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    • 8. 发明申请
    • A METHOD TO MEASURE SURFACTANT IN FLUID
    • 测量流体中表面活性剂的方法
    • WO2013192068A1
    • 2013-12-27
    • PCT/US2013/046074
    • 2013-06-17
    • NALCO COMPANY
    • PACHECO E SILVA, VivianeWANDERLAY BRATFISCH PACE, LuizCARONE JUNIOR, Edmir
    • G01N33/00G01N31/22G01N21/78
    • G01N21/59G01N21/3151G01N21/80Y10T436/173845Y10T436/196666Y10T436/200833
    • The invention is directed towards methods and compositions for identifying the presence of surfactants in water. The invention is quite superior over the prior art because it can form a colorful complex in half the time, avoid the need for difficult separation steps, use a safer solvent, and avoid the formation of messy foam. The invention involves adding to the water a cobalt thiocyanate reagent, pre-prepared from a cobalt salt and a thiocyanate salt, which forms a colorful complex with the surfactant. Chloroform is then added to the water. The cobalt reagent causes the virtually all of the surfactant to form a colored complex which rapidly migrates into the chloroform and prevents the surfactant from foaming. Once in the chloroform, a UV-vis spectrometer can easily and precisely identify the type and amount of surfactant that was in the water.
    • 本发明涉及用于鉴定水中表面活性剂的存在的方法和组合物。 本发明相对于现有技术来说是相当优越的,因为它可以在一半时间内形成多彩的复合物,避免了难以分离的步骤,使用更安全的溶剂,并避免形成混乱的泡沫。 本发明涉及向水中加入由钴盐和硫氰酸盐预先制备的硫氰酸钴试剂,其与表面活性剂形成多彩配合物。 然后将氯仿加入到水中。 钴试剂使几乎所有的表面活性剂形成着色复合物,其迅速迁移到氯仿中并防止表面活性剂起泡。 一旦在氯仿中,紫外可见分光光度计可以容易且准确地识别在水中的表面活性剂的类型和量。