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1. 发明申请

WO2022005612A1 MICROELECTRODE ARRAY WITH A SWITCHABLE HYDROPHILIC SURFACE 审中-公开
公开(公告)号：WO2022005612A1
公开(公告)日：2022-01-06
申请号：PCT/US2021/031468
申请日：2021-05-10
申请人： MICROSOFT TECHNOLOGY LICENSING, LLC
发明人： NGUYEN, Bichlien , SMITH, Jake
IPC分类号： B01L3/00 , B01J19/00 , C12Q1/00 , C25B3/00 , B01L2200/16 , B01L2300/0819 , B01L2300/123 , B01L2300/165 , B01L2400/0427 , B01L2400/082 , B01L3/502792 , B01L7/525 , C07H1/00 , C07H21/04 , C12P19/34 , C12Q1/001 , C12Q1/6844 , C25D9/02
摘要： A switchable hydrophilic surface is created by attaching electrochemically switchable hydrophilicity polymers to the surface of a microelectrode array. Ferrocene polymers are one example of electrochemically switchable hydrophilicity polymers. Activation of electrodes in the microelectrode array changes the oxidation state of metal ions which switches the polymers between hydrophobic and hydrophilic conformations. Selective activation of electrodes can create patterns of wettability on the microelectrode array that may be varied in real time. The switchable hydrophilic surface may be used to control solid-phase synthesis of polymers. Growing polymers may be selectively extended at locations on the microelectrode array that are hydrophilic. The pattern of hydrophobic and hydrophilic regions can be changed during sequential rounds of synthesis to create a variety of different polymers at different locations on the surface of the microelectrode array.

2. 发明申请

WO2020085726A1 리튬 이차 전지용 전극의 제조방법 및 이를 이용하여 제조한 리튬 이차 전지용 전극 审中-公开
公开(公告)号：WO2020085726A1
公开(公告)日：2020-04-30
申请号：PCT/KR2019/013780
申请日：2019-10-18
申请人： 주식회사 엘지화학
发明人： 박솔지 , 안경호 , 한준혁 , 이철행
IPC分类号： H01M4/139 , H01M4/1395 , H01M4/04 , H01M4/66 , H01M4/13 , H01M10/052 , C25D9/02 , C25D9/04
摘要： 본 발명은 전극 집전체를 제1 전해질막 형성용 조성물에 침지시킨 후 전류를 가하여 제1 전해질막을 형성시키는 단계; 및 상기 제1 전해질막이 형성된 전극 집전체를 제2조성물에 침지시킨 후 전류를 가하여 제2 전해질막을 형성시키는 단계;를 포함하고, 상기 제1 전해질막 형성용 조성물 및 제2 전해질막 형성용 조성물 중 하나는 유기 전해질막 형성용 조성물이고, 다른 하나의 조성물은 무기 전해질막 형성용 조성물이며, 상기 무기 전해질막 형성용 조성물은 화학식 1로 표시되는 화합물을 포함하는 것인 리튬 이차 전지용 전극의 제조방법을 제공한다.

3. 发明申请

WO2016203388A1 PROCESS FOR THE PRODUCTION OF FUNCTIONALIZED GRAPHENE 审中-公开
标题翻译：生产功能性石墨的方法
公开(公告)号：WO2016203388A1
公开(公告)日：2016-12-22
申请号：PCT/IB2016/053527
申请日：2016-06-15
申请人： GRAPHENE NANOTECHNOLOGIES HUB S.R.L.
发明人： VALENTINI, Federica
IPC分类号： C01B31/04 , C25B1/00 , C25D9/02
CPC分类号： C25B1/00 , B82Y30/00 , B82Y40/00 , C01B32/19 , C01B32/194 , C25B3/00 , C25D9/02
摘要： Process for the production of nanometric graphene sheets functionalized with at least one biomolecule, wherein an electrochemical cell (1) is provided, comprising two electrodes (2, 3) of graphite immersed in an electrolysis bath (6), wherein the electrolysis bath (6) comprises an electrolytic solution and said biomolecule, the process comprising a step in which a predetermined electric potential (E) is applied to the electrodes (2, 3), whereby the biomolecule covalently binds to a first one (2) of said two electrodes (2, 3) which acts as an anode, and said first electrode (2) exfoliates, thereby producing graphene sheets (7) functionalized with said at least one biomolecule.
摘要翻译：制备用至少一种生物分子官能化的纳米石墨烯片的方法，其中提供了一种电化学电池（1），其包括沉积在电解槽（6）中的两个石墨电极（2,3），其中电解浴（6））包括电解液和所述生物分子，所述方法包括其中向电极（2,3）施加预定电位（E）的步骤，由此生物分子与所述两个电极中的第一个（2）共价结合（2,3），所述第一电极（2）剥离，由此生成用所述至少一种生物分子官能化的石墨烯片（7）。

4. 发明申请

WO2016116683A1 COUCHE DE DIFFUSION GAZEUSE POUR PILE A COMBUSTIBLE, CONSTITUEE PAR UN SUBSTRAT EN CARBONE GREFFE AVEC UN GROUPEMENT AROMATIQUE 审中-公开
标题翻译：燃料电池气体扩散层
公开(公告)号：WO2016116683A1
公开(公告)日：2016-07-28
申请号：PCT/FR2016/050061
申请日：2016-01-14
申请人： COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
发明人： THOMAS, Yohann , BENAYAD, Anass , MORIN, Arnaud , PAUCHET, Joël , SCHRODER, Maxime
IPC分类号： C25D9/02 , H01M8/0234 , B05D1/18
CPC分类号： H01M8/0234 , C25D9/02 , H01M2008/1095
摘要： La présente invention concerne une couche de diffusion gazeuse pour pile à combustible, constituée par un substrat en carbone greffé avec au moins un groupement aromatique de formule (II): dans laquelle: l'astérisque *désigne un atome de carbone étant dépourvu d'hydrogène et de groupement R i , i = 1 à 5, et étant lié de façon covalente au substrat en carbone; au moins deux des groupements R 1 , R 2 , R 3 , R 4 et R 5 sont différents d'un atome d'hydrogène; au moins deux des groupements R 1 , R 2 , R 3 , R 4 et R 5 sont des groupements hydrophobes ou des groupements hydrophiles ou un groupement hydrophobe et un groupement hydrophile.
摘要翻译：燃料电池气体扩散层技术领域本发明涉及一种燃料电池气体扩散层，该燃料电池气体扩散层由接枝有至少一个具有式（II）的芳族基团的碳基底构成：其中： - 星号*表示不含氢和分组的碳原子 Ri，其中i = 1至5，并与碳底物共价键合; - R 1，R 2，R 3，R 4和R 5中的至少两个不同于氢原子; 并且 - R 1，R 2，R 3，R 4和R 5中的至少两个是疏水基团，亲水基团或疏水性基团和亲水基团。

5. 发明申请

WO2015073068A3 LIGHTWEIGHT METAL PARTS PRODUCED BY PLATING POLYMERS 审中-公开
标题翻译：轻质金属部件由聚酯聚合物生产
公开(公告)号：WO2015073068A3
公开(公告)日：2015-08-13
申请号：PCT/US2014045912
申请日：2014-07-09
申请人： UNITED TECHNOLOGIES CORP
发明人： COOK GRANT O
IPC分类号： C25D9/02 , C25D13/04
CPC分类号： G06K19/07749 , B29C37/0025 , B29C64/124 , B29C64/153 , B29C67/0062 , B29C67/0077 , B29C70/42 , B29C70/54 , B29K2079/08 , B29K2105/0058 , B29K2105/12 , B29K2105/251 , B29K2105/253 , B29K2307/04 , B29K2309/08 , B29L2009/008 , B29L2031/082 , B32B27/08 , B32B27/281 , B32B2250/02 , B32B2255/10 , B32B2255/205 , B32B2262/101 , B32B2262/106 , B32B2603/00 , B33Y10/00 , B33Y70/00 , B33Y80/00 , C23C18/1641 , C23C18/1653 , C23C18/1657 , C23C18/166 , C23C18/22 , C23C18/30 , C23C18/32 , C23C28/021 , C23C28/023 , C25D1/003 , C25D1/02 , C25D1/20 , C25D3/02 , C25D5/06 , C25D5/54 , C25D5/56 , C25D7/00 , C25D7/04 , C25D9/02 , C25D17/12 , G01B7/16 , G01D5/12 , G01N3/08 , G01N2203/026 , G01N2203/0268 , G01N2203/0298
摘要： Methods for fabricating lightweight or hollow metal parts are disclosed. First, a polymer is formed into an article of a desired shape or geometry. The outer surface of the article is prepared to receive a catalyst and then the outer surface is activated with the catalyst. A first metallic layer is then plated onto the outer surface to form a structure. Optional additional metallic layers may be applied. The polymer may be removed from the structure before it is subjected to a final heat treatment for alloying purposes.
摘要翻译：公开了制造轻质或中空金属部件的方法。首先，将聚合物形成为所需形状或几何形状的制品。制品的外表面准备接收催化剂，然后用催化剂活化外表面。然后将第一金属层电镀到外表面上以形成结构。可以选择附加的金属层。在进行用于合金化目的的最终热处理之前，可以将聚合物从结构上除去。

6. 发明申请

WO2008047375A1 METHOD FOR ELECTROCHEMICAL DEPOSITION OF MONOLAYERS ON METALLIC SURFACES AND OBJECTS COATED WITH AN ORGANIC MONOLAYER 审中-公开
标题翻译：金属表面单层电化学沉积方法及有机单体涂层
公开(公告)号：WO2008047375A1
公开(公告)日：2008-04-24
申请号：PCT/IL2007/001263
申请日：2007-10-21
申请人： RAMOT AT TEL-AVIV UNIVERSITY LTD , FISHELSON, Nikolay , INBERG, Alexandra , SHACHAM-DIAMAND, Yosi , CROITORU, Nathan
发明人： FISHELSON, Nikolay , INBERG, Alexandra , SHACHAM-DIAMAND, Yosi , CROITORU, Nathan
IPC分类号： B05D1/18 , B05D3/14 , C23C22/02 , C23C22/60 , C25D9/02
CPC分类号： C25D13/04 , B05D1/185 , B05D3/14 , B05D5/00 , B05D7/14 , B05D2202/40 , B82Y30/00 , B82Y40/00 , C23C22/02
摘要： The present invention generally provides methods for the electrodeposition of organic monolayers onto the surfaces of a great variety of objects.
摘要翻译：本发明通常提供了将有机单层电沉积到各种物体的表面上的方法。

7. 发明申请

WO2006081101A3 ELECTROCHEMICAL DEPOSITION PROCESS FOR COMPOSITE STRUCTURES 审中-公开
标题翻译：复合结构的电化学沉积工艺
公开(公告)号：WO2006081101A3
公开(公告)日：2006-09-28
申请号：PCT/US2006001610
申请日：2006-01-17
申请人： BOEING CO , BYRD NORMAN , COKER III ROBERT H , AMUNDSON STEPHEN C , ROJO ARTHUR
发明人： BYRD NORMAN , COKER III ROBERT H , AMUNDSON STEPHEN C , ROJO ARTHUR
IPC分类号： C25D9/02 , C25D9/06 , C25D13/02 , C25D13/04
CPC分类号： C25D13/02 , C25D9/02 , C25D9/06 , C25D13/04
摘要： A method of improving the material properties of a composite by electrodepositing particular polymers, organic compounds or inorganic compounds onto electrically conductiv fibrous substrates, whether individual fibers or as a fabric, to form composites of improved structural properties and having particular physical properties such as being ice phobic, fire resistant, or electrically conductive.
摘要翻译：一种通过将特定聚合物，有机化合物或无机化合物电沉积到导电纤维基材（无论单独的纤维或作为织物）以形成改进的结构性能和具有特定物理性质如冰的复合材料来改进复合材料的材料性能的方法恐惧的，耐火的或导电的。

8. 发明申请

WO2004073034A2 CONTROLLED ELECTROCHEMICAL DEPOSITION OF POLYSACCHARIDES, FILMS AND HYDROGEL AND MATERIALS FORMED THEREFROM 审中-公开
标题翻译：多糖，膜和水合物的控制电化学沉积及其形成的材料
公开(公告)号：WO2004073034A2
公开(公告)日：2004-08-26
申请号：PCT/US2004003878
申请日：2004-02-11
申请人： UNIV MARYLAND , UNIV MARYLAND BIOTECH INST , PAYNE GREGORY F , RUBLOFF GARY W , YI HYUNMIN , FERNANDES ROHAN , WU LI-QUN , GHODSSI REZA , BENTLEY WILLIAM E , CHEN TIANHONG , SMALL DAVID ANDREW
发明人： PAYNE GREGORY F , RUBLOFF GARY W , YI HYUNMIN , FERNANDES ROHAN , WU LI-QUN , GHODSSI REZA , BENTLEY WILLIAM E , CHEN TIANHONG , SMALL DAVID ANDREW
IPC分类号： C08B37/08 , C09D105/08 , C25D9/02 , H01L
CPC分类号： C25D9/02 , C08B37/003 , C09D105/08
摘要： A method is provided for electrochemically depositing a polysaccharide mass having a selected physical state. According to an embodiment, an electrically conductive support of a substrate is contacted with an aqueous solution including a selectively insolubilizable polysaccharide, and the selectively insolubilizable polysaccharide is electrochemically deposited on the electrically conductive support while controlling deposition conditions to form the polysaccharide mass having the selected physical state, such as that of a hydrogel. Deposition may be performed in a spatially and/or temporally controlled manner.
摘要翻译：提供了一种用于电化学沉积具有选定物理状态的多糖物质的方法。根据一个实施方案，将基材的导电载体与包含选择性不溶性多糖的水溶液接触，并且将选择性不溶性多糖电化学沉积在导电载体上，同时控制沉积条件以形成具有选定物理性质的多糖物质状态，例如水凝胶的状态。沉积可以在空间和/或时间上控制的方式进行。

9. 发明申请

WO02098926A3 PROCESS FOR DEPOSITING STRONG ADHEREND POLYMER COATING ONTO AN ELECTRICALLY CONDUCTIVE SURFACE 审中-公开
标题翻译：将强力粘合聚合物涂覆在电导电表面上的工艺
公开(公告)号：WO02098926A3
公开(公告)日：2003-10-16
申请号：PCT/EP0206433
申请日：2002-06-03
申请人： UNIV LIEGE , BERTRAND OLIVIER , JEROME ROBERT , GAUTIER SANDRINE , MAQUET VERONIQUE , DETREMBLEUR CHRISTOPHE , JEROME CHRISTINE , VOCCIA SAMUEL , CLAES MICHAEL , LOU XUDONG , LABAYE DAVID-EMMANUEL
发明人： BERTRAND OLIVIER , JEROME ROBERT , GAUTIER SANDRINE , MAQUET VERONIQUE , DETREMBLEUR CHRISTOPHE , JEROME CHRISTINE , VOCCIA SAMUEL , CLAES MICHAEL , LOU XUDONG , LABAYE DAVID-EMMANUEL
IPC分类号： B05D7/24 , C08F2/58 , C08F8/00 , C08F265/04 , C08F283/06 , C08F285/00 , C08F289/00 , C08F290/00 , C08F290/06 , C08F291/00 , C08F292/00 , C08F293/00 , C09D5/00 , C09D5/25 , C09D5/44 , C09D7/12 , C09D125/18 , C09D133/14 , C09D151/00 , C09D151/08 , C09D151/10 , C09D167/00 , C09D171/02 , C09J151/00 , C09J151/08 , C09J151/10 , C25D9/02 , C25D13/08
CPC分类号： C09J151/10 , C08F2/58 , C08F8/12 , C08F8/42 , C08F265/04 , C08F283/06 , C08F285/00 , C08F289/00 , C08F290/00 , C08F290/06 , C08F291/00 , C08F293/005 , C08F2438/01 , C08F2438/02 , C08F2800/10 , C08L2666/02 , C09D5/4476 , C09D151/003 , C09D151/08 , C09D151/10 , C09J151/003 , C09J151/08 , C08F8/04 , C08F120/18 , C08F212/08
摘要： Process for depositing by electrografting a strong adherent polymer coating onto an electrically conductive surface comprising an electrochemical grafting at the surface of an active monomer for forming a primer coating P onto said surface and having as general formula: X0 (meth)acrylate wherein X is either part of a preformed polymer or is an intermediate agent for polyaddition reaction or is an anchoring group for attachment of a molecule having at least one complementary reactive group. Such process allows formation of new primer by one-step electro-grafting of a reactive polymer called macromonomer. Such process also allows further modification of an initial electrografted polymer (called primer coating) to increase the coating thickness by the so-called grafting-from technique i.e. polymerization of a second monomer or to introduce other types of polymers(also called top coating) via covalent attachment between the primer and the top coating through the X ester group by the so called grafting onto technique. Such process also allows to graft onto the primer coating compounds like functional polymer, peptide, protein, oligonucleotide, dyes, drugs, anti-bacterian compounds.
摘要翻译：通过将强粘附聚合物涂层电致电沉积到导电表面上的方法，其包括在活性单体的表面处的电化学接枝，用于在所述表面上形成底漆涂层P并具有如下通式：XO（甲基）丙烯酸酯，其中X为预先形成的聚合物的一部分或是用于加聚反应的中间体，或者是用于连接具有至少一个互补反应性基团的分子的锚定基团。这种方法允许通过称为大分子单体的反应性聚合物的一步电接枝形成新的引物。这种方法还允许进一步修饰初始的电移植聚合物（称为底漆涂层），以通过所谓的接枝技术即第二单体的聚合或通过其它类型的聚合物（也称为顶涂层）经由通过所谓的接枝技术通过X酯基团将引物和顶部涂层共价连接。这种方法也可以接枝到诸如功能聚合物，肽，蛋白质，寡核苷酸，染料，药物，抗细菌化合物的底漆涂层化合物上。

10. 发明申请

WO2003025257A1 ELECTRODEPOSITION OF REDOX POLYMERS AND CO-ELECTRODEPOSITION OF ENZYMES BY COORDINATIVE CROSSLINKING 审中-公开
标题翻译：氧化还原聚合物的电沉积和辅助交联的酶的共沉淀
公开(公告)号：WO2003025257A1
公开(公告)日：2003-03-27
申请号：PCT/US2002/030105
申请日：2002-09-20
申请人： THERASENSE, INC.
发明人： HELLER, Adam , GAO, Zhiqiang , DEQUAIRE, Murielle
IPC分类号： C25D9/02
CPC分类号： C25D9/02 , C12Q1/004 , C12Q1/6825 , C25D5/18
摘要： Thin films of transition metal complex-based redox polymers (94) are electrodeposited on electrodes (90) via application of fixed or cycled potential. When hydrated, an electrodeposited film conducts electrons by electron exchange between backbone-bound, but mobile, functional segments of its redox polymer constituents. These functional segments, or redox complexes, have labile ligands, such as chloride anions, for example, in their coordinating spheres. The backbones of the redox polymers have strongly coordinating ligands, such as pyridine- or imidazole-containing functions, for example, which are generally not coordinated prior to deposition. Electrodeposition results from coordinative crosslinking by exchange of labile ligands and strongly coordinating ligands between polymer chains, provided sufficient functional segments of the redox polymers are present at the electrode surface. When a biological macromolecule or protein (98), such as redox enzyme, is added to the solution from which the redox polymer is electrodeposited, it is co-electrodeposited on the electrode surface.
摘要翻译：基于过渡金属络合物的氧化还原聚合物（94）的薄膜通过施加固定或循环电位电沉积在电极（90）上。当水合时，电沉积膜通过其氧化还原聚合物组分的主链结合但可移动的功能区段之间的电子交换导电。这些功能区段或氧化还原络合物在其配位球中具有不稳定的配体，例如氯化物阴离子。氧化还原聚合物的主链具有强配位配体，例如含吡啶或咪唑的功能，例如在沉积之前通常不协调。电沉积是通过交换不稳定配体和在聚合物链之间强配位配体而产生的协调交联，只要氧化还原聚合物的足够的功能区段存在于电极表面。当将生物大分子或蛋白质（98）如氧化还原酶加入到电沉积氧化还原聚合物的溶液中时，它共同电沉积在电极表面上。

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