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1. 发明申请

WO1998008918A1 LIQUID CRYSTAL POLYMERS 审中-公开
标题翻译：液晶聚合物
公开(公告)号：WO1998008918A1
公开(公告)日：1998-03-05
申请号：PCT/GB1997002225
申请日：1997-08-20
申请人： THE SECRETARY OF STATE FOR DEFENCE , BLACKWOOD, Keith, Moray , JONES, Michelle , LACEY, David , HALL, Alan, William , TOYNE, Kenneth, Johnson , PRINGLE, Steven
发明人： THE SECRETARY OF STATE FOR DEFENCE
IPC分类号： C09K19/38
CPC分类号： C09K19/3895 , C08F246/00 , C09K19/3842 , C09K19/3852 , Y10T428/10
摘要： Methods, based on the Wittig-Horner reaction, are provided for the synthesis of compounds of formula (I) wherein m is from 5-150, X and Y are independently selected from: CN, H, OH, COCH3, CO2H, CO2R1, where R1 is C1-12alkyl, NCS, SCN, CF3, CH2X where X is F, Cl, Br, OH, CHF2 and formula (IB), wherein J for each X and Y group is independently selected from: CH2, single covalent bond, OOC, CO2, O, CH2O, OCH2, CH2CO2, CH2OOC; p = 1-20; L for each X and Y group is independently selected from: O, CH2, OCO, CO2, S, NH; (a) is defined by formula (IC), wherein rings A, B and C are independently selected from phenyl, cyclohexyl, pyridine and pyrimidine and may be independently of each other substituted with at least one of Cl or F; linking groups A and B may be selected from single bond, CO2, OOC, CH2O, OCH2, CH2CH2, CC; Z is selected from CN, F, Cl, NO2, R, OR, CO2R, CF3, OOCR, NCS, SCN, where R = straight chain or branched chain alkyl and may include from 1-16 carbon atoms and including where one or more non-adjacent CH2 groups may be substituted by CH(CN), CH(CF3), CH(Cl), CH(CH3) in chiral or non-chiral form; provided that at least one of X and Y is selected from (IB); said method comprising the polymerisation of general formula (II), wherein X and Y are as defined for formula (I).
摘要翻译：提供了基于Wittig-Horner反应的合成式（I）化合物，其中m为5-150，X和Y独立地选自：CN，H，OH，COCH 3，CO 2 H，CO 2 R 1，其中R1是C1-12烷基，NCS，SCN，CF3，CH2X，其中X是F，Cl，Br，OH，CHF2和式（IB），其中每个X和Y基团的J独立地选自：CH 2，单共价键，OOC，CO 2，O，CH 2 O，OCH 2，CH 2 CO 2，CH 2 OOC; p = 1-20; 每个X和Y基团的L独立地选自：O，CH 2，OCO，CO 2，S，NH; （a）由式（IC）定义，其中环A，B和C独立地选自苯基，环己基，吡啶和嘧啶，并且可以彼此独立地被Cl或F中的至少一个取代; 连接基团A和B可以选自单键，CO 2，OOC，CH 2 O，OCH 2，CH 2 CH 2，CC; Z选自CN，F，Cl，NO 2，R，OR，CO 2 R，CF 3，OOCR，NCS，SCN，其中R =直链或支链烷基，并且可以包括1-16个碳原子，并且包括其中一个或多个不相邻的CH2基可以被手性或非手性形式的CH（CN），CH（CF 3），CH（Cl），CH（CH 3）取代; 条件是X和Y中的至少一个选自（IB）; 所述方法包括通式（II）的聚合，其中X和Y如式（I）所定义。

2. 发明申请

WO1997016472A1 LIQUID CRYSTAL POLYMERS 审中-公开
标题翻译：液晶聚合物
公开(公告)号：WO1997016472A1
公开(公告)日：1997-05-09
申请号：PCT/GB1996002655
申请日：1996-10-31
申请人： THE SECRETARY OF STATE FOR DEFENCE , HALL, Alan, William , LACEY, David , SAGE, Ian, Charles , BLACKWOOD, Keith, Moray , JONES, Michelle
发明人： THE SECRETARY OF STATE FOR DEFENCE
IPC分类号： C08G61/00
CPC分类号： C08G61/00 , C09K19/3895 , Y10T428/10
摘要： Compounds of formula (I) are provided which may be used in a variety of devices including liquid crystal devices, piezoelectric devices, pyroelectric devices and in optical recording media; in said formula n = at least 5; Rx, Ry, Rz are independently selected from formula (IA), wherein Y is selected from COO, OCO, O, S, CHOH, CHF, CH2; Q = (CH2)n wherein one or more non-adjacent methylenes may be replaced by O and n = 1 - 20; Z is selected from O, S, single covalent bond, COO, OCO; when Y is CH2 then n may also be 0; (IB) represents any mesogenic group; Rx, Ry, Rz are also independently selected from H, OH, OCOR , COOH, CO2R , (CH2)pOH, (CH2)pCO2H, -(CH2)pOR or -(CH2)pCO2R and p = 1 - 20, R = H or C1-16 alkyl; when R = C2-16 alkyl the terminal CH3 group may be replaced by Br or Cl; provided that at least one of Rx, Ry, Rz is selected from formula (IA).
摘要翻译：提供式（I）化合物，其可用于包括液晶装置，压电装置，热电装置和光学记录介质的各种装置中; 在所述式中n =至少5; Rx，Ry，Rz独立地选自式（IA），其中Y选自COO，OCO，O，S，CHOH，CHF，CH 2; Q =（CH 2）n，其中一个或多个不相邻的亚甲基可被O代替，n = 1-20; Z选自O，S，单共价键，COO，OCO; 当Y是CH2时，n也可以是0; （IB）代表任何介晶组; Rx，Ry，Rz也独立地选自H，OH，OCOR 1，COOH，CO 2 R 1，（CH 2）p OH，（CH 2）p CO 2 H， - （CH 2）pOR 1或 - （CH 2）p CO 2 R 1和p = 1-20，R 1 = H或C 1-6烷基; 当R 1 = C2-16烷基时，末端CH 3基团可被Br或Cl取代; 条件是Rx，Ry，Rz中的至少一个选自式（IA）。

3. 发明申请

WO1988006179A1 POLYMER MATERIALS 审中-公开
标题翻译：聚合物材料
公开(公告)号：WO1988006179A1
公开(公告)日：1988-08-25
申请号：PCT/EP1988000105
申请日：1988-02-12
申请人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ... , LATTERMANN, Günter
发明人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ...
IPC分类号： C09K19/38
CPC分类号： C08G63/19 , C08G63/6856 , C08G69/26 , C08G69/44 , C09K19/3804 , C09K19/3833 , C09K19/3895
摘要： Polymer materials containing side groups, which are bound through a spacer in 1,3,5- or 1,2,4,5-position substituted carbo- or heterocyclic 6-membered ring systems are suitable as organic substrates in electronics.
摘要翻译：含有侧基的聚合物材料通过1,3,5-或1,2,4,5-位取代的碳杂环或杂环的6元环系统中的间隔基结合，可用作电子学中的有机底物。

4. 发明申请

WO2016114211A1 重合性化合物及び光学異方体审中-公开
标题翻译：可聚合的化合物和光学的各向异性体
公开(公告)号：WO2016114211A1
公开(公告)日：2016-07-21
申请号：PCT/JP2016/050322
申请日：2016-01-07
申请人： DIC株式会社
发明人：門本　豊 , 堀口　雅弘 , 小磯　彰宏
IPC分类号： C07C251/86 , C07D277/82 , C08F20/34 , C09K19/38
CPC分类号： C07C251/86 , C07D277/82 , C08F20/34 , C08F122/22 , C08F122/24 , C09K19/2014 , C09K19/3068 , C09K19/322 , C09K19/3444 , C09K19/3497 , C09K19/38 , C09K19/3895 , C09K2019/0448 , C09K2019/0481 , C09K2019/0485
摘要：　液晶ディスプレイの視野角を向上させるために、位相差フィルムの複屈折率の波長分散性を小さく、若しくは逆にすることが求められているところ、本発明は、重合性組成物に添加した際に結晶の析出等が起こらず高い保存安定性を有するような重合性化合物を提供し、当該重合性化合物を含有する重合性組成物を重合して得られるフィルム状の重合物を作製した際にムラが生じにくい重合性組成物を提供することを課題とする。更に、当該重合性組成物を重合させることで得られる重合体及び当該重合体を用いた光学異方体を提供することを課題とする。
摘要翻译：为了提高液晶显示器的视角，需要减小相位差膜的双折射的波长分散性的大小或反转，本发明解决了提供高分子量聚合性化合物的问题储存稳定性，并且当将可聚合化合物加入到可聚合组合物中时，不会发生液晶的沉淀等，并且提供含有可聚合化合物的可聚合组合物，从而当膜状聚合时不容易发生不均匀制造通过聚合可聚合组合物获得的材料。本发明还涉及提供通过使可聚合组合物聚合而获得的聚合物和使用该聚合物的光学各向异性体的问题。

5. 发明申请

WO1997016471A1 LIQUID CRYSTAL POLYMERS 审中-公开
标题翻译：液晶聚合物
公开(公告)号：WO1997016471A1
公开(公告)日：1997-05-09
申请号：PCT/GB1996002650
申请日：1996-10-31
申请人： THE SECRETARY OF STATE FOR DEFENCE , HALL, Alan, William , LACEY, David , SAGE, Ian, Charles , BLACKWOOD, Keith, Moray , JONES, Michelle
发明人： THE SECRETARY OF STATE FOR DEFENCE
IPC分类号： C08G61/00
CPC分类号： C09K19/3833 , C08G61/00 , C09K19/3895
摘要： Compounds of formula (I) are provided which may be used in a variety of devices including liquid crystal devices, piezoelectric devices, pyroelectric devices and in optical recording media, wherein X1 and X2 are independently selected from H, CN, COCH3, CO2CH3, m = at least 5; X3 and X4 are independently selected from formula (IA), wherein Y is selected from COO, OCO, O, S, CHOH, CHF, CH2; Q = (CH2)n wherein one or more non-adjacent methylenes may be replaced by O and n = 1-20; Z is selected from O, S, single covalent bond, COO, OCO; when Y is CH2 then n may also be 0; formula (A) represents any mesogenic group; X3 and X4 are also independently selected from H, OH, OCOR , COOH, CO2R , (CH2)pOH, (CH2)pCO2H, -(CH2)pOR or -(CH2)pCO2R and p = 1-20, R = H or C1-16alkyl, when R = C2-16alkyl the terminal CH3 group may be replaced by Br or Cl; provided that at least one of X3 and X4 is selected from formula (IA).
摘要翻译：提供式（I）化合物，其可用于包括液晶装置，压电装置，热电装置和光学记录介质的各种装置中，其中X 1和X 2独立地选自H，CN，COCH 3，CO 2 CH 3，m =至少5; X 3和X 4独立地选自式（IA），其中Y选自COO，OCO，O，S，CHOH，CHF，CH 2; Q =（CH 2）n，其中一个或多个不相邻亚甲基可被O代替，n = 1-20; Z选自O，S，单共价键，COO，OCO; 当Y是CH2时，n也可以是0; 式（A）表示任何介晶组; X和X 4还独立地选自H，OH，OCOR 1，COOH，CO 2 R 1，（CH 2）p OH，（CH 2）p CO 2 H， - （CH 2）pOR 1或 - （CH 2）p CO 2 R 1 >和p = 1-20，R 1 = H或C 1-6烷基，当R 1 = C 2-6-16烷基时，末端CH 3基团可被Br或Cl取代; 条件是X3和X4中的至少一个选自式（IA）。

6. 发明申请

WO1993025634A1 LIQUID CRYSTAL POLYMERS 审中-公开
标题翻译：液晶聚合物
公开(公告)号：WO1993025634A1
公开(公告)日：1993-12-23
申请号：PCT/GB1993001018
申请日：1993-05-19
申请人： THE SECRETARY OF STATE FOR DEFENCE IN HER ... , VERRALL, Mark, Andrew , COATES, David
发明人： THE SECRETARY OF STATE FOR DEFENCE IN HER ...
IPC分类号： C09K19/38
CPC分类号： C09K19/3895 , C08F122/10
摘要： A novel LCP material based on fumarate and maleate di-esters is disclosed having general formula (I); R1 and R2 may or may not be the same but have general structure (II); (a) = (b), (c), (d); p = 2 to 14; q = 0 or 1; r = 1 or 2; s = 1 or 2; X = O, CO2, O2C, CH2; Y = C2H4, O, CO2, O2C; Z = CN, halogen, R, CO2R, OR, O2CR, wherein R = chiral or achiral.
摘要翻译：描述了基于马来酸酯和富马酸酯二酯的新型液晶聚合物（LCP）材料。该物质对应于通式（I），其中R 1和R 2可以相同或不同，但对应于通式（II）; （a）=（b），（c），（d）; p = 2至14; q = 0或1; r = 1或2; s = 1或2; X = O，CO 2，O 2 C，CH 2; Y = C 2 H 4，O，CO 2，O 2 C; Z = CN，卤素，R，CO2R，OR，O2CR，其中R为手性或非手性。

7. 发明申请

WO1997016504A1 LIQUID CRYSTAL POLYMERS 审中-公开
标题翻译：液晶聚合物
公开(公告)号：WO1997016504A1
公开(公告)日：1997-05-09
申请号：PCT/GB1996002654
申请日：1996-10-31
申请人： THE SECRETARY OF STATE FOR DEFENCE , HALL, Alan, William , LACEY, David , SAGE, Ian, Charles , BLACKWOOD, Keith, Moray , JONES, Michelle
发明人： THE SECRETARY OF STATE FOR DEFENCE
IPC分类号： C09K19/38
CPC分类号： C08G61/00 , C09K19/3833 , C09K19/3895
摘要： Compounds of formula (I) are provided which may be used in a variety of devices including liquid crystal devices, piezoelectric devices, pyroelectric devices and in optical recording media: m = at least 5; X1 and X2 are independently selected from formula (IA), wherein Y is selected from COO, OCO, O, S, CHOH, CHF, CH2; Q=(CH2)n wherein one or more non-adjacent methylenes may be replaced by O and n=1-20; Z is selected from O, S, single covalent bond, COO, OCO; when Y is CH2 then n may also be 0; (a) represents any mesogenic group; X1 and X2 are also independently selected from H, OH, OCOR , COOH, CO2R , (CH2)pOH, (CH2)pCO2H, -(CH2)pOR or-(CH2)pCO2R and p=1-20, R =H or C1-16alkyl; when R =C2-16alkyl the terminal CH3 group may be replaced by Br or C1; provided that at least one of X1 and X2 is selected from formula (IA).
摘要翻译：提供式（I）化合物，其可用于包括液晶装置，压电装置，热电装置和光学记录介质的各种装置中：m =至少5; X 1和X 2独立地选自式（IA），其中Y选自COO，OCO，O，S，CHOH，CHF，CH 2; Q =（CH 2）n，其中一个或多个不相邻亚甲基可被O代替，n = 1-20; Z选自O，S，单共价键，COO，OCO; 当Y是CH2时，n也可以是0; （a）代表任何介晶组; X 1和X 2还独立地选自H，OH，OCOR 1，COOH，CO 2 R 1，（CH 2）p OH，（CH 2）p CO 2 H， - （CH 2）pOR 1或 - （CH 2）p CO 2 R 1 且p = 1-20，R 1 = H或C 1-6烷基; 当R 1 = C2-16烷基时，末端的CH3基团可被Br或C1取代; 条件是X1和X2中的至少一个选自式（IA）。

8. 发明申请

WO1993025633A1 LIQUID CRYSTAL POLYMERS 审中-公开
标题翻译：液晶聚合物
公开(公告)号：WO1993025633A1
公开(公告)日：1993-12-23
申请号：PCT/GB1993001017
申请日：1993-05-19
申请人： THE SECRETARY OF STATE FOR DEFENCE IN HER ... , VERRALL, Mark, Andrew , PARRI, Owain, Llyr , COATES, David
发明人： THE SECRETARY OF STATE FOR DEFENCE IN HER ...
IPC分类号： C09K19/38
CPC分类号： C08F120/30 , C08F120/36 , C09K19/3895
摘要： A novel LCP material based on forked side chain acrylates is disclosed having a general formula (I), wherein W = H, CH3, Cl; R1 and R2 may or may not be the same but have general structure (II); α = (a); (b); (c); p = 2 to 14; q = 0 or 1; r = 1 or 2; s = 1 or 2; X = O, CO2, O2C, CH2; Y = C2H4, O, CO2, O2C; Z = CN, halogen, R, CO2R, OR, O2CR, wherein R = chiral or achiral.

9. 发明申请

WO1993025632A1 LIQUID CRYSTAL POLYMERS 审中-公开
标题翻译：液晶聚合物
公开(公告)号：WO1993025632A1
公开(公告)日：1993-12-23
申请号：PCT/GB1993001016
申请日：1993-05-19
申请人： THE SECRETARY OF STATE FOR DEFENCE IN HER ... , VERRALL, Mark, Andrew , GREENFIELD, Simon , COATES, David
发明人： THE SECRETARY OF STATE FOR DEFENCE IN HER ...
IPC分类号： C09K19/38
CPC分类号： C09K19/3895
摘要： A novel LCP material based on di-esters of itaconic acid is disclosed having general formula (I), where R1 and R2 may or may not be the same and have general structure (II); (a) = (b), (c), (d); p = 2 to 14; q = 0 or 1; r = 1 or 2; s = 1 or 2; X = O, CO2, O2C, CH2; Y = C2H4, O, CO2, O2C; Z = CN, halogen, R, CO2R, OR, O2CR; wherein R = chiral or achiral; excluding X = O and X = CH2 when A = phenyl, r = s = 1, Y = CO2, O2C, q = 1 and Z = CN, R, CO2R, OR.
摘要翻译：本发明涉及一种基于衣康酸和通式（I）二酯的新型液晶聚合物材料（LCP）。其中R1和R2可以相同或不同，并具有通式结构（II）; （a）=（b），（c），（d）; p = 2至4; q = 0或1; r = 1或2; s = 1或2; X = O，CO 2，O 2 C，CH 2; Y = C 2 H 4，O，CO 2，O 2 C; Z = CN，卤素，R，CO2R，OR，O2CR; R是手性或非手性的; X可以代表O和CH 2时A =苯基，R = S = 1，Y = CO 2，O 2 C，Q = 1和Z = CN，R，CO 2 R，OR。

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