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    • 2. 发明申请
    • COATING AGENT AND METHOD FOR ITS PRODUCTION
    • 种衣剂与方法研究
    • WO1998027166A2
    • 1998-06-25
    • PCT/EP1997006989
    • 1997-12-12
    • BASF COATINGS AGBARTEL, FritzBAUMGART, HubertRÖCKRATH, Ulrike
    • BASF COATINGS AG
    • C09D00/00
    • C09D167/00C08G18/7893C08G18/8064C09D175/04C08L2666/36
    • The present invention relates to a constituent system for a multiconstituent coating agent containing a hydroxy-functional bonding agent or a mixture of hydroxy-functional bonding agents, tris(alkoxycarbonylamino)triazine and free isocyanate or a mixture of free polyisocyanates. The invention is characterized in that a first constituent (I) is made from at least the hydroxy-functional bonding agent or the mixture of hydroxy-functional bonding agents, a second constituent (II) is made from the free isocyanates or the mixture of free polyisocyanates, and a third constituent is made from the tris(alkoxycarbonylmamino)triazine or a mixture of the tris(alkoxycarbonylamino) triazines.
    • 本发明涉及一种组分体系,其包括羟基官能的粘合剂或羟基官能的粘合剂的混合物的多组分涂料组合物中,三(烷氧基羰基氨基)三嗪或三(烷氧基羰氨基)三嗪,和游离的异氰酸酯的混合物或游离多异氰酸酯的混合物。 它的特征在于gekennzepchnet至少从羟基官能的粘合剂或混合物中的第一组分(I)是从至少从自由的异氰酸酯或游离多异氰酸酯混合物中的第二组分(II)中形成的羟基官能的粘合剂形成的,而且一个 形成为从三(烷氧基羰基氨基)三嗪或三的(烷氧基羰基氨基)三嗪的混合物的第三组分。
    • 3. 发明申请
    • HEAT-HARDENABLE PAINT COMPOSITIONS
    • 热复合油漆组合物
    • WO1998007796A1
    • 1998-02-26
    • PCT/EP1997004111
    • 1997-07-29
    • BASF LACKE + FARBEN AGNOF CORPORATIONNUKITA, AkitoSHIBATO, KishioLÜER, Ingo
    • BASF LACKE + FARBEN AGNOF CORPORATION
    • C09D157/00
    • C09D175/04C08G18/6229C08G18/7893C08L61/32C09D133/066C08L2666/14
    • The invention relates to a heat-hardenable paint composition which contains (A) vinyl based copolymer of hydroxyl group value from 20 to 200 mg KOH/g, being a copolymer of from 5 to 70 wt.% hydroxyl group containing vinyl based monomer which can be represented by general formula (1) and from 95 to 30 wt.% other vinyl based monomer (a-2), and (B) 1,3,5-triazine-2,4,6-triscarbamic acid ester which can be represented by general formula (2): C3N3(NHCOOR)3 or an oligomer thereof, in which the mol ratio of hydroxyl groups originating from the aforementioned (A) component: NHCOOR groups originating from the aforementioned (B) component in the composition is from 1:3 to 3:1. In general formula (1), X , X and X each independently represent a hydrogen atom or a methyl group. Moreover j is an integer of value from 0 to 2, m is an integer of value from 3 to 5, and n is an integer of value from 0 to 5. However, j and n cannot both be 0. In general formula (2), R represents an alkyl group which has from 1 to 20 carbon atoms, an aryl group which has from 6 to 20 carbon atoms or an aralkyl group which has from 7 to 20 carbon atoms, and these groups may be the same or different.
    • 本发明涉及一种热硬化性涂料组合物,它含有(A)羟基值为20-200mg KOH / g的乙烯基共聚物,为含有5-70%(重量)羟基的乙烯基类单体的共聚物,它可以 由通式(1)表示,95〜30重量%的其它乙烯基类单体(a-2)和(B)1,3,5-三嗪-2,4,6-三氨基甲酸酯 由上述(A)成分衍生的上述(B)成分中衍生的上述(A)成分的NHCOOR基团的摩尔比来自组成中的(C)N 3(NHCOOR)3或其低聚物 1:3到3:1。 在通式(1)中,X 1,X 2和X 3各自独立地表示氢原子或甲基。 此外,j为0〜2的整数,m为3〜5的整数,n为0〜5的整数。然而,j,n均不能为0。在通式(2)中, ),R表示碳原子数1〜20的烷基,碳原子数6〜20的芳基或碳原子数7〜20的芳烷基,这些基可以相同也可以不同。
    • 5. 发明申请
    • HEAT-HARDENABLE PAINT COMPOSITIONS
    • 热复合油漆组合物
    • WO1998002495A1
    • 1998-01-22
    • PCT/EP1997003375
    • 1997-06-27
    • BASF LACKE + FARBEN AGNOF CORPORATIONSHIBATOH, KishioNUKITA, AkitoLÜER, Ingo
    • BASF LACKE + FARBEN AGNOF CORPORATION
    • C09D201/06
    • C08G18/4063C08G18/4291C08G18/7893C08G18/80
    • To obtain paint compositions with which it is possible to form paint films which have excellent acid resistance, weather resistance and heat resistance and which also have excellent yellowing resistance. A heat hardenable paint composition which contains (A) polyol which has in each molecule two or more sterically protected secondary hydroxyl groups, being polyol obtained by means of an esterification reaction of an epoxy group containing compound which has one epoxy group and which does not have a polymerizable unsaturated bond and a carboxyl group containing compound which has two or more carboxyl groups; and (B) 1,3,5-triazine-2,4,6-tris-carbamic acid ester which can be represented by the general formula C3N3(NHCOOR)3 or an oligomer thereof, wherein the mol ratio secondary hydroxyl groups originating from the aforementioned (A) component : NHCOOR groups originating from the aforementioned (B) component in the composition is from 1:3 to 3:1. (In said formula, R represents an alkyl group which has from 1 to 20 carbon atoms, an aryl group which has from 6 to 20 carbon atoms or an aralkyl group which has from 7 to 20 carbon atoms.)
    • 为了获得可以形成耐酸性,耐候性和耐热性优异并且耐黄变性优异的漆膜的油漆组合物。 一种热硬化性涂料组合物,其含有(A)在各分子中具有两个或多个空间保护的仲羟基的多元醇,其为通过具有一个环氧基且不具有一个环氧基的含环氧基的化合物的酯化反应得到的多元醇 可聚合不饱和键和具有两个或更多个羧基的含羧基化合物; 和(B)可以由通式C3N3(NHCOOR)3表示的1,3,5-三嗪-2,4,6-三氨基甲酸酯或其低聚物,其中源自 上述(A)成分:由组合物中的上述(B)成分起源的NHCOOR基团为1:3〜3:1。 (式中,R表示碳原子数1〜20的烷基,碳原子数6〜20的芳基或碳原子数7〜20的芳烷基。)
    • 6. 发明申请
    • CURABLE COMPOSITIONS COMPOSITE COATINGS AND PROCESS FOR HAVING IMPROVED MAR AND ABRASION RESISTANCE
    • 可固化组合物复合涂料和具有改进的耐磨性的方法
    • WO1996034905A1
    • 1996-11-07
    • PCT/US1996005971
    • 1996-04-29
    • PPG INDUSTRIES, INC.
    • PPG INDUSTRIES, INC.MAUER, George, W.MEIER, James, A.STAHL, Lynne, R.
    • C08G18/78
    • C08G18/7893C08G18/4294C08G18/581C08G18/62C08G18/6229C08G18/6237C08G18/6407C08G18/792C08G18/8064C08G59/5086C09D175/00Y10T428/31551
    • A curable composition and process of applying the composition and the resulting composite coatings provide improved resistance to acid etch and mar. The curable composition has (a) about 30 to 90 percent by weight, based on total weight of resin solids, of a film-forming composition selected from the group consisting of: (i) a polyepoxide and a polyacid cross-linking agent; (ii) an acrylosilane polymer, an acrylic polyol polymer, and optionally an alkylated melamine-formaldehyde cross-linking agent; and (iii) a polyisocyanate and a polymer having at least one group that is reactive with isocyanate; and (b) about 10 to 70 percent by weight, based on total weight of resin solids, of a tricarbamoyl triazine compound of the formula: C3N3(NHCOXR)3, wherein X is nitrogen, oxygen, sulfur, phosphorus, or carbon, and R is a lower alkyl group having 1 to 12 carbon atoms, or mixtures of lower alkyl groups. The process involves applying the curable coating as a monocoat on a cured primer surfacer coating on a substrate or as a clear coat on a curable base coat that are cured separately or conjointly. The composite coating includes the primer surfacer and monocoat on a substrate or the color-plus-clear coating on an electrodeposited coating layer or a primer surfacer coating layer.
    • 可固化组合物和施加组合物和所得复合涂层的方法提供了改善的耐酸蚀和耐蚀性。 可固化组合物具有(a)约30至90重量%,基于树脂固体的总重量,选自以下的成膜组合物:(i)聚环氧化物和多酸交联剂; (ii)丙烯基硅烷聚合物,丙烯酸多元醇聚合物和任选的烷基化三聚氰胺 - 甲醛交联剂; 和(iii)多异氰酸酯和具有至少一个与异氰酸酯反应的基团的聚合物; 和(b)约10至70重量%,基于树脂固体的总重量,具有下式的三氨甲磺酰三嗪化合物:C3N3(NHCOXR)3,其中X为氮,氧,硫,磷或碳,以及 R是具有1至12个碳原子的低级烷基或低级烷基的混合物。 该方法包括将可固化涂层作为单壳体涂覆在基底上的固化的底漆表面涂层上,或者作为可固化底涂层上的透明涂层单独或共同固化。 复合涂层包括底物上的底漆二
      面体和单面涂层或电沉积涂层或底漆二层涂层上的彩色 - 透明涂层。
    • 10. 发明申请
    • COATING AGENT AND METHOD FOR PRODUCING SAME
    • 种衣剂与方法研究
    • WO1998027135A1
    • 1998-06-25
    • PCT/EP1997007111
    • 1997-12-18
    • BASF COATINGS AGBARTOL, FritzBAUMGART, HubertRÖCKRATH, Ulrike
    • BASF COATINGS AG
    • C08G18/78
    • C09D167/00C08G18/7893C08G18/8064C09D175/04C08L2666/36
    • The invention relates to a component system for a multiple component coating agent containing a binder with hydroxy function or a mixture of binders with hydroxy function, tris(alcoxycarbonylamino)triazine or a mixture of tris(alcoxycarbonylamino)triazines and free isocyanates, or a mixture of free polyisocyanates. Said component system is characterized in that a first component (I) consists of at least the binder with hydroxy function or the mixture of binders with hydroxy function, that a second component (II) consists of at least the free isocyanates or the mixture of free polyisocyanates, and that a third component consists of the tris(alcoxycarbonylamino)triazine or the mixture of tris(alcoxycarbonylamino)triazines.
    • 本发明涉及一种组分体系,其包括羟基官能的粘合剂或羟基官能的粘合剂的混合物的多组分涂料组合物中,三(烷氧基羰基氨基)三嗪或三(烷氧基羰氨基)三嗪,和游离的异氰酸酯的混合物或游离多异氰酸酯的混合物。 它的特征在于,至少从所述羟基官能的粘合剂或混合物中的第一组分(I)是从第二部件在从游离的异氰酸酯或游离多异氰酸酯的混合物至少形成(II)的羟基官能的粘合剂形成的,而且一个 形成为从三(烷氧基羰基氨基)三嗪或三的(烷氧基羰基氨基)三嗪的混合物的第三组分。