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    • 3. 发明申请
    • SOLID SOLUTIONS OF MONOAZO PIGMENTS
    • 单一颜料的固体溶液
    • WO00026303A1
    • 2000-05-11
    • PCT/EP1999/007893
    • 1999-10-19
    • C08K5/23C08L101/00C09B26/02C09B29/14C09B29/16C09B67/20C09B67/22C09D7/12C09D11/00C09D201/00C09B67/48
    • C09B67/0051
    • Solid solutions of monoazo pigments comprising a host lattice and at least one guest material wherein the host lattice is a material having general formula (I) or (II). In formula (I), R = H, CO2 or CO2R, where R may be phenyl which can be substituted one to three times with the following substituents: C1-C4alkyl, C1-C4alkoxy, halogen, NO2 or -NHC(O)CH3, R , R , R , R and R , independently from each other may be C1-C20alkyl, C1-C20alkoxy, C2-C20alkenyl, C1-C20alkylthiol, C1-C20alkoxycarbonyl, hydroxyC1-C4alkoxy, phenyl, benzyl, phenylthio, halogen, -CN, -NO2, -CF3, -COR , -COOR , -CONR R , -SO2R , -SO2NR R , -NR NR or -OR2 in which each R and R are each independently H, C1-C4alkyl or phenyl; M is an earth alkaline metal cation or Mn . In formula (II) R stands for C1-C20alkyl, C1-C20alkoxy, C2-C20alkenyl, C1-C20alkylthiol, C1-C20alkoxycarbonyl, hydroxyC1-C4alkoxy, phenyl, benzyl, phenylthio, halogen, -CN, -NO2, -CF3, -COR , -COOR , -CONR R , -SO2R , -SO2NR R , -NR NR or -OR2 in which each R and R are each independently H, C1-C4alkyl or phenyl, and wherein the guest material(s) have the same general formulae as their respective hosts with the proviso that they differ in molecular structure at at least one position from the respective hosts, as well as compositions comprising the inventive solid solutions and their uses.
    • 包含主晶格和至少一种客体材料的单偶氮颜料的固溶体,其中主晶格是具有通式(I)或(II)的材料。 在式(I)中,R 1 = H,CO 2或CO 2 R,其中R可以是可以被以下取代基取代一至三次的苯基:C 1 -C 4烷基,C 1 -C 4烷氧基,卤素,NO 2或 -NHC(O)CH 3,R 2,R 3,R 4,R 5和R 6彼此独立地可以是C 1 -C 20烷基,C 1 -C 20烷氧基,C 2 -C 20烯基, C 1 -C 20烷基硫醇,C 1 -C 20烷氧基羰基,羟基C 1 -C 4烷氧基,苯基,苄基,苯硫基,卤素,-CN,-NO 2,-CF 3,-COR 7,-COOR 7,-CONR 7 R 8, ,-SO 2 R 7,-SO 2 NR 7 R 8,-NR 7 NR 8或-OR 2,其中每个R 7和R 8各自独立地为H,C 1 -C 4烷基或 苯基; M 2+是碱土金属阳离子或Mn 2+。 在式(II)中,R 9代表C 1 -C 20烷基,C 1 -C 20烷氧基,C 2 -C 20烯基,C 1 -C 20烷基硫醇,C 1 -C 20烷氧基羰基,羟基C 1 -C 4烷氧基,苯基,苄基,苯硫基,卤素,-CN,-NO 2, CF 3,-COR 7,-COOR 7,-CONR 7 R 8,-SO 2 R 7,-SO 2 NR 7 R 8,-NR 7 NR 8或 -OR 2,其中每个R 7和R 8各自独立地为H,C 1 -C 4烷基或苯基,并且其中客体材料具有与它们各自的主体相同的通式,条件是它们在分子 在相应主体的至少一个位置处的结构,以及包含本发明固溶体及其用途的组合物。
    • 10. 发明申请
    • SQUARAINE DYES
    • WO0058405A3
    • 2001-02-01
    • PCT/GB0001223
    • 2000-03-30
    • AMERSHAM PHARM BIOTECH UK LTDWEST RICHARD MARTINCUMMINS WILLIAM JONATHANNAIRNE ROBERT JAMES DOMETTBULL MATTHEW GRAHAM
    • WEST RICHARD MARTINCUMMINS WILLIAM JONATHANNAIRNE ROBERT JAMES DOMETTBULL MATTHEW GRAHAM
    • C07D209/14C07D209/60C07D215/12C07D215/14C07D277/64C07D401/08C07D401/14C07D413/08C07H19/10C07K2/00C09B1/00C09B23/00C09B26/02C09B57/00C09K11/06G01N33/58G01N33/68
    • C09B57/007G01N33/583
    • Compounds having the structure: W = Sq - A where A has the formula: -NR R , where R and R are the same or different and each is H or C1-C20 hydrocarbon or a group -L-G, or one of R and R is -OR or -NR R or -COR or -NR COR or -N =R or R and R together form a single ring or fused ring system, saturated or unsaturated and unsubstituted or substituted, or an azacrown or a metal-binding group, Sq represents formula (A) or formula (B) where m is 1, 2 or 3, W represents a wing moiety having structure (C), L' is a linker of 0-3 moieties selected from carbon atoms and arylene groups, the dotted line represents a single ring or fused ring system, aromatic or heterocyclic, unsubstituted or substituted, containing or joined to a tertiary or quaternary N atom, and having unsaturation co-ordinated with that of L' = Sq, each of R , R , R and R is H or C1-C20 hydrocarbon or a group -L-G, R is a negative charge or a group -L-G, L is a linker chain of 0 to 30 moieties, branched or unbranched which optionally contains one or more arylene groups, or O or N or N or S or S or P or P or Se atoms, and G is a functional or a reactive group by means of which the compound may be covalently linked to a biomolecule, or a group which enhances or reduces water solubility or provides electron donating or withdrawing properties to modify the spectral characteristics of the compound, and homo-dimers and -oligomers and hetero-dimers and -oligomers of the compounds.
    • 具有以下结构的化合物:W = Sq-A其中A具有下式:-NR 1 R 2,其中R 1和R 2相同或不同,并且各自为H或C 1 -C 20烃 或基团-LG,或R 1和R 2中的一个为-OR 5或-NR 6 R 7或-COR 7或-NR 6 COR 7。 或-N = R 8或R 1和R 2一起形成饱和或不饱和的且未取代或取代的单环或稠环体系,或偶氮染料或金属结合基团,Sq表示式( A)或式(B)其中m为1,2或3,W表示具有结构(C)的翼部分,L'为选自碳原子和亚芳基的0-3个部分的连接体,虚线表示 单环或稠环系,未取代或取代的,含有或连接至叔或季N原子,并且具有与L'= Sq的不饱和键相互独立的R 5,R 6, >,R 7和R 8是H或C 1 -C 20烃或基团-LG,R 9是负电荷或基团-LG,L是连接基团 0至30个部分,任选含有一个或多个亚芳基,或O或N或N +或S或S +或P或P +或Se原子的支链或非支链,并且G是官能团 或反应性基团,通过其可以将化合物共价连接到生物分子,或提高或降低水溶性或提供给电子或取出性质以改变化合物的光谱特征的基团,以及同型二聚体和低聚物 和化合物的异二聚体和低聚物。