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1. 发明申请

WO2011093848A1 THERMOSETTING MONOMERS AND COMPOSITIONS CONTAINING PHOSPHORUS AND CYANATO GROUPS 审中-公开
标题翻译：热固性单体和含有磷和氰基的组合物
公开(公告)号：WO2011093848A1
公开(公告)日：2011-08-04
申请号：PCT/US2010/003231
申请日：2010-12-22
申请人： DOW GLOBAL TECHNOLOGIES LLC , MULLINS, Michael, J. , HEFNER, Robert, E. , WILSON, Mark, B.
发明人： MULLINS, Michael, J. , HEFNER, Robert, E. , WILSON, Mark, B.
IPC分类号： C07F9/6571
CPC分类号： C07F9/657172
摘要： A thermosetting monomer comprising at least two of an aryl-cyanato group and at least two of a phosphorus group.
摘要翻译：包含芳基 - 氰酸根基团和至少两个磷基团中的至少两个的热固性单体。

2. 发明申请

WO2009091670A1 SULFONATED ORGANOPHOSPHINE COMPOUNDS AND USE THEREOF IN HYDROFORMYLATION PROCESSES 审中-公开
标题翻译：硫化有机磷化合物及其在氢化方法中的应用
公开(公告)号：WO2009091670A1
公开(公告)日：2009-07-23
申请号：PCT/US2009/030556
申请日：2009-01-09
申请人： DOW GLOBAL TECHNOLOGIES INC. , HEFNER, Robert, E., Jr. , TULCHINSKY, Michael, L.
发明人： HEFNER, Robert, E., Jr. , TULCHINSKY, Michael, L.
IPC分类号： C07F9/50
CPC分类号： B01J31/2404 , B01J31/2447 , B01J31/4046 , B01J31/4053 , B01J2231/321 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/845 , B01J2531/96 , B01J2540/32 , B01J2540/64 , C07F9/5004 , C07F9/5018 , Y02P20/584
摘要： A compound comprising a class of sulfonated triorganophosphine compounds of formula R 1 R 2 P-R 3 [-O-(CH 2 ) n -(SO 3 M)] m , wherein the R 1 and R 2 are selected individually from alkyl, aralkyl, and alicyclic groups, wherein R 3 represents a divalent or polyvalent alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents via an alkylether link, and further wherein R 3 does not contain any aryl moieties; n is an integer reflecting a number of methylene groups in the alkylether link; M represents a monovalent cation; and m is an integer representing a total number of sulfonated alkylether substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alky-aryl exchange, thereby leading to reduced ligand usage and improving ligand and rhodium recovery and recycling.
摘要翻译：包含一类式R1R2P-R3 [-O-（CH2）n-（SO3M）] m的磺化三有机膦化合物的化合物，其中R1和R2分别选自烷基，芳烷基和脂环族基团，其中R3表示通过烷基醚连接键合到磷原子和一个或多个磺酸酯取代基的二价或多价亚烷基或脂环族基团，其中R3不含任何芳基部分; n是反映烷基链接中亚甲基数的整数; M表示一价阳离子; m为代表磺化烷基醚取代基总数的整数。该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的加氢甲酰化形成一种或多种相应的醛产物。配体不能进行烷基 - 芳基交换，从而导致配体使用减少，并改善配体和铑的回收和再循环。

3. 发明申请

WO2003068825A3 MULTIFUNCTIONAL MONOMERS AND THEIR USE IN MAKING CROSS-LINKED POLYMERS AND POROUS FILMS 审中-公开
公开(公告)号：WO2003068825A3
公开(公告)日：2003-08-21
申请号：PCT/US2003/004221
申请日：2003-02-12
申请人： DOW GLOBAL TECHNOLOGIES INC. , NIU, Qing, Shan, J. , HEFNER, Robert, E., Jr. , GODSCHALX, James, P. , PECHACEK, James T. , ARNDT, Kim E.
发明人： NIU, Qing, Shan, J. , HEFNER, Robert, E., Jr. , GODSCHALX, James, P. , PECHACEK, James T. , ARNDT, Kim E.
IPC分类号： C07C49/753
摘要： This invention is a monomer comprising at least two dienophile groups and at least two ring structures which ring structures are characterized by the presence of two conjugated carbon-to-carbon double bonds and the presence of a leaving group L, wherein L is characterized that when the ring structure reacts with a dienophile in the presence of heat or other energy sources, L is removed to form an aromatic ring structure. This invention is also curable oligomers and polymers and highly cross-linked polymers made with such monomers. Moreover, this invention is a method of making porous films by combining such monomers or their oligomers with a porogen, curing the polymer and removing the porogen.

4. 发明申请

WO03068825A2 MULTIFUNCTIONAL MONOMERS AND THEIR USE IN MAKING CROSS-LINKED POLYMERS AND POROUS FILMS 审中-公开
标题翻译：多功能单体及其在制造交联聚合物和多孔膜中的用途
公开(公告)号：WO03068825A2
公开(公告)日：2003-08-21
申请号：PCT/US0304221
申请日：2003-02-12
申请人： DOW GLOBAL TECHNOLOGIES INC , NIU QING SHAN J , HEFNER ROBERT E JR , GODSCHALX JAMES P
发明人： NIU QING SHAN J , HEFNER ROBERT E JR , GODSCHALX JAMES P
IPC分类号： C07D309/38 , C07C45/30 , C07C45/46 , C07C45/48 , C07C45/65 , C07C45/66 , C07C45/68 , C07C45/81 , C07C49/683 , C07C49/753 , C07C49/84 , C08G61/00 , C08J9/26 , H01L23/532 , C08F
CPC分类号： C07C49/753 , C07C45/30 , C07C45/46 , C07C45/48 , C07C45/65 , C07C45/66 , C07C45/68 , C07C45/81 , C07C49/683 , C07C49/84 , C07D309/38 , H01L23/5329 , H01L2924/0002 , C07C49/233 , H01L2924/00
摘要： This invention is a monomer comprising at least two dienophile groups and at least two ring structures which ring structures are characterized by the presence of two conjugated carbon-to-carbon double bonds and the presence of a leaving group L, wherein L is characterized that when the ring structure reacts with a dienophile in the presence of heat or other energy sources, L is removed to form an aromatic ring structure. This invention is also curable oligomers and polymers and highly cross-linked polymers made with such monomers. Moreover, this invention is a method of making porous films by combining such monomers or their oligomers with a porogen, curing the polymer and removing the porogen.
摘要翻译：本发明是包含至少两个亲双烯体基团和至少两个环结构的单体，所述环结构的特征在于存在两个共轭碳 - 碳双键和存在离去基团L，其中L表征为在热或其他能量源的存在下，环结构与亲二烯体反应，除去L形成芳环结构。本发明也是可固化的低聚物和聚合物以及用这些单体制成的高度交联的聚合物。此外，本发明是通过将这些单体或其低聚物与致孔剂结合，固化聚合物并除去致孔剂来制造多孔膜的方法。

5. 发明申请

WO9412556A3 THERMOSETTABLE COMPOSITION CONTAINING MESOGENIC MOIETIES 审中-公开
标题翻译：含有致热成分的热稳定组合物
公开(公告)号：WO9412556A3
公开(公告)日：1994-09-01
申请号：PCT/US9310196
申请日：1993-10-26
申请人： DOW CHEMICAL CO , HEFNER ROBERT E JR , EARLS JIMMY D
发明人： HEFNER ROBERT E JR , EARLS JIMMY D
IPC分类号： C09K19/32 , C07C37/20 , C07C39/17 , C08F290/00 , C08F290/06 , C08G59/17 , C08G59/20 , C08G59/32 , C08G75/02 , C08G75/06 , C08G75/08 , C08L63/00 , C09K19/38 , C08G59/14
CPC分类号： C07C39/17 , C07C37/055 , C07C37/20 , C07C2603/42 , C07C2603/92 , C08G59/3218 , C08G75/06 , C09K19/38 , C09K19/3833 , C09K19/388
摘要： PCT No. PCT/US93/10196 Sec. 371 Date May 18, 1995 Sec. 102(e) Date May 18, 1995 PCT Filed Oct. 26, 1993 PCT Pub. No. WO94/12556 PCT Pub. Date Jun. 9, 1994Thermosettable resins, including epoxy resins, polythiirane resins and vinyl ester resins were prepared from compounds containing one or more discotic mesogenic moieties. The resultant thermosettable resins may be processed to provide the discotic liquid crystalline state. The thermosettable resin compositions can be employed in coating, casting, encapsulation, electronic or structural laminate or composite, filament winding, molding and the like applications.
摘要翻译： PCT No.PCT / US93 / 10196 Sec。 371日期1995年5月18日 102（e）日期1995年5月18日PCT提交1993年10月26日PCT公布。第WO94 / 12556号公报日期1994年6月9日由含有一个或多个盘状介晶部分的化合物制备包含环氧树脂，聚噻吩环乙烯树脂和乙烯基酯树脂的可嗜热树脂。所得到的热固性树脂可以被加工以提供盘状液晶状态。热固性树脂组合物可以用于涂布，浇铸，封装，电子或结构层压板或复合材料，长丝缠绕，模塑等应用中。

6. 发明申请

WO2012047420A2 THERMOSETTABLE COMPOSITIONS AND THERMOSETS THEREFROM 审中-公开
标题翻译：热稳定性组合物和热稳定剂
公开(公告)号：WO2012047420A2
公开(公告)日：2012-04-12
申请号：PCT/US2011/049840
申请日：2011-08-31
申请人： DOW GLOBAL TECHNOLOGIES LLC , HEFNER, Robert E.
发明人： HEFNER, Robert E.
IPC分类号： C08L63/00
CPC分类号： C08G59/00 , C08G59/022 , C08G59/025 , C08G59/04 , C08L63/00
摘要： A thermosettable (curable) epoxy resin composition including (A) a residual oligomeric product; wherein the residual oligomeric product comprises a polyfunctional aliphatic or cycloaliphatic epoxy resin which has been isolated from an epoxy resin product formed as a result of an epoxidation process comprising the reaction of (i) an aliphatic or cycloaliphatic hydroxyl-containing material with (ii) an epihalohydrin, (iii) a basic-acting substance, (iv) a non-Lewis acid catalyst, and (V) optionally one or more solvents; (B) an epoxy curing material comprising (i) an epoxy resin curing agent, (ii) an epoxy resin catalyst, or both an epoxy resin curing agent (i) and an epoxy resin catalyst (ii); and (C) optionally, an epoxy resin compound other than the aliphatic or cycloaliphatic polyfunctional epoxy resin (A). A thermoset may also be made from the above thermosettable composition.
摘要翻译：一种可热固化（可固化）环氧树脂组合物，其包含（A）残余低聚产物; 其中所述残余低聚产物包含多官能脂族或脂环族环氧树脂，所述多官能脂族或脂环族环氧树脂已经从作为环氧化方法的结果形成的环氧树脂产物中分离，所述环氧树脂产物包含（i）脂族或脂环族含羟基材料与（ii）（iii）碱性作用物质，（iv）非路易斯酸催化剂，和（V）任选的一种或多种溶剂; （B）包含（i）环氧树脂固化剂，（ii）环氧树脂催化剂或环氧树脂固化剂（i）和环氧树脂催化剂（ii）二者的环氧固化材料; 和（C）任选的除脂族或脂环族多官能环氧树脂（A）以外的环氧树脂化合物。热固性材料也可以由上述热固性组合物制成。

7. 发明申请

WO2009142899A1 THERMOSET POLYURETHANES COMPRISING CIS, TRANS-1, 3- AND 1, 4-CYCLOHEXANEDIMETHYLETHER GROUPS 审中-公开
标题翻译：包含CIS，TRANS-1,3,3-和1,4-环己基甲硅烷基醚的热固性聚氨酯
公开(公告)号：WO2009142899A1
公开(公告)日：2009-11-26
申请号：PCT/US2009/042644
申请日：2009-05-04
申请人： DOW GLOBAL TECHNOLOGIES INC. , HEFNER, Robert, E., Jr. , RINGER, James, W.
发明人： HEFNER, Robert, E., Jr. , RINGER, James, W.
IPC分类号： C08G18/64 , C08G59/18
CPC分类号： C08G59/1477
摘要： Thermoset polyurethanes comprising a cis, trans- 1,3- and -1,4- cyclohexanedimethylether moiety. Adducts of epoxy resins comprising a cis, trans- 1,3- and -1,4-cyclohexanedimethylether moiety are used to react with a polyisocyanate to produce the thermoset polyurethanes.
摘要翻译：包含顺式，反式-1,3-和-1,4-环己烷二甲醚部分的热固性聚氨酯。使用包含顺式，反式-1,3-和-1,4-环己烷二甲醚部分的环氧树脂的加合物与多异氰酸酯反应以制备热固性聚氨酯。

8. 发明申请

WO2009142898A1 ADDUCTS OF EPOXY RESINS AND PROCESS FOR PREPARING THE SAME 审中-公开
标题翻译：环氧树脂的添加剂及其制备方法
公开(公告)号：WO2009142898A1
公开(公告)日：2009-11-26
申请号：PCT/US2009/042643
申请日：2009-05-04
申请人： DOW GLOBAL TECHNOLOGIES INC. , HEFNER, Robert, E., Jr. , RINGER, James, W.
发明人： HEFNER, Robert, E., Jr. , RINGER, James, W.
IPC分类号： C08G59/24 , C08L63/00
CPC分类号： C08G59/182 , C08L63/00
摘要： An adduct comprises at least one reaction product of (i) an epoxy resin material (A) and (ii) a reactive compound (B). The epoxy resin material (A) comprises a cis, trans- 1,3- and -1,4-cyclohexanedimethylether moiety and the reactive compound (B) comprises a compound having two or more reactive hydrogen atoms per molecule, wherein the reactive hydrogen atoms are reactive with epoxide groups. A curable epoxy resin composition comprises the adduct described above. A cured epoxy resin is prepared by a process of curing the curable epoxy resin composition.
摘要翻译：加合物包含（i）环氧树脂材料（A）和（ii）反应性化合物（B）的至少一种反应产物。环氧树脂材料（A）包含顺式，反式-1,3-和-1,4-环己烷二甲醚部分，反应性化合物（B）包括每分子具有两个或多个反应性氢原子的化合物，其中反应性氢原子与环氧基反应。可固化环氧树脂组合物包含上述加合物。通过固化可固化环氧树脂组合物的方法制备固化的环氧树脂。

9. 发明申请

WO2005037761A3 MULTIFUNCTIONAL ETHYNYL SUBSTITUTED MONOMERS AND POLYARYLENE COMPOSITIONS THEREFROM 审中-公开
公开(公告)号：WO2005037761A3
公开(公告)日：2005-04-28
申请号：PCT/US2004/034327
申请日：2004-10-19
申请人： DOW GLOBAL TECHNOLOGIES INC. , HEFNER, Robert, E., Jr.
发明人： HEFNER, Robert, E., Jr.
IPC分类号： C08G61/10
摘要： A compound (monomer) comprising i) one or more arylethynyl groups (A-functional groups), ii) one or more ring structures comprising two conjugated carbon-to-carbon double bonds and a leaving group L (B-functional groups), and iii) one or more ethynyl groups (C'-functional groups), characterized in that said A- and C'-functional groups are capable of reaction under cycloaddition reaction conditions with said B-functional groups to thereby form a cross-linked, polyphenylene polymer.

10. 发明申请

WO2012044490A1 COATING COMPOSITIONS 审中-公开
标题翻译：涂料组合物
公开(公告)号：WO2012044490A1
公开(公告)日：2012-04-05
申请号：PCT/US2011/052236
申请日：2011-09-20
申请人： DOW GLOBAL TECHNOLOGIES LLC , JIN, Xin , DRUMRIGHT, Ray E. , KAINZ, Bernhard , WHITE, Jerry E. , HEFNER, Robert E.
发明人： JIN, Xin , DRUMRIGHT, Ray E. , KAINZ, Bernhard , WHITE, Jerry E. , HEFNER, Robert E.
IPC分类号： C08G59/24 , C08G59/42 , C08G63/137 , C08G63/187 , C08G63/199 , C08G63/42 , C08G63/66 , C08G65/26 , C09D167/02
CPC分类号： C09D167/025 , C08G59/066 , C08G59/4223 , C08L2205/05 , C09D163/00 , C09D167/02 , C08L33/02 , C08L67/00
摘要： A coating composition comprising an advanced poly epoxy ester resin polymeric composition having the following chemical structure: where n is a number from 1 to about 3000; each m independently has a value of 0 or 1; each R 0 is independently -H or -CH 3; each R 1 is independently -H or a C 1 to C 6 alkylene radical (saturated divalent aliphatic hydrocarbon radical); Ar is a divalent aromatic fused -ring moiety, which is most preferably a divalent naphthalene group, substituted divalent naphthalene group, where the substitute groups include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent; and X is cycloalkylene group, including substituted cycloalkylene group, where the substitute group include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substitute group, for example, a halogen, a nitro, a blocked isocyanate, or an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between.
摘要翻译：一种涂料组合物，其包含具有以下化学结构的先进的聚环氧酯树脂聚合物组合物：其中n为1至约3000的数; 每个m独立地具有0或1的值; 每个R 0独立地是-H或-CH 3; 每个R 1独立地为-H或C 1至C 6亚烷基（饱和二价脂族烃基）; Ar是二价芳族稠合部分，其最优选二价萘基，取代的二价萘基，其中取代基包括烷基，环烷基，芳基或芳烷基或其它取代基; X是亚环烷基，包括取代的亚环烷基，其中取代基包括烷基，环烷基，芳基或芳烷基或其它取代基，例如卤素，硝基，封端异氰酸酯或烷氧基; 亚环烷基和亚烷基的组合以及亚烷基和亚环烷基之间的桥连部分的组合。

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