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1. 发明申请

WO2009066141A1 AN AGENT FOR THE TREATMENT OF TOP-COAT PAINT FILMS TO IMPART STAIN RESISTANCE AND A METHOD FOR THE TREATMENT OF TOP-COAT PAINT FILMS TO IMPART STAIN-RESISTANCE 审中-公开
标题翻译：用于处理顶层涂膜以促进耐污性的代理和用于处理顶部涂层膜以抵抗抗性的方法
公开(公告)号：WO2009066141A1
公开(公告)日：2009-05-28
申请号：PCT/IB2008/002859
申请日：2008-10-22
申请人： BASF COATINGS JAPAN LTD. , SHIBATO, Kishio , SHINJO, Tsuyoshi , NOMOTO, Takeshi
发明人： SHIBATO, Kishio , SHINJO, Tsuyoshi , NOMOTO, Takeshi
IPC分类号： B05D7/14 , C09D183/08 , C09K3/18 , C09D5/16 , C09G1/16
CPC分类号： C09G1/16 , C09D5/1675 , C09D5/1687 , C09D183/08
摘要： To provide an agent for the treatment of a top¬ coat paint film to impart stain resistance with which a stain resisting function can be imparted easily to a top-coat paint film which is the outermost paint film irrespective of the type or history of the top-coat paint film, with which a clean paint film is maintained over a long period of time and with which the abovementioned function is retained even when it is shielded from light for long periods of time, and a method for the treatment of a top-coat paint film to impart stain resistance. [Means of Resolution] An agent for the treatment of a top-coat paint film to impart stain resistance which contains (a) from 3 to 10 mass% of a compound which can be represented by the formula (1) which is indicated below or a partial hydrolysis condensate thereof, (b) from 0.01 to 1 mass% of a catalyst with which the aforementioned (a) component can be hydrolyzed, (c) from 0.5 to 3 mass% of an alkylsulf osuccinic acid salt based surfactant and (d) from 86 to 96.49 mass% of an alcohol based solvent which has not more than 3 carbon atoms. Formula (1) R 1 -(OCH 2 CH 2 ) n -O-Si(OR 2 ) 3 (1) (In this formula R 1 is an alkyl group which has from 1 to 6 carbon atoms or a hydrogen atom, R 2 is an alkyl group which has from 1 to 6 carbon atoms, and the three R 2 may be the same or different. Moreover n is an integer value from 2 to 4. )
摘要翻译：为了提供一种用于处理顶涂漆膜以赋予耐污染性的试剂，其可以容易地赋予耐污染功能的顶漆涂料膜，而不管顶部的类型或历史如何并且长时间保持干净的漆膜，并且即使长时间遮光也能保持上述功能，因此，涂漆膜赋予耐污性。 [解决方法]一种用于处理顶涂漆膜以赋予耐污染性的试剂，其含有（a）3〜10质量％的由下述式（1）表示的化合物或其部分水解缩合物，（b）0.01〜1质量％的上述（a）成分可以水解的催化剂，（c）0.5〜3质量％的烷基硫代琥珀酸盐系表面活性剂和（d ）86〜96.49质量％的碳原子数为3以下的醇系溶剂。式（1）R1-（OCH2CH2）nO-Si（OR2）3（1）（式中，R1表示碳原子数1〜6的烷基或氢原子，R2表示烷基，至6个碳原子，并且三个R 2可以相同或不同，此外，n为2〜4的整数。）

2. 发明申请

WO1998007796A1 HEAT-HARDENABLE PAINT COMPOSITIONS 审中-公开
标题翻译：热复合油漆组合物
公开(公告)号：WO1998007796A1
公开(公告)日：1998-02-26
申请号：PCT/EP1997004111
申请日：1997-07-29
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , NUKITA, Akito , SHIBATO, Kishio , LÜER, Ingo
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： C09D157/00
CPC分类号： C09D175/04 , C08G18/6229 , C08G18/7893 , C08L61/32 , C09D133/066 , C08L2666/14
摘要： The invention relates to a heat-hardenable paint composition which contains (A) vinyl based copolymer of hydroxyl group value from 20 to 200 mg KOH/g, being a copolymer of from 5 to 70 wt.% hydroxyl group containing vinyl based monomer which can be represented by general formula (1) and from 95 to 30 wt.% other vinyl based monomer (a-2), and (B) 1,3,5-triazine-2,4,6-triscarbamic acid ester which can be represented by general formula (2): C3N3(NHCOOR)3 or an oligomer thereof, in which the mol ratio of hydroxyl groups originating from the aforementioned (A) component: NHCOOR groups originating from the aforementioned (B) component in the composition is from 1:3 to 3:1. In general formula (1), X , X and X each independently represent a hydrogen atom or a methyl group. Moreover j is an integer of value from 0 to 2, m is an integer of value from 3 to 5, and n is an integer of value from 0 to 5. However, j and n cannot both be 0. In general formula (2), R represents an alkyl group which has from 1 to 20 carbon atoms, an aryl group which has from 6 to 20 carbon atoms or an aralkyl group which has from 7 to 20 carbon atoms, and these groups may be the same or different.
摘要翻译：本发明涉及一种热硬化性涂料组合物，它含有（A）羟基值为20-200mg KOH / g的乙烯基共聚物，为含有5-70％（重量）羟基的乙烯基类单体的共聚物，它可以由通式（1）表示，95〜30重量％的其它乙烯基类单体（a-2）和（B）1,3,5-三嗪-2,4,6-三氨基甲酸酯由上述（A）成分衍生的上述（B）成分中衍生的上述（A）成分的NHCOOR基团的摩尔比来自组成中的（C）N 3（NHCOOR）3或其低聚物 1：3到3：1。在通式（1）中，X 1，X 2和X 3各自独立地表示氢原子或甲基。此外，j为0〜2的整数，m为3〜5的整数，n为0〜5的整数。然而，j，n均不能为0。在通式（2）中，），R表示碳原子数1〜20的烷基，碳原子数6〜20的芳基或碳原子数7〜20的芳烷基，这些基可以相同也可以不同。

3. 发明申请

WO9521895A3 ELASTICITY IMPARTING AGENTS FOR PAINTS, A METHOD OF MANUFACTURE AND PAINTS 审中-公开
标题翻译：用于涂料的弹性改进剂，制造方法和涂料
公开(公告)号：WO9521895A3
公开(公告)日：2000-09-21
申请号：PCT/EP9500412
申请日：1995-02-06
申请人： BASF LACKE & FARBEN , NOF CORP , SHIBATO KISHIO , MOMNA YASUHIRO , SUGIHARA YASUSHI
发明人： SHIBATO KISHIO , MOMNA YASUHIRO , SUGIHARA YASUSHI
IPC分类号： C09D5/00 , C09D7/12
CPC分类号： C09D7/69 , C09D7/65 , C09D7/67 , C09D7/68
摘要： To obtain elasticity imparting agents for paints comprised of liquid non-aqueous polymer dispersions which, when added to paints, improve the scratch resistance without lowering the acid resistance of the hardened paint film. A liquid non-aqueous polymer dispersion which contains (a) 40 - 90 percent by weight organic solvent, (b) 10 - 50 percent by weight particle component comprised vinyl based copolymer which contains 30 percent by weight or more of structural units of formula (1), and (c) 5 - 40 percent by weight dispersion stabilizer for dispersing the (b) component in the (a) component. In formula (1) R - R are H or methyl groups, m is 0 - 2, n is 0 - 10, p is 0 or 1, q is 0 - 3 and r is 0 - 3.
摘要翻译：为了获得由液体非水性聚合物分散体组成的涂料的弹性赋予剂，当添加到涂料中时，改善耐刮擦性而不降低硬化漆膜的耐酸性。含有（a）40-90重量％有机溶剂的液体非水聚合物分散体，（b）10-50重量％的颗粒组分包含乙烯基类共聚物，其含有30重量％以上的结构单元（式 1）和（c）5-40重量％的（b）成分分散在（a）成分中的分散稳定剂。在式（1）中，R 1 -R 5是H或甲基，m是0-2，n是0-10，p是0或1，q是0-3，r是0-3。

4. 发明申请

WO1995021895A2 ELASTICITY IMPARTING AGENTS FOR PAINTS, A METHOD OF MANUFACTURE AND PAINTS 审中-公开
标题翻译：用于涂料的弹性加工剂，制造方法和涂料
公开(公告)号：WO1995021895A2
公开(公告)日：1995-08-17
申请号：PCT/EP1995000412
申请日：1995-02-06
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , SHIBATO, Kishio , MOMNA, Yasuhiro , SUGIHARA, Yasushi
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： C09D07/12
CPC分类号： C09D7/69 , C09D7/65 , C09D7/67 , C09D7/68
摘要： To obtain elasticity imparting agents for paints comprised of liquid non-aqueous polymer dispersions which, when added to paints, improve the scratch resistance without lowering the acid resistance of the hardened paint film. A liquid non-aqueous polymer dispersion which contains (a) 40 - 90 percent by weight organic solvent, (b) 10 - 50 percent by weight particle component comprised vinyl based copolymer which contains 30 percent by weight or more of structural units of formula (1), and (c) 5 - 40 percent by weight dispersion stabilizer for dispersing the (b) component in the (a) component. In formula (1) R - R are H or methyl groups, m is 0 - 2, n is 0 - 10, p is 0 or 1, q is 0 - 3 and r is 0 - 3.
摘要翻译：为了获得由液体非水性聚合物分散体组成的涂料的弹性赋予剂，当添加到涂料中时，改善耐划伤性而不降低硬化漆膜的耐酸性。含有（a）40-90重量％有机溶剂的液体非水聚合物分散体，（b）10-50重量％的颗粒组分包含乙烯基类共聚物，其含有30重量％以上的结构单元（式 1）和（c）5-40重量％的（b）成分分散在（a）成分中的分散稳定剂。在式（1）中，R 1 -R 5是H或甲基，m是0-2，n是0-10，p是0或1，q是0-3，r是0-3。

5. 发明申请

WO1995020003A1 THERMOSET COVERING COMPOSITION 审中-公开
标题翻译：热固性覆盖组合物
公开(公告)号：WO1995020003A1
公开(公告)日：1995-07-27
申请号：PCT/EP1995000172
申请日：1995-01-18
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , MORIYA, Joichi , MARUYAMA, Fumi , SHIBATO, Kishio , BETZ, Peter
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： C08G18/62
CPC分类号： C08G18/8093 , C08G18/6233 , C09D175/04 , C08L2666/16
摘要： To provide compositions with which paints which have excellent acid resistance and scratching resistance, and with which a poor appearance can be avoided, can be obtained. A thermoset covering composition comprised of (A) vinyl based copolymer comprised of lactone modified acrylic monomer and other monomer, (B) blocked polyisocyanate compound which has been reacted with a mixture of malonic acid ester and acetoacetic acid ester, and (C) alkyl etherified amino resin.
摘要翻译：为了提供具有优异耐酸性和耐划伤性，可以避免外观差的涂料。由（A）由内酯改性的丙烯酸单体和其它单体组成的乙烯基共聚物，（B）与丙二酸酯和乙酰乙酸酯的混合物反应的封端多异氰酸酯化合物和（C）烷基醚化的热固性涂料组合物氨基树脂。

6. 发明申请

WO1996034064A1 THERMOSET PAINT COMPOSITIONS 审中-公开
标题翻译：热固性涂料组合物
公开(公告)号：WO1996034064A1
公开(公告)日：1996-10-31
申请号：PCT/EP1996001633
申请日：1996-04-19
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , HAYAKAWA, Takeshi , SHIBATO, Kishio , MONMA, Yasuhiro
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： C09D175/04
CPC分类号： C08G18/6279 , C08G18/4063 , C08G18/6229 , C08G18/6233 , C09D175/04 , C08L2666/16
摘要： Thermoset paint compositions with which paint films can be formed which have excellent acid resistance, abrasion resistance and adhesion, and with which the water repelling properties and staining resistance can be retained for a longer period of time than with the conventional fluorine resin based paint films, are obtained. Constitution: Thermoset paint film compositions which contain (a) from 20 to 80 % by weight of fluorine containing copolymer, comprising fluoro-olefin and vinyl based monomer, of which the solubility parameter value is from 9.0 to 10.5 and the hydroxy group value is within the range from 60 to 150 mgKOH/g; (b) from 20-80 % by weight of vinyl based (co)polymer, comprising vinyl based monomer which contains at least 10 % by weight of monomer which can be repesented by formula (1), of which the solubility parameter is from 9.0 to 10.5 and the hydroxy group value is within the range from 60 to 150 mgKOH/g; (c) from 5 to 40 % by weight of alkyl etherified melanine resin; and (d) from 2 to 40 % by weight of blocked polyisocyanate compound, and with which the glass transition temperature of the paint film after hardening is at least 50 DEG C. In formula (1), R to R each independently represent H or methyl group, i is 0-2, j is 0 or 1, k is 0-3, m is 0-3 and n is 0-10.
摘要翻译：可以形成具有优异的耐酸性，耐磨性和粘合性的耐油性涂料组合物，并且耐久性能和耐污染性能比常规氟树脂基涂料膜更长时间地保持，获得。结构：热固性漆膜组合物，其含有（a）20〜80重量％的含氟共聚物，包含氟代烯烃和乙烯基类单体，溶解度参数值为9.0-10.5，羟基值在范围为60至150 mgKOH / g; （b）20-80重量％的乙烯基（共）聚合物，其包含含有至少10重量％可通过式（1）重新反应的单体的乙烯基类单体，其溶解度参数为9.0 至10.5，羟基值在60〜150mgKOH / g的范围内; （c）5至40重量％的烷基醚化的蜜胺树脂; 和（d）2-40重量％的封端多异氰酸酯化合物，硬化后漆膜的玻璃化转变温度至少为50℃。在式（1）中，R 1至R 5 各自独立地表示H或甲基，i为0-2，j为0或1，k为0-3，m为0-3，n为0-10。

7. 发明申请

WO1994009916A1 METHOD FOR FORMING A PAINT FILM AND COATING OBTAINED BY THE METHOD 审中-公开
标题翻译：形成涂膜和方法获得的方法
公开(公告)号：WO1994009916A1
公开(公告)日：1994-05-11
申请号：PCT/EP1993003035
申请日：1993-10-30
申请人： BASF LACKE + FARBEN AKTIENGESELLSCHAFT , SHIBATO, Kishio , KAWAMURA, Masataka , SATO, Atsushi , SATO, Shigekazu
发明人： BASF LACKE + FARBEN AKTIENGESELLSCHAFT
IPC分类号： B05D07/26
CPC分类号： B05D7/532 , C08G18/6229 , C08G18/6233 , C08L1/00 , C08L33/06 , C08L33/14 , C08L61/28 , C09D133/06 , C09D133/14 , C09D161/28 , Y10T428/31692 , Y10T428/31699 , C08L2666/14 , C08L2666/02 , C08L2666/04
摘要： Method for forming paint films by the 2-coats/1-bake method, using a clearcoat paint in which the resin component comprises (a) a copolymer of a vinyl monomer mixture containing at least 20 wt% (meth)acrylic acid cycloalkyl esters 40-90 wt%, (b) alkyl-etherified melamine resin 5-50 wt%, and (c) blocked polyisocyanate 5-50 wt%, and a basecoat paint in which the resin component comprises (d) a copolymer of a vinyl monomer mixture containing at least 10 % of monomers represented by general formula (1) (X1-X5 are H or a methyl group, i is 0-2, j is 0 or 1, k is 0-3, m is 0-3, and n is 1-10), 40-80 wt%, (e) alkyl-etherified melamine resin 10-50 wt%, (f) blocked polyisocyanate 0-40 wt%, (g) cellulose type resin 0-20 wt%, and (h) organic crosslinked fine particles 0-30 wt%, and coatings obtained by the said method.
摘要翻译：通过2-涂层/ 1烘烤法形成漆膜的方法，使用透明涂料，其中树脂组分包含（a）含有至少20重量％（甲基）丙烯酸环烷基酯40的乙烯基单体混合物的共聚物 -90重量％，（b）5-50重量％的烷基醚化三聚氰胺树脂和（c）5-50重量％的封端多异氰酸酯，和其中所述树脂组分包含（d）乙烯基单体的共聚物的底漆含有至少10％由通式（1）表示的单体的混合物（X1-X5为H或甲基，i为0-2，j为0或1，k为0-3，m为0-3，（e）0-50重量％的烷基醚化三聚氰胺树脂，（f）0-40重量％的封端多异氰酸酯，（g）0-20重量％的纤维素类树脂，，和（h）0-30重量％的有机交联微粒，以及通过所述方法获得的涂层。

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