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    • 8. 发明申请
    • AQUEOUS SILSESQUIOXANE DISPERSIONS HAVING LOW CONCENTRATIONS OF REACTION BYPRODUCTS
    • 具有低反应性浓度的水性硅油分散体
    • WO2010105071A3
    • 2011-01-20
    • PCT/US2010027008
    • 2010-03-11
    • INVISTA TECH SARLRUDAT MARTIN AUGUST
    • RUDAT MARTIN AUGUST
    • C07F7/18C08J3/02C08K5/5419C09C1/28D06M15/19
    • D06M13/513B82Y30/00C01P2004/64C01P2004/84C07F7/21C09C1/3081D06M15/643D06M23/08Y10T428/23986
    • Methods of making a composition are disclosed, which comprises: i) forming a dispersion of particles comprising: a) silica, b) a non- volatile cation, and c) water, wherein the non-volatile cation is not ammonium; ii) adding at least one organosilyl coupling agent of formula R1-(R2-O)3-Si where R1 is selected from the group consisting of a substituted alkyl and unsubstituted alkyl, and R2 is selected from the group consisting of methyl, ethyl, propyl and butyl, wherein the substituted alkyl of R1 is not aminoalkyl; iii) reacting the organosilyl coupling agent with the dispersion of particles to form a mixture comprising a silsesquioxane and an alcohol; and iv) removing the alcohol from the mixture by vacuum distillation, wherein final concentration of the alcohol is about 1% by weight or less of the total mixture. Further disclosed are compositions comprising an aqueous dispersion comprising silsesquioxane, a non- volatile cation and an alcohol, and methods of using the composition.
    • 公开了制备组合物的方法,其包括:i)形成颗粒分散体,其包括:a)二氧化硅,b)非挥发性阳离子,和c)水,其中所述非挥发性阳离子不是铵; ii)加入至少一种式R1-(R2-O)3-Si的有机甲硅烷基偶联剂,其中R1选自取代的烷基和未取代的烷基,R2选自甲基,乙基, 丙基和丁基,其中R 1的取代的烷基不是氨基烷基; iii)使有机甲硅烷基偶联剂与颗粒分散体反应形成包含硅倍半氧烷和醇的混合物; 和iv)通过真空蒸馏从混合物中除去醇,其中醇的最终浓度为总混合物的约1重量%或更少。 进一步公开的是包含含有倍半硅氧烷,非挥发性阳离子和醇的水分散体的组合物和使用该组合物的方法。
    • 10. 发明申请
    • TEXTILE SURFACE
    • 纺织区域
    • WO02075038A3
    • 2002-12-19
    • PCT/EP0200539
    • 2002-01-21
    • SCHOELLER TEXTIL AGHUEBNER HANS-JUERGENLOTTENBACH ROLAND
    • HUEBNER HANS-JUERGENLOTTENBACH ROLAND
    • D06M13/02D06M15/256D06M15/643D06N3/00D06N3/18D06N7/00D06B1/00D06M15/19
    • D06N3/0088D06N3/047D06N3/128D06N3/186D06N2205/02D06N2209/141D06N2209/142D06N2211/10
    • The aim of the invention is to produce a textile surface (1), one side of which exhibits hydrophilic properties and the other side hydrophobic properties, whose overall cross-section is hydrophilic. To achieve this, a paste (11) consisting of a viscous emulsion or dispersion of paraffin, polysiloxane and/or fluorine compounds is applied to one side. The layer that has been formed by the first paste (11) is then stabilised by means of a drying process (4) and a second paste (12), consisting of a hydrophilic polymer is subsequently applied to the other side of the textile surface (1), said paste being stabilised by an additional drying process (5). Said steps provide a textile surface (1), which can be produced simply and cost-effectively, is extremely comfortable to wear and which ensures that moisture is immediately absorbed on the hydrophilic side, dispersed over a large area and rapidly removed, whereas the hydrophobic side of said textile surface (1) repels water.
    • 对于织物表面(1),其是具有亲水性和疏水性上的一侧上的其它性质的制造中,被形成在整个横截面的亲水性,贴合(11)被连续地涂布在一侧上,它由一个粘性乳化剂的 或石蜡,聚硅氧烷和/或氟的化合物的分散体。 接着,由第一糊剂(11)被稳定化通过干燥工序(4)形成的层和(1)然后对织物表面的另一侧上施加由亲水性聚合物(12)形成的第二糊(由另外的干燥过程 5)稳定化。 通过这些工艺步骤中,(1)提供了一种织物表面,它以非常简单和经济的方式,其具有高的穿着舒适度和在确保特别是在亲水处理面的水分立即被吸收到产生,分布在大面积 和快速放电,织物表面(1),但在疏水性处理过的一侧西撒克斯剂。