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1. 发明授权

US08962091B2 Polyheterosilxoanes for high refractive index materials 有权
$Polyheterosilxoanes for high refractive index materials$
标题翻译：用于高折射率材料的聚异辛二烯
公开(公告)号：US08962091B2
公开(公告)日：2015-02-24
申请号：US13885693
申请日：2012-01-05
申请人： Masaaki Amako , Maki Itoh , Nanguo Liu , Shawn Keith Mealey , Randall Gene Schmidt
发明人： Masaaki Amako , Maki Itoh , Nanguo Liu , Shawn Keith Mealey , Randall Gene Schmidt
IPC分类号： B05D3/02 , C09D185/00 , C09D183/14 , C08G77/00 , C08L83/04 , C08L85/00 , C08G77/58 , G02B1/04 , C08G79/14
CPC分类号： C09D185/00 , B05D3/02 , C08G77/58 , C08G77/80 , C08G79/14 , C08L83/04 , C08L85/00 , C09D183/14 , G02B1/04
摘要： Polyheterosiloxane compositions are disclosed containing at least 70% by weight of the following components: (A) a first metal (M1) selected from Ti, Zr, or Zn, (B) a second metal (M2) selected from a non-lanthanide metal, (C) siloxy units having the formula R2SiO2/2 or R′SiO3/2, where R′ is independently a hydrocarbon group or halogen substituted hydrocarbon group containing 1 to 18 carbon atoms. The disclosed compositions are useful to prepare high refractive index materials.
摘要翻译：公开了含有至少70重量％以下组分的聚异氰酸酯组合物：（A）选自Ti，Zr或Zn的第一金属（M1），（B）选自非镧系元素金属，（C）具有式R2SiO2 / 2或R'SiO3 / 2的甲硅烷氧基单元，其中R'独立地为烃基或含有1至18个碳原子的卤素取代的烃基。所公开的组合物可用于制备高折射率材料。

2. 发明申请

US20140187733A1 Organopolysiloxane, And Method For Producing Same 审中-公开
标题翻译：有机聚硅氧烷及其生产方法
公开(公告)号：US20140187733A1
公开(公告)日：2014-07-03
申请号：US14131319
申请日：2012-07-04
申请人： Tadashi Okawa , Kazuhiro Nishijima , Masaaki Amako , Maki Itoh , Yoshitsugu Mortia
发明人： Tadashi Okawa , Kazuhiro Nishijima , Masaaki Amako , Maki Itoh , Yoshitsugu Mortia
IPC分类号： C08G77/06 , C08G77/04
CPC分类号： C08G77/06 , C08G77/04 , C08G77/045 , C08G77/12 , C08G77/20 , C08G77/80 , C09D183/04 , C09J183/04 , C08L83/00
摘要： An organopolysiloxane which forms a cured product having a high refractive index, high transparency, and excellent heat resistance when subjected to a hydrosilylation reaction and which is represented by the following average unit formula: (R13SiO1/2)a(R12SiO2/2)b(R2SiO3/2)c(SiO4/2)d wherein, R1 are alkyl groups, alkenyl groups, phenyl groups, or hydrogen atoms; R2 is a group represented by R1 or a condensed polycyclic aromatic group or a group containing a condensed polycyclic aromatic group, but at least one of R1 or R2 in a molecule is an alkenyl group or a hydrogen atom, at least one R2 in a molecule is a condensed polycyclic aromatic group or a group containing a condensed polycyclic aromatic group; and a, b, c and d are numbers that satisfy: 0.01≦a≦0.8, 0≦b≦0.5, 0.2≦c≦0.9, 0≦d
摘要翻译：形成具有高折射率，高透明度和耐氢解性的固化产物的有机聚硅氧烷，其经受氢化硅烷化反应并由以下平均单元式表示：（R13SiO1 / 2）a（R12SiO2 / 2）b（ R2SiO3 / 2）c（SiO4 / 2）d其中R1是烷基，烯基，苯基或氢原子; R2是由R1或稠合多环芳基或含有缩合多环芳基的基团表示的基团，但分子中的R 1或R 2中的至少一个为链烯基或氢原子，分子中至少1个是稠合多环芳族基团或含缩合多环芳基的基团; 并且a，b，c和d是满足：0.01＆nlE; a＆nlE; 0.8,0和nlE; b＆nlE; 0.5,0.2＆nlE; c＆nlE; 0.9,0＆amp; nlE; d <0.2和a + b + c + d = 1的数字。

3. 发明申请

US20150290887A1 OPTICAL ARTICLE AND METHOD OF FORMING 有权
标题翻译：光学文章和形成方法
公开(公告)号：US20150290887A1
公开(公告)日：2015-10-15
申请号：US14372465
申请日：2013-01-16
申请人： Steven SWIER , Masaaki AMAKO , Shin YOSHIDA , Dow Corning Corporation , Dow Corning Toray Co., Ltd.
发明人： Steven SWIER , Masaaki AMAKO , Shin YOSHIDA
IPC分类号： B29D11/00
CPC分类号： B29D11/0073 , B29C35/02 , B29D11/00451 , B29D11/00807 , B29K2083/00 , B29K2995/0026
摘要： A method of forming an optical article includes the step of applying a silicone composition to a surface, wherein the silicone composition is a solid and has a glass transition temperature greater than room temperature. The silicone composition is heated to a temperature at or above the glass transition temperature such that the silicone composition flows. The silicone composition forms a light transmitting sheet upon cooling following the heating.
摘要翻译：形成光学制品的方法包括将硅氧烷组合物施加到表面上的步骤，其中硅氧烷组合物是固体并且具有大于室温的玻璃化转变温度。将硅氧烷组合物加热到等于或高于玻璃化转变温度的温度，使得硅氧烷组合物流动。有机硅组合物在加热后冷却时形成透光片。

4. 发明申请

US20130256742A1 Siloxane-Compositions Including Metal-Oxide Nanoparticles Suitable For Forming Encapsulants 审中-公开
标题翻译：包含适合形成密封剂的金属氧化物纳米颗粒的硅氧烷组合物
公开(公告)号：US20130256742A1
公开(公告)日：2013-10-03
申请号：US13991840
申请日：2011-12-06
申请人： Brian R. Harkness , Ann W. Norris , Shellene K. Thurston , Masaaki Amako , Maki Itoh , Michitaka Suto
发明人： Brian R. Harkness , Ann W. Norris , Shellene K. Thurston , Masaaki Amako , Maki Itoh , Michitaka Suto
IPC分类号： H01L33/56
CPC分类号： H01L33/56 , C08G77/20 , C08K3/22 , C08L83/04 , C09D7/61 , C09D7/67 , H01L23/3171 , H01L2924/0002 , H01L2924/00
摘要： A composition includes an organopolysiloxane component (A) having at least one aryl group and having an average of at least two alkenyl groups per molecule. The composition further includes an organohydrogensiloxane component (B) having at least one of an alkyl group and an aryl group and an average of at least two silicon-bonded hydrogen atoms per molecule. Components (A) and (B) each independently have a number average molecular weight less than or equal to 1500 (g/mole). The composition yet further includes a catalytic amount of a hydrosilylation catalyst component (C), and metal-oxide nanoparticles (D) other than titanium dioxide (TiO2) nanoparticles. The composition has a molar ratio of alkyl groups to aryl groups ranging from 1:0.25 to 1:3.0. A product of the present invention is the reaction product of the composition, which may be used to make a light emitting diode.
摘要翻译：组合物包括每分子具有至少一个芳基并且平均具有至少两个烯基的有机聚硅氧烷组分（A）。该组合物还包括具有烷基和芳基中的至少一个并且每个分子具有至少两个与硅键合的氢原子平均的有机氢硅氧烷组分（B）。组分（A）和（B）各自独立地具有小于或等于1500（g / mol）的数均分子量。该组合物还包括催化量的氢化硅烷化催化剂组分（C）和除二氧化钛（TiO 2）纳米颗粒以外的金属氧化物纳米颗粒（D）。该组合物的烷基与芳基的摩尔比范围为1:0.25至1:3.0。本发明的产品是可用于制造发光二极管的组合物的反应产物。

5. 发明申请

US20130230656A1 Polyheterosilxoanes For High Refractive Index Materials 有权
$Polyheterosilxoanes For High Refractive Index Materials$
标题翻译：高折射率材料的聚异辛二烯
公开(公告)号：US20130230656A1
公开(公告)日：2013-09-05
申请号：US13885693
申请日：2012-01-05
申请人： Masaaki Amako , Maki Itoh , Nanguo Liu , Shawn Keith Mealey , Randall Gene Schmidt
发明人： Masaaki Amako , Maki Itoh , Nanguo Liu , Shawn Keith Mealey , Randall Gene Schmidt
IPC分类号： C09D185/00 , C08G79/14
CPC分类号： C09D185/00 , B05D3/02 , C08G77/58 , C08G77/80 , C08G79/14 , C08L83/04 , C08L85/00 , C09D183/14 , G02B1/04
摘要： Polyheterosiloxane compositions are disclosed containing at least 70% by weight of the following components: (A) a first metal (M1) selected from Ti, Zr, or Zn, (B) a second metal (M2) selected from a non-lanthanide metal, (C) siloxy units having the formula R2SiO2/2 or R′SiO3/2, where R′ is independently a hydrocarbon group or halogen substituted hydrocarbon group containing 1 to 18 carbon atoms. The disclosed compositions are useful to prepare high refractive index materials.
摘要翻译：公开了含有至少70重量％以下组分的聚异氰酸酯组合物：（A）选自Ti，Zr或Zn的第一金属（M1），（B）选自非镧系元素金属，（C）具有式R2SiO2 / 2或R'SiO3 / 2的甲硅烷氧基单元，其中R'独立地为烃基或含有1至18个碳原子的卤素取代的烃基。所公开的组合物可用于制备高折射率材料。

6. 发明申请

US20090130463A1 Coated Substrates and Methods for their Preparation 审中-公开
标题翻译：涂层基材及其制备方法
公开(公告)号：US20090130463A1
公开(公告)日：2009-05-21
申请号：US11992871
申请日：2006-09-18
申请人： John Dean Albaugh , Masaaki Amako , Robert Charles Camilletti , Dong Choi , William Weidner , Ludmil Zambov
发明人： John Dean Albaugh , Masaaki Amako , Robert Charles Camilletti , Dong Choi , William Weidner , Ludmil Zambov
IPC分类号： B32B27/00 , B05D1/36
CPC分类号： H01L21/3122 , C08J7/045 , H01L21/02126 , H01L21/02216 , H01L21/02282 , H01L21/02348 , H01L21/3124 , H01L21/318 , H01L51/5256 , Y10T428/31663
摘要： Coated substrates comprising an inorganic barrier coating and an interfacial coating, wherein the interfacial coating comprises a cured product of a silicone resin having silicon-bonded radiation-sensitive groups; and methods of preparing the coated substrates.
摘要翻译：包括无机阻隔涂层和界面涂层的涂覆基材，其中所述界面涂层包含具有硅键合的辐射敏感基团的硅树脂的固化产物; 以及制备涂覆的基材的方法。

7. 发明授权

US06417309B2 Curable organosiloxane composition 有权
标题翻译：固化有机硅氧烷组合物
公开(公告)号：US06417309B2
公开(公告)日：2002-07-09
申请号：US09808789
申请日：2001-03-15
申请人： Masaaki Amako , Tadashi Okawa
发明人： Masaaki Amako , Tadashi Okawa
IPC分类号： C08G7708
CPC分类号： C08G77/045 , C07F7/0838
摘要： A curable organosiloxane composition comprising: (A) an organopolysiloxane having at least two silicon atom-bonded alkenyl groups per molecule; (B) an organopolysiloxane having at least two silicon atom-bonded hydrogen atoms per molecule; (C) a compound having an alkenyl group and a phenol residue of the formula: where R1 is an alkyl group or alkoxy group, a is 1 or 2, and b is an integer from 0 to 3; and (D) a hydrosilylation reaction catalyst.
摘要翻译：一种可固化的有机硅氧烷组合物，其包含：（A）每分子具有至少两个硅原子键合的烯基的有机聚硅氧烷; （B）每分子具有至少两个与硅原子键合的氢原子的有机聚硅氧烷; （C）具有烯基的化合物和下式的酚残基：其中R1是烷基或烷氧基，a是1或2，b是0-3的整数; 和（D）氢化硅烷化反应催化剂。

8. 发明授权

US06369185B1 Curable organopolysiloxane composition, cured products formed therefrom and unified articles 失效
标题翻译：固化有机聚硅氧烷组合物，由其形成的固化产品和统一制品
公开(公告)号：US06369185B1
公开(公告)日：2002-04-09
申请号：US09531934
申请日：2000-03-21
申请人： Masaaki Amako , Tadashi Okawa , Kazumi Nakayoshi , Osamu Mitani
发明人： Masaaki Amako , Tadashi Okawa , Kazumi Nakayoshi , Osamu Mitani
IPC分类号： C08G7704
CPC分类号： C09J183/04 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/70 , C08L83/00 , C08L83/04 , C08L2666/44
摘要： A curable organopolysiloxane composition, comprising (A) an organopolysiloxane containing an average of at least 2 alkenyl groups and at least 2 silicon-bonded hydrogen atoms per molecule; (B) a compound containing alkenyl and hydroxyphenyl groups in each molecule, and (C) a hydrosilylation catalyst. A product formed by curing the organopolysiloxane composition and a unified article comprising a substrate and a product formed by curing the organopolysiloxane, wherein the substrate is unified into a single integral body with the cured product.
摘要翻译：一种可固化的有机聚硅氧烷组合物，其包含（A）每分子平均含有至少2个烯基和至少2个硅键合的氢原子的有机聚硅氧烷; （B）每个分子中含有烯基和羟基苯基的化合物，和（C）氢化硅烷化催化剂。通过固化有机聚硅氧烷组合物形成的产品和包含基材和通过固化有机聚硅氧烷形成的产物的统一制品，其中基材与固化产物一体化成单个整体。

9. 发明申请

US20140191161A1 Curable Silicon Composition, Cured Product Thereof, And Optical Semiconductor Device 审中-公开
标题翻译：可固化硅组合物，其固化产物和光半导体器件
公开(公告)号：US20140191161A1
公开(公告)日：2014-07-10
申请号：US14131331
申请日：2012-07-04
申请人： Masaaki Amako , Tadashi Okawa , Tomohiro Iimura , Kazuhiro Nishijima , Maki Itoh , Yoshitsugu Morita
发明人： Masaaki Amako , Tadashi Okawa , Tomohiro Iimura , Kazuhiro Nishijima , Maki Itoh , Yoshitsugu Morita
IPC分类号： C08G77/04 , C09K11/08
CPC分类号： C08G77/04 , C08G77/045 , C08G77/12 , C08G77/20 , C08G77/80 , C08L83/00 , C08L83/04 , C09J183/04 , C09K11/08 , H01L23/24 , H01L23/296 , H01L33/502 , H01L2224/48091 , H01L2224/48247 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
摘要： A hydrosilylation curable silicone composition that forms a cured product with a high refractive index, high transparency, excellent heat resistance, and excellent flexibility, the hydrosilylation curable silicone composition comprising, as a main component, an organopolysiloxane represented by the following average unit formula: (R13SiO1/2)a(R12SiO2/2)b(R2SiO3/2)c(SiO4/2)d wherein, R1 are alkyl groups, alkenyl groups, phenyl groups, or hydrogen atoms; R2 is a group recited for R1, a condensed polycyclic aromatic group, or a group containing a condensed polycyclic aromatic group, provided that at least one of R1 or R2 in a molecule is an alkenyl group or hydrogen atom, and at least one R2 in a molecule is a condensed polycyclic aromatic group or a group containing a condensed polycyclic aromatic group; and a, b, c, and d are numbers satisfying: 0.01≦a≦0.8, 0≦b≦0.5, 0.2≦c≦0.9, 0≦d
摘要翻译：一种形成具有高折射率，高透明度，优异的耐热性和优异柔韧性的固化产物的氢化硅烷化可固化的硅氧烷组合物，所述氢化硅烷化可固化的有机硅组合物包含以下平均单元式代表的有机聚硅氧烷作为主要成分：（ R13SiO1 / 2）a（R12SiO2 / 2）b（R2SiO3 / 2）c（SiO4 / 2）d其中R1为烷基，烯基，苯基或氢原子; R2是R1，稠合多环芳基或含有稠合多环芳基的基团，只要分子中的R 1或R 2中的至少一个为烯基或氢原子，并且至少一个R 2为分子是缩合多环芳基或含缩合多环芳基的基团; 和a，b，c和d是满足：0.01＆nlE; a＆nlE; 0.8,0和nlE; b＆nlE; 0.5,0.2＆amp; nlE; c＆nlE; 0.9,0和nlE; d <0.2和a + b + c + d = 1。

10. 发明授权

US6001942A Silicon-containing polyimide resin and silicon-containing polyamic acid 有权
标题翻译：含硅聚酰亚胺树脂和含硅聚酰胺酸
公开(公告)号：US6001942A
公开(公告)日：1999-12-14
申请号：US217075
申请日：1998-12-21
申请人： Masaaki Amako , Haruhiko Furukawa , Yoshitsugu Morita , Hiroshi Ueki
发明人： Masaaki Amako , Haruhiko Furukawa , Yoshitsugu Morita , Hiroshi Ueki
IPC分类号： C08G73/10 , C08G77/455 , C08G77/04
CPC分类号： C08G73/1042 , C08G73/106 , C08G77/455
摘要： The invention relates to a silicon-containing polyimide resin comprising (I) 0.1 to 100 mole % of structural units represented by the formula: ##STR1## where Ar.sup.1 is a tetra valent organic group having at least one aromatic ring, R independently represents a monovalent hydrocarbon group free of aliphatic unsaturated bonds, X is selected from an alkyleneoxyalkylene or an alkylene group having 2 or more carbon atoms, Y is an oxygen atom, an alkyleneoxyalkylene group, or an alkylene group having 2 or more carbon atoms, l, m, n are each integers having a value of 1 to 10, p is an integer having a value of 1 to 80, and a is 0 or 1; and (II) 99.9 to 0 mole % of structural units represented by the formula: ##STR2## where Ar.sup.2 is a tetravalent organic group having at least one aromatic ring, and Ar.sup.3 is a divalent organic group having at least one aromatic group.
摘要翻译：本发明涉及一种含硅聚酰亚胺树脂，其包含（I）0.1-100摩尔％的由下式表示的结构单元：其中Ar1是具有至少一个芳族环的四价有机基团，R独立地表示一价无烃基团的脂肪族不饱和键，X选自亚烷氧基亚烷基或碳原子数2以上的亚烷基，Y为氧原子，亚烷基氧化烯基或碳原子数2以上的亚烷基，l，m，n分别为整数值为1〜10，p为1〜80的整数，a为0或1; 和（II）99.9至0摩尔％的由下式表示的结构单元：其中Ar 2是具有至少一个芳环的四价有机基团，Ar 3是具有至少一个芳族基团的二价有机基团。

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