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91. 发明授权

US06759560B2 Method for producing alkali methylates 有权
标题翻译：碱甲酯的制备方法
公开(公告)号：US06759560B2
公开(公告)日：2004-07-06
申请号：US10148929
申请日：2002-06-05
申请人： Josef Guth , Holger Friedrich , Hans-Josef Sterzel , Gerd Kaibel , Kirsten Burkart , Elke Hoffmann
发明人： Josef Guth , Holger Friedrich , Hans-Josef Sterzel , Gerd Kaibel , Kirsten Burkart , Elke Hoffmann
IPC分类号： C07C3130
CPC分类号： B01D3/141 , B01D1/2856 , C07C29/70 , C07C31/30
摘要： Alkali metal methoxides are prepared from aqueous alkali metal hydroxide, which may have been admixed with methanol, and methanol in a reaction column having at least 5, preferably from 15 to 30, theoretical plates between the feed point for the aqueous alkali metal hydroxide and the feed point for the methanol. The gaseous methanol/water mixture formed in the reaction is fractionated in a rectification column. In one variant of the invention, the trays chosen for the reaction column configured as a bubble cap tray, valve tray or sieve tray column are trays in which not more than 5%, preferably
摘要翻译：碱金属甲醇盐由碱金属氢氧化物水溶液制成，碱金属氢氧化物可与甲醇混合，甲醇在反应塔中具有至少5个，优选15至30个理论塔板的碱金属氢氧化物水溶液和甲醇的进料点。在反应中形成的气态甲醇/水混合物在精馏塔中分馏。在本发明的一个变体中，为构成气泡盖，阀盘或筛板塔的反应塔选择的塔板是不在其中的托盘超过5％，优选<1％的液体通过相应的托盘。在本发明方法的另一变型中，双壁反应塔的双壁温度为3至10℃ 高于柱内部温度，并且具有随机或有序填料，其中液体流量与蒸气流量的平均比率在塔的所有子区域中不超过15％以上，优选不超过3％截面对应于总柱横截面的2％以上。

92. 发明授权

US06521767B1 Method for suspension hydrogenation of an anthraquinone compound in a special reactor in order to produce hydrogen peroxide 失效
标题翻译：用于制备过氧化氢的专用反应器中的蒽醌化合物的悬浮氢化
公开(公告)号：US06521767B1
公开(公告)日：2003-02-18
申请号：US09622852
申请日：2000-08-28
申请人： Arnd Böttcher , Jochem Henkelmann , Franz Josef Bröcker , Gerd Kaibel , Heinz Rütter
发明人： Arnd Böttcher , Jochem Henkelmann , Franz Josef Bröcker , Gerd Kaibel , Heinz Rütter
IPC分类号： C07J5300
CPC分类号： B01J8/0015 , B01J8/007 , B01J8/06 , B01J8/067 , B01J8/1863 , B01J8/20 , B01J8/22 , B01J8/228 , B01J8/34 , B01J19/2425 , B01J19/2465 , B01J2208/00212 , B01J2219/00103 , B01J2219/185 , B01J2219/1943 , B01J2219/32286 , B01J2219/32416 , C01B15/023 , C07C37/07 , C07C2602/24 , C07C39/12
摘要： In a process for the suspension hydrogenation of an anthraquinone compound or a mixture of two or more thereof in a reactor in which there are present the working solution in which at least one catalyst is suspended and, in addition, a hydrogen-containing gas phase, the working solution and the gas phase are, in the reactor, passed at least partly through a fitting having openings or channels whose hydraulic diameter is from 0.5 to 20 mm, preferably from 1 to 10 mm, particularly preferably from 1 to 3 mm.
摘要翻译：在其中存在悬浮至少一种催化剂的工作溶液的反应器中的蒽醌化合物或其两种或更多种的混合物的悬浮氢化方法中，另外，含氢气相，反应器中的工作溶液和气相至少部分地通过具有水力直径为0.5至20mm，优选为1至10mm，特别优选为1至3mm的开口或通道的配件。

93. 发明授权

US06511053B2 Packing for heat-exchange and mass-transfer columns 失效
公开(公告)号：US06511053B2
公开(公告)日：2003-01-28
申请号：US09888610
申请日：2001-06-26
申请人： Gerd Kaibel , Achim Stammer , Manfred Stroezel
发明人： Gerd Kaibel , Achim Stammer , Manfred Stroezel
IPC分类号： B01F304
CPC分类号： B01J19/32 , B01J2219/3221 , B01J2219/32213 , B01J2219/32237 , B01J2219/32262 , B01J2219/32408 , Y10S261/72
摘要： The invention relates to a packing sheet having straight-line kinks which divide the packing sheet into kink areas which have a width a, measured from kink edge to kink edge, and passage apertures, where a proportion X of at least 60% of the passage apertures has a separation b of at most 0.4 a from a kink edge.

94. 发明授权

US06307106B1 Process for preparing unsaturated ketones 失效
标题翻译：制备不饱和酮的方法
公开(公告)号：US06307106B1
公开(公告)日：2001-10-23
申请号：US09440280
申请日：1999-11-15
申请人： Carsten Oost , Manfred Stroezel , Heinz Etzrodt , Dietmar Weller , Gerd Kaibel , Hagen Jaedicke
发明人： Carsten Oost , Manfred Stroezel , Heinz Etzrodt , Dietmar Weller , Gerd Kaibel , Hagen Jaedicke
IPC分类号： C07C4500
CPC分类号： C07C45/68 , B01J19/1881 , B01J31/0211 , B01J2219/00038 , Y02P20/582 , C07C49/203
摘要： An improved process for preparing lower unsaturated ketones by reacting the corresponding &agr;,&bgr;-unsaturated alcohols with alkyl acetoacetates in a Carroll reaction in the presence of from 0.1 to 5 mol %, based on the alkyl acetoacetate to be reacted, of an organic aluminum compound as catalyst with elimination and continuous removal by distillation of the alkanol eliminated during the reaction from the alkyl acetoacetate in a reactor system with a fitted fractionation column, wherein A an &agr;,&bgr;-unsaturated alcohol which boils below 140° C. is introduced, in the absence of effective amounts of a solvent, together with the organic aluminum compound into the reaction vessel, B a reaction temperature which is as constant as possible between 170° C. and 250° C. is set under elevated pressure, C at this temperature, the alkyl acetoacetate is metered into the mixture, obtained in A, of the &agr;,&bgr;-unsaturated alcohol and the organic aluminum compound, and D during the reaction the content of alkyl acetoacetate in the reaction mixture is set at a value which is as constant as possible between 0.1 and 10% by weight.
摘要翻译：一种改进的制备低级不饱和酮的方法，该方法通过在卡罗尔反应中使相应的α，β-不饱和醇与烷基乙酰乙酸酯在0.1至5摩尔％存在下反应的待反应的乙酰乙酸烷基酯的有机铝化合物作为催化剂，在具有适合的分馏塔的反应器系统中通过蒸馏从乙酰乙酸烷基酯反应中消除的烷醇消除并连续除去，其中引入沸点低于140℃的α，β-不饱和醇，在没有有效量的溶剂与有机铝化合物一起进入反应容器B中，在170℃和250℃之间的反应温度一直保持在升高的压力下，在此温度下，将乙酰乙酸烷基酯计量加入到A，得自α，β-不饱和醇和有机铝化合物的混合物中，并且在反应期间将D 将反应混合物中乙酰乙酸烷基酯的含量设定为0.1至10重量％之间尽可能恒定的值。

95. 发明授权

US5965751A Process for hydrogenation of dihydrofurans to give tetrahydrofurans 失效
标题翻译：二氢呋喃氢化制得四氢呋喃的方法
公开(公告)号：US5965751A
公开(公告)日：1999-10-12
申请号：US68978
申请日：1998-05-22
申请人： Franz Josef Brocker , Rolf Fischer , Gerd Kaibel , Rolf Pinkos
发明人： Franz Josef Brocker , Rolf Fischer , Gerd Kaibel , Rolf Pinkos
IPC分类号： B01J37/02 , C07D307/08 , C23C14/16 , B01J23/44
CPC分类号： C07D307/08 , B01J37/0225 , B01J37/0238 , C23C14/16
摘要： In a process for the catalytic hydrogenation of 2,5- and 2,3-dihydrofuran with hydrogen to give tetrahydrofuran, use is made of a catalyst in which a metal or a plurality of metals have been deposited by vapor deposition or sputtering on a metal wire mesh or a metal foil as support.
摘要翻译： PCT No.PCT / EP96 / 05071 Sec。 371日期：1998年5月22日 102（e）日期1998年5月22日PCT 1996年11月18日PCT公布。第WO97 / 19939号公报日期：1997年6月5日在用氢气将2,5-和2,3-二氢呋喃催化氢化得到四氢呋喃的方法中，使用其中通过气相沉积沉积金属或多种金属的催化剂或溅射在金属丝网或金属箔上作为载体。

96. 发明授权

US4517391A Continuous preparation of ethanol 失效
标题翻译：连续制备乙醇
公开(公告)号：US4517391A
公开(公告)日：1985-05-14
申请号：US496573
申请日：1983-05-20
申请人： Schuster, Ludwig , Franz-Josef Mueller , Axel Anderlohr , Peter Blei , Gerhart Eigenberger , Bernd Hoppner , Gerd Kaibel , Wolfgang Steiner
发明人： Schuster, Ludwig , Franz-Josef Mueller , Axel Anderlohr , Peter Blei , Gerhart Eigenberger , Bernd Hoppner , Gerd Kaibel , Wolfgang Steiner
IPC分类号： C07C29/149 , C07C29/136 , C07C31/08
CPC分类号： C07C29/149
摘要： Ethanol is prepared by hydrogenating acetic acid under superatmospheric pressure and at elevated temperatures by a process wherein a predominantly cobalt-containing catalyst is used and acetic acid and hydrogen are passed through the reactor, at from 210.degree. to 330.degree. C. and under from 10 to 350 bar, under conditions such that a liquid phase in not formed during this procedure.
摘要翻译：乙醇通过在超大气压下和升高的温度下通过使用主要含钴催化剂并且使乙酸和氢气通过反应器的方法在210至330℃和10以下的方法制备乙酸至350巴，条件是在此过程中未形成液相。

97. 发明授权

US4399001A Separating off organic iodine compounds from acetaldehyde-free carbonylation products of methanol, methyl acetate and dimethyl ether 失效
标题翻译：将有机碘化合物从甲醇，乙酸甲酯和二甲醚的无乙醛羰基化产物中分离出来
公开(公告)号：US4399001A
公开(公告)日：1983-08-16
申请号：US315726
申请日：1981-10-28
申请人： Horst Hartmann , Waldhelm Hochstein , Gerd Kaibel , Franz-Josef Mueller
发明人： Horst Hartmann , Waldhelm Hochstein , Gerd Kaibel , Franz-Josef Mueller
IPC分类号： C07C27/00 , C07C27/30 , C07C51/46 , C07C51/573 , C07C67/00 , B01D3/36
CPC分类号： C07C51/573 , C07C51/46 , C07C67/54
摘要： A process for separating off organic iodine compounds from acetaldehyde-free carbonylation products of methanol, methyl acetate and dimethyl ether by removing the iodine compounds by azeotropic distillation with a hydrocarbon having a boiling point, under atmospheric pressure, of 25-55.degree. C.
摘要翻译：通过用沸点在25-55℃的大气压下共沸蒸馏除去碘化合物，分离有机碘化合物与甲醇，乙酸甲酯和二甲醚的无乙醛羰基化产物的方法。

98. 发明授权

US4310705A Preparation of higher unsaturated ketones 失效
标题翻译：制备较高级的不饱和酮
公开(公告)号：US4310705A
公开(公告)日：1982-01-12
申请号：US163401
申请日：1980-06-26
申请人： Axel Nissen , Gerd Kaibel , Otto Woerz , Lothar Arnold , Manfred Braun , Walter Rebafka
发明人： Axel Nissen , Gerd Kaibel , Otto Woerz , Lothar Arnold , Manfred Braun , Walter Rebafka
IPC分类号： C07C49/20 , B01J31/14 , C07C45/00 , C07C45/67 , C07C45/68 , C07C67/00 , C07C45/48
CPC分类号： C07C45/676
摘要： An improved process for the preparation of higher unsaturated ketones, such as geranylacetone and farnesylacetone, by reacting a .beta.,.gamma.-unsaturated alcohol and an alkyl acetoacetate at an elevated temperature in the presence of an organic aluminum compound, with elimination, and removal, of the alcohol derived from the alkyl acetoacetate in a reactor system carrying a fractionating column. The improvement in the purity, yield, and especially space-time yield of the product is achieved by starting from an alcohol having a higher boiling point than that of the alkyl acetoacetate used, carrying out the reaction in the presence of a small amount of an inert liquid which has a boiling point between that of the alkyl acetoacetate and the alcohol to be eliminated therefrom, and ensuring that the temperature at the bottom of the fractionating column is only slightly higher than the boiling point of the added liquid, under the prevailing pressure.
摘要翻译：通过在有机铝化合物的存在下在升高的温度下使β，γ-不饱和醇和乙酰乙酸烷基酯反应来制备高级不饱和酮，如香叶基丙酮和法呢基丙酮的改进方法，消除和除去在含有分馏塔的反应器系统中衍生自乙酰乙酸烷基酯的醇。通过从具有比所用乙酰乙酸烷基酯的沸点高的醇开始的醇开始，在少量的存在下进行反应来实现产物的纯度，产率和特别的时空产率的改善沸点在乙酰乙酸烷基酯和被除去的醇之间的沸点的惰性液体，并且确保分馏塔底部的温度仅略高于添加液体的沸点，在主要压力下。

99. 发明授权

US4262140A Production of anhydrous or substantially anhydrous formic acid 失效
标题翻译：生产无水或基本无水的甲酸
公开(公告)号：US4262140A
公开(公告)日：1981-04-14
申请号：US99760
申请日：1979-12-03
申请人： Kaspar Bott , Gerd Kaibel , Herwig Hoffmann , Otto Kratzer , Rudolf Irnich
发明人： Kaspar Bott , Gerd Kaibel , Herwig Hoffmann , Otto Kratzer , Rudolf Irnich
IPC分类号： C07C53/02 , C07C51/00 , C07C51/09 , C07C51/44 , C07C51/48 , C07C67/00 , B01D3/34
CPC分类号： C07C51/44 , C07C51/09 , C07C51/48
摘要： A process for the production of anhydrous or substantially anhydrous formic acid by hydrolysis of methyl formate which is carried out in a column having an upper fractionating section, a middle hydrolysis section and a lower extraction section and in which(a) the hydrolysis is carried out in the middle section of the columm, with water and methyl formate in countercurrent,(b) the resulting formic acid is extracted, in the lower section of the column, by means of a carboxylic acid amide which is fed into the lower end of the middle section of the column,(c) the extract phase, consisting in the main of formic acid and the carboxylic acid amide, is distillatively dehydrated, or substantially dehydrated, in the lower section of the column,(d) the methanol and uncovered methyl formate are removed by fractional distillation in the upper section of the column and(e) the pure formic acid or concentrated aqueous formic acid is distilled from the anhydrous or substantially anhydrous extract phase in a second column, leaving the carboxylic acid amide.
摘要翻译：一种通过水解甲酸甲酯生产无水或基本上无水的甲酸的方法，该甲酸甲酯在具有上部分馏段，中间水解段和下部萃取段的塔中进行，其中（a）进行水解在水的中间部分，与水和甲酸甲酯逆流，（b）所得甲酸在柱的下部通过羧酸酰胺萃取，该羧酸酰胺进料到塔的中间部分，（c）主要由甲酸和羧酸酰胺组成的提取相在塔的下部进行蒸馏脱水或基本上脱水，（d）甲醇和未被覆盖的甲基甲酸盐在塔的上部通过分馏除去，（e）从无水或基本上无水的提取物中蒸馏出纯甲酸或浓缩的甲酸水溶液相在第二塔中，留下羧酸酰胺。

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