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1. 发明申请

WO2019038099A1 POLYLACTIDE BASED COMPOSITIONS 审中-公开
公开(公告)号：WO2019038099A1
公开(公告)日：2019-02-28
申请号：PCT/EP2018/071665
申请日：2018-08-09
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： COUPIN, Thierry
IPC分类号： C08L67/04 , C08G63/08 , C08F36/22
摘要： The present invention relates to composition comprising at least two polymers, wherein, (a) the first polymer is a block copolymer comprising at least one polyfarnesene block and at least one poly-L-lactide block; and, (b) the second polymer is selected from poly-D-lactide, or a block copolymer 5 comprising at least one polyfarnesene block and at least one poly-D-lactide block; or, (a) the first polymer is a block copolymer comprising at least one polyfarnesene block and at least one poly-D-lactide block; and, (b) the second polymer is selected from poly-L-lactide, or a block copolymer 10 comprising at least one polyfarnesene block and at least one poly-L-lactide block. The present invention relates to a process for preparing said composition, articles comprising said composition, the use of block copolymers as nucleating agent and stereo-complex forming agent.

2. 发明申请

WO2020169549A1 POLYOLEFIN COMPOSITIONS AND PROCESS TO PRODUCE SUCH COMPOSITIONS BY THE ADDITION OF COUPLING AGENTS 审中-公开
公开(公告)号：WO2020169549A1
公开(公告)日：2020-08-27
申请号：PCT/EP2020/054148
申请日：2020-02-18
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： COUPIN, Thierry
IPC分类号： C08L23/04
摘要： The disclosure relates to a process to produce a polyolefin composition comprising a blend of polyethylene and polypropylene and to said polyolefin compositions. The process comprises the steps of: - providing from 10 to 90 wt.% of a component A, being one or more polyethylenes; - providing from 10 to 90 wt.% of a component B, being one or more polypropylenes; - providing a component H, wherein component H is one or more grafted and/or modified polyolefins selected from acid-grafted polyolefins and/or anhydride-modified polyolefins; wherein the polyolefin is selected from polyethylene and/or polypropylene; - melt-blending the components to form an intermediate polyolefin composition; - providing a component C, wherein component C is one or more coupling agents selected from one or more diol functionalized polymers and/or one or more metallic salts; - melt-blending the intermediate polyolefin composition with component C to form a polyolefin composition.

3. 发明申请

WO2017191089A1 3D-PRINTED PLA ARTICLES 审中-公开
标题翻译： 3D打印PLA解决方案
公开(公告)号：WO2017191089A1
公开(公告)日：2017-11-09
申请号：PCT/EP2017/060333
申请日：2017-05-02
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： COUPIN, Thierry
IPC分类号： C08L67/04 , B33Y80/00 , B33Y70/00 , B33Y10/00 , B29C67/00
摘要： A 3D printed article comprising a 3D printable composition comprising from 92.0 to 99.5 % by weight of a poly-lactide based on the total weight of the 3D printable composition; and from 0.5 to 8.0 % by weight of a co- or ter-polymer based on the total weight of the 3D printable composition; said co- or ter-polymer comprising (i) 50.0 to 99.9 % by weight of ethylene monomer based on the total weight of the co- or ter-polymer composition; (ii) 0.1 to 50.0 % by weight of an unsaturated anhydride-, epoxide- or carboxylic acid- containing monomer based on the total weight of the co- or ter-polymer composition; and iii) 0 to 50.0 % by weight of a (meth)acrylic ester monomer based on the total weight of the co- or ter-polymer composition.
摘要翻译：包含基于3D可印刷组合物的总重量包含92.0-99.5重量％的聚丙交酯的3D可印刷组合物; 和基于所述3D可印刷组合物的总重量为0.5-8.0重量％的共聚物或三元共聚物; 所述共聚物或三元共聚物包含（i）基于所述共聚物或三元共聚物组合物的总重量，50.0至99.9重量％的乙烯单体; （ii）基于所述共聚物或三元共聚物组合物的总重量，0.1至50.0重量％的不饱和酸酐 - ，环氧化物或羧酸 - 单体; 和iii）基于所述共聚物或三元共聚物组合物的总重量计0至50.0重量％的（甲基）丙烯酸酯单体。

4. 发明申请

WO2019038098A1 POLYLACTIDE BASED COMPOSITIONS 审中-公开
公开(公告)号：WO2019038098A1
公开(公告)日：2019-02-28
申请号：PCT/EP2018/071661
申请日：2018-08-09
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： COUPIN, Thierry , HELOU, Marion , SLAWINSKI, Martine , HENNING, Steven
IPC分类号： C08F210/14 , C08F4/48 , C08G63/08
摘要： The present invention relates to a block copolymer, being the reaction product of: at least one functionalized polyfarnesene comprising a polymeric chain derived from farnesene and having at least one functional terminal end selected from the group comprising hydroxyl, amino, epoxy, isocyanato, and carboxylic acid; and at least one lactide; forming at least one polyfarnesene block and at least one polylactide block. The present invention also relates to a process for preparing said block copolymer, a polymer composition comprising said block copolymer, an article comprising said block copolymer, the use of said block copolymers as impact modifier and the use of said block copolymer as compatibilizer.

5. 发明申请

WO2015197610A1 COMPOSITION COMPRISING POLY-LACTIDE-BASED POLYMER 审中-公开
标题翻译：包含基于聚合物的聚合物的组合物
公开(公告)号：WO2015197610A1
公开(公告)日：2015-12-30
申请号：PCT/EP2015/064102
申请日：2015-06-23
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： COUPIN, Thierry
IPC分类号： C08K5/11 , C08K5/12
CPC分类号： C08K5/11 , C08J3/203 , C08J2367/04 , C08K5/12 , C08L67/04 , C08L75/06 , C08L53/00
摘要： The present invention relates to a composition comprising: (a) at least one poly-lactide comprising polymer selected from the group consisting of poly-lactide, poly-lactide-polybutadiene block copolymer, poly-lactide-urethane-polybutadiene block copolymer, poly-lactide-urethane, and mixture thereof; and (b) at least one compound of formula (I), wherein, L 1 is C 1-8 alkylene; C 3-6 cycloalkylene; each optionally substituted with one or more C 1-4 alkyl; L 2 is C 1-6 alkylene; L 3 is C 1-6 alkylene; L 4 is C 1-6 alkylene; L 5 is C 1-6 alkylene; n is an integer selected from 1, 2, 3 or 4; m is an integer selected from 1, 2, 3 or 4; R 1 is H; or C 1-6 alkyl; R 2 is H; or C 1-6 alkyl; wherein the poly-lactide in said poly-lactide comprising polymer is selected from poly-L-lactide comprising a content of D isomer of at least 10% by weight based on the total weight of the poly-L-lactide; poly-D-lactide comprising a content of L isomer of at least 10% by weight based on the total weight of the poly-D-lactide; poly-DL-lactide; poly(meso-lactide); and mixture thereof. The present invention also relates to a process for preparing said composition. The present invention also relates to the use of said composition in polymers, membranes, adhesives, foams, sealants, molded articles, films, extruded articles, fibers, elastomers, polymer based additives, pharmaceutical and biomedical products, varnishes, paints, coatings, inks, composite material, organic LEDs, organic semiconductors, conducting organic polymers, or 3D printed articles. The present invention also relates to an article comprising said composition and to a process for reshaping and/or repairing said article.
摘要翻译：本发明涉及一种组合物，其包含：（a）至少一种包含聚丙交酯的聚丙交酯，所述聚丙交酯包含聚丙交酯，聚丙交酯 - 聚丁二烯嵌段共聚物，聚丙交酯 - 聚氨酯 - 聚丁二烯嵌段共聚物，聚 - 丙交酯 - 氨基甲酸酯及其混合物; 和（b）至少一种式（I）化合物，其中L 1为C 1-8亚烷基; C3-6cycloalkylene; 各自任选被一个或多个C 1-4烷基取代; L2是C1-6亚烷基; L3是C1-6亚烷基; L4是C1-6亚烷基; L5是C1-6亚烷基; n是选自1,2,3或4的整数; m是选自1,2,3或4的整数; R1是H; 或C 1-6烷基; R2为H; 或C 1-6烷基; 其中所述聚丙交酯包含聚合物中的聚丙交酯选自包含基于聚-L-丙交酯总重量的至少10重量％的D异构体含量的聚-L-丙交酯; 包含基于聚-D-丙交酯的总重量的至少10重量％的L异构体含量的聚-D-丙交酯; 聚DL-丙交酯; 聚（内消旋丙交酯）; 及其混合物。本发明还涉及制备所述组合物的方法。本发明还涉及所述组合物在聚合物，膜，粘合剂，泡沫，密封剂，模塑制品，薄膜，挤出制品，纤维，弹性体，基于聚合物的添加剂，药物和生物医学产品，清漆，油漆，涂料，油墨中的用途复合材料，有机LED，有机半导体，导电有机聚合物或3D印刷品。本发明还涉及包含所述组合物的制品和用于整形和/或修复所述制品的方法。

6. 发明申请

WO2015165919A1 POLYLACTIDE BASED COMPOSITIONS 审中-公开
标题翻译：基于聚合物的组合物
公开(公告)号：WO2015165919A1
公开(公告)日：2015-11-05
申请号：PCT/EP2015/059244
申请日：2015-04-28
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： COUPIN, Thierry
IPC分类号： C08L53/00 , C08L67/04
CPC分类号： C08L67/04 , C08J3/005 , C08J2367/04 , C08J2453/00
摘要： The present invention relates to a composition comprising: (a) at least one first polymer selected from polylactide-polybutadiene (PLA-PB) block copolymer, polylactide-urethane-polybutadiene block copolymer, or a mixture thereof; and (b) at least one second polymer selected from polylactide, polylactide-urethane, or a mixture thereof; wherein the composition comprises from 20 % to 50 % by weight of said first polymer based on the total weight of the composition and from 50 % to 80 % by weight of said second polymer based on the total weight of the composition. The present invention also relates to a process for preparing said composition. The present invention also relates to an article comprising said composition.
摘要翻译：本发明涉及一种组合物，其包含：（a）至少一种选自聚丙交酯 - 聚丁二烯（PLA-PB）嵌段共聚物，聚丙交酯 - 聚氨酯 - 聚丁二烯嵌段共聚物或其混合物的第一聚合物; 和（b）至少一种选自聚丙交酯，聚丙交酯 - 氨基甲酸酯或其混合物的第二聚合物; 基于组合物的总重量，所述组合物占所述第一聚合物的20重量％至50重量％，基于组合物的总重量为50重量％至80重量％。本发明还涉及制备所述组合物的方法。本发明还涉及包含所述组合物的制品。

7. 发明申请

WO2020169552A1 POLYOLEFIN COMPOSITIONS AND PROCESS TO PRODUCE SUCH COMPOSITIONS BY THE ADDITION OF IONOMERS 审中-公开
公开(公告)号：WO2020169552A1
公开(公告)日：2020-08-27
申请号：PCT/EP2020/054151
申请日：2020-02-18
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： COUPIN, Thierry
IPC分类号： C08L23/04
摘要： The disclosure relates to a process to produce a polyolefin composition comprising a blend of polyethylene and polypropylene as component A and B, and a component C being one or more ionomers. The process comprises a step of melt-blending the components to form a polyolefin composition, wherein the content of component C ranges from 1 to 30 wt. % as based on the total weight of the polyolefin composition. The disclosure also relates to a polyolefin composition comprising the components A, B and C and to articles made from this composition.

8. 发明申请

WO2020169548A1 POLYOLEFIN COMPOSITIONS AND PROCESS TO PRODUCE SUCH COMPOSITIONS BY THE ADDITION OF COUPLING AGENTS 审中-公开
公开(公告)号：WO2020169548A1
公开(公告)日：2020-08-27
申请号：PCT/EP2020/054146
申请日：2020-02-18
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： COUPIN, Thierry
IPC分类号： C08L23/04
摘要： The disclosure relates to a process to produce a polyolefin composition comprising a blend of polyethylene and polypropylene and to said polyolefin compositions. The process comprises the steps of: - providing a component A, wherein component A is one or more polyethylenes; - providing a component B, wherein component B is one or more polypropylenes; - providing a component C, wherein component C is one or more epoxy functionalized polymers; - providing a component H, wherein component H is one or more grafted and/or modified polyolefins selected from acid-grafted polyolefins and/or anhydride- modified polyolefins; wherein the polyolefin is selected from polyethylene and/or polypropylene; and wherein component H has an MI2 of at least 50 g/10 min as determined according to ISO 1133:1997 and; - melt-blending the said components to form a polyolefin composition.

9. 发明申请

WO2015165918A1 POLYMER COMPOSITION COMPRISING POLY-LACTIDE-POLYBUTADIENE BASED BLOCK COPOLYMER 审中-公开
标题翻译：聚合物 - 聚丁二烯基嵌段共聚物的聚合物组合物
公开(公告)号：WO2015165918A1
公开(公告)日：2015-11-05
申请号：PCT/EP2015/059242
申请日：2015-04-28
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： COUPIN, Thierry
IPC分类号： C08L53/00 , C08L67/04
CPC分类号： C08L67/04 , C08G81/027 , C08J3/005 , C08J2367/04 , C08J2467/04 , C08L53/00 , C08L2205/02 , C08L2205/025
摘要： The present invention relates to a composition comprising: (a) at least one first polymer selected from the group consisting of poly-L-lactide- polybutadiene (PLLA-PB) block copolymer, poly-D-lactide-polybutadiene (PDLA-PB) block copolymer, poly-L-lactide-urethane-polybutadiene block copolymer, and poly-D-lactide- urethane-polybutadiene block copolymer; and (b) at least one second polymer selected from the group consisting of poly-L-lactide, poly- L-lactide-polybutadiene (PLLA-PB) block copolymer, poly-L-lactide-urethane- polybutadiene block copolymer, poly-L-lactide-urethane, poly-D-lactide, poly-D-lactide- polybutadiene (PDLA-PB) block copolymer, poly-D-lactide-urethane-polybutadiene block copolymer, poly-D-lactide-urethane, and mixture thereof, wherein when the at least one first polymer is poly-L-lactide-polybutadiene (PLLA-PB) block copolymer, or poly-L-lactide-urethane-polybutadiene block copolymer, then the at least one second polymer is selected from the group consisting of poly-D-lactide, or poly- D-lactide-polybutadiene (PDLA-PB) block copolymer, poly-D-lactide-urethane- polybutadiene block copolymer, poly-D-lactide-urethane, and mixture thereof, or wherein when the at least one first polymer is poly-D-lactide-polybutadiene block copolymer, or poly-D-lactide-urethane-polybutadiene block copolymer, then the at least one second polymer is selected from the group consisting of poly-L-lactide, or poly-L- lactide-polybutadiene block copolymer, poly-L-lactide-urethane-polybutadiene block copolymer, poly-L-lactide-urethane, and mixture thereof; wherein said composition comprises from 40 % to 99 % by weight of said second polymer based on the total weight of the composition. The present invention also relates to a process for preparing said composition. The present invention also relates to an article comprising said composition.
摘要翻译：本发明涉及一种组合物，其包含：（a）至少一种选自聚-L-丙交酯 - 聚丁二烯（PLLA-PB）嵌段共聚物，聚-D-丙交酯 - 聚丁二烯（PDLA-PB）嵌段共聚物，聚-L-丙交酯 - 聚氨酯 - 聚丁二烯嵌段共聚物和聚-D-丙交酯 - 聚氨酯 - 聚丁二烯嵌段共聚物; 和（b）至少一种选自聚-L-丙交酯，聚-L-丙交酯 - 聚丁二烯（PLLA-PB）嵌段共聚物，聚-L-丙交酯 - 聚氨酯 - 聚丁二烯嵌段共聚物，聚 - L-丙交酯 - 氨基甲酸酯，聚-D-丙交酯，聚-D-丙交酯 - 聚丁二烯（PDLA-PB）嵌段共聚物，聚-D-丙交酯 - 聚氨酯 - 聚丁二烯嵌段共聚物，聚-D-丙交酯 - 氨基甲酸酯及其混合物其中当所述至少一种第一聚合物是聚-L-丙交酯 - 聚丁二烯（PLLA-PB）嵌段共聚物或聚-L-丙交酯 - 聚氨酯 - 聚丁二烯嵌段共聚物时，所述至少一种第二聚合物选自由聚-D-丙交酯或聚-D-丙交酯 - 聚丁二烯（PDLA-PB）嵌段共聚物，聚-D-丙交酯 - 聚氨酯 - 聚丁二烯嵌段共聚物，聚-D-丙交酯 - 氨基甲酸酯及其混合物组成，或其中当至少一种第一聚合物是聚-D-丙交酯 - 聚丁二烯嵌段共聚物或聚-D-丙交酯 - 聚氨酯 - 聚丁二烯嵌段共聚物时，则至少一个聚合物选自聚-L-丙交酯或聚-L-丙交酯 - 聚丁二烯嵌段共聚物，聚-L-丙交酯 - 聚氨酯 - 聚丁二烯嵌段共聚物，聚-L-丙交酯 - 氨基甲酸酯及其混合物; 其中所述组合物包含基于组合物总重量的40-99重量％的所述第二聚合物。本发明还涉及制备所述组合物的方法。本发明还涉及包含所述组合物的制品。

10. 发明申请

WO2014202481A1 POLYMER COMPOSITION 审中-公开
标题翻译：聚合物组合物
公开(公告)号：WO2014202481A1
公开(公告)日：2014-12-24
申请号：PCT/EP2014/062411
申请日：2014-06-13
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： COUPIN, Thierry
IPC分类号： C08L3/02 , C08L67/02 , C08L67/04 , C08L9/00 , C08L25/10 , C08L53/00
CPC分类号： C08L67/04 , B29C41/003 , B29C41/04 , B29C45/0001 , B29C47/0004 , B29C47/0014 , B29C47/0021 , B29C47/0023 , B29C47/06 , B29K2009/00 , B29K2067/046 , B29L2007/002 , B29L2007/008 , B29L2009/00 , B29L2023/22 , C08L3/02 , C08L47/00 , C08L53/00 , C08L67/02 , C08L2205/03 , C08L2205/06 , C08L9/00 , C08L9/06
摘要： The present invention relates to a composition comprising: at least one first polymer, selected from the group comprising polylactic acid, starch, polybutylene succinate, poly(butylene adipate-co-terephthalate), and mixtures thereof; at least one second polymer selected from polybutadiene, high impact polystyrene, or mixtures thereof; and at least one block copolymer of polylactic acid and polybutadiene. The present invention also relates to a process for preparing said composition. The present invention also relates to an article comprising said composition.
摘要翻译：本发明涉及一种组合物，其包含：至少一种选自聚乳酸，淀粉，聚丁二酸丁二醇酯，聚（己二酸丁二醇酯 - 对苯二甲酸丁二醇酯）及其混合物的第一聚合物; 至少一种选自聚丁二烯，高抗冲聚苯乙烯或其混合物的第二种聚合物; 和聚乳酸和聚丁二烯的至少一种嵌段共聚物。本发明还涉及制备所述组合物的方法。本发明还涉及包含所述组合物的制品。

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