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    • 5. 发明申请
    • PROCESS AND INSTALLATION FOR RECOVERING CATALYST COMPONENTS
    • 方法和装置用于回收成分的催化剂
    • WO1995003887A1
    • 1995-02-09
    • PCT/DE1994000865
    • 1994-07-26
    • SIEMENS AKTIENGESELLSCHAFTHUMS, Erich
    • SIEMENS AKTIENGESELLSCHAFT
    • B01J38/42
    • C22B34/345B01J23/92B01J37/0036B01J38/00C22B34/1222C22B34/225C22B34/365Y02P10/23
    • A process is disclosed for recovering components of a catalyst (4, 6, 8), in particular a spent DeNox catalyst. The catalyst (4,6, 8) is ground and the ground catalyst is then shaped into bodies (18) having a defined grain. Alternatively, the ground catalyst (4, 6, 8) is applied on a reducing agent (36) with a defined grain and hardened thereon. The thus produced bodies (18) or the thus modified reducing agents (38), and if required an additional reducing agent (20, 36), are then chlorinated in reducing conditions. Titanium tetrachloride TiCl4 is then separated by distillation from the other chlorine and/or chlorine-oxygen compounds contained in the gas mixture produced during chlorination. The thus obtained titanium tetrachloride TiCl4 is burned with oxygen O2 or with oxygen O2 and hydrogen H2. The thus recovered titanium dioxide pigment meets the specification of commercially available titanium dioxide pigments and may thus be used for producing new DeNOx catalysts. This process and the arrangement (2, 32) are in principle suitable for reusing the most different types of metal oxide catalysts that contain titanium dioxide as base material.
    • 用于回收催化剂的组分(4,6,8),insbesonder废DeNOx催化剂erfindugsgemäss提供了一种方法,其中催化剂后的数(4,6,8)是地,和研磨产物的催化剂(以形成成形体 18)具有限定颗粒尺寸进行处理。 可替换地,研磨产物Katalaysator(4,6,8)上的还原剂(36)被提供,施加有规定的晶粒尺寸和固化在那里。 其后,将模制体制得的(18)或所谓改性的还原剂(38),和任选的其它还原剂(20,36)可在还原条件下进行氯化。 四氯化钛的TiCl 4然后,通过蒸馏,从该被包含在该氯化所得到的气体混合物的其他氯和/或氯氧化合物分离。 以这种方式获得的四氯化钛的TiCl 4中燃烧与氧气O 2或O 2的氧气和氢气H 2。 将由此得到的二氧化钛颜料具有商业的二氧化钛颜料的规格,因此可以用于制造新的脱硝催化剂。 该方法和设备(2,32)原则上适用于含有二氧化钛作为原料的各种金属氧化物催化剂的处理。