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    • 7. 发明申请
    • PROCESS FOR PRODUCING POLYPROPYLENE FROM C3 OLEFINS SELECTIVELY PRODUCED IN A FLUID CATALYTIC CRACKING PROCESS
    • 在流体催化裂化过程中选择性生产的C3烯烃生产聚丙烯的方法
    • WO0164763A3
    • 2002-01-31
    • PCT/US0106687
    • 2001-03-01
    • EXXONMOBIL CHEM PATENTS INC
    • LADWIG PAUL KASPLIN JOHN ESTUNTZ GORDON FCHEN TAN-JEN
    • C07C4/06C07B61/00C07C11/06C08F2/00C08F4/18C08F10/00C08F10/06C10G11/05C10G11/08C10G11/18C10G51/02C10G57/02
    • C10G57/02C10G51/026C10G2400/20
    • A process for producing polymers from olefins selectively produced from a catalytically cracked or thermally cracked naphtha stream is disclosed herein. The naphtha stream is introduced into a process unit comprised of a reaction zone, a stripping zone, a catalyst regeneration zone, and a fractionation zone. The naphtha feedstream is contacted in the reaction zone with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500 DEG to 650 DEG C and a hydrocarbon partial pressure from about 10 to 40 psia. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with stream in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, which is then recycled to the reaction zone. Overhead products from the reaction zone are passed to a fractionation zone where a stream of C3 products is recovered and a stream rich in C4 and/or C5 olefins is recycled to the stripping zone. The olefins can be further processed and polymerized to form a variety of polymer materials.
    • 本文公开了从由催化裂化或热裂解的石脑油流选择性地生产的烯烃生产聚合物的方法。 将石脑油流引入由反应区,汽提区,催化剂再生区和分馏区组成的工艺单元中。 石脑油原料流在反应区中与含有约10至50wt。 在包括温度在约500至650℃和烃分压约10至40psia的反应条件下具有平均孔径小于约0.7纳米的结晶沸石的%。 蒸气产物被顶部收集,催化剂颗粒在通向催化剂再生区的途中通过汽提区。 挥发物在汽提区中用气流汽提,催化剂颗粒被送到催化剂再生区,其中焦炭从催化剂燃烧,然后再循环到反应区。 来自反应区的开销产物被送入分馏区,其中回收C3产物流,并且将富含C4和/或C5烯烃的物流再循环到汽提区。 烯烃可以进一步加工和聚合以形成各种聚合物材料。