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1. 发明申请

WO1992004389A1 CYANATO GROUP CONTAINING PHENOLIC RESINS, AND PHENOLIC TRIAZINES DERIVED THEREFROM 审中-公开
标题翻译：含有酚醛树脂的CYANATO集团及其衍生的酚醛树脂
公开(公告)号：WO1992004389A1
公开(公告)日：1992-03-19
申请号：PCT/US1991006360
申请日：1991-09-05
申请人： ALLIED-SIGNAL INC.
发明人： ALLIED-SIGNAL INC. , DAS, Sajal , PREVORSEK, Dusan, C.
IPC分类号： C08G08/28
CPC分类号： C08G8/00 , C08G8/28 , C08G73/0655
摘要： The present invention is a cyanato group containing phenolic resin, and phenolic triazine resins derived therefrom. The resin of the present invention is stable and has a long shelf life. This is indicated by the gel time of greater than 3 minutes and by a shelf life equal to or greater than 3 days.
摘要翻译：本发明是含有氰基的酚醛树脂和衍生自其的酚醛三嗪树脂。本发明的树脂是稳定的并且具有长的保质期。凝胶时间大于3分钟，保质期等于或大于3天。

2. 发明申请

WO1991003507A1 PROCESS FOR MAKING CYANATO CONTAINING PHENOLIC RESINS 审中-公开
标题翻译：制备含有酚醛树脂的CYANATO的方法
公开(公告)号：WO1991003507A1
公开(公告)日：1991-03-21
申请号：PCT/US1990004922
申请日：1990-08-30
申请人： ALLIED-SIGNAL INC.
发明人： ALLIED-SIGNAL INC. , DAS, Sajal
IPC分类号： C08G08/28
CPC分类号： C08G8/28
摘要： The present invention is directed to a process of preparing a cyanato group containing phenolic resin by reacting the corresponding phenolic resin with a tertiary amine in a water immiscible, non-hydrogen bonding solvent at a temperature of preferably less than about 25 °C to form the corresponding ammonium salt of the phenolic resin; and reacting the ammonium salt with a cyanogen halide at a temperature equal to or less than about 0 °C in said solvent to form the cyanato containing phenolic resin.

3. 发明申请

WO1997019970A1 A PROCESS FOR THE PRODUCTION OF CYANATE ESTER RESINS HAVING UNIQUE COMPOSITION 审中-公开
标题翻译：一种生产具有独特成分的氰酸酯树脂的方法
公开(公告)号：WO1997019970A1
公开(公告)日：1997-06-05
申请号：PCT/US1996018277
申请日：1996-11-21
申请人： ALLIEDSIGNAL INC.
发明人： ALLIEDSIGNAL INC. , BEDWELL, William, B. , SWEDO, Raymond, L. , DEBONA, Bruce, T. , GREEN, George, D.
IPC分类号： C08G08/28
CPC分类号： B01J19/2415 , B01J2219/00058 , B01J2219/00099 , B01J2219/00166 , B01J2219/00186 , C08G8/28
摘要： A continuous process for the production of a phenolic-based cyanate ester resin is provided and includes the steps of: feeding a phenolic organic compound, a trialkylamine and a cyanogen halide into a continuous, plug-flow type reactor; causing the reactants to flow through and react in the reactor over a period of time defined as a residence time; continuously reacting the phenolic organic compound, the trialkylamine and the cyanogen halide in the reactor; and maintaining a temperature in the reactor of between -75 DEG C to 0 DEG C. The reactor has a length which is equal to or greater than ten times its internal diameter. The mol equivalent concentration of the cyanogen halide is greater than the mol equivalent concentration of the trialkylamine, and the mol equivalent of the trialkylamine is greater than the mol equivalent of the phenolic organic compound. The reactants are resident for a long enough time in the reactor to achieve at least substantial conversion of the phenol groups to cyanate ester groups, but for short enough a time to substantially suppress undesirable side reactions. The phenolic-based cyanate ester resins prepared by the continuous process may contain as much as 95 percent by weight or more cyanate ester groups.
摘要翻译：提供了一种用于生产酚类氰酸酯树脂的连续方法，包括以下步骤：将酚类有机化合物，三烷基胺和氰卤化物进料到连续的流动型反应器中; 使反应物在定义为停留时间的时间内流过并在反应器中反应; 在反应器中使酚类有机化合物，三烷基胺和氰卤化物连续反应; 并将反应器中的温度保持在-75℃至0℃之间。反应器的长度等于或大于其内径的十倍。氰卤化物的摩尔当量浓度大于三烷基胺的摩尔当量浓度，三烷基胺的摩尔当量大于酚类有机化合物的摩尔当量。反应物在反应器中驻留足够长的时间以实现酚基团至少基本上转化为氰酸酯基团，但足够短的时间以基本上抑制不期望的副反应。通过连续方法制备的酚基氰酸酯树脂可以含有多达95重量％或更多个氰酸酯基团。

4. 发明申请

WO1996023013A1 PROCESS FOR PRODUCTION OF MULTICYANATE ESTERS 审中-公开
标题翻译：生产多糖酯的方法
公开(公告)号：WO1996023013A1
公开(公告)日：1996-08-01
申请号：PCT/IB1996000168
申请日：1996-01-29
申请人： ALLIEDSIGNAL INC.
发明人： ALLIEDSIGNAL INC. , ROTH, David, W., H., Jr. , DAS, Sajal
IPC分类号： C08G08/28
CPC分类号： C08G8/28 , Y10S210/904 , Y10S210/908
摘要： The invention is directed to a process of preparing multicyanate esters by: a) reacting an adduct of a tertiary amine and a phenol-formaldehyde oligomer with cyanogen halide in a solvent to form a reaction product stream containing at least one compound selected from the group consisting of tertiary amine-hydrohalide salt, solvent, and impurities, and, based upon the total weight of the reaction product stream excluding the weight of the tertiary amine-hydrohalide salt, from about 10 percent to about 40 percent of a multicyanate ester; b) recycling a portion of the reaction product stream into the mixture of step a; and c) separating and recovering the solvent and tertiary amine from the reaction product stream. The multicyanate ester products produced are useful as bonding agents in friction materials, molding materials, coatings, and adhesives.
摘要翻译：本发明涉及通过以下方法制备多氰酸酯的方法：a）使叔胺和苯酚 - 甲醛低聚物的加合物与氰卤化物在溶剂中反应，形成含有至少一种选自以下的化合物的反应产物流：的叔胺 - 氢卤酸盐，溶剂和杂质，并且基于除了叔胺 - 氢卤酸盐的重量之外的反应产物流的总重量，约10％至约40％的多氰酸酯; b）将一部分反应产物流再循环到步骤a的混合物中; 和c）从反应产物流中分离和回收溶剂和叔胺。所生产的多氰酸酯产物可用作摩擦材料，模塑材料，涂料和粘合剂中的粘合剂。

5. 发明申请

WO1984001952A1 THERMOSETTING RESINOUS POLYOL 审中-公开
标题翻译：热固性树脂POLYOL
公开(公告)号：WO1984001952A1
公开(公告)日：1984-05-24
申请号：PCT/US1983001090
申请日：1983-07-18
申请人： GEORGIA-PACIFIC CORPORATION
发明人： GEORGIA-PACIFIC CORPORATION , BORNSTEIN, Leopold, F.
IPC分类号： C08G08/28
CPC分类号： C08G8/28 , C08G8/36
摘要： A new phenolic-aldehyde based resinous, thermosetting polyol and a method for its production. According to the invention, phenol is condensed using acid catalysis, under freely evaporated atmospheric conditions with a molar excess of aldehyde, in the presence of polyhydroxyl component.
摘要翻译：一种新的酚醛树脂，热固性多元醇及其生产方法。根据本发明，在多羟基组分的存在下，在自由蒸发的大气条件下用摩尔过量的醛在酸性催化下将苯酚缩合。

6. 发明申请

WO1998003568A1 THERMOSETTING PHENOLIC RESIN COMPOSITION 审中-公开
标题翻译：热固性酚醛树脂组合物
公开(公告)号：WO1998003568A1
公开(公告)日：1998-01-29
申请号：PCT/US1997012274
申请日：1997-07-15
申请人： GEORGIA-PACIFIC RESINS, INC.
发明人： GEORGIA-PACIFIC RESINS, INC. , QURESHI, Shahid , CHAN, Charles
IPC分类号： C08G08/28
CPC分类号： C08G8/28
摘要： This invention relates to a resin composition capable of being thermally cured having both a long pot life at low temperatures and a fast curing rate at higher temperatures containing a mixture of (a) a phenol-formaldehyde resole resin, and (b) a latent curing agent selected from a particular class of nitrogen-containing acidic phosphorus compounds made from either phosphoric acid or phosphorous acid.
摘要翻译：本发明涉及能够热固化的树脂组合物，其在低温下具有长的适用期和在较高温度下具有快速固化速率，其中含有（a）苯酚 - 甲醛甲阶酚醛树脂的混合物，和（b）潜在固化选自由磷酸或亚磷酸制成的特定种类的含氮酸性磷化合物的试剂。

7. 发明申请

WO1997000900A1 STRONGLY BASIC TERTIARY AMINO ALCOHOLS AS CATALYST 审中-公开
标题翻译：作为催化剂的强碱性碱性氨基醇
公开(公告)号：WO1997000900A1
公开(公告)日：1997-01-09
申请号：PCT/US1996010868
申请日：1996-06-24
申请人： ANGUS CHEMICAL COMPANY
发明人： ANGUS CHEMICAL COMPANY , WU, Gaoming
IPC分类号： C08G08/28
CPC分类号： C08G14/06 , C08G8/10
摘要： A process for preparing ashless and low-ash phenolic resole resins having no amine odor, and a process for preparing storage-stable mixtures or premix solutions of phenol-formaldehyde resin and urea or urea-formaldehyde resins. These processes react phenol and formaldehyde in the presence of an effective catalytic amount of a low-volatile and strongly basic tertiary amino alcohol either alone or in combination with an inorganic base.
摘要翻译：一种不具有胺气味的无灰和低灰分酚醛树脂树脂的制备方法，以及制备苯酚 - 甲醛树脂和脲 - 脲 - 甲醛树脂的储存稳定的混合物或预混合溶液的方法。这些方法在有效催化量的低挥发性和强碱性叔氨基醇存在下单独或与无机碱组合反应苯酚和甲醛。

8. 发明申请

WO1992005211A1 CYANATO GROUP CONTAINING PHENOLIC RESINS, AND PHENOLIC TRIAZINES DERIVED THEREFROM 审中-公开
标题翻译：含有酚醛树脂的CYANATO集团及其衍生的酚醛树脂
公开(公告)号：WO1992005211A1
公开(公告)日：1992-04-02
申请号：PCT/US1991006345
申请日：1991-09-05
申请人： ALLIED-SIGNAL INC.
发明人： ALLIED-SIGNAL INC. , DAS, Sajal
IPC分类号： C08G08/28
CPC分类号： C08G8/00 , C08G8/28 , C08G73/0655
摘要： The present invention is a cyanato group containing phenolic resin, and to phenolic triazine resins derived therefrom. The cyanato group containing phenolic resin of the present invention can be completely cured to form a phenolic triazine resin having a glass transition temperature equal to or greater than 250 DEG C.
摘要翻译：本发明是含有氰基的酚醛树脂，和由其衍生的酚醛三嗪树脂。本发明的含氰基酚醛树脂可以完全固化，形成玻璃化转变温度等于或大于250℃的酚三嗪树脂。

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