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1. 发明授权

US5294667A Preparation of thermoplastic molding materials based on pulverulent polyphenylene ethers and aromatic vinyl polymers 失效
标题翻译：基于粉状聚亚苯基醚和芳族乙烯基聚合物制备热塑性成型材料
公开(公告)号：US5294667A
公开(公告)日：1994-03-15
申请号：US994635
申请日：1992-12-21
申请人： Robert Weiss , Axel Gottschalk , Klaus Muehlbach , Carola Hedtmann-Rein , Robert Heinz
发明人： Robert Weiss , Axel Gottschalk , Klaus Muehlbach , Carola Hedtmann-Rein , Robert Heinz
IPC分类号： C08G65/46 , C08J3/00 , C08L25/02 , C08L71/12 , C08L25/04
CPC分类号： C08L25/02 , C08G65/46 , C08J3/005 , C08L71/123 , C08L71/12
摘要： In order to prepare thermoplastic molding materials from pulverulent polyphenylene ethers and aromatic vinyl polymers by melt extrusion, the pulverulent polyphenylene ether is first of all compacted and/or sintered under pressure and if necessary with the addition of heat, preferably under a pressure corresponding to a nip pressure of from 1 to 100 kN/cm, to form a porous compact. The compact is then fed in the form of agglomerates having a particle size of from about 0.5 mm to about 20 mm into an extruder or the like, mixed with the aromatic vinyl polymer and if desired further components, and melted. In this way the proportion of the fines in the polyphenylene ether is considerably reduced, with the result that there is virtually no further danger of dust explosions. Further advantages include improved ease of metering and reduced electrostatic charge of the agglomerates. The extruded molding materials have good mechanical properties and also high thermal stability.
摘要翻译：为了通过熔融挤出从粉状聚亚苯基醚和芳族乙烯基聚合物制备热塑性成型材料，粉状聚苯醚首先在压力下压实和/或烧结，如果需要加热，优选在相当于压区压力为1至100kN / cm，以形成多孔压块。然后将压块以粒度为约0.5mm至约20mm的附聚物的形式进料到挤出机等中，与芳族乙烯基聚合物混合并且如果需要，进一步熔融。以这种方式，聚苯醚中的细粉比例大大降低，实际上没有进一步的灰尘爆炸危险。另外的优点包括提高计量的容易性和降低凝聚体的静电电荷。挤出成型材料具有良好的机械性能和高的热稳定性。

2. 发明授权

US5296563A Preparation of polyphenylene ether/polyamide molding materials 失效
标题翻译：聚苯醚/聚酰胺成型材料的制备
公开(公告)号：US5296563A
公开(公告)日：1994-03-22
申请号：US994255
申请日：1992-12-21
申请人： Axel Gottschalk , Robert Weiss , Klaus Muehlbach , Carola Hedtmann-Rein , Robert Heinz
发明人： Axel Gottschalk , Robert Weiss , Klaus Muehlbach , Carola Hedtmann-Rein , Robert Heinz
IPC分类号： C08L71/12 , C08L77/00 , C08G65/48 , C08G71/04 , C08G77/10
CPC分类号： C08L77/00 , C08L71/12 , C08L71/126
摘要： In order to prepare thermoplastic molding materials ofA) 5-95% by weight of a modified polyphenylene ether,B) 5 to 95% by weight of a thermoplastic polyamide,C) 0 to 25% by weight of an impact-modifying rubber, andD) 0 to 50% by weight of auxiliaries and/or additives,the components A and B and if necessary the components C and D are fed individually at one or more points into an extruder, mixed with one another, and melted. The component A present in a pulverulent consistency is compacted and/or sintered under pressure and if necessary with the addition of heat, preferably at a pressure corresponding to a nip pressure of 1 to 100 kn/cm to form a porous compact before it is fed into the extruder. The compact is then modified and added as granules to the feed zone of the extruder. In this way the proportion of the fines in the polyphenylene ether is considerably reduced, so that there is virtually no further danger of dust explosions. Further advantages include an improved ease of metering and reduced electrostatic charge.
摘要翻译：为了制备A）5-95重量％的改性聚苯醚的热塑性成型材料，B）5-95重量％的热塑性聚酰胺，C）0-25重量％的抗冲击改性橡胶，和D）0至50重量％的助剂和/或添加剂，组分A和B以及组分C和D如果需要，在一个或多个点分别进料到彼此混合并熔化的挤出机中。存在粉碎稠度的组分A在压力下压实和/或烧结，如果需要加热，优选在相当于1至100kn / cm的压区压力的压力下形成多孔压块，然后再进料进入挤出机。然后将压块改性并作为颗粒加入挤出机的进料区。以这种方式，聚苯醚中细粉的比例大大降低，实际上没有进一步的粉尘爆炸危险。另外的优点包括改进的计量方便性和减少的静电电荷。

3. 发明授权

US5237039A Preparation of polyphenylene ethers in the presence of defoamer 失效
标题翻译：在存在缺陷的情况下制备聚苯乙烯
公开(公告)号：US5237039A
公开(公告)日：1993-08-17
申请号：US876163
申请日：1992-04-30
申请人： Doris Zeltner , Peter Steieri , Heike Feldman , Klaus Muehlbach , Carola Hedtmann-Rein , Bernhard Czauderna , Karl Hennig
发明人： Doris Zeltner , Peter Steieri , Heike Feldman , Klaus Muehlbach , Carola Hedtmann-Rein , Bernhard Czauderna , Karl Hennig
IPC分类号： C08G65/40 , C08G65/44
CPC分类号： C08G65/44
摘要： Polyphenylene ethers are prepared from monohydric phenols by oxidative coupling with oxygen-containing gases in the presence of an oxidation catalyst in an organic solvent by carrying out the polycondensation in the presence of a defoamer.
摘要翻译：通过在有机溶剂中的氧化催化剂存在下，通过在消泡剂的存在下进行缩聚，通过与含氧气体的氧化偶联，由一元酚制备聚苯醚。

4. 发明授权

US5612425A Molding compositions based on modified polyaryl ethers 失效
标题翻译：基于改性聚芳醚的成型组合物
公开(公告)号：US5612425A
公开(公告)日：1997-03-18
申请号：US61537
申请日：1993-05-14
申请人： Martin Weber , Klaus Muehlbach , Eckhard M. Koch
发明人： Martin Weber , Klaus Muehlbach , Eckhard M. Koch
IPC分类号： C08F283/08 , C08G65/48 , C08L71/00 , C08L77/00 , C08F283/00
CPC分类号： C08L77/00 , C08F283/08 , C08G65/48 , C08L71/00
摘要： Molding compositions based on polyaryl ethers A, are obtainable by reacting polyaryl ethers I with repeating structural elements ##STR1## or derivatives thereof substituted by C.sub.1 -C.sub.6 -alkyl, alkoxy, aryl, chlorine or fluorine in the nucleus, where X and Z, independently of one another, are each --SO.sub.2 --, --O--, --S--, >C.dbd.O a chemical bond or --CRR'--, R and R' are each hydrogen, C.sub.1 -C.sub.6 -alkyl or alkoxy, R' is also aryl or fluoro- or chloro-substituted aryl, with the proviso that X and Z are not both --O--, with a reactive compound which, besides a C--C double or triple bond, contains one or more carbonyl, carboxylic acid, carboxylate, acid anhydride, amide, imide, carboxylic ester, amino, hydroxyl, epoxy, oxazoline, urethane, urea, lactam or halobenzyl moieties.
摘要翻译：通过使聚芳基醚I与重复结构单元（I）或其在核心中被C 1 -C 6 - 烷基，烷氧基，芳基，氯或氟取代的衍生物反应，可获得基于聚芳基醚A的成型组合物，其中X和 Z独立地为-SO 2 - ， - O - ， - S - ，> C = O化学键或-CRR' - ，R和R'各自为氢，C 1 -C 6烷基或烷氧基， R'也是芳基或氟或氯取代的芳基，条件是X和Z不同时为-O-，与反应性化合物一起，除了CC双键或三键外，还含有一个或多个羰基，羧酸羧酸酯，酸酐，酰胺，酰亚胺，羧酸酯，氨基，羟基，环氧，恶唑啉，氨基甲酸酯，脲，内酰胺或卤代苄基部分。

5. 发明授权

US08697820B2 Process for preparing high-reactivity isobutene homo- or copolymers 有权
标题翻译：制备高反应异丁烯均聚物或共聚物的方法
公开(公告)号：US08697820B2
公开(公告)日：2014-04-15
申请号：US13568421
申请日：2012-08-07
申请人： Hannah Maria Koenig , Klaus Muehlbach , Thomas Wettling , Ulrich Eichenauer , Herbert Mayr
发明人： Hannah Maria Koenig , Klaus Muehlbach , Thomas Wettling , Ulrich Eichenauer , Herbert Mayr
IPC分类号： C08F4/06 , C08F2/00 , C08F10/00
CPC分类号： C08F110/10 , C08F10/10 , C08F4/00 , C08F4/06 , C08F2500/02 , C08F2500/03
摘要： Preparation of high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 50 mol % by polymerization of isobutene or isobutene-comprising monomer mixtures in the presence of Lewis acids suitable as polymerization catalysts or of complexes which are effective as polymerization catalysts and are formed from Lewis acids and donors, and in the presence of initiators, wherein the initiators used are organic sulfonic acids Z—SO3H in which the variable Z denotes an alkyl radical, haloalkyl radical, cycloalkyl radical, aryl radical or arylalkyl radical.
摘要翻译：通过在适合作为聚合催化剂的路易斯酸存在下异丁烯或含异丁烯的单体混合物的聚合制备具有至少50mol％的聚异丁烯链末端亚乙烯基双键含量的高反应性异丁烯均聚物或共聚物，或者作为聚合催化剂有效并且由路易斯酸和供体形成的络合物，并且在引发剂的存在下，其中所用的引发剂是有机磺酸Z-SO 3 H，其中变量Z表示烷基，卤代烷基，环烷基，芳基或芳基烷基。

6. 发明授权

US08536108B2 Care polymers 有权
标题翻译：护理聚合物
公开(公告)号：US08536108B2
公开(公告)日：2013-09-17
申请号：US13105201
申请日：2011-05-11
申请人： Rajan Keshav Panandiker , Julie Ann Menkhaus , Dieter Boeckh , Rainer Dobrawa , Frank Huelskoetter , Valentin Cepus , Jack Tinsley , Klaus Muehlbach , Markus Brym , Sophia Ebert , Ivette Garcia Castro
发明人： Rajan Keshav Panandiker , Julie Ann Menkhaus , Dieter Boeckh , Rainer Dobrawa , Frank Huelskoetter , Valentin Cepus , Jack Tinsley , Klaus Muehlbach , Markus Brym , Sophia Ebert , Ivette Garcia Castro
IPC分类号： B08B3/04 , C11D1/00 , C11D3/18
CPC分类号： C11D3/373 , C11D3/001 , C11D3/3749 , D06M15/227 , D06M15/643 , D06M2200/50
摘要： The present application relates to care polymers and fabric and home care compositions comprising such care polymers, as well as processes for making and using such care polymers and such compositions. The performance of the care polymers that Applicants teach, can be further increased by following the emulsification teaching of the present specification and/or combining such care polymers with silicone materials.
摘要翻译：本申请涉及包含这种护理聚合物的护理聚合物和织物和家庭护理组合物，以及制备和使用这种护理聚合物和这种组合物的方法。申请人教导的护理聚合物的性能可以通过遵循本说明书的乳化教导和/或将这些护理聚合物与硅氧烷材料组合来进一步提高。

7. 发明授权

US5482998A Thermoplastic molding materials based on partly aromatic copolyamides and polyolefins 失效
标题翻译：基于部分芳族共聚酰胺和聚烯烃的热塑性成型材料
公开(公告)号：US5482998A
公开(公告)日：1996-01-09
申请号：US287524
申请日：1994-08-08
申请人： Klaus Muehlbach , Petra Baierweck , Wolfgang F. Mueller , Gerd Blinne , Gerhard Ramlow
发明人： Klaus Muehlbach , Petra Baierweck , Wolfgang F. Mueller , Gerd Blinne , Gerhard Ramlow
IPC分类号： C08K7/14 , C08L23/08 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L51/06 , C08L53/00 , C08L77/00 , C08L77/10 , C08L23/26
CPC分类号： C08L23/12 , C08G69/36 , C08L23/10 , C08L23/142 , C08L23/16 , C08L77/00 , C08L77/06 , C08K7/14 , C08L2205/03 , C08L2205/035 , C08L2205/08 , C08L23/0869 , C08L23/14 , C08L51/06 , C08L53/00
摘要： Thermoplastic molding materials containA) 4-94% by weight of a partly aromatic, semicrystalline copolyamide having a triamine content of less than 0.5% by weight and composed of(A.sub.1) 20-90% by weight of units derived from terephthalic acid and hexamethylenediamine,(A.sub.2) 0-50% by weight of units derived from .epsilon.-caprolactam,(A.sub.3) 0-80% by weight of units derived from adipic acid and hexametheylenediamine and(A.sub.4) 0-40% by weight of further polyamide-forming monomers, the amount of components (A.sub.2) or (A.sub.3) or (A.sub.4) or of mixtures thereof being not less than 10% by weight,B) 4-94% by weight of a polyolefin homo- or copolymer or a mixture thereof,C) 2-20% by weight of an adhesion promoter,D) 0-20% by weight of a toughening polymer andE) 0-60 % by weight of additives and processing assistants.
摘要翻译：热塑性成型材料包含A）4-94重量％的三胺含量小于0.5重量％的部分芳族半结晶共聚酰胺，由（A1）20-90重量％的衍生自对苯二甲酸和六亚甲基二胺的单元组成，（A2）0-50重量％衍生自ε-己内酰胺的单元，（A3）0-80重量％衍生自己二酸和六亚甲基二胺的单元和（A4）0-40重量％进一步聚酰胺形成单体，组分（A2）或（A3）或（A4）或其混合物的量不小于10重量％，B）4-94重量％的聚烯烃均聚物或共聚物或其混合物， C）2-20重量％的粘合促进剂，D）0-20重量％的增韧聚合物和E）0-60重量％的添加剂和加工助剂。

8. 发明授权

US5453463A Molding materials based on polyaryl ethers and toughened partly aromatic copolyamides 失效
标题翻译：基于聚芳基醚和增韧的部分芳族共聚酰胺的成型材料
公开(公告)号：US5453463A
公开(公告)日：1995-09-26
申请号：US318192
申请日：1994-10-05
申请人： Martin Weber , Klaus Muehlbach
发明人： Martin Weber , Klaus Muehlbach
IPC分类号： C08L51/00 , C08L71/00 , C08L71/10 , C08L77/00 , C08L81/06 , C08L77/10
CPC分类号： C08L77/00 , C08L71/00 , C08L81/06 , C08L51/00
摘要： Molding materials are composed ofA) from 5 to 95% by weight of polyaryl ethers,B) from 5 to 95% by weight of a mixture (B) ofB.sub.I) from 75 to 97% by weight of partly aromatic polyamides andB.sub.II) from 3 to 25% by weight of a rubber impact modifierand furthermoreC) from 0 to 40% by weight of additives and/or processing assistants.
摘要翻译：成型材料由以下组成：A）5〜95重量％的聚芳基醚，B）5〜95重量％的BI的混合物（B）75〜97重量％的部分芳族聚酰胺和BII） 3至25重量％的橡胶抗冲改性剂，以及C）0至40重量％的添加剂和/或加工助剂。

9. 发明授权

US5290859A Thermoplastic molding materials based on polycarbonates, styrene/acrylonitrile polymers and polyolefins 失效
标题翻译：基于聚碳酸酯，苯乙烯/丙烯腈聚合物和聚烯烃的热塑性成型材料
公开(公告)号：US5290859A
公开(公告)日：1994-03-01
申请号：US906722
申请日：1992-06-30
申请人： Norbert Niessner , Klaus Muehlbach
发明人： Norbert Niessner , Klaus Muehlbach
IPC分类号： C08L23/02 , C08L25/12 , C08L51/00 , C08L51/04 , C08L69/00
CPC分类号： C08L25/12 , C08L51/003 , C08L69/00 , C08L23/02 , C08L51/04
摘要： Thermoplastic molding materials contain, as essential components,A) polycarbonates,B) graft polymers,C) styrene copolymers andD) polyolefins.
摘要翻译：热塑性成型材料含有A）聚碳酸酯，B）接枝聚合物，C）苯乙烯共聚物和D）聚烯烃作为必要组分。

10. 发明申请

US20120165473A1 PREPARATION OF DERIVATIVES OF ISOBUTENE COPOLYMERS 有权
标题翻译： ISOBUTENE共聚物衍生物的制备
公开(公告)号：US20120165473A1
公开(公告)日：2012-06-28
申请号：US13305132
申请日：2011-11-28
申请人： Hannah Maria Koenig , Klaus Muehlbach , Helmut Mach , Ulrich Eichenauer
发明人： Hannah Maria Koenig , Klaus Muehlbach , Helmut Mach , Ulrich Eichenauer
IPC分类号： C08F10/10
CPC分类号： C08F8/30 , C08F8/14 , C08F8/32 , C08F8/42 , C08F10/10 , C08F290/042 , C08F210/12
摘要： A process for producing an isobutene copolymer derivative by: (I) free-radically copolymerizing (a) 10-90 mol % of a monoethylenically unsaturated C4- to C12-dicarboxylic acid, anhydride, or ester, (b) 10-90 mol % of a high-reactivity isobutene polymer having Mn=110-250000 and obtained by polymerizing isobutene in the presence of an iron-halide-, aluminum trihalide-, or alkylaluminum halide-donor complex, each donor being an ether or carboxylic ester function, or in the presence of a Lewis acid complex containing an organic sulfonic acid, and (c) 0-50 mol % of a monoethylenically unsaturated compound copolymerizable with (a) and (b), to obtain an intermediate isobutene copolymer; and (II) reacting the carboxylic acid functions in the intermediate with at least one of ammonia, an amine, and an alcohol, to form a moiety containing at least one of a hydroxyl, carboxylic ester, amino, quaternized amino, amido, and imido group.
摘要翻译：异丁烯共聚物衍生物的制备方法：（I）10-90摩尔％的单烯属不饱和C4-至C12-二羧酸，酸酐或酯的自由基共聚合，（b）10-90摩尔％的Mn = 110-250000的高反应异丁烯聚合物，并且通过在卤化铁，三卤化铝或卤化烷基铝卤化物供体络合物的存在下聚合异丁烯获得，每个供体是醚或羧酸酯官能团，或在含有有机磺酸的路易斯酸络合物的存在下，和（c）0-50mol％可与（a）和（b）共聚的单烯键式不饱和化合物，得到中间体异丁烯共聚物; 和（II）使中间体中的羧酸官能团与氨，胺和醇中的至少一种反应，以形成含有羟基，羧酸酯，氨基，季铵化氨基，酰胺基和亚氨基中的至少一个的部分组。

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