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1. 发明授权

US5965751A Process for hydrogenation of dihydrofurans to give tetrahydrofurans 失效
标题翻译：二氢呋喃氢化制得四氢呋喃的方法
公开(公告)号：US5965751A
公开(公告)日：1999-10-12
申请号：US68978
申请日：1998-05-22
申请人： Franz Josef Brocker , Rolf Fischer , Gerd Kaibel , Rolf Pinkos
发明人： Franz Josef Brocker , Rolf Fischer , Gerd Kaibel , Rolf Pinkos
IPC分类号： B01J37/02 , C07D307/08 , C23C14/16 , B01J23/44
CPC分类号： C07D307/08 , B01J37/0225 , B01J37/0238 , C23C14/16
摘要： In a process for the catalytic hydrogenation of 2,5- and 2,3-dihydrofuran with hydrogen to give tetrahydrofuran, use is made of a catalyst in which a metal or a plurality of metals have been deposited by vapor deposition or sputtering on a metal wire mesh or a metal foil as support.
摘要翻译： PCT No.PCT / EP96 / 05071 Sec。 371日期：1998年5月22日 102（e）日期1998年5月22日PCT 1996年11月18日PCT公布。第WO97 / 19939号公报日期：1997年6月5日在用氢气将2,5-和2,3-二氢呋喃催化氢化得到四氢呋喃的方法中，使用其中通过气相沉积沉积金属或多种金属的催化剂或溅射在金属丝网或金属箔上作为载体。

2. 发明授权

US5939589A Process and reactor for carrying out conversion with catalysts suspended in liquids 失效
标题翻译：用于悬浮在液体中的催化剂进行转化的工艺和反应器
公开(公告)号：US5939589A
公开(公告)日：1999-08-17
申请号：US820001
申请日：1997-03-18
申请人： Gerd Kaibel , Franz Josef Brocker , Manfred Stroezel
发明人： Gerd Kaibel , Franz Josef Brocker , Manfred Stroezel
IPC分类号： B01F5/06 , B01J8/00 , B01J8/06 , B01J8/18 , B01J8/20 , B01J8/22 , B01J8/34 , C07C45/62 , C07C49/00
CPC分类号： C07C45/62 , B01J8/0015 , B01J8/007 , B01J8/06 , B01J8/1863 , B01J8/20 , B01J8/22 , B01J8/34
摘要： Catalytic reactions are carried out in a reactor which contains a liquid phase in which at least one catalyst is suspended, and which may additionally contain a gas phase, by a process in which the liquid phase and, if present, also the gas phase are fed, at least partly, through an apparatus having orifices or channels in the reactor, the hydraulic diameter of which orifices or channels is from 0.5 to 20 mm, preferably from 1 to 10 mm, particularly preferably from 1 to 3 mm.
摘要翻译：催化反应在包含液相的反应器中进行，其中至少一种催化剂悬浮在其中，并且其可以另外含有气相，通过其中液相和（如果存在的话）气相被加料的方法至少部分地通过具有反应器中的孔或通道的装置，其孔径或通道的水力直径为0.5至20mm，优选为1至10mm，特别优选为1至3mm。

3. 发明授权

US6150564A Selective liquid-phase hydrogenation of .alpha.,.beta.-unsaturated carbonyl compounds 失效
标题翻译： α，β-不饱和羰基化合物的选择性液相氢化
公开(公告)号：US6150564A
公开(公告)日：2000-11-21
申请号：US275867
申请日：1999-03-25
申请人： Franz Josef Brocker , Gerd Kaibel , Werner Aquila , Hartwig Fuchs , Gunter Wegner , Manfred Stroezel
发明人： Franz Josef Brocker , Gerd Kaibel , Werner Aquila , Hartwig Fuchs , Gunter Wegner , Manfred Stroezel
IPC分类号： B01J23/44 , B01J8/20 , B01J8/22 , B01J19/24 , B01J23/46 , C07B61/00 , C07C45/62 , C07C49/04
CPC分类号： C07C45/62 , B01J19/2465 , B01J19/2495 , B01J8/20 , B01J8/22 , B01J2219/00103 , B01J2219/0011 , B01J2219/32
摘要： The invention relates to a process for the selective liquid-phase hydrogenation of .alpha.,.beta.-unsaturated carbonyl compounds of the formula I, ##STR1## where R.sub.1 is hydrogen or an organic radical, and R.sub.2, R.sub.3 and R.sub.4, independently of one another, are hydrogen or a C.sub.1 -- to C.sub.4 --alkyl group, to saturated carbonyl compounds of the formula II ##STR2## using hydrogen in the presence of a pulverulent palladium and/or rhodium catalyst and in the presence of an organic base. The process is carried out in a packed bubble column reactor (1, 2) with product recycling (11, 17) and circulating hydrogen gas (4, 15, 16). It is particularly suitable for the selective hydrogenation of citral to citronellal.
摘要翻译：本发明涉及用于式I的α，β-不饱和羰基化合物的选择性液相氢化的方法，其中R 1是氢或有机基团，并且R 2，R 3和R 4彼此独立地是氢或使用氢气在粉状钯和/或铑催化剂存在下并在有机碱的存在下，使C1至C4烷基与饱和的式II化合物反应。该方法在具有产品再循环（11,17）和循环氢气（4,15,16）的包装泡罩塔反应器（1,2）中进行。它特别适用于柠檬醛对香茅醛的选择性氢化。

4. 发明授权

US06002027A Preparation of 1,2-butylene oxide 失效
标题翻译： 1,2-环氧丁烷的制备
公开(公告)号：US06002027A
公开(公告)日：1999-12-14
申请号：US46124
申请日：1998-03-23
申请人： Christoph Sigwart , Franz Josef Brocker , Rolf Fischer , Peter Lingelbach
发明人： Christoph Sigwart , Franz Josef Brocker , Rolf Fischer , Peter Lingelbach
IPC分类号： B01J23/44 , B01J23/46 , B01J23/52 , B01J23/62 , B01J23/63 , B01J37/02 , B01J37/34 , C07D301/00 , C07D303/04 , C07D301/02 , C07C5/03
CPC分类号： B01J37/347 , B01J37/0225 , C07D301/00 , B01J23/44 , B01J23/464 , B01J23/52
摘要： A process for preparing 1,2-butylene oxide by catalytic hydrogenation of vinyloxirane over a heterogeneous catalyst comprises using a catalyst comprising an element of subgroup I, VII or VIII of the periodic table, or mixtures of a plurality of these elements, in the presence or absence of one or more promoter elements, these elements and promoters having been applied by means of a vacuum vapor deposition technique to a support of metal foil or metal wire fabric.
摘要翻译：通过在非均相催化剂上催化氢化乙烯环氧乙烷来制备1,2-环氧丁烷的方法包括使用包含元素周期表第I，VII或VIII族元素或多种这些元素的混合物的催化剂，或不存在一种或多种促进剂元件，这些元素和助催化剂已经通过真空气相沉积技术施加到金属箔或金属丝织物的载体上。

5. 发明授权

US5869707A Preparation of 1,2-butylene oxide 失效
标题翻译： 1,2-环氧丁烷的制备
公开(公告)号：US5869707A
公开(公告)日：1999-02-09
申请号：US704733
申请日：1996-09-09
申请人： Christoph Sigwart , Franz Josef Brocker , Rolf Fischer , Peter Lingelbach
发明人： Christoph Sigwart , Franz Josef Brocker , Rolf Fischer , Peter Lingelbach
IPC分类号： B01J23/44 , B01J23/46 , B01J23/52 , B01J23/62 , B01J23/63 , B01J37/02 , B01J37/34 , C07D301/00 , C07D303/04 , C07D301/02
CPC分类号： B01J37/347 , B01J37/0225 , C07D301/00 , B01J23/44 , B01J23/464 , B01J23/52
摘要： A process for preparing 1,2-butylene oxide by catalytic hydrogenation of vinyloxirane over a heterogeneous catalyst comprises using a catalyst comprising an element of subgroup I, VII or VIII of the periodic table, or mixtures of a plurality of these elements, in the presence or absence of one or more promoter elements, these elements and promoters having been applied by means of a vacuum vapor deposition technique to a support of metal foil or metal wire fabric.
摘要翻译： PCT No.PCT / EP95 / 00656 Sec。 371日期1996年9月9日 102（e）日期1996年9月9日PCT提交1995年2月23日PCT公布。 WO95 / 24401 PCT出版物日期1995年9月14日一种通过在非均相催化剂上催化氢化乙烯环氧化物制备1,2-环氧丁烷的方法包括使用包含元素周期表中I族，VII或VIII族元素的催化剂，或多种这些的混合物元素，在存在或不存在一种或多种助催化剂元素的情况下，这些元素和促进剂已经通过真空气相沉积技术施加到金属箔或金属丝织物的载体上。

6. 发明授权

US6106797A Gauze catalyst based on titanium or vanadium zeolites and inert gauze fabrics for accelerating oxidation reactions 失效
标题翻译：基于钛或钒沸石和惰性纱布织物的纱布催化剂，用于加速氧化反应
公开(公告)号：US6106797A
公开(公告)日：2000-08-22
申请号：US117293
申请日：1998-08-26
申请人： Ulrich Muller , Franz Josef Brocker , Georg Heinrich Grosch , Hermann Putter , Michael Schulz , Norbert Rieber , Wolfgang Harder
发明人： Ulrich Muller , Franz Josef Brocker , Georg Heinrich Grosch , Hermann Putter , Michael Schulz , Norbert Rieber , Wolfgang Harder
IPC分类号： B01J29/04 , B01J29/89 , B01J35/04 , B01J35/06 , B01J37/02 , C01B15/029 , C01B21/14 , C07D301/12
CPC分类号： B01J29/04 , B01J29/89 , C01B15/029 , C01B21/1436 , C01B21/1454 , C07D301/12 , B01J35/04 , B01J37/0246
摘要： The present invention relates to a gauze catalyst based on titanium or vanadium zeolites and inert gauze fabrics which is suitable for accelerating oxidation reactions such as epoxidation of olefins, hydrogen peroxide production or hydroxylamine synthesis.
摘要翻译： PCT No.PCT / EP97 / 00804 Sec。 371日期：1998年8月26日 102（e）日期1998年8月26日PCT 1997年2月20日PCT PCT。出版物WO97 / 31711 日期1997年9月4日本发明涉及一种基于钛或钒沸石和惰性纱布织物的纱布催化剂，其适用于加速氧化反应，例如烯烃的环氧化，过氧化氢生产或羟胺合成。

7. 发明授权

US5935897A Monomodal and polymodal catalyst supports and catalysts having narrow pore size distributions and their production 失效
标题翻译：单峰和多模式催化剂载体和具有窄孔径分布及其生产的催化剂
公开(公告)号：US5935897A
公开(公告)日：1999-08-10
申请号：US711043
申请日：1996-09-10
申请人： Peter Trubenbach , Alfred Hagemeyer , Gunter Lauth , Uwe Dingerdissen , Franz Josef Brocker , Klemens Flick
发明人： Peter Trubenbach , Alfred Hagemeyer , Gunter Lauth , Uwe Dingerdissen , Franz Josef Brocker , Klemens Flick
IPC分类号： C12N11/14 , B01D53/86 , B01D53/94 , B01J21/00 , B01J21/04 , B01J21/06 , B01J23/00 , B01J23/10 , B01J27/00 , B01J27/224 , B01J27/24 , B01J29/00 , B01J35/10 , B01J37/00 , B01J37/08 , C01B7/04 , C07B61/00 , C07C5/333 , C07C5/48 , C07C15/46 , C07C37/06 , C07C37/07 , C07C39/06 , C07D203/00
CPC分类号： B01J27/224 , B01J27/24 , B01J35/10 , B01J37/0018 , C01B7/04 , C07C37/07 , C07C5/48 , B01D2255/2022 , B01D2255/2027 , B01D2255/20738 , B01D2255/20761 , B01D2255/9205 , B01D2255/9207 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/108 , B01J35/109 , C07C2531/06
摘要： Monomodal or polymodal catalyst supports or catalysts having a BET specific surface area of from 0.01 to 250 m.sup.2 /g and a monomodal or polymodal pore size distribution having a mean pore diameter of from 50 to 300,000 nm measured by the mercury pressure porosimetry method, whereina) from 10 to 95% of the pore volume is at from 0.2 to 100 times the mean pore diameter and/orb) from 10 to 80% of the pore volume is at from 0.8 to 100 times the mean pore diameter and/orc) from 50 to 95% of the pore volume is at from 0.2 to 1 times the mean pore diameter and/ord) from 50 to 80% of the pore volume is at from 0.8 to 1 times the mean pore diameter ande) the width at half height of the pore size distribution is less than 0.6 times the mean pore diameter, whichare useful for the preparation of chlorine from hydrogen chloride in a non-steady-state Deacon process, for the reaction of ethylbenzene to give styrene in a non-steady-state oxydehydrogenation, for preparing aziridine from ethanolamine, in reductions, hydrogenations, oxidations, dehydrogenations, acid- or base-catalyzed reactions or reactions in a fluidized bed, for removing combustion residues from diesel exhaust gases and for removing NO.sub.x from waste gases, in bioreactors together with bacteria and as biocatalyst supports with immobilized enzymes or microbes, and a process for producing said monomodal or polymodal catalyst support or catalyst.
摘要翻译：单峰或多模式催化剂载体或BET比表面积为0.01至250m 2 / g的催化剂载体和通过汞压孔隙度法测量的平均孔径为50至300,000nm的单峰或多模孔径分布，其中a ）孔体积的10至95％为平均孔径的0.2至100倍和/或b）孔体积的10至80％为平均孔径的0.8至100倍和/或c ）孔体积的50至95％为平均孔径的0.2至1倍，和/或d）孔体积的50至80％为平均孔径的0.8至1倍，e）孔径分布的半高宽度小于平均孔径的0.6倍，这可用于在非稳态Deacon方法中从氯化氢制备氯，以使乙苯在苯乙烯中反应非稳态氧化脱氢，用于从乙醇胺制备氮丙啶在生物反应器中与细菌一起减少，氢化，氧化，脱氢，酸或碱催化的反应或在流化床中的反应，用于从柴油废气中除去燃烧残余物和从废气中除去NOx，并且作为生物催化剂载体，固定化酶或微生物，以及用于生产所述单峰或多模式催化剂载体或催化剂的方法。

8. 发明授权

US5750806A Preparation of alkenes by partial hydrogenation of alkynes over fixed-bed palladium catalysts 失效
标题翻译：通过固定床钯催化剂部分氢化制备烯烃
公开(公告)号：US5750806A
公开(公告)日：1998-05-12
申请号：US679118
申请日：1996-07-12
申请人： Franz Josef Brocker , Manfred Stroezel , Udo Rheude
发明人： Franz Josef Brocker , Manfred Stroezel , Udo Rheude
IPC分类号： B01J23/44 , B01J35/06 , B01J37/02 , C07B61/00 , C07C5/08 , C07C5/09 , C07C11/02 , C07C29/17 , C07C33/02
CPC分类号： B01J37/0238 , B01J23/44 , C07C5/09 , B01J37/0225 , C07C2523/44
摘要： Alkenes are prepared by partial hydrogenation of alkynes in the liquid phase over palladium catalysts by a process which comprises A. using a fixed-bed catalyst which is obtainable by heating the preferably metallic carrier in the air, cooling, coating under reduced pressure with metallic palladium, suitable molding and processing to a monolithic catalyst elements and B. adding from 10 to 180 ppm of CO to the hydrogen used for the hydrogenation.
摘要翻译：烯烃通过钯催化剂的液相中炔烃的部分氢化制备，该方法包括A.使用固定床催化剂，其可通过在空气中加热优选金属载体而获得，冷却，用金属钯在减压下涂覆，适合于整体催化剂元件的模塑和加工，以及将B加入到用于氢化的氢气中的10至180ppm的CO。

9. 发明授权

US5866734A Hydrogenation process 失效
标题翻译：氢化过程
公开(公告)号：US5866734A
公开(公告)日：1999-02-02
申请号：US923899
申请日：1997-09-04
申请人： Klemens Flick , Cristina Freire Erdbrugger , Franz Josef Brocker , Gerald Meyer , Ekkehard Schwab , Christof Herion
发明人： Klemens Flick , Cristina Freire Erdbrugger , Franz Josef Brocker , Gerald Meyer , Ekkehard Schwab , Christof Herion
IPC分类号： B01J23/56 , B01J23/38 , B01J23/44 , B01J23/50 , B01J23/60 , B01J23/62 , B01J35/06 , B01J37/02 , C07B61/00 , C07C5/05 , C07C5/09 , C07C7/163 , C07C11/02 , C07C11/06 , C07C11/08 , C07C5/02 , C07C7/167
CPC分类号： B01J23/38 , B01J35/06 , C07C7/163 , B01J23/44 , B01J23/50 , B01J23/60 , B01J23/624 , B01J37/0238 , Y02P20/127
摘要： In a process for the hydrogenation of multiply unsaturated C.sub.2 -C.sub.8 hydrocarbons, in particular C.sub.2 -C.sub.8 -alkynes and/or C.sub.4 -C.sub.8 -alkynenes and/or C.sub.4 -C.sub.8 -alkadienes in fluids comprising these by contact with a catalyst packing in the presence of free hydrogen, the catalyst packing can be produced by applying at least one substance which is active as catalyst and/or promoter to woven or knitted meshes or foils as support material.
摘要翻译：在包含这些物质的流体中，通过在存在下与催化剂填料接触来氢化多不饱和C2-C8烃，特别是C2-C8-炔烃和/或C4-C8-炔烃和/或C4-C8-炔二烯的方法的游离氢气，催化剂填料可以通过将作为催化剂和/或助催化剂的至少一种物质作为载体材料施加到机织或针织网或箔上来制备。

10. 发明授权

US5817891A Preparation of alkylphenols 失效
标题翻译：烷基酚的制备
公开(公告)号：US5817891A
公开(公告)日：1998-10-06
申请号：US715830
申请日：1996-09-19
申请人： Franz Josef Brocker , Peter Trubenbach , Manfred Baumann , Jurgen Schubert
发明人： Franz Josef Brocker , Peter Trubenbach , Manfred Baumann , Jurgen Schubert
IPC分类号： C07C37/07
CPC分类号： C07C37/07
摘要： A process for the preparation of alkylphenols of the formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 stand for hydrogen or C.sub.1 -C.sub.8 alkyl, by reaction of an alkylcyclohex-2-en-1-one of the formula II ##STR2## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 have the aforementioned meanings, at temperatures of from 200.degree. to 400.degree. C. and pressures ranging from 0.01 to 50 bar in the presence of palladium-on-.alpha.-Al.sub.2 O.sub.3 catalysts, wherein the catalyst used has a specific surface area (BET) of from 1 to 10 m.sup.2 /g, a pore diameter of from 5 nm to 300 .mu.m and a pore volume of from 0.1 to 0.5 cm.sup.3 /g, from 80 to 100% of the pores having a diameter of from 40 to 400 nm, and also novel palladium-on-.alpha.-Al.sub.2 O.sub.3 catalysts as obtained from a fine-grained alumina powder by steps of molding, pyrolysis and calcination.
摘要翻译：通过烷基环己-2-烯-1-酮的反应制备式I的烷基酚的方法，其中R 1，R 2，R 3，R 4和R 5代表氢或C 1 -C 8烷基，其中R 1，R 2，R 3，R 4和R 5具有上述含义的式II（II）中的一种，在200-400℃的温度和0.01至50巴的压力下，的钯 - α-Al 2 O 3催化剂，其中使用的催化剂具有1至10m 2 / g的比表面积（BET）为1至10m 2 / g，孔径为5nm至300μm，孔体积为0.1至 0.5cm 3 / g，直径为40〜400nm的孔的80〜100％，以及由细晶粒状氧化铝粉末得到的新型钯 - α-Al 2 O 3催化剂，其通过成型，热解和煅烧。

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