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    • 7. 发明授权
    • Hydroxyphenyl group-containing organosilicon compound, and method for manufacturing same
    • 含羟基苯基的有机硅化合物及其制造方法
    • US06252029B1
    • 2001-06-26
    • US09409810
    • 1999-09-30
    • Masaaki AmakoTadashi Okawa
    • Masaaki AmakoTadashi Okawa
    • C08G7720
    • C08G77/045C07F7/0838
    • This invention relates to a hydroxyphenyl group-containing organosilicon compound of the formula: where X is an alkenyl group; Z is a phenylene group or a carbonyloxy group expressed by —C(O)O-1, Y is a substituted or unsubstituted hydroxyphenyl group, R1 is a hydrocarbon group with two or more carbon atoms, with the various groups being the same or different, R is a monovalent hydrocarbon group containing no aliphatic unsaturated bonds, A is a divalent hydrocarbon group with one or more carbon atoms or a group expressed by the formula —R2—O—R2— where R2 is a divalent hydrocarbon group, m and p are 0 or 1, n is a number from 0 to 2, and q is an integer from 0 to 7. These compounds are useful in curable organosiloxane compositions.
    • 本发明涉及下式的含羟基苯基的有机硅化合物:其中X是烯基; Z是由-C(O)O-1表示的亚苯基或羰氧基,Y是取代或未取代的羟基苯基,R 1是具有两个或更多个碳原子的烃基,各个基团相同或不同 R是不含脂族不饱和键的一价烃基,A是具有一个或多个碳原子的二价烃基或由式-R 2 -O-R 2 - 表示的基团,其中R 2是二价烃基,m和p 为0或1,n为0至2的数,q为0至7的整数。这些化合物可用于可固化的有机硅氧烷组合物。
    • 9. 发明授权
    • Polyorganosiloxane containing methacryloxy group or acryloxy group and method for producing the same
    • 含有甲基丙烯酰氧基或丙烯酰氧基的聚有机硅氧烷及其制造方法
    • US09018332B2
    • 2015-04-28
    • US12863165
    • 2009-01-14
    • Tadashi OkawaEiji Ando
    • Tadashi OkawaEiji Ando
    • C08G77/20C08G77/38C08G77/12C08G77/46
    • C08G77/38C08G77/12C08G77/46
    • A methacryloxy group- or acryloxy group-containing polyorganosiloxane in which a methacryloxy group or acryloxy group is bonded to a silicon atom in the polyorganosiloxane across a long-chain alkylene group or poly(alkyleneoxy)-long chain-alkylene group having 11 to 20 carbon atoms. A method of producing this methacryloxy group- or acryloxy group-containing polyorganosiloxane, in which a silicon-bonded hydrogen atom-containing polyorganosiloxane is addition reacted in the presence of a hydrosilylation reaction catalyst with a 1-alkenyl methacrylate or a 1-alkenyl acrylate or a 1-alkenyloxypolyalkylene glycol methacrylate or a 1-alkenyloxypolyalkylene glycol acrylate.
    • 含有甲基丙烯酰氧基或丙烯酰氧基的聚有机硅氧烷,其中甲基丙烯酰氧基或丙烯酰氧基通过长链亚烷基或聚(亚烷氧基) - 长链亚烷基键合到聚有机硅氧烷中的硅原子上,其具有11至20个碳 原子 在含硅键合的含氢原子的聚有机硅氧烷的加成反应催化剂的存在下,在氢化硅烷化反应催化剂与1-链烯基甲基丙烯酸酯或1-烯基丙烯酸酯的情况下生产该含甲基丙烯酰氧基或含丙烯酰氧基的聚有机硅氧烷的方法,或 1-链烯氧基聚亚烷基二醇甲基丙烯酸酯或1-链烯氧基聚亚烷基二醇丙烯酸酯。