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1. 发明授权

US3563874A Halide-sensitive electrochemical electrodes and method of making same 失效
标题翻译：敏感电化学电极及其制备方法
公开(公告)号：US3563874A
公开(公告)日：1971-02-16
申请号：US3563874D
申请日：1967-10-02
申请人： ORION RESEARCH
发明人： ROSS JAMES W , FRANT MARTIN S , RISEMAN JOHN H
IPC分类号： G01N27/333 , G01N27/54
CPC分类号： G01N27/333
摘要： AN ELECTRODE SENSITIVE TO CHLORIDE IONS IN SOLUTION, THE ION-SENSITIVE PORTION BEING AN IMPOROUS MEMBRANE OF SILVER SULFIDE AND SILVER CHLORIDE. THE ELECTRODE IS PREPARED BY COPRECIPITATING THE SILVER SALTS, AND AFTER WASHING AND DRYING, COMPRESSING THE COPRECIPITATE, UNDER VACUUM CONDITIONS, INTO A DENSE, IMPOROUS PELLET. BROMIDE AND IODIDE SENSITIVE ELECTRODES ARE PREPARED IN SUBSTANTIALLY THE SAME MANNER FROM SILVER SULFIDE AND THE CORRESPONDING SILVER HALIDE.

2. 发明授权

US3894917A Electrochemical measuring systems and method of measuring ionic strength in a flow stream 失效
标题翻译：电化学测量系统和测量流动中离子强度的方法
公开(公告)号：US3894917A
公开(公告)日：1975-07-15
申请号：US15366771
申请日：1971-06-16
申请人： ORION RESEARCH
发明人： RISEMAN JOHN H , FRANT MARTIN , ROSS JAMES W
IPC分类号： G01N27/416 , G01N27/46
CPC分类号： G01N27/4166
摘要： A system for making electrochemical measurements in a flow stream, which system employs reagent addition to a sample stream and a pair of ion-sensing electrodes responsive respectively to the ion of interest in the sample stream and a tag ion in the reagent stream. The electrodes are so disposed in the system that the latter becomes relatively insensitive to variations in the flow rate of either or both the sample and reagent streams.
摘要翻译：一种用于在流动流中进行电化学测量的系统，该系统使用试剂添加到样品流中，以及一对离子感测电极，其分别响应于样品流中感兴趣的离子和标签离子。电极被布置在系统中，后者对样品和试剂流中的任一个或两者的流速变化相对不敏感。

3. 发明授权

US3859191A Hydrogen cyanide sensing cell 失效
标题翻译：氢氰化物感测细胞
公开(公告)号：US3859191A
公开(公告)日：1975-01-07
申请号：US34922473
申请日：1973-04-09
申请人： ORION RESEARCH
发明人： FRANT MARTIN S , RISEMAN JOHN H , KRUEGER JOHN A
IPC分类号： G01N27/403 , G01N27/46
CPC分类号： G01N27/4035
摘要： An improved gas-sensing electrochemical cell for measuring hydrogen cyanide gas in a sample solution. The cell comprises a potentiometric silver ion-sensitive electrode and a reference electrode, both in contact with an internal standard solution comprising an aqueous solution of an argento cyanide complex. A hydrophobic hydrogen cyanide gas-permeable membrane separates the sample solution from the internal solution.

4. 发明授权

US3624638A Signal-converting method and apparatus 失效
标题翻译：信号转换方法和装置
公开(公告)号：US3624638A
公开(公告)日：1971-11-30
申请号：US3624638D
申请日：1970-09-23
申请人： ORION RESEARCH
发明人： RISEMAN JOHN H , GOLDBERG HAROLD S , GRIMES JOHN
IPC分类号： H03M1/00 , H03K13/02
CPC分类号： H03M1/56
摘要： A method and apparatus for converting an input analog signal to an antilog output signal which comprises the generation of a linear ramp signal which increases toward a predetermined response level. A clock signal having a predetermined cycle is provided so that when coincidence is detected between the ramp signal and the input signal, an exponential signal asymptotically approaching a predetermined amplitude with a time constant of predetermined value is then generated until the clock signal reaches the end of its predetermined cycle. At that time, a second linear ramp signal having an instantaneous absolute value of slope determined in accordance with the absolute value of slope of the first ramp signal and an initial absolute value determined in accordance with the absolute amplitude value of the exponential signal at the end of the predetermined cycle is generated. The antilog output signal is proportional to the time period measured from the end of the predetermined cycle until coincidence occurs between the second ramp signal and a reference signal which has a predetermined relationship to the input analog signal.

5. 发明授权

US3910607A Apparatus for determining the concentration of species 失效
标题翻译：用于确定物种浓度的装置
公开(公告)号：US3910607A
公开(公告)日：1975-10-07
申请号：US22414572
申请日：1972-02-07
申请人： ORION RESEARCH
发明人： RISEMAN JOHN H
IPC分类号： G01N31/16 , G06G1/14 , B41L1/00
CPC分类号： G01N31/162 , G06G1/14
摘要： A special plotting paper for determining the unknown concentration of a sample species in titrations utilizing Nernstian response sensing devices. The paper comprises lines defining a vertical and horizontal axis, a set of parallel vertical lines spaced equally apart, and a set of transverse lines spaced anti-logarithmically apart and skewed with respect to the horizontal axis. The intersection of the vertical lines with the horizontal axis forms a linear scale which represents the volume of titrant added. The intersection of the transverse lines with the vertical axis forms an anti-logarithmic scale which represents the electrode potential of the Nernstian device. The transverse lines are skewed to adjust the potential readings for the fractional change in the volume of sample solution due to the addition of titrant. In a titration, the electrode potential readings of the Nernstian device are plotted versus volume of titrant added. A straight line is fitted through the plotted points and is extrapolated to the horizontal axis. The intercept of the straight line and horizontal axis represents the equivalence point from which the unknown concentration of the sample species is easily determined.
摘要翻译：一种特殊的绘图纸，用于使用Nernstian响应感测装置确定滴定中样品物种的未知浓度。该纸包括限定垂直和水平轴线，一组间隔开间隔的一组平行垂直线以及相对于水平轴反对数分离和偏斜地间隔开的一组横向线。垂直线与横轴的交点形成线性刻度，表示添加的滴定剂的体积。横线与垂直轴的交点形成反对数刻度，表示可计算器件的电极电位。横向线偏斜，以调整由于添加滴定剂而导致样品溶液体积分数变化的潜在读数。在滴定过程中，可计算Nernstian器件的电极电位读数相对于添加的滴定剂体积。通过绘制的点拟合一条直线，并将其外推到水平轴。直线和横轴的截距表示容易确定样品物种的未知浓度的当量点。

6. 发明授权

US3492216A Electrochemical device 失效
公开(公告)号：US3492216A
公开(公告)日：1970-01-27
申请号：US3492216D
申请日：1967-03-09
申请人： ORION RESEARCH
发明人： RISEMAN JOHN H , SHILLER STANLEY
IPC分类号： G01N27/333 , G01N27/403 , B01K3/04
CPC分类号： G01N27/4035 , G01N27/333

7. 发明授权

US3605722A Method of diagnosing cystic fibrosis 失效
标题翻译：诊断CYSTIC FIBROSIS的方法
公开(公告)号：US3605722A
公开(公告)日：1971-09-20
申请号：US3605722D
申请日：1969-11-18
申请人： ORION RESEARCH
发明人： RISEMAN JOHN H , SHILLER STANLEY
IPC分类号： A61B5/00 , A61B5/05
CPC分类号： A61B5/4261 , A61B5/4266 , Y10T436/193333
摘要： A METHOD FOR ELECTRICALLY DIAGNOSING CYSTIC FIBROSIS BY WETTING THE CLEANSED SKIN OF A PATIENT WITH A SOLUTION CONTAINING CHLORIDE IONS IN A CONCENTRATION OF ABOUT FORTY (40) MILLIEQUIVALENTS PER LITER AND THEN DETERMINING THE DIRECTION OF A SIGNAL DEVELOPED BY CHLORIDE RESPONSE ELECTRODE IN CONTACT WITH THE PATIENT''S SKIN. THIS TECHNIQUE IS ADVANTAGEOUSLY CARRIED OUT WITH AN ELECTROCHEMICAL ELECTRODE STRUCTURE HAVING AN ELONGATED BODY WITH AN AXIAL CHAMBER AND AN ANNULAR CHAMBER, BOTH SEPARATED FROM ONE ANOTHER. BOTH CHAMBERS CONTAIN A REFERENCE ELECTRODE AND A REFERENCE ELECTROLYTE. ONE END OF THE STRUCTURE INCLUDES AN INSET, FLAT, MEMBRANE SENSI-

TIVE TO SPECIFIC IONS OF ONE POLARITY FORMING A WALL FOR THE AXIAL CHAMBER. IN ONE FORM OF THE ELECTRODE, AN ANNULAR LEAK, COMMUNICATING WITH THE ANNULAR CHAMBER, SURROUNDS AND IS SPACED FROM THE MEMBRANE SURFACE, THAT END OF THE STRUCTURE THEREFORE PROVIDING A SUBSTANTIALLY FLAT, RIDGELESS SURFACE. IN ANOTHER FORM, A RING-SHAPED MEMBRANE, SENSITIVE TO IONS OF OPPOSITE PLARITY, SURROUNDS AND IS SPACED FROM THE CENTRAL MEMBRANE, AND NO LEAK IS USED.

8. 发明授权

US3591481A Concentration measuring system 失效
标题翻译：浓度测量系统
公开(公告)号：US3591481A
公开(公告)日：1971-07-06
申请号：US3591481D
申请日：1968-11-12
申请人： ORION RESEARCH
发明人： RISEMAN JOHN H
IPC分类号： G01N27/416 , G01N27/46
CPC分类号： G01N27/4035
摘要： A SYSTEM FOR MEASURING THE CONTRATION OF SPECIES OF IONS IN A SAMPLE SOLUTION WITH A POTENTIOMETRIC ELECTRODE HAVING A NERNSTIAN RESPONE. THE ELECTRODE AND A REFERENCE ELECTRODE ARE CONNECTED TO A METER WHICH CAN BE NULLED AT CENTRAL INDICIUM ON THE METER SCALE. THE METER SCALE IS DIVIDED TO ONE SIDE OF THE NULL INDICIUM INTO INCREMENTS OVER A RANGE FROM A FIRST MINIMUM VALUE TO INFINITY AT THE NULL POINT ACCORDING TO THE FUNCTION LOG (C+Q/C) WHERE C IS THE CONCENTRATION OF THE SPECIES IN THE SAMPLE SOLUTION AND Q IS THE FIXED MOLARITY OF THE SPECIES OF ION OF INTEREST IN A STANDARD SOLUTION. THE SCALE IS DIVIDED TO THE OTHER SIDE OF THE NULL INDICUIM IN A SIMILAR MANNER BUT ACCORDING TO THE FUNCTION LOG (C/C-Q) INSECTION OF THE ELECTRODES INTO THE SAMPLE SOLUTION PROVIDES A RESPONES WHICH IS NULLED AT THE METER. THE ADDITION OF THE STANDARD SOLUTION CREATES A NEW POTENTIAL WHICH WHEN READ ON THE APPROPRIATE SCALE, INDICATES THE CONCENTRATION OF THE SPECIES OF ION TO WHICH THE POTENTIOMETRIC ELECTRODE IS RESPONSIVE.

9. 发明授权

US3426184A Logarithmic circuit 失效
标题翻译：逻辑电路
公开(公告)号：US3426184A
公开(公告)日：1969-02-04
申请号：US3426184D
申请日：1966-04-04
申请人： ORION RESEARCH
发明人： RISEMAN JOHN H
IPC分类号： G06F7/556 , H03M1/00 , G06F1/02
CPC分类号： G06F7/556 , G06F2207/5561 , H03M1/62

10. 发明授权

US3923608A Method of detecting low levels of cyanide 失效
标题翻译：检测氰化物含量低的方法
公开(公告)号：US3923608A
公开(公告)日：1975-12-02
申请号：US27933672
申请日：1972-08-10
申请人： ORION RESEARCH
发明人： FRANT MARTIN S , ROSS JAMES , RISEMAN JOHN H
IPC分类号： G01N27/416 , G01N27/46
CPC分类号： G01N27/4166
摘要： A system for electrochemical measurement of the concentration of cyanide ions in titrations utilizing Nerstian responsive electrochemical devices for sensing silver ions. The system involves successive additions of a standard solution containing cyanide ion to the sample, in the presence of an indicator comprising an at least partially dissociable silver cyanide complex. Electrode potential measurements of the potentials for the silver ion in equilibrium with the cyanide ion are taken before and after each addition. The potentials are plotted antilogarithmically versus the known increase in concentration of the ion of interest. The original concentration of the ion of interest is obtained by extrapolation of the plot using Gran''s method. The system is especially useful for trace sample determinations.
摘要翻译：用于电化学测量滴定中氰离子浓度的系统，利用用于感测银离子的Nerstian响应电化学装置。在包含至少部分可离解的氰化银络合物的指示剂的存在下，该系统包括连续添加含有氰化物离子的标准溶液。在每次添加之前和之后，对与氰化物离子平衡的银离子的电位进行电极电位测量。相对于所关注的离子的浓度的已知增加，电位相对于对数绘制。通过使用Gran's方法外推图来获得感兴趣离子的原始浓度。该系统对痕量样品测定特别有用。

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