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    • 1. 发明申请
    • PRODUCTION OF ACID SOLUBLE TITANIA
    • 酸溶性钛酸钠的生产
    • WO1990013614A1
    • 1990-11-15
    • PCT/AU1990000190
    • 1990-05-10
    • WIMMERA INDUSTRIAL MINERALS PTY. LTD.HOLLITT, Michael, JohnO'BRIEN, Brian, Anthony
    • WIMMERA INDUSTRIAL MINERALS PTY. LTD.
    • C10G23/047
    • C22B34/1236
    • The specification discloses a method of making acid digestible titania. The method comprises the steps of: (1) adding a magnesium or manganese compound to a titaniferous mineral if the content of manganese and magnesium in the mineral is insufficient; (2) heating the mineral in the presence of a reductant for a sufficient length of time and at a sufficiently high temperature to permit the reduction of iron containing compounds to metallic iron and enable titania present to convert to an acid digestible form; (3) cooling the mineral; and (4) separating iron from the mineral by means of an aqueous aeration step. The titaniferous mineral contains insufficient magnesium and manganese if the following expression is not satisfied: 1.98a + 1.14b/d >/= 0.08 where a represents the percentage by weight of MgO contained in the mineral, (b) represents the percentage by weight fo MnO contained in the mineral; and (d) represents the percentage by weight of TiO2 contained in the mineral. The magnesium or manganese compound is either an oxide or a compound that is capable of converting to an oxide under reaction conditions. An aqueous aeration technique described in the specification involves the use of a sequesterant that is capable of sequestering iron from the mineral without significantly lowering the local pH while at the same time permitting the formation of an oxide of iron at a point away from the mineral. An example of such a sequesterant is citric acid.
    • 该说明书公开了一种制备酸可消化的二氧化钛的方法。 该方法包括以下步骤:(1)如果矿物中锰和镁的含量不足,则将镁或锰化合物加入含钛矿物中; (2)在还原剂存在下将矿物加热足够长的时间和足够高的温度以允许将含铁化合物还原成金属铁,并使二氧化钛存在以转化成酸可消化形式; (3)冷却矿物; 和(4)通过含水曝气步骤从矿物中分离铁。 如果不满足以下表达式,则含钛矿物含有不足的镁和锰:1.98a + 1.14b / d> / = 0.08其中a表示矿物中所含的MgO的重量百分数,(b) 矿物中含有MnO; 和(d)表示矿物中所含的TiO 2的重量百分比。 镁或锰化合物是在反应条件下能够转化为氧化物的氧化物或化合物。 说明书中描述的含水曝气技术涉及使用能够从矿物中螯合铁的螯合剂,而不显着降低局部pH,同时允许在远离矿物质的点形成铁氧化物。 这种螯合剂的实例是柠檬酸。
    • 3. 发明申请
    • CONTINUOUS NON-POLLUTING LIQUID PHASE TITANIUM DIOXIDE PROCESS
    • 连续非喷射液相二氧化钛工艺
    • WO98054095A1
    • 1998-12-03
    • PCT/US1998/006499
    • 1998-04-01
    • B01J8/08B01J8/22C01G23/02C01G23/053C22B3/00C22B3/08C22B34/12
    • C22B34/1236B01J8/22C01G23/0532
    • A process and apparatus for producing titanium dioxide from titanium ore or slag is disclosed. The ore or slag (2) is reacted with sulfuric acid (3) in a reactor (1) in which hot gas for agitation (4) is used. Makeup acid from line (6) is fed to line (3). Together with recovered acid from the spray evaporator (34) reacted product overflows from the reactor to rotary filter (8). The filter cake is washed in the rotary filter whose water comes in through line (14). The washed filter cake is delivered to dissolving tank (10). Concentrated acid together with wash water is returned to the reactor through line (3). Filtrate is hydrolized in hydrolysis tank (21) to form titanium dioxide hydrate which is then calcined in a fluid bed calciner (30) to form titanium dioxide.
    • 公开了一种用于从钛矿石或炉渣生产二氧化钛的方法和设备。 在其中使用用于搅拌热气(4)的反应器(1)中,矿石或炉渣(2)与硫酸(3)反应。 来自线(6)的补充酸被喂入线(3)。 与来自喷雾蒸发器(34)的回收酸一起使产物从反应器溢出到旋转过滤器(8)。 滤饼在水通过管线(14)进入的旋转过滤器中洗涤。 将洗涤过的滤饼送至溶解槽(10)。 浓酸与洗涤水一起通过管线(3)返回反应器。 滤液在水解槽(21)中水解以形成二氧化钛水合物,然后在流化床煅烧炉(30)中煅烧以形成二氧化钛。
    • 4. 发明申请
    • EXTRACTION PROCESS FOR REACTIVE METAL OXIDES
    • 反应性金属氧化物的萃取方法
    • WO2004113230A1
    • 2004-12-29
    • PCT/GB2004/002543
    • 2004-06-11
    • THE UNIVERSITY OF LEEDSJHA, AnimeshMALPAN, Pailo, AntonyTATHAVADKAR, Vilas, Dattatray
    • JHA, AnimeshMALPAN, Pailo, AntonyTATHAVADKAR, Vilas, Dattatray
    • C01G23/047
    • C22B34/1236C01F7/142C01F7/38C01G23/047C01G49/06C22B1/02C22B5/10C22B7/04C22B21/0038C22B34/1209C22B34/1259Y02P10/214Y02P10/218Y02P10/224Y02P10/23
    • The present invention relates to a zero-waste process for extraction of alumina from différent types of bauxite ores and red mud residues and of titanium dioxide from ilmenite. Iron oxide is first reduced to metallic iron above the melting point of C-saturated cast iron alloy which yields a high-C iron alloy and an AI and Ti metal oxide rich slag which is then treated with alkali carbonate to form alkali aluminates and titanates. The alkali aluminates are separated by water leaching from which the hydroxide of alumina is precipitated by bubbling C0 2 . The residue from water leaching is treated with sulphuric acid and Ti0 2 is precipitated via a hydrolysis route. The process recovers most of the metal values and generates only small quantities of silicious residues at pH 4-5 which can be used for soil conditioning. The present also relates to a method for selective separation of Ti0 2 -rich oxides from titaniferrous ore/residue materials via oxidative roasting in the presence of alkali carbonate or carbonates followed by aqueous leaching of the roasted material and selective precipitation of Ti0 2 under controlled condition below pH=4.
    • 本发明涉及从不同类型的铝土矿和红泥渣以及来自钛铁矿的二氧化钛提取氧化铝的零废弃方法。 首先将氧化铁还原成高于C饱和铸铁合金的熔点的金属铁,其产生高C铁合金和富含Al和Ti的富含金属氧化物的炉渣,然后用碱金属碳酸盐处理以形成碱金属铝酸盐和钛酸盐。 碱金属铝酸盐通过水浸出分离,氧化铝的氢氧化物通过鼓泡形成CO 2沉淀。 用硫酸处理来自水浸的残渣,经水解路线沉淀出TiO 2。 该过程恢复大部分金属值,并在pH 4-5下仅产生少量的可用于土壤调理的硅残余物。 本发明还涉及一种通过在碱金属碳酸盐或碳酸盐存在下通过氧化焙烧从钛铁矿/残渣物质中选择性分离富含TiO 2的氧化物的方法,然后将焙烧物料进行含水浸出并在低于pH的控制条件下选择性沉淀TiO 2 = 4。
    • 6. 发明申请
    • IMPROVED METHOD FOR METAL PRODUCTION
    • 改进的金属生产方法
    • WO2014060766A1
    • 2014-04-24
    • PCT/GB2013/052719
    • 2013-10-17
    • UNIVERSITY OF BRADFORD
    • KUMARI, JeyaPATEL, Raj
    • C22B5/04C22B34/00C22B34/12
    • C22B3/04C22B1/02C22B5/04C22B34/00C22B34/10C22B34/1236C22B34/1268C22B34/14C22B34/20C22B59/00
    • The invention provides a method for the production of a metal, the method comprising the steps of mixing an oxide of the metal with a reducing agent comprising a Group II metal or a hydride thereof in the presence of water and/or an organic solvent, heating the mixture of oxide and reducing agent, leaching the resulting material with water; and washing the leached material with a dilute aqueous acid. Typically, the metal is a transition or rare earth metal, the oxide of the metal is an oxide of a transition or rare earth metal, and the reducing agent is selected from calcium or magnesium or the hydrides of calcium and magnesium. The metal is generally obtained at a purity of around 98.5-99.1 %, and the method is much quicker than the methods of the prior art and has a much lower carbon footprint, thereby providing an option which is more sustainable, environmentally friendly, and accommodative for industries. Particularly good results are observed in the production of transition metals such as titanium, tantalum and niobium.
    • 本发明提供一种生产金属的方法,该方法包括以下步骤:在水和/或有机溶剂的存在下,将金属的氧化物与包含第II族金属或其氢化物的还原剂混合,加热 氧化还原剂的混合物,用水浸出所得材料; 并用稀酸水溶液洗涤沥滤材料。 通常,金属是过渡金属或稀土金属,金属的氧化物是过渡金属或稀土金属的氧化物,还原剂选自钙或镁或钙和镁的氢化物。 该金属的纯度通常为约98.5-99.1%,该方法比现有技术方法快得多,并且具有低得多的碳足迹,从而提供了更可持续,环保和调节的选择 为行业。 在过渡金属如钛,钽和铌的生产中观察到特别好的结果。
    • 10. 发明申请
    • PROCESS AND FURNACE FOR THE PRODUCTION OF TiO2 PIGMENT ACCORDING TO THE SULFATE PROCESS
    • 根据硫酸盐工艺生产TiO2颜料的工艺和工艺
    • WO99041317A1
    • 1999-08-19
    • PCT/IB1999/000273
    • 1999-02-16
    • C01G23/08C01G23/053C09C1/36C22B34/12
    • C01G23/0532C01P2004/54C01P2006/12C22B34/1236
    • A process for the production of titanium dioxide by dissolving titanium raw materials with sulfuric acid, producing a metal sulfate-containing titanyl sulfate solution, hydrolyzing the titanyl sulfate, separating the titanium dioxide hydrate from the metal sulfate-containing sulfuric acid by filtration, optionally bleaching the titanium dioxide hydrate by reducing treatment in acidic solution and calcining the titanium dioxide hydrate optionally mixed with doping chemicals and rutile nuclei to titanium dioxide, characterized in that the sulfate-containing titanium dioxide hydrate is dried in a dryer at temperatures from 90 to 400 DEG C, preferably 90 to 200 DEG C, especially 90 to 150 DEG C, and the titanium dioxide hydrate dust from the dryer exhaust is separated by filtration, the dried titanium dioxide hydrate is calcined in a rotary kiln directly heated with flue gasses at temperatures in the range from 800 to 1100 DEG C (solids temperature) and the exhaust is de-dusted and de-sulfurized as well as a calcining furnace for the production of titanium dioxide from dried sulphate-containing titanium dioxide hydrate in the form of a rotary kiln with a length-diameter ratio in the range of 5 to 10.
    • 通过用硫酸溶解钛原料生产二氧化钛的方法,制备含硫酸金属硫酸硫酸盐溶液,水解硫酸氧钛,通过过滤从含金属硫酸盐的硫酸中分离二氧化钛水合物,任选地漂白 二氧化钛水合物通过在酸性溶液中还原处理和煅烧二氧化钛水合物,任选地与掺杂化学品和金红石核混合到二氧化钛上,其特征在于将含硫酸盐的二氧化钛水合物在干燥器中在90-400℃的温度下干燥 优选90〜200℃,特别是90〜150℃,通过过滤分离来自干燥机排气口的二氧化钛水合物粉末,将干燥的二氧化钛水合物在直接用烟道气体加热的回转窑中煅烧, 在800至1100℃(固体温度)的范围内,排气除尘和脱硫 以及用于从长度比在5至10范围内的回转窑形式的干燥含硫酸盐的二氧化钛水合物生产二氧化钛的煅烧炉。