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    • 3. 发明申请
    • METHOD OF SALT BATH NITRIDING FOR PRODUCING IRON MEMBER HAVING IMPROVED CORROSION RESISTANCE AND IRON PARTS
    • 用于生产具有改善的耐腐蚀性和铁件的铁构件的盐浴氮化方法
    • WO02044438A1
    • 2002-06-06
    • PCT/JP2001/010369
    • 2001-11-28
    • C23C8/50C23C8/52C23C12/02C23C28/04
    • C23C8/50C23C8/52
    • A method of immersing an iron member in a molten salt bath containing Li, Na and K as cation components and CNO and CO3 to form a nitride layer on the surface thereof, characterized in that one or more selected from among lithium hydroxide, sodium hydroxide and potassium hydroxide is further added to the molten salt bath, to thereby form a nitride layer on the surface of the iron member and simultaneously a iron lithium composite oxide layer on the uppermost surface thereof. A bath-preparing agent or a component-replenishing agent containing a hydrate or free water may be added to the molten salt bath in place of the sodium hydroxide or the like. The salt bath is preferably agitated with a wet air having (1 X 10 kg or more of H2O)/(1 kg of dry air). Li, Na and K components are preferably present in the salt bath in such a range that provides a mixture of carbonates of the three elements having a solidifying point of 500 DEG C or lower and the mole ratio of Na : K is preferably 2:8 to 8:2. CNO is preferably contained in an amount of 5 to 35 wt %. The accumulation of by-produced CN in the salt bath is preferably suppressed to a content of 2 wt % or less. The salt bath preferably has a temperature of 450 to 650 DEG C. The resultant iron member exhibits improved wear resistance and also improved corrosion resistance.
    • 将铁构件浸渍在含有Li,Na和K作为阳离子成分和CNO 2和CO 3 2-的熔盐浴中以在其表面上形成氮化物层的方法,其特征在于,选自 在氢氧化锂中,进一步向熔融盐浴中加入氢氧化钠和氢氧化钾,从而在铁构件的表面上形成氮化物层,同时在其最表面上形成铁锂复合氧化物层。 可以将熔融制剂或含有水合物或游离水的组分补充剂代替氢氧化钠等添加到熔融盐浴中。 盐浴优选用(1×10 -2 kg或更多的H 2 O)/(1kg干燥空气)的湿空气搅拌。 Li,Na和K成分优选存在于盐浴中,其提供具有500℃以下凝固点的三元素的碳酸酯的混合物,Na:K的摩尔比优选为2:8 到8:2。 CNO - 优选含量为5〜35重量%。 在盐浴中副产物CN的积聚优选抑制在2重量%以下的含量。 盐浴的温度优选为450〜650℃。所得的铁构件具有改善的耐磨性,并且还具有改善的耐腐蚀性。