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    • 1. 发明申请
    • SULFODERIVATIVES OF INDANTHRONE, LYOTROPIC LIQUID CRYSTAL SYSTEM AND ANISOTROPIC FILM ON THEIR BASE
    • IND ONE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE
    • WO2003104242A2
    • 2003-12-18
    • PCT/US2003/018175
    • 2003-06-09
    • OPTIVA, INC.NAZAROV, Victor, V.SIDORENKO, Elena, N.
    • NAZAROV, Victor, V.SIDORENKO, Elena, N.
    • C07F
    • C09B5/58C09B5/56C09B67/0038C09K19/3483C09K19/603Y10T428/10Y10T428/1036Y10T428/1041
    • The present invention relates to organic chemistry, in particular, to synthesis of sulfoderivatives of the polycyclic compounds and fabrication of optically anisotropic coatings on their base.The indanthrone sulfoderivatives of the general structural formulas I or II capable of forming LLC phase are disclosed. The disclosed compounds could be used, in particular, for producing optically isotropic or anisotropic and at least partially crystalline films. The application also includes the liquid crystal systems based on the disclosed compounds, and anisotropic films. (I) (II) wherein n is 3 or 4,R = CH3, C2H5, OCH3, OC2H5, Cl, Br, OH, NH2,z is the value selected from the list including 0, 1, 2, 3, and 4, M -counterion, andj - number of counterions in a dye molecule, and which can be fractional in case of one counterion belonging to several molecules, and in case n>1, counterions may be different.
    • 本发明涉及有机化学,特别涉及多环化合物的磺基衍生物的合成和其底物上的光学各向异性涂料的制造。公开了能够形成LLC相的通式结构式I或II的阴丹酮磺化衍生物。 所公开的化合物可以特别用于制备光学各向同性或各向异性和至少部分结晶的膜。 该应用还包括基于所公开的化合物的液晶体系和各向异性薄膜。 (I)(II)其中n为3或4,R = CH 3,C 2 H 5,OCH 3,OC 2 H 5,Cl,Br,OH,NH 2,z为从包括0,1,2,3和4的列表中选择的值 ,M-对中,和 - 染料分子中的抗衡离子数,并且在一个抗衡离子属于几个分子的情况下可以是分数,并且在n≥1的情况下,抗衡离子可能不同。