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1. 发明申请

WO2010111288A2 SPRAY PROCESS FOR SELECTIVE OXIDATION 审中-公开
标题翻译：用于选择性氧化的喷雾方法
公开(公告)号：WO2010111288A2
公开(公告)日：2010-09-30
申请号：PCT/US2010028343
申请日：2010-03-23
申请人： UNIV KANSAS , SUBRAMANIAM BALA , BUSCH DARYLE H , NIU FENGHUI
发明人： SUBRAMANIAM BALA , BUSCH DARYLE H , NIU FENGHUI
IPC分类号： C07C51/255 , B01J8/00 , B01J12/00 , B01J19/26 , C07C63/00
CPC分类号： C07C51/255 , B01J4/002 , B01J10/007 , B01J2219/00006 , B01J2219/00063 , B01J2219/00065 , B01J2219/00162 , C07C51/265 , C07C63/00
摘要： Oxidation process can include: introducing small droplets of liquid reaction mixture having oxidizable reactant, catalyst, and solvent into a reaction zone containing oxygen and diluent gas; and oxidizing the reactant with the oxygen at a suitable reaction temperature and a suitable reaction pressure to produce an oxidized product. The liquid reaction mixture can have an aromatic feedstock having an oxidizable substituent as the oxidizable reactant. The oxidized product can include an aromatic compound having at least one carboxylic acid. For example, the aromatic feedstock can include a benzene ring having at least one oxidizable alkyl substituent, furan hetero-ring having at least one oxidizable alkyl substituent, a naphthalene poly-ring having at least one oxidizable alkyl substituent, derivatives thereof, and mixtures thereof.
摘要翻译：氧化过程可以包括：将具有可氧化反应物，催化剂和溶剂的小液滴的液体反应混合物引入含有氧气和稀释气体的反应区; 并在合适的反应温度和合适的反应压力下用氧氧化反应物以产生氧化产物。液体反应混合物可具有具有可氧化取代基的芳族原料作为可氧化反应物。氧化产物可以包括具有至少一个羧酸的芳族化合物。例如，芳族原料可以包括具有至少一个可氧化烷基取代基的苯环，具有至少一个可氧化烷基取代基的呋喃异环，具有至少一个可氧化烷基取代基的萘多环，其衍生物及其混合物。

2. 发明申请

WO2007050678A3 PROCESS FOR SELECTIVE OXIDATION OF OLEFINS TO EPOXIDES 审中-公开
标题翻译：烯烃选择性氧化成环氧化物的方法
公开(公告)号：WO2007050678A3
公开(公告)日：2007-09-27
申请号：PCT/US2006041617
申请日：2006-10-25
申请人： UNIV KANSAS , BUSCH DARYLE H , SUBRAMANIAM BALA , LEE HYUN-JIN , SHI TIE-PAN
发明人： BUSCH DARYLE H , SUBRAMANIAM BALA , LEE HYUN-JIN , SHI TIE-PAN
IPC分类号： C07D303/00
CPC分类号： C07D301/12 , Y02P20/582
摘要： A process for the selective oxidation of olefins to epoxides comprising the step of contacting the olefin (propylene) with an oxidant (hydrogen peroxide) in the presence of a Lewis acid oxidation catalyst (MTO), organic base (pyridine or its N-oxide), in a solvent system comprising an organic water-miscible solvent (methanol); and adding a pressurizing gas (nitrogen) to increase the pressure, whereby olefin is further dissolved in organic solvent system to increase the selectivity and yield of the desired epoxide (propylene oxide).
摘要翻译：一种将烯烃选择性氧化成环氧化物的方法，包括在路易斯酸氧化催化剂（MTO），有机碱（吡啶或其N-氧化物）存在下使烯烃（丙烯）与氧化剂（过氧化氢）接触的步骤，，在包含有机水混溶性溶剂（甲醇）的溶剂体系中; 并加入加压气体（氮气）以增加压力，从而使烯烃进一步溶解在有机溶剂体系中以提高所需环氧化物（环氧丙烷）的选择性和产率。

3. 发明申请

WO2013033081A3 PROCESS FOR PRODUCING BOTH BIOBASED SUCCINIC ACID AND 2,5-FURANDICARBOXYLIC ACID 审中-公开
标题翻译：生产双酚化酸和2,5-呋喃糖基酸的方法
公开(公告)号：WO2013033081A3
公开(公告)日：2013-05-30
申请号：PCT/US2012052641
申请日：2012-08-28
申请人： UNIV KANSAS , ARCHER DANIELS MIDLAND CO , SUBRAMANIAM BALA , ZUO XIAOBIN , BUSCH DARYLE H , VENKITASUBRAMANIAM PADMESH
发明人： SUBRAMANIAM BALA , ZUO XIAOBIN , BUSCH DARYLE H , VENKITASUBRAMANIAM PADMESH
IPC分类号： C07C51/42 , C07C55/10 , C07D307/46
CPC分类号： C07D307/68 , C07C51/245 , C07D307/46 , C07C55/10
摘要： A process is provided for carrying out an oxidation on a feed including levulinic acid and/or a levulinic acid oxidation precursor to succinic acid, one or more furanic oxidation precursors of 2,5-furandicarboxylic acid and a catalytically effective combination of cobalt, manganese, and bromide components for catalyzing the oxidation of the levulinic acid component and of the one or more furanic oxidation precursors to produce both succinic acid and 2,5-furandicarboxylic acid products, which process comprises supplying the feed to a reactor vessel, supplying an oxidant, reacting the levulinic acid component and the one or more furanic oxidation precursors with the oxidant to produce both succinic acid and 2,5-furandicarboxylic acid (FDCA) and then recovering the succinic acid and FDCA products. A crude dehydration product from the dehydration of fructose, glucose or both, including 5-hydroxymethylfurfural, can be directly oxidized by the process to produce 2,5-furandicarboxylic acid and succinic acid.
摘要翻译：提供了一种方法，用于对包含乙酰丙酸和/或乙酰丙酸氧化前体的进料进行氧化，所述前体包含琥珀酸，一种或多种呋喃二恶烷的呋喃型氧化前体和钴，锰，以及用于催化乙酰丙酸组分和一种或多种呋喃氧化前体的氧化以产生琥珀酸和2,5-呋喃二羧酸产物的溴化物组分，该方法包括将进料供应到反应器容器中，供应氧化剂，使乙酰丙酸组分和一种或多种呋喃氧化前体与氧化剂反应以产生琥珀酸和2,5-呋喃二羧酸（FDCA），然后回收琥珀酸和FDCA产物。由脱水果糖，葡萄糖或两者（包括5-羟甲基糠醛）的粗脱水产物可直接氧化，生成2,5-呋喃二羧酸和琥珀酸。

4. 发明申请

WO2008070279A3 METHOD FOR PRECIPITATION OF SMALL MEDICAMENT PARTICLES INTO USE CONTAINERS 审中-公开
标题翻译：将小药物颗粒沉淀为用于容器的方法
公开(公告)号：WO2008070279A3
公开(公告)日：2008-11-06
申请号：PCT/US2007081092
申请日：2007-10-11
申请人： CRITITECH INC , RAJEWSKI ROGER A , SUBRAMANIAM BALA , NIU FENGHUI
发明人： RAJEWSKI ROGER A , SUBRAMANIAM BALA , NIU FENGHUI
IPC分类号： A61K9/14
CPC分类号： A61K9/1688 , B01J2/02 , B01J2/04 , B01J2/18
摘要： Commercially feasible methods for lyophobic precipitation of liquid-dispersed or dissolved material (e.g., medicaments) are provided wherein a plurality of individual, open containers (22) each containing a quantity (84) of a solution or dispersion are treated within a common pressurizable chamber (12). In this process, desired near-supercritical or supercritical temperature and pressure conditions are established for a selected antisolvent gas such as carbon dioxide, and an ultrasonic device (14) is actuated to generate high energy ultrasonic waves in the chamber (12). This leads to intense mixing of the antisolvent with the liquid solution or dispersion within the containers (22), with consequent solvent removal and material precipitation.
摘要翻译：提供了用于液体分散或溶解材料（例如药物）的疏液沉淀的商业上可行的方法，其中在共同的可加压室内处理多个各自含有一定量（84）溶液或分散体的单独开放容器（22）（12）。在该过程中，针对所选反溶剂气体如二氧化碳建立期望的近超临界或超临界温度和压力条件，并且启动超声装置（14）以在腔室（12）中产生高能超声波。这导致反溶剂与容器（22）内的液体溶液或分散体剧烈混合，随后除去溶剂和材料沉淀。

5. 发明申请

WO2006133354A3 METHODS FOR PRODUCING NANOPARTICULATE METAL COMPLEXES AND ALTERING NANOPARTICLE MORPHOLOGY 审中-公开
标题翻译：生产纳米材料金属络合物和改性纳米晶形态的方法
公开(公告)号：WO2006133354A3
公开(公告)日：2007-02-01
申请号：PCT/US2006022269
申请日：2006-06-08
申请人： UNIV KANSAS , SUBRAMANIAM BALA , BOROVIK ANDREW S , JOHNSON CHAD , SHARMA SARIKA
发明人： SUBRAMANIAM BALA , BOROVIK ANDREW S , JOHNSON CHAD , SHARMA SARIKA
IPC分类号： A61K9/14
CPC分类号： A61K49/00
摘要： Nanoparticulate metal complexes, such as those involving ruthenium, iron, cobalt, and nickel salens, are formed using precipitation with compressed antisolvent technology. The nanoparticle morphology may be altered by altering the planarity of molecular structure of the metal complex starting material.
摘要翻译：纳米微粒金属络合物，如涉及钌，铁，钴和镍盐的纳米微粒金属络合物，是用压缩反溶剂技术沉淀形成的。可以通过改变金属络合物原料的分子结构的平面性来改变纳米颗粒形态。

6. 发明申请

WO03018182A2 PRESSURE-TUNED SOLID CATALYZED HETEROGENEOUS CHEMICAL REACTIONS 审中-公开
标题翻译：压力调节固体催化异构化学反应
公开(公告)号：WO03018182A2
公开(公告)日：2003-03-06
申请号：PCT/US0227340
申请日：2002-08-26
申请人： UNIV KANSAS , SUBRAMANIAM BALA , LYON CHRISTOPHER JAMES
发明人： SUBRAMANIAM BALA , LYON CHRISTOPHER JAMES
IPC分类号： B01J3/00 , B01J8/02 , B01J31/10 , B01J31/40 , B01J35/10 , B01J38/00 , B01J38/04 , C07B61/00 , C07C2/58 , C07C2/62 , C07C9/15 , C07C9/16 , C07C9/18 , C07C9/21 , C07C11/02 , C10G29/20 , B01J
CPC分类号： B01J31/4007 , B01J3/008 , B01J8/0207 , B01J8/0278 , B01J31/10 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J38/00 , B01J2038/005 , B01J2208/00628 , B01J2219/00202 , B01J2219/00213 , B01J2219/00231 , B01J2231/323 , B01J2231/52 , B01J2231/641 , C07C2/58 , C07C2531/10 , C10G29/205 , Y02P20/544 , Y02P20/584 , Y10S585/952
摘要： Improved methods for conduction solid acid-catalyzed, near- or supercritical heterogeneous chemical reactions (e.g., alkylation reactions) are provided which give enhanced product yields and permit longer processing runs. The preferred reactions of the invention are carried out in the presence of a solid macroporous catalyst having a surface area of from about 50-400 m /g and a pore size of from about 70-150 ANGSTROM . Product selectivity is enhanced by pressure-tuning of the reaction to promote production and separation of desired reaction products. In continuous processing, the chemical reaction may be interrupted before significant catalyst deactivation, followed by increasing reactor pressure and/or reducing reactor temperature to remove the accumulating coke; when the catalyst is regenerated, the original reaction conditions and reactant introduction may be resumed.
摘要翻译：提供了用于传导固体酸催化，接近或超临界异质化学反应（例如烷基化反应）的改进方法，其提供增强的产物产率并允许更长的处理运行。本发明的优选反应在表面积为约50-400m 2 / g和孔径为约70-150安培的固体大孔催化剂存在下进行。产物选择性通过反应的压力调节来增强，以促进所需反应产物的产生和分离。在连续加工中，化学反应可能在显着的催化剂失活之前中断，随后增加反应器压力和/或降低反应器温度以除去积聚的焦炭; 当再生催化剂时，可以恢复原始的反应条件和反应物的引入。

7. 发明申请

WO2012121838A2 SINGLE SOLVENT GAS EXPANDED HYDROFORMYLATION PROCESS 审中-公开
标题翻译：单溶剂气体膨胀加氢甲酰化过程
公开(公告)号：WO2012121838A2
公开(公告)日：2012-09-13
申请号：PCT/US2012024941
申请日：2012-02-14
申请人： SUBRAMANIAM BALA , CHAUDHARI RAGHUNATH V , SARKAR BIBHAS , UNIV KANSAS
发明人： SUBRAMANIAM BALA , CHAUDHARI RAGHUNATH V , SARKAR BIBHAS
IPC分类号： C07C45/50 , B01J19/24 , B01J23/46 , C07C47/02
CPC分类号： C07C45/505 , B01J19/24 , B01J31/1683 , B01J31/2404 , B01J31/4046 , B01J31/4053 , B01J31/4061 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C47/02 , Y02P20/584 , C07C47/19
摘要： Allyl alcohol, particularly from biobased sources such as glycerol, is hydroformylated to products including 4-hydroxybutyraldehyde and 4-hydroxy-2-methylpropionaldehyde by forming a homogeneous reaction mixture including allyl alcohol, a rhodium-based hydroformylation catalyst and a near critical liquefiable petroleum gas or mixture of such gases, reacting the near critical liquefiable petroleum gas (or gas mixture)-expanded allyl alcohol substrate with carbon monoxide and with hydrogen in the presence of the catalyst, and recovering substantially all of the petroleum gas or gases overhead by reducing the pressure and degassing the product mixture. Dense propane is especially useful as a single inert solvent/diluent, and substantially no other solvent/diluent is needed.
摘要翻译：通过形成包括烯丙醇，铑基加氢甲酰化催化剂和近临界可液化石油气的均相反应混合物，将烯丙醇，特别是来自生物基源如甘油的烯丙醇加氢甲酰化成包括4-羟基丁醛和4-羟基-2-甲基丙醛的产物或这些气体的混合物，在催化剂存在下使近临界可液化石油气（或气体混合物）膨胀的烯丙醇基质与一氧化碳和氢反应，并通过还原基本上回收所有石油气或多种气体压力和产物混合物脱气。致密丙烷作为单一的惰性溶剂/稀释剂特别有用，并且基本不需要其他溶剂/稀释剂。

8. 发明申请

WO2010144448A3 POLYOL HYDROGENOLYSIS BY IN-SITU GENERATED HYDROGEN 审中-公开
标题翻译：多元醇氢原位生成氢
公开(公告)号：WO2010144448A3
公开(公告)日：2011-03-24
申请号：PCT/US2010037774
申请日：2010-06-08
申请人： UNIV KANSAS , CHAUDHARI RAGHUNATH V , ROY DEBDUT S , SUBRAMANIAM BALA
发明人： CHAUDHARI RAGHUNATH V , ROY DEBDUT S , SUBRAMANIAM BALA
IPC分类号： B01J23/46 , B01J23/656 , C07C29/128 , C07C31/00
CPC分类号： B01J23/462 , B01J21/04 , B01J21/18 , B01J23/6567 , B01J35/0006 , C07C29/60 , C07C31/205
摘要： A catalyst composition/system can include: a platinum catalyst metal (Pt) and/or rhenium catalyst metal (Re) on a first support; and a ruthenium catalyst metal (Ru) and /or rhenium catalyst metal (Re) on a second support or a platinum catalyst metal (Pt) and a ruthenium catalyst metal (Ru) and/or a rhenium catalyst metal (Re) on the same support. The Pt:Ru, Re:Pt and/or Re:Ru weight ratio can be between about 1 :4 and about 4: 1. The support can be alumina, carbon, silica, a zeolite, TiO2, ZrO2 or another suitable material. The first and second support can be on the same support structure or on different support structures. In one option, the first and second supports can be positioned such that the Pt and/or Re are capable of catalyzing a dehydrogenation and/or reforming reaction that produces hydrogen and the Ru and/or Re are capable of catalyzing a hydrogenolysis reaction.
摘要翻译：催化剂组合物/体系可以包括：在第一载体上的铂催化剂金属（Pt）和/或铼催化剂金属（Re）; 和在其上的第二载体或铂催化剂金属（Pt）和钌催化剂金属（Ru）和/或铼催化剂金属（Re）上的钌催化剂金属（Ru）和/或铼催化剂金属（Re）支持。 Pt：Ru，Re：Pt和/或Re：Ru重量比可以在约1:4至约4:1之间。载体可以是氧化铝，碳，二氧化硅，沸石，TiO 2，ZrO 2或其它合适的材料。第一和第二支撑件可以在相同的支撑结构上或在不同的支撑结构上。在一个选择中，第一和第二载体可以被定位成使得Pt和/或Re能够催化产生氢的脱氢和/或重整反应，并且Ru和/或Re能够催化氢解反应。

9. 发明申请

WO2014004768A2 ALKYLENE EPOXIDATION WITH MESOPOROUS CATALYSTS 审中-公开
标题翻译：用中孔催化剂进行烯烃环氧化
公开(公告)号：WO2014004768A2
公开(公告)日：2014-01-03
申请号：PCT/US2013048077
申请日：2013-06-27
申请人： UNIV KANSAS , SUBRAMANIAM BALA , RAMANATHAN ANAND , GHANTA MADHAV , YAN WENJUAN
发明人： SUBRAMANIAM BALA , RAMANATHAN ANAND , GHANTA MADHAV , YAN WENJUAN
IPC分类号： C07D301/12
CPC分类号： C07D301/19 , C07D301/12
摘要： A process for epoxidizing an olefin comprising contacting an olefin with an oxidant in the presence of an insoluble oxidation catalyst in a solvent system comprising an organic water-miscible solvent to form an alkylene oxide. The insoluble oxidation catalyst comprises a metal, preferably selected from the group consisting of tungsten, cerium, and niobium. The metal is directly incorporated within a solid mesoporous silicate support, such as one selected from the group consisting of KIT-5, KIT-6, and TUD-1.
摘要翻译：一种使烯烃环氧化的方法，包括在不溶性氧化催化剂存在下，在包含有机水混溶性溶剂的溶剂体系中，使烯烃与氧化剂接触以形成烯化氧。不溶性氧化催化剂包含金属，优选选自钨，铈和铌。金属直接掺入固体中孔硅酸盐载体中，例如选自KIT-5，KIT-6和TUD-1中的一种。

10. 发明申请

WO2010144558A3 NANO-METAL CATALYSTS FOR POLYOL HYDROGENOLYSIS 审中-公开
标题翻译：用于多元醇氢化的纳米金属催化剂
公开(公告)号：WO2010144558A3
公开(公告)日：2011-03-31
申请号：PCT/US2010037948
申请日：2010-06-09
申请人： UNIV KANSAS , SUBRAMANIAM BALA , ROY DEBDUT S , CHAUDHARI RAGHUNATH V
发明人： SUBRAMANIAM BALA , ROY DEBDUT S , CHAUDHARI RAGHUNATH V
IPC分类号： B01J23/46 , B01J29/12 , B01J37/02 , C07C29/128 , C07C29/157
CPC分类号： B01J35/006 , B01J23/462 , B01J29/126 , B01J29/166 , B01J31/1633 , B01J31/1805 , B01J2229/20 , B01J2231/641 , B01J2531/821 , C07C29/132 , C07C29/60 , Y02P20/52 , C07C31/26 , C07C31/205 , C07C31/202
摘要： A catalyst composition can include: a support; a ruthenium catalyst (Ru) nanoparticle; and a linker linking the Ru nanoparticle to the support, wherein the linker is stable under hydrogenolysis conditions. In one aspect, the linker can include 3-aminopropyl trimethoxysilane (APTS) or derivatives thereof, such as those with amine functionality. In another aspect, the linker can include phosphotungstic acid (PTA) or other similar solid acid agents. In another aspect, the support can be selected from alumina, carbon, silica, a zeolite, TiO2, ZrO2, or another suitable material. A specific example of a support includes zeolite, such as a NaY zeolite. The Ru nanoparticle can have a size range from about 1 nm to about 25 nm. and can be obtained by reduction of Ru salts.
摘要翻译：催化剂组合物可以包括：载体; 钌催化剂（Ru）纳米颗粒; 和将Ru纳米颗粒连接到载体的接头，其中接头在氢解条件下是稳定的。在一个方面，接头可以包括3-氨基丙基三甲氧基硅烷（APTS）或其衍生物，例如具有胺官能团的那些。另一方面，接头可以包括磷钨酸（PTA）或其它类似的固体酸剂。另一方面，载体可以选自氧化铝，碳，二氧化硅，沸石，TiO 2，ZrO 2或其它合适的材料。载体的具体实例包括沸石，例如NaY沸石。 Ru纳米颗粒可以具有约1nm至约25nm的尺寸范围。并且可以通过还原Ru盐来获得。

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