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1. 发明授权

US06221937B1 Triazine compounds containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials 有权
标题翻译：含有2,2,6,6-四甲基-4-哌啶基的三嗪化合物作为有机材料的稳定剂
公开(公告)号：US06221937B1
公开(公告)日：2001-04-24
申请号：US09426025
申请日：1999-10-25
申请人： Dario Lazzari , Fabrizio Guizzardi
发明人： Dario Lazzari , Fabrizio Guizzardi
IPC分类号： C08J708
CPC分类号： C07D401/14 , C08K5/34926
摘要： A product of the formula (I) in which n is a number from 2 to 14; the radicals R1 are for example hydrogen or C1-C8alkyl; R2 is for example C2-C12alkylene; the radicals A are for example C1-C8acyl; the radicals B are independently of one another —OR3, —N(R4)(R5) or a group of the formula R3, R4 and R5, which are identical or different, are for example hydrogen or C1-C18alkyl, or —N(R4)(R5) is additionally a group of the formula with Y being —O—, —CH2—, —CH2CH2— or >N—CH3; X is —O— or >N—R6; R6 is for example hydrogen or C1-C18alkyl; R is preferably a group of the formula with the proviso that in the individual recurrent units of the formula (I), each of the radicals B, R, R1 and R2 has the same or a different meaning. The indicated product is useful as light stabilizer, heat stabilizer and oxidation stabilizer for organic materials, in particular synthetic polymers.
摘要翻译：式（I）的产物，其中n为2至14的数; 基团R1是例如氢或C1-C8烷基; R2是例如C 2 -C 12亚烷基; 基团A是例如C 1 -C 8酰基; 基团B彼此独立地为-OR3，-N（R4）（R5）或相同或不同的式R3，R4和R5的基团为例如氢或C1-C18烷基，或-N（R4 ）（R 5）另外是一个基团，Y是-O - ， - CH 2 - ， - CH 2 CH 2 - 或> N-CH 3; X是-O-或> N-R6; R6是例如氢或C1-C18烷基; R优选为一组公开的条件，即在式（I）的各个反复单元中，基团B，R，R 1和R 2各自具有相同或不同的含义。所指示的产物可用作光稳定剂，用于有机材料的热稳定剂和氧化稳定剂，特别是合成聚合物。

2. 发明授权

US06177491B1 Block oligomers containing 1-Hydrocarbyloxy-2,2,6,6-Tetramethyl-4-piperidyl groups as stabilizers for organic materials 有权
标题翻译：含有1-烃氧基-2,2,6,6-四甲基-4-哌啶基的嵌段低聚物作为有机材料的稳定剂
公开(公告)号：US06177491B1
公开(公告)日：2001-01-23
申请号：US09424140
申请日：1999-11-18
申请人： James Peter Galbo , Dario Lazzari , Fabrizio Guizzardi
发明人： James Peter Galbo , Dario Lazzari , Fabrizio Guizzardi
IPC分类号： C08K53492
CPC分类号： C07D401/14 , C08K5/34926 , C09K15/20
摘要： Compounds of formula (I), wherein n is a number from 2 to 14; R1 is for example C1-C18alkyl or C5-C12cycloalkyl; R2 is for example C2-C12alkylene; A is for example acetyl, (C1-C4alkoxy)carbonyl, (C1-C4alkyl)aminocarbonyl or C1-C4alkyl; B is —OR3, —N(R4(R5) or a group of formula (II); R3, R4 and R5, which are identical or different, are for example hydrogen or C1-C18alkyl, or —N(R4)(R5) is additionally a group of formula (III) with Y being —O—, —CH2—, —CH2CH2— or >N—CH3; X is —O— or >N—R6; R6 is for example hydrogen or C1-C18alkyl; and R is preferably a group of formula (IV); with the proviso that in the individual recurrent units of formula (I), each of the radicals B, R, R1 and R2 has the same or a different meaning. The indicated compounds are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.
摘要翻译：式（I）的化合物，其中n为2至14的数; R1是例如C1-C18烷基或C5-C12环烷基; R2是例如C 2 -C 12亚烷基; A是例如乙酰基，（C 1 -C 4烷氧基）羰基，（C 1 -C 4烷基）氨基羰基或C 1 -C 4烷基; B是-OR 3，-N（R 4（R 5）或式（II）基团）; R 3，R 4和R 5相同或不同，例如是氢或C 1 -C 18烷基或-N（R 4））另外是式（III）的基团，其中Y是-O-，-CH 2 - ， - CH 2 CH 2 - 或> N-CH 3; X是-O-或> N-R6; R 6是例如氢或C 1 -C 18烷基 ; R优选为式（IV）的基团;条件是在式（I）的各个反复单元中，基团B，R，R 1和R 2各自具有相同或不同的含义，可用作有机材料的光稳定剂，热稳定剂和氧化稳定剂，特别是合成聚合物。

3. 发明授权

US06046304A Block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials 失效
标题翻译：含有2,2,6,6-四甲基-4-哌啶基的嵌段低聚物作为有机材料的稳定剂
公开(公告)号：US06046304A
公开(公告)日：2000-04-04
申请号：US756225
申请日：1996-11-25
申请人： Valerio Borzatta , Fabrizio Guizzardi
发明人： Valerio Borzatta , Fabrizio Guizzardi
IPC分类号： C08K5/3477 , C07D20060101 , C07D401/14 , C08G73/02 , C08G73/06 , C08K20060101 , C08K5/3432 , C08K5/3492 , C08L79/00 , C08L79/02 , C08L79/04 , C07D403/00 , C07D403/12
CPC分类号： C07D401/14 , C08K5/34926
摘要： Compounds of the formula (I) ##STR1## in which the polydispersity Mw/Mn is 1; n is 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14 or 15; the radicals R.sub.1 are for example hydrogen or C.sub.1 -C.sub.8 alkyl; R.sub.2 is for example C.sub.2 -C.sub.12 alkylene; the radicals A are independently of one another --OR.sub.3, --N(R.sub.4)(R.sub.5) or a group of the formula ##STR2## R.sub.3, R.sub.4 and R.sub.5, which are identical or different, are for example hydrogen or C.sub.1 -C.sub.18 alkyl,or --N(R.sub.4)(R.sub.5) is additionally a group of the formula ##STR3## with Y being --O--, --CH.sub.2 --, --CH.sub.2 CH.sub.2 -- or >N--CH.sub.3 ; X is --O-- or >N--R.sub.6 ; R.sub.6 is for example hydrogen or C.sub.1 -C.sub.18 alkyl; R is preferably a group of the formula ##STR4## and the radicals B have independently of one another one of the definitions given for A; with the proviso that in the individual recurrent units of the formula (I), each of the radicals B, R, R.sub.1 and R.sub.2 has the same or a different meaning.The indicated compounds are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.
摘要翻译：其中多分散性+ E，ovs M + EE w / + E，ovs M + EE n为1的式（I）化合物; n为3，4，5，6，7，8，9，10，11，12，13，14或15; 基团R1是例如氢或C1-C8烷基; R2是例如C 2 -C 12亚烷基; 基团A彼此独立地为-OR3，-N（R4）（R5）或相同或不同的式R3，R4和R5的基团为例如氢或C1-C18烷基或-N（ R4）（R5）另外是下式的基团，其中Y是-O - ， - CH 2 - ， - CH 2 CH 2 - 或> N-CH 3; X是-O-或> N-R6; R6是例如氢或C1-C18烷基; R优选为式的基团，基团B彼此独立地为A给出的定义之一; 条件是在式（I）的各个反复单元中，基团B，R，R 1和R 2中的每一个具有相同或不同的含义。所指示的化合物可用作有机材料的光稳定剂，热稳定剂和氧化稳定剂，特别是合成聚合物。

4. 发明授权

US5449776A Piperidine-triazine compounds for use as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials 失效
标题翻译：用作光稳定剂的哌啶 - 三嗪化合物，用于有机材料的热稳定剂和氧化稳定剂
公开(公告)号：US5449776A
公开(公告)日：1995-09-12
申请号：US249004
申请日：1994-05-25
申请人： Graziano Vignali , Fabrizio Guizzardi , Graziano Zagnoni
发明人： Graziano Vignali , Fabrizio Guizzardi , Graziano Zagnoni
IPC分类号： C07D401/12 , C07D401/14 , C08K5/3492 , C09K15/30 , C07D403/12 , C07D403/14
CPC分类号： C07D401/14 , C08K5/34926
摘要： Novel piperidine compounds of the formula (I) are suitable for use as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials.The definitions of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, A and n in the formula (I) are given in the text. ##STR1##
摘要翻译：式（I）的新型哌啶化合物适用于有机材料的光稳定剂，热稳定剂和氧化稳定剂。式（I）中R1，R2，R3，R4，R5，A和n的定义在文中给出。（一）

5. 发明授权

US08603233B2 Inks for digital printing on ceramic materials, a process for digital printing on ceramic materials using said inks, and ceramic material obtained by means of said printing process 有权
标题翻译：用于陶瓷材料上的数字印刷的油墨，使用所述油墨的陶瓷材料上的数字印刷方法以及通过所述印刷方法获得的陶瓷材料
公开(公告)号：US08603233B2
公开(公告)日：2013-12-10
申请号：US12809094
申请日：2008-12-18
申请人： Graziano Vignali , Fabrizio Guizzardi , Elisa Canto , Iuri Bernardi , Michele Giorgi
发明人： Graziano Vignali , Fabrizio Guizzardi , Elisa Canto , Iuri Bernardi , Michele Giorgi
IPC分类号： C09D11/02
CPC分类号： C09D11/40 , B41M5/0047 , B41M5/007 , C04B33/34 , C04B41/009 , C04B41/5007 , C04B41/85 , C04B2111/80 , Y10T428/24926 , C04B33/00 , C04B41/4535 , C04B41/4572
摘要： The present invention relates to an ink set containing chromophoric metals for digital printing on ceramic materials additive-treated with silica and titanium dioxide, a process for decorating ceramic materials by digital printing using said ink set and decorated ceramic articles obtainable by said process.
摘要翻译：本发明涉及一种含有用于数字印刷的发色金属的油墨组，用于用二氧化硅和二氧化钛进行添加处理的陶瓷材料，通过使用所述油墨组和通过所述方法获得的装饰陶瓷制品来装饰陶瓷材料的方法。

6. 发明授权

US06297299B1 Block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials 有权
标题翻译：含有2,2,6,6-四甲基-4-哌啶基的嵌段低聚物作为有机材料的稳定剂
公开(公告)号：US06297299B1
公开(公告)日：2001-10-02
申请号：US09433468
申请日：1999-11-04
申请人： Valerio Borzatta , Fabrizio Guizzardi
发明人： Valerio Borzatta , Fabrizio Guizzardi
IPC分类号： C08J545
CPC分类号： C07D401/14 , C08K5/34926
摘要： Compounds of the formula (I) in which the polydispersity {overscore (M)}w/{overscore (M)}n is 1; n is 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14 or 15; the radicals R1 are for example hydrogen or C1-C8alkyl; R2 is for example C2-C12alkylene; the radicals A are independently of one another —OR3, —N(R4)(R5) or a group of the R3, R4 and R5, which are identical or different, are for example hydrogen or C1-C18alkyl, or —N(R4)(R5) is additionally a group of the formula with Y being —O—, —CH2—, —CH2CH2— or >N—CH3; X is —O— or >N—R6; R6 is for example hydrogen or C1-C18alkyl; R is preferably a group of the formula and the radicals B have independently of one another one of the definitions given for A; with the proviso that in the individual recurrent units of the formula (I), each of the radicals B, R, R1 and R2 has the same or a different meaning, are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.
摘要翻译：其中多分散性（超核（M）} w / {超核（M）} n为1的式（I）化合物; n为3，4，5，6，7，8，9，10，11，12，13，14或15; 基团R1是例如氢或C1-C8烷基; R2是例如C 2 -C 12亚烷基; 基团A彼此独立地为-OR3，-N（R4）（R5）或相同或不同的R 3，R 4和R 5的基团为例如氢或C 1 -C 18烷基或-N（R 4）（R5）另外是一个基团，Y是-O - ， - CH 2 - ， - CH 2 CH 2 - 或> N-CH 3; X是-O-或> N-R6; R6是例如氢或C1-C18烷基; R优选为下式的基团，基团B彼此独立地为A给出的定义之一; 条件是在式（I）的各个反复单元中，基团B，R，R 1和R 2各自具有相同或不同的含义，可用作有机材料的光稳定剂，热稳定剂和氧化稳定剂，特别是合成聚合物。

7. 发明授权

US5696261A Piperidine-triazine compounds suitable for use as stabilisers for organic materials 失效
标题翻译：适用于有机材料稳定剂的哌啶 - 三嗪化合物
公开(公告)号：US5696261A
公开(公告)日：1997-12-09
申请号：US555353
申请日：1995-11-08
申请人： Valerio Borzatta , Graziano Vignali , Fabrizio Guizzardi
发明人： Valerio Borzatta , Graziano Vignali , Fabrizio Guizzardi
IPC分类号： C07D401/12 , C07D401/14 , C07D493/10 , C08K5/3477 , C08K5/3492 , C09K15/30 , C07D251/40 , C07D251/14 , C07D251/48
CPC分类号： C07D401/14 , C08K5/34926 , C09K15/30
摘要： Novel piperidine-triazine compounds of the formula (Ia) and (Ib) suitable for use as light stabilisers, heat stabilisers and oxidation stabilisers for organic materials. The meanings of R.sub.1, R.sub.2, R.sub.3, G.sub.1, G.sub.2, L.sub.1, L.sub.2, m and n are defined in the text. ##STR1##
摘要翻译：适合用作光稳定剂的式（Ia）和（Ib）的新型哌啶 - 三嗪化合物，用于有机材料的热稳定剂和氧化稳定剂。在文中定义了R1，R2，R3，G1，G2，L1，L2，m和n的含义。（1a）（图）

8. 发明授权

US5652364A Process for the preparation of 2,2,6,6-tetramethyl-4-piperidyloxy-1,3,5-triazines with two or more triazine rings 失效
标题翻译：制备具有两个或更多个三嗪环的2,2,6,6-四甲基-4-哌啶氧基-1,3,5-三嗪的方法
公开(公告)号：US5652364A
公开(公告)日：1997-07-29
申请号：US514341
申请日：1995-08-10
申请人： Graziano Vignali , Fabrizio Guizzardi , Graziano Zagnoni , Roberto Scrima
发明人： Graziano Vignali , Fabrizio Guizzardi , Graziano Zagnoni , Roberto Scrima
IPC分类号： C07D401/14 , C08K5/3492 , C07D403/12 , C07D403/06 , C07D403/14
CPC分类号： C07D401/14 , C08K5/34926
摘要： Novel process for the preparation of 2,2,6,6-tetramethyl-4-piperidyloxy-1,3,5-triazines, based on the reaction of cyanuric chloride with C.sub.1 -C.sub.4 alkanols or with sodium or potassium C.sub.1 -C.sub.4 alkoxides and subsequent reaction with 2,2,6,6-tetramethyl-4-piperidinols in the presence of a transesterification catalyst.The various reactions can be carried out in the same reactor, without isolation of the intermediates. ##STR1##
摘要翻译：用于制备2,2,6,6-四甲基-4-哌啶氧基-1,3,5-三嗪的新方法，基于氰尿酰氯与C 1 -C 4烷醇或与C 1 -C 4烷基氧化钠或钾的反应，随后反应与2,2,6,6-四甲基-4-哌啶醇在酯交换催化剂存在下反应。各种反应可以在相同的反应器中进行，而不分离中间体。公式（I）

9. 发明授权

US07811508B2 Process for colouring ceramic materials 有权
标题翻译：陶瓷材料着色方法
公开(公告)号：US07811508B2
公开(公告)日：2010-10-12
申请号：US10584257
申请日：2004-12-22
申请人： Graziano Vignali , Fabrizio Guizzardi , Michele Giorgi
发明人： Graziano Vignali , Fabrizio Guizzardi , Michele Giorgi
IPC分类号： B28B1/00
CPC分类号： C04B33/14
摘要： The invention relates to a new process for coloring ceramic materials by using aqueous solutions of chromophore ions. In particular, certain types of silica are added to the ceramic mixes which are to be colored, after which aqueous or organic solutions comprising inorganic salts of Fe (II) and/or Fe (III), or organic derivatives of Fe (II) and/or Fe (III) are applied to the surface of the said additive-containing ceramic mixes.
摘要翻译：本发明涉及通过使用发色团离子的水溶液着色陶瓷材料的新方法。特别地，将某些类型的二氧化硅加入要着色的陶瓷混合物中，之后将含有Fe（II）和/或Fe（III）的无机盐或Fe（II）的有机衍生物和 /或Fe（III）施加到所述含添加剂的陶瓷混合物的表面。

10. 发明授权

US06607816B1 Formulations based on water soluble gold compounds suitable for coloring ceramic manufactured articles 失效
标题翻译：基于适用于着色陶瓷制品的水溶性金化合物的配方
公开(公告)号：US06607816B1
公开(公告)日：2003-08-19
申请号：US09763110
申请日：2001-02-16
申请人： Graziano Vignali , Fabrizio Guizzardi
发明人： Graziano Vignali , Fabrizio Guizzardi
IPC分类号： B32B306
CPC分类号： C04B41/5116 , C04B41/009 , C04B41/52 , C04B41/88 , C04B2111/82 , C04B33/00 , C04B41/4535 , C04B41/4554 , C04B41/4578 , C04B41/502 , C04B41/0072
摘要： Composition whereby ceramic manufactured articles are colored in shades from pink to violet, such composition includes of a monovalent gold thiolate water solution or mixture of water with a water soluble organic solvent according to the following formulas Au—S—R—X and Au—S—R—H, where R stands for a linear or branched bivalent radical of aliphatic or aromatic or cycloaliphatic or heterocyclic type optionally with substituents, such as for example aminic, amidic, hydroxylic, carboxylic, hydrocarbylic or carbonylic groups or CONH—, in the chain; X stands for a monovalent group selected out of —COOH, SO2OH, —OH, —CONH2, —NH2; O—P(O)(OH)2, in which H atoms may be replaced by alkyl groups and wherein acid group may be salified with amines or alkaline or alkaline earth metals and basic groups may optionally be salified with organic acids
摘要翻译：由陶瓷制品以粉红色至紫色着色的组合物，根据下列公式Au-SRX和Au-SRH，该组合物包括一价金硫醇盐水溶液或水与水溶性有机溶剂的混合物，其中R为对于链中任选具有取代基，例如氨基，酰胺基，羟基，羧基，烃基或羰基或CONH-的脂族或芳族或脂环族或杂环类型的直链或支链二价基团; X代表选自-COOH，SO 2 OH，-OH，-CONH 2，-NH 2的一价基团; O-P（O）（OH）2，其中H原子可以被烷基取代，并且其中酸基团可以用胺或碱金属或碱土金属盐化，碱性基团可任选地用有机酸盐化

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