专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明申请

WO2015095369A1 DISTILLED EPOXY NOVOLAC RESINS 审中-公开
标题翻译：蒸馏环氧NOVOLAC树脂
公开(公告)号：WO2015095369A1
公开(公告)日：2015-06-25
申请号：PCT/US2014/070919
申请日：2014-12-17
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： FAN, William W. , JEWELL, Dennis W. , WALLACE, Stephen B. , DETTLOFF, Marvin L. , LARSEN, Travis H.
IPC分类号： C08G59/02 , B01D1/06 , C08G59/08
CPC分类号： C08G59/025 , B01D3/32 , B01D5/006 , C08G59/08
摘要： A continuous process comprising a) separating an epoxy novolac resin comprising oligomers having an average functionality of greater than 2.5 and a hydrolyzable chlorine content of less than 450 ppm with a continuous evaporator apparatus to form i) a first distillate vapor fraction comprising epoxy novolac resin having more than 75 weight percent of 2 functional components and wherein the mass of the first distillate vapor fraction is in the range of from 15 to 40 weight percent of the starting epoxy novolac resin; and ii) a first bottom fraction comprising epoxy novolac resin having less than 5 weight percent of 2 functional components and having a glass transition temperature of at least 15C higher compared to the starting epoxy novolac resin when cured; b) recovering the first bottom fraction product; and c) condensing the first distillate vapor fraction to form a first condensed distillate vapor fraction; d) separating the first condensed distillate vapor fraction with a second continuous evaporator apparatus to form i) a second distillate vapor fraction wherein the mass of the second distillate vapor fraction is in the range of from 40 to 70 weight percent of the first condensed distillate vapor fraction; and ii) a second bottom fraction; e) recovering the second bottom fraction product; and f) condensing the second distillate vapor fraction to form a second condensed distillate vapor fraction product comprising at least 98 weight percent of 2 functional components with a total chlorine content less than 900 ppm, is disclosed.
摘要翻译：一种连续方法，其包括：a）第一蒸馏馏分，其包含环氧酚醛清漆树脂，其包含平均官能度大于2.5且低于450ppm的可水解氯含量小于450ppm的环氧酚醛清漆树脂，大于75重量％的2个功能组分，并且其中第一馏出物蒸气馏分的质量在起始环氧酚醛清漆树脂的15至40重量％的范围内; 和ii）包含环氧酚醛清漆树脂的第一底部馏分，其与固化时的起始环氧酚醛清漆树脂相比，具有小于5重量％的2个功能组分，玻璃化转变温度至少高15℃; b）回收第一底部馏分产物; 和c）冷凝第一馏出物蒸气馏分以形成第一冷凝馏出物蒸气馏分; d）用第二连续蒸发器装置分离第一浓缩馏出物蒸气馏分以形成i）第二馏出物蒸气馏分，其中第二馏出物蒸气馏分的质量在第一馏分馏出物的40至70重量％的范围内分数; 和ii）第二底部馏分; e）回收第二底部馏分产物; 并且f）冷凝第二馏出物蒸气馏分以形成包含至少98重量％的总氯含量低于900ppm的2个功能组分的第二冷凝馏出物蒸气馏分产物。

2. 发明申请

WO2012044442A1 PROCESS FOR PREPARING EPOXY RESINS 审中-公开
标题翻译：制备环氧树脂的方法
公开(公告)号：WO2012044442A1
公开(公告)日：2012-04-05
申请号：PCT/US2011/050597
申请日：2011-09-07
申请人： DOW GLOBAL TECHNOLOGIES LLC , HEFNER, Robert, E.
发明人： HEFNER, Robert, E.
IPC分类号： C08G59/02 , C07D301/32
CPC分类号： C08G65/2696 , C07D301/28 , C07D301/32 , C08G59/025 , Y02P20/582
摘要： A process for preparing an aliphatic or cycloaliphatic epoxy resin including the steps of: (I) reacting a mixture of (a) an aliphatic or cycloaliphatic hydroxyl containing material, (b) an epihalohydrin, (c) a basic acting substance, (d) a non-Lewis acid catalyst, and (e) optionally, a solvent, forming an epoxy resin composition; (II) subjecting the epoxy resin composition produced in step (I) to a separation process to remove (A) "light" components such as, for example, solvent used in the epoxidation reaction, if any, unreacted epihalohydrin, and co-products such as di(epoxypropyl)ether; (B) unreacted aliphatic or cycloaliphatic hydroxyl containing material, if any; (C) partially epoxidized aliphatic or cycloaliphatic hydroxyl containing material, such as, for example, MGE; (D) fully epoxidized aliphatic or cycloaliphatic hydroxyl containing material, such as, for example, DGE, such that the (E) aliphatic or cycloaliphatic polyfunctional epoxy resin product remaining contains no more than 50 % by weight of said fully epoxidized aliphatic or cycloaliphatic hydroxyl containing material (D); and (III) recycling the isolated partially epoxidized aliphatic or cycloaliphatic hydroxyl containing material (C) and any mixtures of partially epoxidized aliphatic or cycloaliphatic hydroxyl containing material (C) with fully epoxidized aliphatic or cycloaliphatic hydroxyl containing material (D) from step (II) to a new reaction mixture of step (I).
摘要翻译：一种制备脂族或环脂族环氧树脂的方法，包括以下步骤：（I）使（a）含脂肪族或脂环族羟基的材料，（b）表卤代醇，（c）碱性作用物质，（d）非路易斯酸催化剂和（e）任选的形成环氧树脂组合物的溶剂; （II）将步骤（I）中制备的环氧树脂组合物进行分离处理以除去（A）“轻”成分，例如环氧化反应中使用的溶剂（如果有的话）未反应的表卤代醇和共同产物如二（环氧丙基）醚; （B）未反应的脂肪族或脂环族羟基的物质，如果有的话; （C）部分环氧化脂族或脂环族羟基的材料，例如MGE; （D）完全环氧化的脂族或脂环族羟基的材料，例如DGE，使得（E）脂族或脂环族多官能环氧树脂产物含有不超过50重量％的所述完全环氧化的脂族或脂环族羟基（D）; 和（III）将来自步骤（II）的分离的部分环氧化脂族或脂环族羟基的材料（C）和部分环氧化的含脂肪族或含脂环族羟基的材料（C）的混合物与完全环氧化的脂族或脂环族羟基化合物（D）与步骤（I）的新的反应混合物。

3. 发明申请

WO2016035668A1 エポキシ樹脂、エポキシ樹脂の製造方法、硬化性樹脂組成物、その硬化物、繊維強化複合材料、及び成形品审中-公开
标题翻译：环氧树脂，环氧树脂生产方法，可固化树脂组合物，固化产品，纤维增强复合材料和模制品
公开(公告)号：WO2016035668A1
公开(公告)日：2016-03-10
申请号：PCT/JP2015/074204
申请日：2015-08-27
申请人： DIC株式会社
发明人：森永　邦裕 , 木村　真実 , 林　弘司 , 中村　高光
IPC分类号： C08G59/20
CPC分类号： C08G59/60 , C08G59/025 , C08G59/08 , C08G59/3218 , C08G59/58 , C08G59/621 , C08J5/042 , C08J2363/02
摘要：　硬化物における耐熱性及び強靭性に優れ、湿熱条件下に晒された場合にもこれら物性の低下が少ない硬化性樹脂組成物、その硬化物、繊維強化複合材料及び成型品を提供する。具体的には、エポキシ樹脂と硬化剤とを含有し、前記エポキシ樹脂が、フェノールノボラック樹脂をポリグリシジルエーテル化して得られるエポキシ樹脂であって、前記フェノールノボラック樹脂が、結合部位の異なるビスフェノールＦを含有しており、当該ビスフェノールＦ成分のうち、液体クロマトグラフ測定における［ｏ，ｐ'］結合体の含有量が、｛［ｏ，ｐ'］結合体＋［ｏ，ｏ'］結合体＋［ｐ，ｐ'］結合体｝に占める面積比率で３０～４５％の範囲であることを特徴とする硬化性樹脂組成物、その硬化物及び当該組成物を含む繊維強化複合材料とその成型品を提供する。
摘要翻译：提供：固化性树脂组合物，其固化物具有优异的耐热性和韧性，并且即使在暴露于潮湿的热条件下时也不会降低这些性能; 其固化产物; 纤维增强复合材料; 和模制品。具体地说，提供了包含环氧树脂和固化剂的固化性树脂组合物，其中环氧树脂通过包含具有不同结合位点的双酚F的苯酚酚醛清漆树脂的多缩水甘油醚化获得，并且在双酚F组分通过液相色谱测量法测定的[o，p']共轭物的含量在[o，p']共轭物相对于{[o，p']共轭物的面积比为30-45％的范围内） [o，o']缀合物+ [p，p']共轭}; 其固化产物; 包含该组合物的纤维增强复合材料; 及其成型体。

4. 发明申请

WO2015095364A1 DISTILLED EPOXY NOVOLAC RESINS 审中-公开
标题翻译：蒸馏环氧NOVOLAC树脂
公开(公告)号：WO2015095364A1
公开(公告)日：2015-06-25
申请号：PCT/US2014/070913
申请日：2014-12-17
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： FAN, William W. , JEWELL, Dennis W. , WALLACE, Stephen B. , LARSEN, Travis H.
IPC分类号： C08G59/02 , B01D1/06 , C08G59/08
CPC分类号： C08G59/025 , C08G59/08
摘要： A continuous process comprising: a) separating a starting epoxy novolac resin comprising oligomers having an average functionality of greater than 2.5 and a hydrolyzable chlorine content of less than 450 ppm with a first continuous evaporator apparatus under a vaporization temperature in the range of from 150°C to 250°C and an absolute pressure of from 0.05 to 1 mmHg absolute to form a first vapor fraction comprising epoxy novolac resin having more than 95 weight percent of 2-functional components and wherein the mass of the first vapor fraction is in the range of from 5 to 20 weight percent of the starting epoxy novolac resin; and a first bottom fraction comprising epoxy novolac resin having a lower weight percent of 2-functional components in comparison with the weight percent of 2-functional components of the starting epoxy novolac resin; b) recovering the first bottom fraction; and c) condensing from 95 weight percent to 99.95 weight percent of the first vapor fraction at a temperature in the range of from 50°C to 200°C to form a first partially condensed vapor fraction product having at least 95 weight percent of 2-functional components and having a total chlorine content of less than 900 ppm and an uncondensed vapor product comprising halogenated impurities, is disclosed.
摘要翻译：一种连续方法，包括：a）在蒸发温度为150℃的范围内，用第一连续蒸发器装置分离包含平均官能度大于2.5且低于450ppm的可水解氯含量的低聚物的起始环氧酚醛清漆树脂 C至250℃和绝对压力为0.05至1mmHg绝对压力以形成包含具有大于95重量％的2-功能组分的环氧酚醛清漆树脂的第一蒸气馏分，并且其中第一蒸气馏分的质量在为起始环氧酚醛清漆树脂的5至20重量％; 以及与起始环氧酚醛清漆树脂的2-官能组分的重量百分比相比，包含具有较低重量百分比的2-官能组分的环氧酚醛清漆树脂的第一底部馏分; b）回收第一底部馏分; 和c）在50℃至200℃的温度范围内从95重量％至99.95重量％的第一蒸气馏分冷凝，以形成第一部分冷凝的蒸气馏分产物，其具有至少95重量％的2- 功能组分，总氯含量低于900ppm，含有卤化杂质的未冷凝蒸气产物。

5. 发明申请

WO2012047420A3 THERMOSETTABLE COMPOSITIONS AND THERMOSETS THEREFROM 审中-公开
标题翻译：可热固化的组合物和热稳定剂
公开(公告)号：WO2012047420A3
公开(公告)日：2012-07-05
申请号：PCT/US2011049840
申请日：2011-08-31
申请人： DOW GLOBAL TECHNOLOGIES LLC , HEFNER ROBERT E
发明人： HEFNER ROBERT E
IPC分类号： C08G59/02 , C08G59/04
CPC分类号： C08G59/00 , C08G59/022 , C08G59/025 , C08G59/04 , C08L63/00
摘要： A thermosettable (curable) epoxy resin composition including (A) a residual oligomeric product; wherein the residual oligomeric product comprises a polyfunctional aliphatic or cycloaliphatic epoxy resin which has been isolated from an epoxy resin product formed as a result of an epoxidation process comprising the reaction of (i) an aliphatic or cycloaliphatic hydroxyl-containing material with (ii) an epihalohydrin, (iii) a basic-acting substance, (iv) a non-Lewis acid catalyst, and (V) optionally one or more solvents; (B) an epoxy curing material comprising (i) an epoxy resin curing agent, (ii) an epoxy resin catalyst, or both an epoxy resin curing agent (i) and an epoxy resin catalyst (ii); and (C) optionally, an epoxy resin compound other than the aliphatic or cycloaliphatic polyfunctional epoxy resin (A). A thermoset may also be made from the above thermosettable composition.
摘要翻译：一种热固性（可固化）环氧树脂组合物，其包含（A）残余低聚产物; 其中所述残余低聚产物包含多官能脂族或脂环族环氧树脂，所述多官能脂族或脂环族环氧树脂已经从作为环氧化方法的结果形成的环氧树脂产物中分离出来，所述环氧树脂产物包含（i）脂肪族或脂环族羟基材料与（ii）表卤代醇，（iii）碱作用物质，（iv）非路易斯酸催化剂和（V）任选的一种或多种溶剂; （B）环氧固化材料，其包含（i）环氧树脂固化剂，（ii）环氧树脂催化剂或环氧树脂固化剂（i）和环氧树脂催化剂（ii）两者; 和（C）任选地，除脂族或脂环族多官能环氧树脂（A）以外的环氧树脂化合物。热固性材料也可以由上述可热固组合物制成。

6. 发明申请

WO2010066660A1 GLYCEROL TREATMENT PROCESS 审中-公开
标题翻译：甘油处理工艺
公开(公告)号：WO2010066660A1
公开(公告)日：2010-06-17
申请号：PCT/EP2009/066478
申请日：2009-12-07
申请人： SOLVAY SA , GILBEAU, Patrick
发明人： GILBEAU, Patrick
IPC分类号： C07C31/22 , C07C29/88 , C07C29/62 , C08G59/06
CPC分类号： C07C29/88 , C07C29/62 , C08G59/022 , C08G59/025 , C08G59/04 , C07C31/36 , C07C31/225
摘要： Process for treating a glycerol product contaminated with at least one glycerol alkyl ether in order to convert at least one portion of the glycerol alkyl ether to glycerol, in which the glycerol product is subjected to a reaction with at least one halo-de-alkoxylation agent introduced during the treatment, and in which the molar ratio of the total amount of the halo-de-alkoxylation agent to the total amount of the glycerol alkyl ether present in the glycerol product before the treatment, is greater than or equal to 0.1 and less than or equal to 1 000 000.
摘要翻译：用于处理被至少一种甘油烷基醚污染的甘油产品以将至少一部分甘油烷基醚转化为甘油的方法，其中甘油产物与至少一种卤代脱烷基化剂进行反应在处理期间引入，并且其中卤代脱烷基化剂的总量与存在于处理前的甘油产物中的甘油烷基醚的总量的摩尔比大于或等于0.1和更小超过或等于1 000 000。

7. 发明申请

WO2017074760A1 PRODUCTION PROCESS FOR DIGLYCIDYL-CAPPED POLYALKYLENE GLYCOLS WITH IN-SITU REMOVAL OF 1,4-DIOXANE 审中-公开
标题翻译：具有原位去除1,4-二恶烷的用于甘油基封端的聚亚烷基二醇的生产方法
公开(公告)号：WO2017074760A1
公开(公告)日：2017-05-04
申请号：PCT/US2016/057674
申请日：2016-10-19
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： KNIGHT, Troy E. , YOUNG, Thomas C. , DARE, Gerald W. , CRAMPTON, Hannah L. , HOOK, Bruce D. , SIRIGNANO, Pasquale , VINCI, Daniele
IPC分类号： C08G59/02 , C08G59/04 , C08G59/22
CPC分类号： C08G59/04 , C08G59/022 , C08G59/025 , C08G59/22
摘要： Produce diglycidyl-capped polyalkylene glycol by (a) providing epihalohydrin, a polyalkylene glycol that contains and ethylene oxide component and a Lewis acid; (b) coupling the epihalohydrin to the polyalkylene glycol using the Lewis acid as a catalyst to produce a coupling product; (c) stripping 1,4-dioxane from the coupling product; and (d) epoxidation of the coupling product by addition of a base to form diglycidyl-capped polyalkylene glycol in an organic phase.
摘要翻译：通过（a）提供表卤代醇，包含环氧乙烷组分和路易斯酸的聚亚烷基二醇，制备二缩水甘油基封端的聚亚烷基二醇; （b）使用路易斯酸作为催化剂将表卤代醇与聚亚烷基二醇偶联以产生偶联产物; （c）从偶联产物中汽提1,4-二恶烷; 和（d）通过加入碱将偶联产物环氧化以在有机相中形成二缩水甘油基封端的聚亚烷基二醇。

8. 发明申请

WO2012047420A2 THERMOSETTABLE COMPOSITIONS AND THERMOSETS THEREFROM 审中-公开
标题翻译：热稳定性组合物和热稳定剂
公开(公告)号：WO2012047420A2
公开(公告)日：2012-04-12
申请号：PCT/US2011/049840
申请日：2011-08-31
申请人： DOW GLOBAL TECHNOLOGIES LLC , HEFNER, Robert E.
发明人： HEFNER, Robert E.
IPC分类号： C08L63/00
CPC分类号： C08G59/00 , C08G59/022 , C08G59/025 , C08G59/04 , C08L63/00
摘要： A thermosettable (curable) epoxy resin composition including (A) a residual oligomeric product; wherein the residual oligomeric product comprises a polyfunctional aliphatic or cycloaliphatic epoxy resin which has been isolated from an epoxy resin product formed as a result of an epoxidation process comprising the reaction of (i) an aliphatic or cycloaliphatic hydroxyl-containing material with (ii) an epihalohydrin, (iii) a basic-acting substance, (iv) a non-Lewis acid catalyst, and (V) optionally one or more solvents; (B) an epoxy curing material comprising (i) an epoxy resin curing agent, (ii) an epoxy resin catalyst, or both an epoxy resin curing agent (i) and an epoxy resin catalyst (ii); and (C) optionally, an epoxy resin compound other than the aliphatic or cycloaliphatic polyfunctional epoxy resin (A). A thermoset may also be made from the above thermosettable composition.
摘要翻译：一种可热固化（可固化）环氧树脂组合物，其包含（A）残余低聚产物; 其中所述残余低聚产物包含多官能脂族或脂环族环氧树脂，所述多官能脂族或脂环族环氧树脂已经从作为环氧化方法的结果形成的环氧树脂产物中分离，所述环氧树脂产物包含（i）脂族或脂环族含羟基材料与（ii）（iii）碱性作用物质，（iv）非路易斯酸催化剂，和（V）任选的一种或多种溶剂; （B）包含（i）环氧树脂固化剂，（ii）环氧树脂催化剂或环氧树脂固化剂（i）和环氧树脂催化剂（ii）二者的环氧固化材料; 和（C）任选的除脂族或脂环族多官能环氧树脂（A）以外的环氧树脂化合物。热固性材料也可以由上述热固性组合物制成。

9. 发明申请

WO01042230A1 PROCESS FOR THE ELIMINATION OF MATERIALS CONTAINING HYDROLYZABLE HALIDES AND OTHER HIGH MOLECULAR WEIGHT MATERIALS FROM EPIHALOHYDRIN DERIVED EPOXY RESINS 审中-公开
标题翻译：消除含有氢化衍生环氧树脂的可水解化合物和其他高分子量物质的材料的方法
公开(公告)号：WO01042230A1
公开(公告)日：2001-06-14
申请号：PCT/US2000/009622
申请日：2000-04-11
IPC分类号： C07D301/32 , C07D303/24 , C07D303/27 , C08G59/00 , C08G59/02 , C07D303/00 , C08F6/00
CPC分类号： C07D301/32 , C07D303/24 , C08G59/00 , C08G59/025 , Y10S525/93
摘要： The present invention provides a process for eliminating contaminants from epihalohydrin-derived epoxy resins. Another embodiment of the present invention is an epoxy product formed using said process. Yet another embodiment of the present invention is an epoxy derived in part from epihalohydrin wherein said epoxy is has a hydrolyzable halogen content of less than 10 ppm and an epoxide equivalent weight within 2 percent of the theoretical epoxide equivalent weight.
摘要翻译：本发明提供了从表卤代醇衍生的环氧树脂中除去污染物的方法。本发明的另一个实施方案是使用所述方法形成的环氧树脂产品。本发明的另一个实施方案是部分由表卤代醇衍生的环氧树脂，其中所述环氧树脂具有小于10ppm的可水解卤素含量和环氧当量重量在理论环氧当量当量的2％以内。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式