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    • 1. 发明申请
    • INTEGRATED PROCESS FOR PRODUCING AMMONIUM NITRATE
    • 用于生产硝酸铵的综合方法
    • WO2012155173A1
    • 2012-11-22
    • PCT/AU2011/001557
    • 2011-12-01
    • THE UNIVERSITY OF SYDNEYORICA INTERNATIONAL PTE LTDJOHNSTON, Anthony MatthewHAYNES, Brian Scott
    • JOHNSTON, Anthony MatthewHAYNES, Brian Scott
    • C01C1/18
    • C01C1/185C01B21/26C01C1/18Y02P20/125
    • A process for producing ammonium nitrate is disclosed and in which: a) a gaseous oxidiser feed composed at least substantially of ammonia, steam and an oxidising gas is exposed to conditions whereby the ammonia is oxidised to produce a reaction mixture including nitrogen monoxide and water vapour, b) the reaction mixture is cooled in a heat exchanger whereby the nitrogen monoxide is oxidised, the water vapour is condensed and the products of the nitrogen monoxide oxidation react with and are absorbed by the condensed water to form a nitric acid stream, with substantially all of the nitrogen monoxide in the reaction mixture being converted to nitric acid, and c) the nitric acid stream is reacted with a stream of ammonia in an ammonium nitrate producing stage to form the ammonium nitrate Substantially all of the steam within the oxidiser feed is derived from the ammonium nitrate producing stage, and at least 10% of the ammonia within the oxidiser feed is derived and carried by the steam from the ammonium nitrate producing stage. Also disclosed is ammonium nitrate, in any of its various possible forms, when produced by the disclosed process.
    • 公开了一种生产硝酸铵的方法,其中:a)至少基本上由氨,蒸汽和氧化气体组成的气态氧化剂进料暴露于氨被氧化以产生包括一氧化氮和水蒸汽的反应混合物 b)将反应混合物在热交换器中冷却,一氧化氮被氧化,水蒸气冷凝,一氧化氮氧化物的产物与冷凝水反应并被冷凝水吸收,形成硝酸流,基本上 反应混合物中的所有一氧化氮都转化为硝酸,和c)硝酸流在硝酸铵生成阶段与氨气流反应形成硝酸铵。基本上氧化剂进料中的所有蒸汽都是 来自硝酸铵生产阶段,并且氧化剂进料中的至少10%的氨由蒸汽导出和携带 从硝酸铵生产阶段。 还公开了当通过所公开的方法制备时,其各种可能形式的任何一种硝酸铵。
    • 4. 发明申请
    • FLUE GAS DESULFURIZATION PROCESS AND APPARATUS FOR REMOVING NITROGEN OXIDES
    • 氟气脱硫工艺及去除氮氧化物的设备
    • WO2003103803A2
    • 2003-12-18
    • PCT/US2003/017854
    • 2003-06-05
    • MARSULEX ENVIRONMENTAL TECHNOLOGIES, CORP.
    • HAMMER, Michael, T.MENGEL, Michael, L.
    • B01D53/00
    • B01D53/56B01D53/1456B01D53/73C01C1/185C01C1/242
    • An apparatus (10) and process for removing acidic gases and NOx from flue gases produced by utility and industrial plants. The process and apparatus (10) convert NOx, and particularly nitric oxide, to nitrogen dioxide, which is then reacted to form a valuable byproduct. The process generally entails contacting a flue gas with a scrubbing medium (14) to absorb acidic gases from flue gas and produce an intermediate flue gas. The intermediate flue gas is then cooled to cause nitric oxide present therein to be oxidized to form nitrogen dioxide, which is then absorbed from the flue gases to produce a nitrogen dioxide-containing solution (36) and a scrubbed flue gas. The nitrogen dioxide in the nitrogen dioxide-containing solution (36) is then reacted with ammonium hydroxide to form ammonium nitrate as a valuable byproduct.
    • 一种用于从公用事业和工厂生产的烟道气中除去酸性气体和NOx的装置(10)。 方法和装置(10)将NOx(特别是一氧化氮)转化为二氧化氮,然后将其反应以形成有价值的副产物。 该方法通常需要使烟气与洗涤介质(14)接触以吸收来自烟道气的酸性气体并产生中间烟道气。 然后将中间烟道气冷却以使其中存在的一氧化氮被氧化以形成二氧化氮,然后从烟道气中吸收二氧化氮,以产生含二氧化氮的溶液(36)和洗涤的废气。 然后将含二氧化氮的溶液(36)中的二氧化氮与氢氧化铵反应,形成硝酸铵作为有价值的副产物。