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1. 发明申请

WO2009010435A2 METHOD FOR THE CHEMICAL DEPOLYMERIZATION OF WASTE POLYETHYLENE TEREPHTHALATE 审中-公开
标题翻译：废弃聚乙烯三烯酸盐的化学分解方法
公开(公告)号：WO2009010435A2
公开(公告)日：2009-01-22
申请号：PCT/EP2008/058917
申请日：2008-07-09
申请人： USTAV CHEMICKYCH PROCESU AKADEMIE VED CESKE REPUBLIKY , HAJEK, Milan , SOBEK, Jiri , BRUSTMAN, Jaroslav
发明人： HAJEK, Milan , SOBEK, Jiri , BRUSTMAN, Jaroslav
IPC分类号： C08J11/10 , C07C51/09
CPC分类号： C08J11/10 , C07C51/09 , C08J11/22 , C08J11/24 , C08J2367/02 , Y02W30/702 , Y02W30/706 , C07C63/26
摘要： A method for the chemical depolymerization of waste polyethylene terephthalate by application of microwave radiation and solvolysis in the presence of a catalyst comprising the first stage where the waste polyethylene terephthalate is mixed up with an microwaves absorbing activator, the mixture is melted by its exposing to a microwave radiation on a frequency from 915 to 2450 MHz and with a power output from 0.1 to 0.5 kW per kg of a charge, at a temperature from 230 to 330° C, under atmospheric pressure and the second stage, where the molten mixture is subjected to solvolysis, including acidic or basic hydrolysis, alcoholysis or glycolysis in the presence of a catalyst under continuing microwave radiation and atmospheric pressure yielding terephthalic acid, salts or esters thereof, and ethylene glycol.
摘要翻译：一种在含有废聚对苯二甲酸乙二醇酯与微波吸收活化剂混合的第一阶段的催化剂存在下通过应用微波辐射和溶剂解作用的废聚对苯二甲酸乙二醇酯的化学解聚的方法，该混合物通过暴露于频率从915到2450MHz的微波辐射，以及在大气压下在230-330℃的温度下，每千克电荷的功率输出为0.1至0.5kW的第二阶段，其中熔融混合物经受溶剂解，包括酸性或碱性水解，醇解或糖酵解在催化剂存在下在连续的微波辐射和大气压下产生对苯二甲酸，其盐或酯和乙二醇。

2. 发明申请

WO2010079408A1 MICROWAVE METHOD AND DEVICE FOR RECYCLING REFINED STEEL CORD FROM WASTE TIRES 审中-公开
标题翻译：用于从废物轮胎回收精炼钢丝的微波方法和装置
公开(公告)号：WO2010079408A1
公开(公告)日：2010-07-15
申请号：PCT/IB2009/055986
申请日：2009-12-29
申请人： USTAV CHEMICKYCH PROCESU AKADEMIIE VED CESKE REPUBLIKY , HAJEK, Milan , SOBEK, Jiri
发明人： HAJEK, Milan , SOBEK, Jiri
IPC分类号： C22B7/00 , H05B6/64 , H05B6/78 , B29B17/02 , C08J11/12 , C10B53/07
CPC分类号： C22B7/001 , B29B17/0206 , B29K2305/12 , B29L2030/00 , C10B19/00 , C10B53/07 , C22B7/005 , H05B6/80 , Y02P10/214 , Y02P20/143 , Y02W30/622
摘要： A method for refining metal material separated from crushed waste tires by heating the metal material and distilling off a portion of non-metallic constituents wherein the fragments of metal material comprising steel cord containing 82 - 98 % of steel by weight are exposed in a closed space to a microwave radiation with a frequency of 890 MHz to 2450 MHz to reach a temperature of 100 to 700 °C of the metal material at which the volatile fraction of the non-metal constituents is distilled off and separated by cooling and condensation and the solid constituents comprising mixture of steel cord and black carbon are cooled and the steel cord is isolated in high quality. A device for performing the method comprises a batch reactor, continuous furnace equipped with an endless conveyor or a rotary kiln.
摘要翻译：一种用于通过加热金属材料并蒸馏掉一部分非金属成分来精炼与粉碎废轮胎分离的金属材料的方法，其中包含82-98％重量的钢的钢帘线的金属材料碎片暴露在封闭空间涉及频率为890MHz至2450MHz的微波辐射，以达到金属材料的温度为100至700℃，在该温度下蒸发非金属成分的挥发分，并通过冷却和冷凝分离，固体包括钢帘线和黑碳的混合物的组分被冷却并且钢帘线被高质量地隔离。用于执行该方法的装置包括间歇式反应器，配备有循环输送机或回转窑的连续炉。

3. 发明申请

WO2009024102A4 METHOD OF RECYCLING WASTE POLYURETHANE FOAMS 审中-公开
公开(公告)号：WO2009024102A4
公开(公告)日：2009-02-26
申请号：PCT/CZ2008/000095
申请日：2008-08-20
申请人： INSTITUTE OF MACROMOLECULAR CHEMISTRY AS CR, V.V.I. , INSTITUTE OF CHEMICAL PROCESS FUNDAMENTALS AS CR, V.V.I. , KRULIS, Zdenek , HORAK, Zdenek , BENES, Hynek , HAJEK, Milan
发明人： KRULIS, Zdenek , HORAK, Zdenek , BENES, Hynek , HAJEK, Milan
IPC分类号： C08J11/24
摘要： The invention concerns the method of recycling waste polyurethane foams to a polyol mixture characterized in that the waste polyurethane is decomposed by the reaction with a low- molecular-weight polyhydric alcohol selected from the group consisting of ethylene glycol, propylene glycol, butanediol, pentanediol, hexanediol, 2-methylpropane-l,3-diol, diethylene glycol, dipropylene glycol, triethylene glycol, tripropylene glycol, trimethylolpropane (2,2- bis(hydroxymethyl)propan-l-ol), glycerol or their mixtures under the condition that the waste polyurethane and polyhydric alcohol are used in the weight ratio at least 3:1 and at most 1:3 and the reaction mixture is subjected to the action of electromagnetic radiation of a frequency ranging from 1 MHz to 10 GHz at the temperature from 50 °C - 300 °C.

4. 发明申请

WO2007095871A3 SUPERPARAMAGNETIC NANOPARTICLES BASED ON IRON OXIDES WITH MODIFIED SURFACE, METHOD OF THEIR PREPARATION AND APPLICATION 审中-公开
公开(公告)号：WO2007095871A3
公开(公告)日：2007-08-30
申请号：PCT/CZ2007/000012
申请日：2007-02-23
申请人： USTAV MAKROMOLEKULARNI CHEMIE AKADEMIE VEDCESKE REPUBLIKY, V.V.I , USTAV EXPERIMENTALNI MEDICINY AKADEMIE VEDCESKE REPUBLIKY.V.V.I , HORAK, Daniel , SYKOVA, Eva , BABIC, Michal , JENDELOVA, Pavla , HAJEK, Milan
发明人： HORAK, Daniel , SYKOVA, Eva , BABIC, Michal , JENDELOVA, Pavla , HAJEK, Milan
IPC分类号： C01G49/08 , C01G49/06 , A61K49/18 , C09C1/24
摘要： The subject of the invention is superparamagnetic nanoparticle probes based on iron oxides, to advantage magnetite or maghemite, with modified surface, coated with mono-, di- or polysaccharides from the group including D-arabinose, D-glucose, D-galactose, D-mannose, lactose, maltose, dextrans and dextrins, or with amino acids or poly(amino acid)s from the group including alanine, glycine, glutamine, asparagine, histidine, arginine, L-lysine, aspartic and glutamic acid or with synthetic polymers based on (meth)acrylic acid and their derivatives selected from the group containing poly( N , N -dimethylacrylamide), poly( N,N - dimethylmethacrylamide), poly( N, N- diethylacrylamide), poly (N, iV-diethylmethacrylamide), poly( N -isopropylacrylamide), poly( N -isopropylmethacrylamide), which form a colloid consisting of particles with narrow distribution with polydispersity index smaller than 1.3, the average size of which amounts to 0.5-30 nm, to advantage 1-10 nm, the iron content is 70- 99.9 wt.%, to advantage 90 wt.%, the modification agent content 0.1-30 wt.%, to advantage 10 wt.%. The particles of size smaller than 2 nm with polydispersity index smaller than 1.1 can be obtained by a modified method of preparation. Superparamagnetic nanoparticle probes according to the invention are prepared by pre- precipitation of colloidal Fe(OH) 3 by the treatment of aqueous 0.1-0.2M solution of Fe(III) salt, to advantage FeCl 3 , with less than an equimolar amount Of NH 4 OH, at 21°C, under sonication, to which a solution of a Fe(II) salt, to advantage FeCl2, is added in the mole ratio Fe(III)/Fe(II) = 2 under sonication and the mixture is poured into five- to tenfold, to advantage eightfold, molar excess of 0.5M NH 4 OH. The mixture is left aging for 0-30 min, to advantage 15 min, and then the precipitate is repeatedly, to advantage 7-10 times, magnetically separated and washed with deionized water. Then 1-3 fold amount, to advantage 1.5 fold amount, relative to the amount of magnetite, of 0.1 M aqueous solution of sodium citrate is added and then, drop wise, 1-3 fold amount, to advantage 1.5 fold amount, relative to the amount of magnetite, of 0.7 M aqueous solution of sodium hypochlorite. The precipitate is repeatedly, to advantage 7-10 times, washed with deionized water under the formation of colloidal maghemite to which, after dilution, is added drop wise, to advantage under 5 -min sonication, an aqueous solution of a modification agent, in the weight ratio modification agent/iron oxide = 0.1-10, to advantage 0.2 for amino acids and poly(amino acid)s and 5 for saccharides. The particles smaller than 2 nm. with polydispersity index smaller than 1.1 are prepared by mixing at 21°C 1 volume part of 10-60 wt. %, to advantage 50 wt.%, of an aqueous solution of a saccharide, disaccharide or polysaccharide, such as D-arabinose, D-glucose, D-galactose, D-mannose, lactose, maltose, dextran and dextrins, and 1 volume part of aqueous solution of a Fe(II) and Fe(III) salt, to advantage FeCl 2 and FeCl 3 , where the molar ratio Fe(III)/Fe(II) = 2. A 5-15 %, to advantage 7.5 %, solution Of NH 4 OH is added until pH 12 is attained and

5. 发明申请

WO2009024102A3 METHOD OF RECYCLING WASTE POLYURETHANE FOAMS 审中-公开
公开(公告)号：WO2009024102A3
公开(公告)日：2009-02-26
申请号：PCT/CZ2008/000095
申请日：2008-08-20
申请人： INSTITUTE OF MACROMOLECULAR CHEMISTRY AS CR, V.V.I. , INSTITUTE OF CHEMICAL PROCESS FUNDAMENTALS AS CR, V.V.I. , KRULIS, Zdenek , HORAK, Zdenek , BENES, Hynek , HAJEK, Milan
发明人： KRULIS, Zdenek , HORAK, Zdenek , BENES, Hynek , HAJEK, Milan
IPC分类号： C08J11/24
摘要： The invention concerns the method of recycling waste polyurethane foams to a polyol mixture characterized in that the waste polyurethane is decomposed by the reaction with a low- molecular-weight polyhydric alcohol selected from the group consisting of ethylene glycol, propylene glycol, butanediol, pentanediol, hexanediol, 2-methylpropane-l,3-diol, diethylene glycol, dipropylene glycol, triethylene glycol, tripropylene glycol, trimethylolpropane (2,2- bis(hydroxymethyl)propan-l-ol), glycerol or their mixtures under the condition that the waste polyurethane and polyhydric alcohol are used in the weight ratio at least 3:1 and at most 1:3 and the reaction mixture is subjected to the action of electromagnetic radiation of a frequency ranging from 1 MHz to 10 GHz at the temperature from 50 °C - 300 °C.

6. 发明申请

WO2009024102A2 METHOD OF RECYCLING WASTE POLYURETHANE FOAMS 审中-公开
标题翻译：回收废聚氨酯泡沫的方法
公开(公告)号：WO2009024102A2
公开(公告)日：2009-02-26
申请号：PCT/CZ2008/000095
申请日：2008-08-20
申请人： INSTITUTE OF MACROMOLECULAR CHEMISTRY AS CR, V.V.I. , INSTITUTE OF CHEMICAL PROCESS FUNDAMENTALS AS CR, V.V.I. , KRULIS, Zdenek , HORAK, Zdenek , BENES, Hynek , HAJEK, Milan
发明人： KRULIS, Zdenek , HORAK, Zdenek , BENES, Hynek , HAJEK, Milan
IPC分类号： C08J11/24
CPC分类号： C08J11/24 , C08G18/831 , C08J2375/04 , Y02W30/706
摘要： The invention concerns the method of recycling waste polyurethane foams to a polyol mixture characterized in that the waste polyurethane is decomposed by the reaction with a low- molecular-weight polyhydric alcohol selected from the group consisting of ethylene glycol, propylene glycol, butanediol, pentanediol, hexanediol, 2-methylpropane-l,3-diol, diethylene glycol, dipropylene glycol, triethylene glycol, tripropylene glycol, trimethylolpropane (2,2- bis(hydroxymethyl)propan-l-ol), glycerol or their mixtures under the condition that the waste polyurethane and polyhydric alcohol are used in the weight ratio at least 3:1 and at most 1:3 and the reaction mixture is subjected to the action of electromagnetic radiation of a frequency ranging from 1 MHz to 10 GHz at the temperature from 50 °C - 300 °C.
摘要翻译：本发明涉及将废聚氨酯泡沫再循环到多元醇混合物中的方法，其特征在于废聚氨酯通过与选自乙二醇，丙二醇，丁二醇，戊二醇，戊二醇，己二醇，己二醇，2-甲基丙烷-1,3-二醇，二甘醇，二丙二醇，三甘醇，三丙二醇，三羟甲基丙烷（2,2-双（羟甲基）丙-1-醇），甘油或它们的混合物废聚氨酯和多元醇以重量比至少3:1且至多1:3使用，并且反应混合物在50℃的温度下经受频率范围为1MHz至10GHz的电磁辐射的作用 C - 300°C。

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