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1. 发明申请

WO2008002381A3 IMPROVED POLYMERIZATION PROCESSES USING METALLOCENE CATALYSTS, THEIR POLYMER PRODUCTS AND END USES 审中-公开
公开(公告)号：WO2008002381A3
公开(公告)日：2008-01-03
申请号：PCT/US2007/013231
申请日：2007-06-05
申请人： UNIVATION TECHNOLOGIES, LLC , KOLB, Rainer , AGAPIOU, Agapios, K. , FARLEY, James, M. , MARKEL, Eric, J. , SAVATSKY, Bruce, J. , DAVEY, Christopher, R. , PANNELL, Richard, B.
发明人： KOLB, Rainer , AGAPIOU, Agapios, K. , FARLEY, James, M. , MARKEL, Eric, J. , SAVATSKY, Bruce, J. , DAVEY, Christopher, R. , PANNELL, Richard, B.
IPC分类号： C08F210/16
摘要： A process for the production of an ethylene alpha-olefin copolymer is disclosed, the process including polymerizing ethylene and at least one alpha- olefin by contacting the ethylene and the at least one alpha-olefin with a metallocene catalyst in at least one gas phase reactor at a reactor pressure of from 0.7 to 70 bar and a reactor temperature of from 20°C to 150°C to form an ethylene alpha-olefin copolymer. The resulting ethylene alpha-olefin copolymer may have a density D of 0.927 g/cc or less, a melt index (I 2 ) of from 0.1 to 100 dg/min, a MWD of from 1.5 to 5.0. The resulting ethylene alpha-olefin copolymer may also have a peak melting temperature Tmax second meit satisfying the following relation: T max second melt > D*398 - 245.

2. 发明申请

WO2007037839A1 METHOD FOR SEED BED TREATMENT BEFORE A POLYMERIZATION REACTION 审中-公开
标题翻译：聚合反应之前的种子处理方法
公开(公告)号：WO2007037839A1
公开(公告)日：2007-04-05
申请号：PCT/US2006/032621
申请日：2006-08-22
申请人： UNIVATION TECHNOLOGIES, LLC , PANNELL, Richard, B. , AGAPIOU, Agapios, K. , MARKEL, Eric, J.
发明人： PANNELL, Richard, B. , AGAPIOU, Agapios, K. , MARKEL, Eric, J.
IPC分类号： C08F10/00 , C08F2/34
CPC分类号： C08F10/00 , Y02P20/582 , C08F2/34 , C08F2/005
摘要： In some embodiments, a method in which at least one continuity additive ("CA") and a seed bed are pre-loaded into a reactor, and a polymerization reaction is optionally then performed in the reactor. In other embodiments, at least one flow improver, at least one CA, and a seed bed are pre-loaded into a reactor. Pre¬ loading of a reactor with a CA can significantly improve continuity of a subsequent polymerization reaction in the reactor during its initial stages, including by reducing sheeting and fouling. The CA can be pre-loaded in dry form (e.g., as a powder), or in liquid or slurry form (e.g., as an oil slurry). To aid delivery of a dry CA to the reactor and combination of the dry CA with a seed bed in the reactor, the dry CA can be combined with a flow improver and the combination of CA and flow improver then loaded into the reactor. Alternatively, the CA and flow improver can be sequentially loaded into the reactor, and then mixed together (and mixed with a seed bed) in the reactor after both the CA and flow improver have been separately loaded into the reactor.
摘要翻译：在一些实施方案中，其中将至少一种连续性添加剂（“CA”）和种子床预加载到反应器中的方法，然后任选地在反应器中进行聚合反应。在其它实施方案中，将至少一种流动改进剂，至少一种CA和种子床预加载到反应器中。具有CA的反应器的预加载可以显着改善反应器在其初始阶段期间的后续聚合反应的连续性，包括通过减少片材和结垢。 CA可以以干燥形式（例如，作为粉末）或以液体或浆料形式（例如作为油浆）预加载。为了帮助将干燥的CA输送到反应器中并将干燥的CA与反应器中的种子床的组合，干燥的CA可与流动改进剂组合，然后将CA和流动改进剂的组合装入反应器中。或者，CA和流动改进剂可以顺序加载到反应器中，然后在CA和流动改进剂已经分别装载到反应器中之后混合在一起（并与种子床混合）在反应器中。

3. 发明申请

WO2010129634A1 SYSTEMS AND METHODS FOR MONITORING A POLYMERIZATION REACTION 审中-公开
标题翻译：用于监测聚合反应的系统和方法
公开(公告)号：WO2010129634A1
公开(公告)日：2010-11-11
申请号：PCT/US2010/033659
申请日：2010-05-05
申请人： UNIVATION TECHNOLOGIES, LLC , MUHLE, Michael, E. , PANNELL, Richard, B. , MARKEL, Eric, J. , HAGERTY, Robert, O.
发明人： MUHLE, Michael, E. , PANNELL, Richard, B. , MARKEL, Eric, J. , HAGERTY, Robert, O.
IPC分类号： C08F2/00 , C08F2/34 , C08F210/16
CPC分类号： C08F210/16 , C08F2400/02 , C08F2/34 , C08F2/002
摘要： Systems and methods for monitoring a polymerization reactor are provided. The method can include estimating an acoustic condition of a polymer produced in a reactor. The method can also include estimating a stickiness control parameter of the polymer produced in the reactor. The method can further include pairing the acoustic condition with the stickiness control parameter to provide a paired acoustic condition and stickiness control parameter.
摘要翻译：提供了用于监测聚合反应器的系统和方法。该方法可以包括估计在反应器中产生的聚合物的声学条件。该方法还可以包括估计在反应器中产生的聚合物的粘性控制参数。该方法还可以包括将声学条件与粘性控制参数配对以提供成对的声学条件和粘性控制参数。

4. 发明申请

WO2008100368A1 METHOD FOR ON-LINE MONITORING AND CONTROL OF POLYMERIZATION PROCESSES AND REACTORS TO PREVENT DISCONTINUITY EVENTS 审中-公开
标题翻译：用于在线监测和控制聚合过程和反应物以防止不连续事件的方法
公开(公告)号：WO2008100368A1
公开(公告)日：2008-08-21
申请号：PCT/US2008/000732
申请日：2008-01-18
申请人： UNIVATION TECHNOLOGIES, LLC , HAGERTY, Robert, O. , BURDETT, Ian, D. , DECHELLIS, Marc, L. , HUSSEIN, F., David , MARKEL, Eric, J. , MUHLE, Michael, E. , PANNELL, Richard, B. , ZILKER, Daniel, P.
发明人： HAGERTY, Robert, O. , BURDETT, Ian, D. , DECHELLIS, Marc, L. , HUSSEIN, F., David , MARKEL, Eric, J. , MUHLE, Michael, E. , PANNELL, Richard, B. , ZILKER, Daniel, P.
IPC分类号： C08F2/00 , C08G85/00
CPC分类号： C08F10/00 , C08F2400/02 , C08F2/34 , C08F2/002 , C08F2/00
摘要： Generally, a method of monitoring a polymerization reaction in a fluid bed reactor to generate, in on-line fashion, data indicative of the imminent occurrence of a discontinuity event (for example, sheeting) and optionally also control the reaction to prevent the occurrence of the discontinuity event is provided. Typical embodiments include the steps of generating in on-line fashion at least one of bed static data indicative of static charge in the fluidized bed and carryover static data indicative of carryover static; and generating at least one of temperature data (in on-line fashion using at least one monitored reaction parameter) indicative of a first temperature and acoustic emission data indicative of resin stickiness in the reactor, where the first temperature is indicative of at least one of degree of resin stickiness in the reactor and a characteristic of melting behavior of polymer resin in the reactor in the presence of at least one diluent.
摘要翻译：通常，监测流化床反应器中的聚合反应的方法，以在线方式产生指示即将发生不连续事件（例如，片材）的数据，并且任选地还控制反应以防止发生提供不连续事件。典型的实施方案包括以在线方式产生指示流化床中的静电荷的床静态数据中的至少一种并携带指示携带静电的静态数据的步骤; 并且产生指示在反应器中指示树脂粘性的第一温度和声发射数据的温度数据（以在线方式使用至少一个监测的反应参数）中的至少一个，其中第一温度表示以下中的至少一个：在至少一种稀释剂存在下，反应器中的树脂粘性程度和聚合物树脂在反应器中的熔融行为的特征。

5. 发明申请

WO2009014682A2 METHOD FOR MONITORING A POLYMERIZATION REACTION 审中-公开
标题翻译：监测聚合反应的方法
公开(公告)号：WO2009014682A2
公开(公告)日：2009-01-29
申请号：PCT/US2008/008871
申请日：2008-07-22
申请人： UNIVATION TECHNOLOGIES, LLC , MUHLE, Michael, E. , PANNELL, Richard, B. , MARKEL, Eric, J. , HAGERTY, Robert, O.
发明人： MUHLE, Michael, E. , PANNELL, Richard, B. , MARKEL, Eric, J. , HAGERTY, Robert, O.
IPC分类号： B01J8/24 , B01J19/00
CPC分类号： B01J8/1809 , B01J19/0033 , B01J2208/00061 , B01J2208/00176 , B01J2208/00194 , B01J2208/00212 , B01J2208/0061 , B01J2208/00619 , B01J2219/00198 , B01J2219/002 , B01J2219/00202 , B01J2219/00209 , B01J2219/00216 , B01J2219/00218 , B01J2219/00225 , B01J2219/00231 , B01J2219/00234 , B01J2219/00238 , B01J2219/00243 , C08F10/00 , C08F2400/02 , C08F2/002 , C08F2/00 , C08F2/34
摘要： In some embodiments, a method of monitoring a resin-producing polymerization reaction in a fluid bed reactor system to generate reaction parameter data in on-line fashion, wavelet transforming the reaction parameter data to generate frequency-domain data or determining kurtosis of each of at least two subsets of the reaction parameter data, and optionally also determining from the frequency-domain data or kurtosis values an indication of at least one of degree of resin stickiness, an approach to or imminence of resin stickiness, and an approach to or imminence of an unsafe or undesired reactor operating condition that can result in sheeting or chunking. Optionally also, the reaction is controlled in response to the kurtosis values or frequency-domain data, for example, in an effort to prevent the occurrence of sheeting or another discontinuity event or to maintain the reactor in a stable, non-sticking condition.
摘要翻译：在一些实施方案中，一种监测流化床反应器系统中产生树脂的聚合反应以在线方式产生反应参数数据的方法，小波变换反应参数数据以产生频域数据或确定每一个的峰域数据的峰度反应参数数据的至少两个子集，并且可选地还根据频域数据或峰度值确定树脂粘性程度，树脂粘性的接近或迫切性中的至少一种的指示，以及接近或迫在眉睫的方法不安全或不合需要的反应堆操作条件，可能导致片材或分块。也可选地，响应于峰度值或频域数据来控制反应，例如，为了防止片材的发生或另外的不连续事件或将反应器保持在稳定的不粘附状态。

6. 发明申请

WO2011103280A1 METHODS FOR OPERATING A POLYMERIZATION REACTOR 审中-公开
标题翻译：操作聚合反应器的方法
公开(公告)号：WO2011103280A1
公开(公告)日：2011-08-25
申请号：PCT/US2011/025231
申请日：2011-02-17
申请人： UNIVATION TECHNOLOGIES, LLC , MARKEL, Eric, J. , HAGERTY, Robert, O. , PANNELL, Richard, B. , SIELOFF, Michael, E. , HOLVECK, Jerome
发明人： MARKEL, Eric, J. , HAGERTY, Robert, O. , PANNELL, Richard, B. , SIELOFF, Michael, E. , HOLVECK, Jerome
IPC分类号： C08F10/00 , C08F2/42 , C08F2/34
CPC分类号： C08F10/00 , C08F4/6592 , C08F210/16 , C08F2/34 , C08F2/42 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/18
摘要： Methods for shutting down and restarting polymerization in a gas phase polymerization reactor are provided. The method can include introducing a polymerization neutralizer to the reactor in an amount sufficient to stop polymerization therein. The method can also include stopping recovery of a polymer product from the reactor and stopping introduction of a catalyst feed and a reactor feed to the reactor. The method can also include adjusting a pressure within the reactor from an operating pressure to an idling pressure. The method can also include adjusting a superficial velocity of a cycle fluid through the reactor from an operating superficial velocity to an idling superficial velocity. The method can also include maintaining the reactor in an idled state for a period of time.
摘要翻译：提供了在气相聚合反应器中关闭和重新开始聚合的方法。该方法可以包括以足以阻止其中聚合的量向反应器中引入聚合中和剂。该方法还可以包括停止从反应器中回收聚合物产物，并停止将催化剂进料和反应器进料引入反应器。该方法还可以包括将反应器内的压力从操作压力调节到空载压力。该方法还可以包括调节通过反应器的循环流体的表观速度从操作的表观速度到空转的表观速度。该方法还可以包括将反应器维持在空闲状态一段时间。

7. 发明申请

WO2010036446A1 METHODS FOR CLEANING THE DISTRIBUTOR PLATE IN A FLUIDIZED BED REACTOR SYSTEM 审中-公开
标题翻译：在流化床反应器系统中清洁分布板的方法
公开(公告)号：WO2010036446A1
公开(公告)日：2010-04-01
申请号：PCT/US2009/051478
申请日：2009-07-23
申请人： UNIVATION TECHNOLOGIES, LLC , MARKEL, Eric, J. , HAGERTY, Robert, O. , IMPELMAN, Ryan, W. , PANNELL, Richard, B. , SALADINO, Cecile, F.
发明人： MARKEL, Eric, J. , HAGERTY, Robert, O. , IMPELMAN, Ryan, W. , PANNELL, Richard, B. , SALADINO, Cecile, F.
IPC分类号： B01J8/18 , B01J8/24 , B01J19/00 , C08F2/34
CPC分类号： B01J8/1827 , B01J8/1809 , B01J8/1818 , B01J19/0026 , B01J2208/00274 , B01J2208/00707 , B01J2219/00247 , B01J2219/00272 , C08F10/00 , C08F110/02 , Y02P20/582 , C08F2/34 , C08F2/002 , C08F2/01
摘要： A method for cleaning a distributor plate in a fluidized bed polymerization reactor system according to one embodiment includes, in a first mode, operating with about a normal, baseline value of superficial gas velocity in a fluidized bed polymerization reactor system having a reactor vessel, a recycle line, and a distributor plate in the reactor vessel near an inlet of the reactor vessel. In a second mode, the superficial gas velocity is increased above the baseline value of the first mode to a level sufficient to raise the temperature of the cycle gas at the inlet above an average temperature of the cycle gas at the inlet in the first mode, and to a level sufficient to dislodge foulant from holes in the distributor plate.
摘要翻译：根据一个实施方案的用于清洁流化床聚合反应器系统中的分配板的方法包括在具有反应器容器的流化床聚合反应器系统中以大约正常的表观气体速度的基准值操作的第一模式，循环管线和反应器容器附近的分配器板。在第二模式中，将表观气体速度增加到高于第一模式的基准值，至足以使入口处的循环气体的温度高于第一模式中入口处循环气体的平均温度的水平，并且达到足以从分配器板中的孔中排出污垢的水平。

8. 发明申请

WO2008030313A1 METHODS FOR DETERMINING TEMPERATURE VALUE INDICATIVE OF RESIN STICKINESS FROM DATA GENERATED BY POLYMERIZATION REACTION MONITORING 审中-公开
标题翻译：通过聚合反应监测产生的数据确定树脂粘度的温度值的方法
公开(公告)号：WO2008030313A1
公开(公告)日：2008-03-13
申请号：PCT/US2007/017730
申请日：2007-08-09
申请人： UNIVATION TECHNOLOGIES, LLC , MARKEL, Eric, J. , HAGERTY, Robert, O. , PANNELL, Richard, B.
发明人： MARKEL, Eric, J. , HAGERTY, Robert, O. , PANNELL, Richard, B.
IPC分类号： C08F2/00
CPC分类号： C08F10/00 , C08F210/16 , C08F2400/02 , C08F2/34 , C08F2/00 , C08F210/08 , C08F210/14 , C08F2500/20
摘要： In some embodiments, a method including the steps of monitoring a polymerization reaction which produces a polymer resin in a flμid bed reactor, where a dry melt reference temperature is characteristic of melting behavior of a dry version of the resin, and in response to data indicative of at least one monitored parameter of the reaction, determining in on-line fashion a reduced melt reference temperature that is at least substantially equal to the difference between the dry melt reference temperature and a temperature by which the dry melt reference temperature is depressed by the presence of condensable diluent gas with the resin in the reactor. Optionally, the method also includes the step of controlling the reaction in response to the reduced melt reference temperature or a stickiness parameter determined from the reduced melt reference temperature.
摘要翻译：在一些实施方案中，一种方法包括以下步骤：监测聚合反应，其在纤维床反应器中产生聚合物树脂，其中干熔体参考温度是干燥形式的树脂的熔融特性的特征，并且响应于数据指示的反应的至少一个监测参数，以在线方式确定降低的熔融参考温度，其至少基本上等于干熔体参考温度与干熔体参考温度被压下的温度之间的差异在反应器中存在可冷凝稀释气体与树脂。任选地，该方法还包括响应于降低的熔融参考温度或从降低的熔融参考温度确定的粘性参数来控制反应的步骤。

9. 发明申请

WO2008030294A1 METHODS FOR ON-LINE DETERMINATION OF DEGREE OF RESIN STICKINESS USING A MODEL FOR DEPRESSION OF MELT INITIATION TEMPERATURE 审中-公开
标题翻译：使用用于降低熔融温度的模型来确定树脂粘度的方法的方法
公开(公告)号：WO2008030294A1
公开(公告)日：2008-03-13
申请号：PCT/US2007/016047
申请日：2007-07-13
申请人： UNIVATION TECHNOLOGIES, LLC , PANNELL, Richard, B. , HAGERTY, Robert, O. , MARKEL, Eric, J.
发明人： PANNELL, Richard, B. , HAGERTY, Robert, O. , MARKEL, Eric, J.
IPC分类号： C08F10/00 , C08F2/00 , G05B17/00
CPC分类号： C08F10/00 , C08F210/16 , C08F2400/02 , C08F2/00 , C08F2/34 , C08F210/08 , C08F210/14
摘要： In some embodiments, a method including the steps of: during a polymerization reaction producing a polymer resin in a fluid bed reactor, measuring reaction parameters including at least reactor temperature, at least one property of the resin, and amount of at least one condensable diluent gas in the reactor; determining from at least one measured resin property using a predetermined correlation, a dry melt initiation temperature value for a dry version of the polymer resin; and during the reaction, using a melt initiation temperature depression model to determine in on-line fashion a reduced melt initiation temperature.for the resin (e.g., a temperature at which the resin is expected to begin to melt) in the presence of the at least one condensable diluent gas in the reactor.
摘要翻译：在一些实施方案中，一种方法包括以下步骤：在聚合反应期间在流化床反应器中制备聚合物树脂，测量反应参数至少包括反应器温度，树脂的至少一种性质和至少一种可冷凝稀释剂反应堆中的气体; 使用预定的相关性从至少一种测量的树脂性质确定干燥型聚合物树脂的干熔体起始温度值; 并且在反应期间，使用熔体引发温度下降模型以在线方式确定在存在下的树脂（例如树脂预期开始熔化的温度）时熔体起始温度降低在反应器中至少一种可冷凝的稀释气体。

10. 发明申请

WO2009096937A1 SYSTEMS AND METHODS FOR DETECTING LIQUID POOLING IN REACTOR SYSTEMS 审中-公开
标题翻译：用于检测反应器系统中的液体池的系统和方法
公开(公告)号：WO2009096937A1
公开(公告)日：2009-08-06
申请号：PCT/US2008/013701
申请日：2008-12-15
申请人： UNIVATION TECHNOLOGIES, INC. , PANNELL, Richard, B. , MARKEL, Eric, J. , MUHLE, Michael, E. , HAGERTY, Robert, O, , EHRMAN, Fred, D.
发明人： PANNELL, Richard, B. , MARKEL, Eric, J. , MUHLE, Michael, E. , HAGERTY, Robert, O, , EHRMAN, Fred, D.
IPC分类号： C08F10/00 , C08F2/34
CPC分类号： B01J8/1827 , B01J8/1809 , B01J8/1872 , B01J2208/00601 , B01J2219/00268 , C08F10/02 , C08F110/02 , C08F2400/02 , C08F2/00 , C08F2/34
摘要： Various methods and systems for detecting pooling of liquids in reactor systems are provided. In certain embodiments, the methods and systems include a polymerization reactor system such as a gas-phase reactor system.
摘要翻译：提供了用于检测反应堆系统中液体汇集的各种方法和系统。在某些实施方案中，方法和系统包括聚合反应器系统，例如气相反应器系统。

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