘要： The present invention relates to selected 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 trimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom; a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,6 dimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.
摘要翻译：本发明涉及在4位被氧或氮取代的选择的1-烷氧基-2,2-二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-三甲基哌啶衍生物原子; 一种可聚合组合物，其包含a）至少一种烯属不饱和单体和b）所述哌啶衍生物。本发明的其它方面是使烯属不饱和单体聚合的方法，以及使用1-烷氧基-2,2-二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,6-二甲基哌啶衍生物，其中在4位被氧或氮原子取代用于受控聚合。中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的主题。

8. 发明授权

US06664353B2 Heterocyclic alkoxyamines as regulators in controlled radical polymerization processes 有权
公开(公告)号：US06664353B2
公开(公告)日：2003-12-16
申请号：US10191193
申请日：2002-07-09
申请人： Peter Nesvadba , Andreas Kramer , Marie-Odile Zink
发明人： Peter Nesvadba , Andreas Kramer , Marie-Odile Zink
IPC分类号： C08F200
CPC分类号： C07D241/08 , C07D233/32 , C07D233/36 , C07D243/08 , C07D265/32
摘要： The present invention is aimed at a process for controlled polymerization of ethylenically unsaturated monomers in the presence of heterocyclic sterically hindered alkoxyamine compounds. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention. Still further subjects of the invention are novel amine precursors and a novel process for manufacturing 5-ring heterocyclic amines.

9. 发明授权

US07199245B2 4-imino-n-alkoxy or oxy-polyalkyl-piperidine compounds and their use as polymerization regulators 有权
标题翻译： 4-亚氨基正烷氧基或氧 - 聚烷基 - 哌啶化合物及其作为聚合调节剂的用途
公开(公告)号：US07199245B2
公开(公告)日：2007-04-03
申请号：US10480188
申请日：2002-06-04
申请人： Peter Nesvadba , Tobias Hintermann , Andreas Kramer , Marie-Odile Zink , Lucienne Bugnon
发明人： Peter Nesvadba , Tobias Hintermann , Andreas Kramer , Marie-Odile Zink , Lucienne Bugnon
IPC分类号： C07D401/02
CPC分类号： C07D211/94
摘要： The present invention relates to selected 4-imino-N-alkoxy-polyalkyl-peperidine compounds preparation, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a 4-imino-N-alkoxy-polyalkyl-piperidine compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 4-imino-N-alkoxy-polyalkyl-piperidine compounds for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention
摘要翻译：本发明涉及选择的4-亚氨基-N-烷氧基 - 多烷基 - 哌啶化合物，其可聚合组合物包含a）至少一种烯属不饱和单体和b）4-亚氨基-N-烷氧基 - 多烷基 - 哌啶化合物。本发明的其它方面是用于聚合烯属不饱和单体的方法，以及4-亚氨基-N-烷氧基 - 聚烷基 - 哌啶化合物用于受控聚合的方法。中间体N-氧基衍生物，具有烯属不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的受试者

10. 发明授权

US06875831B1 Mono and multifunctional alkoxyamines for the preparation of functionalized macromers 有权
标题翻译：用于制备官能化大分子单体的单官能和多官能烷氧基胺
公开(公告)号：US06875831B1
公开(公告)日：2005-04-05
申请号：US10019618
申请日：2000-06-26
申请人： Andreas Kramer , Peter Nesvadba , Marie-Odile Zink , Wiebke Wunderlich
发明人： Andreas Kramer , Peter Nesvadba , Marie-Odile Zink , Wiebke Wunderlich
IPC分类号： C07D241/08 , C07C239/20 , C07D211/94 , C07D295/24 , C07D401/14 , C07F7/18 , C07F9/40 , C08F4/00 , C08F4/32 , C08F2/00
CPC分类号： C07D295/24 , C07D211/94 , C07F7/1804 , C07F9/4006 , C08F4/00
摘要： The invention pertains to a compound of formula (I), (II) or (III) wherein R1 and R2 are independently of each other hydrogen, C1-C18alkyl, C3-C18alkenyl, C3-C18alkinyl or phenyl which are unsubstituted or substituted by NO2, halogen, amino, hydroxy, cyano, carboxy, C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylamino or di(C1-C4alkyl)amino; A is a group capable of forming a stable free nitroxyl radical A*, which is bound via its oxygen atom to the carbon atom; Y is O, NR3 or CHR3—Xa, wherein Xa is O, S or NR3; R3 is hydrogen, C1-C18alkyl, C3-C18alkenyl, C3-C18alkinyl or phenyl which are unsubstituted or substituted by NO2, halogen, amino, hydroxy, cyano, carboxy, C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylamino or di(C1-C4alkyl)amino; Q1 is an organic or inorganic radical, derived from a compound having at least one functional group being capable of reacting with a hydroxy group; Q2 is an organic radical derived from a mono or polyfunctional alcohol, mono or polyfunctional aminoalcohol, mono or polyfunctional amine mono or polyfunctional mercaptane, mono or polyfunctional phenol or mono or polyfunctional thiophenol; and n is a number from 1 to 20; with the proviso, that in formula (I) if n is 1, Q1 is not or if n is 2, R1 is H and R2 is —CH2—O-tert-butyl, A is not 2,2,6,6-tetramethylpiperidine or 2,2,6,6-tetramethylpiperidine-4-carboxylic acid. Further subjects of the invention are a composition comprising above compounds and at least one ethylenically unsaturated monomer, process for polymerization and the (co)polymers obtained therefrom.
摘要翻译：本发明涉及式（I），（II）或（III）的化合物，其中R 1和R 2彼此独立地为氢，C 1 -C 18烷基，C 3 -C 18烯基，C 3 -C 18炔基或苯基，其未被取代或被NO 2 ，卤素，氨基，羟基，氰基，羧基，C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基氨基或二（C 1 -C 4烷基）氨基; A是能够形成稳定的游离硝酰基A *的基团，其通过其氧原子与碳原子结合; Y是O，NR 3或CHR 3 -Xa，其中X a是O，S或NR 3; R3是氢，C1-C18烷基，C3-C18链烯基，C3-C18链烯基或未被NO2，卤素，氨基，羟基，氰基，羧基，C1-C4烷氧基，C1-C4烷硫基，C1-C4烷基氨基或二（C1 -C 1-4烷基）氨基; Q1是具有至少一个能够与羟基反应的官能团的化合物衍生的有机或无机基团; Q2是衍生自单官能或多官能醇，单或多官能氨基醇，单官能或多官能胺单官能或多官能硫醇，单或多官能苯酚或单官能或多官能苯硫酚的有机基团; n为1〜20的数; 条件是式（I）中n为1时，如果n为2，则Q1为原子，R1为H，R2为-CH2-0-叔丁基，A为2,2,6,6-四甲基哌啶或2,2,6,6-四甲基哌啶-4-羧酸。本发明的其它主题是包含上述化合物和至少一种烯属不饱和单体，聚合方法和由其获得的（共）聚合物）的组合物。

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