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1. 发明申请

WO2017125759A1 PROCESS FOR THE PREPARATION OF GLYCEROL CARBONATE 审中-公开
标题翻译：制备甘油碳酸酯的方法
公开(公告)号：WO2017125759A1
公开(公告)日：2017-07-27
申请号：PCT/GB2017/050151
申请日：2017-01-20
申请人： THE QUEEN'S UNIVERSITY OF BELFAST , COLEMAN, Fergal , TYRRELL, Sophie , ATKINS, Martin Philip , UGALDE, Albert Ferrer , SCARLATA, Ignazio , DELAVOUX, Yoan
发明人： COLEMAN, Fergal , TYRRELL, Sophie , ATKINS, Martin Philip , UGALDE, Albert Ferrer , SCARLATA, Ignazio , DELAVOUX, Yoan
IPC分类号： C07D317/36 , C07C68/06
CPC分类号： C07D317/36
摘要： This invention relates to aprocess for the preparation of glycerolcarbonate from the reaction of glycerol and a dialkylcarbonate, for example dimethyl carbonate, or a cyclic alkylene carbonate. More specifically, the invention relates to a process where the synthesis of glycerolcarbonate is conducted in the presence of a homogeneous transesterificationcatalyst and involves the partial reaction of a glycerol reactant stream and a dialkyl carbonateor cyclic alkylene carbonate reactant stream and an intermediate step of alcohol by-product separation before further reaction in order to improve glycerol conversion and glycerol carbonate selectivity and yield.
摘要翻译：本发明涉及由甘油与碳酸二烷基酯（例如碳酸二甲酯）或环状碳酸亚烷基酯反应制备甘油碳酸酯的方法。更具体地说，本发明涉及一种方法，其中在均相酯交换催化剂存在下进行甘油碳酸酯的合成，并且涉及甘油反应物流和碳酸二烷基酯或环状碳酸亚烷基酯反应物流的部分反应以及醇副产物的中间步骤，在进一步反应之前进行产物分离以提高甘油转化率和甘油碳酸酯选择性和产率。

2. 发明申请

WO2016005769A1 OLIGOMERISATION PROCESS 审中-公开
标题翻译：低估过程
公开(公告)号：WO2016005769A1
公开(公告)日：2016-01-14
申请号：PCT/GB2015/052007
申请日：2015-07-10
申请人： THE QUEEN'S UNIVERSITY OF BELFAST , COLEMAN, Fergal , COFFIE, Sesime , ATKINS, Martin Philip , HOGG, James , UGALDE, Albert Ferrer , SWADZBA-KWASNY, Malgorzata , FEDOR, Gabriela
发明人： COLEMAN, Fergal , COFFIE, Sesime , ATKINS, Martin Philip , HOGG, James , UGALDE, Albert Ferrer , SWADZBA-KWASNY, Malgorzata , FEDOR, Gabriela
IPC分类号： C07C2/32 , C07C11/02 , B01J31/02 , B01J31/14
CPC分类号： C07C2/30 , B01J31/0277 , B01J31/146 , B01J2231/20 , C07C2527/10 , C07C2527/11 , C07C2527/12 , C07C2527/125 , C07C2527/128 , C07C2527/133 , C07C2527/135 , C07C2527/18 , C07C2531/025 , C07C2531/14 , C10M107/02 , C07C11/02
摘要： Disclosed is an oligomerisation process for forming base oils for lubrication compositions, and in particular, a process for the selective oligomerisation of C 5 to C 20 alpha-olefins to produce polyalphaolefin oligomers, preferably with a molecular weight distribution that is suitable for use in lubricant base oils, in which the olefinic feedstock is contacted with an ionic liquid comprising (i) at least one borenium cation of the formula [BX 2 L] + , wherein L is a Lewis basic donor ligand and each X is independently selected from fluorine, chlorine and bromine; and (ii) at least one non-coordinating anion.
摘要翻译：公开了一种用于形成用于润滑组合物的基础油的低聚方法，特别是一种用于选择性低聚C5至C20α-烯烃以生产聚α-烯烃低聚物的方法，优选具有适用于润滑油基础油的分子量分布其中烯烃原料与离子液体接触，所述离子液体包含（i）至少一种式[BX2L] +的铌阳离子，其中L是路易斯碱供体配体，并且每个X独立地选自氟，氯和溴; 和（ii）至少一种非配位阴离子。

3. 发明申请

WO2015019108A1 GLYCIDOL PREPARATION 审中-公开
标题翻译：甘氨酸制剂
公开(公告)号：WO2015019108A1
公开(公告)日：2015-02-12
申请号：PCT/GB2014/052435
申请日：2014-08-08
申请人： THE QUEEN'S UNIVERSITY OF BELFAST , COLEMAN, Fergal , HOLBREY, John , SEDDON, Kenneth , ATKINS, Martin , DELAVOUX, Yoan , TOLAND, Jeni , YAN, Ting
发明人： COLEMAN, Fergal , HOLBREY, John , SEDDON, Kenneth , ATKINS, Martin , DELAVOUX, Yoan , TOLAND, Jeni , YAN, Ting
IPC分类号： C07D301/02
CPC分类号： C07D301/02
摘要： This invention relates to an improved one-pot synthetic process for the preparation of glycidol from the reaction of glycerol and dimethyl carbonate. More specifically, the invention relates to a one-pot synthetic process for the preparation of glycidol comprising the reaction of glycerol and dimethyl carbonate in the presence of an ionic liquid catalyst having the formula: [Cat+][X] wherein: [Cat] represents one or more cationic species, and [X] represents one or more anionic species; wherein the reaction is conducted at a temperature of from 100°C to 160°C and wherein the molar ratio of glycerol to dimethylcarbonate is from 1:4 to 1:10.
摘要翻译：本发明涉及从甘油和碳酸二甲酯的反应制备缩水甘油的改进的一锅合成方法。更具体地说，本发明涉及一种用于制备缩水甘油的一锅合成方法，其包括在具有下式的离子液体催化剂存在下，甘油和碳酸二甲酯的反应：[Cat +] [X]其中：[Cat]代表一种或多种阳离子物质，[X]表示一种或多种阴离子物质; 其中反应在100℃至160℃的温度下进行，其中甘油与碳酸二甲酯的摩尔比为1:4至1:10。

4. 发明申请

WO2015145182A1 PROCESS FOR PREPARING ALKANOLAMINES USEFUL IN REMOVAL OF ACID-GAS FROM A GASEOUS STREAM 审中-公开
标题翻译：制备用于从气体流中除去酸气的有用的烷醇胺的方法
公开(公告)号：WO2015145182A1
公开(公告)日：2015-10-01
申请号：PCT/GB2015/050952
申请日：2015-03-27
申请人： THE QUEEN'S UNIVERSITY OF BELFAST , ATKINS, Martin , COLEMAN, Fergal , DELAVOUX, Yoan
发明人： ATKINS, Martin , COLEMAN, Fergal , DELAVOUX, Yoan
IPC分类号： C07D301/02 , C07C213/02 , C07D303/14
CPC分类号： C07C213/02 , B01D53/1462 , B01D53/1493 , B01D2252/20489 , B01D2256/245 , B01D2257/304 , B01D2257/504 , B01D2258/0283 , B01D2258/05 , B01J31/0282 , C07C68/00 , C07C209/80 , C07C209/84 , C07C213/04 , C07C2523/00 , C07D207/06 , C07D301/02 , C07D301/32 , C07D303/14 , F23J15/02 , Y02C10/04 , Y02C10/06 , Y02E20/326 , Y02P20/152 , Y02P20/51 , C07C215/10
摘要： The invention relates to a process for preparing alkanolamines, useful in the removal of CO 2 and/or H 2 S from a CO 2 and/or H 2 S containing gaseous stream, wherein the preparation of the alkanolamines is conducted using specifically selected ionic liquids under specifically selected reaction conditions.
摘要翻译：本发明涉及一种制备可用于从含CO 2和/或含H 2 S的气流中除去CO 2和/或H 2 S的链烷醇胺的方法，其中使用特定选择的离子液体在特定选择的反应条件下进行烷醇胺的制备。

5. 发明申请

WO2014167332A1 OLIGOMERISATION PROCESS 审中-公开
标题翻译：低估过程
公开(公告)号：WO2014167332A1
公开(公告)日：2014-10-16
申请号：PCT/GB2014/051115
申请日：2014-04-09
申请人： THE QUEEN'S UNIVERSITY OF BELFAST , ATKINS, Martin Philip , SEDDON, Kenneth Richard , SWADZBA-KWASNY, Malgorzata , COLEMAN, Fergal
发明人： ATKINS, Martin Philip , SEDDON, Kenneth Richard , SWADZBA-KWASNY, Malgorzata , COLEMAN, Fergal
IPC分类号： B01J31/02 , B01J31/14 , C07C2/20
CPC分类号： C07C2/22 , B01J31/0249 , B01J31/143 , B01J2231/20 , B01J2531/31 , B01J2531/32 , C07C2527/125 , C07C2527/126 , C07C2527/16 , C07C2527/20 , C07C2527/24 , C07C2527/26 , C07C2531/14 , C10M105/04 , C10M2203/022 , C07C11/02
摘要： This invention relates to base oils for lubricating compositions. In particular, the present invention provides a process for the selective oligomerisation of C5 to C20 alpha-olefins to produce polyalphaolefin oligomers with a molecular weight distribution that is suitable for use in lubricant base oils.
摘要翻译：本发明涉及用于润滑组合物的基础油。特别地，本发明提供了一种选择性低聚C5至C20α-烯烃以产生具有适用于润滑油基础油的分子量分布的聚α-烯烃低聚物的方法。

6. 发明申请

WO2014167331A1 OLIGOMERISATION PROCESS 审中-公开
标题翻译：低估过程
公开(公告)号：WO2014167331A1
公开(公告)日：2014-10-16
申请号：PCT/GB2014/051114
申请日：2014-04-09
申请人： THE QUEEN'S UNIVERSITY OF BELFAST , ATKINS, Martin Philip , SEDDON, Kenneth Richard , SWADZBA-KWASNY, Malgorzata , COLEMAN, Fergal
发明人： ATKINS, Martin Philip , SEDDON, Kenneth Richard , SWADZBA-KWASNY, Malgorzata , COLEMAN, Fergal
IPC分类号： B01J31/02 , B01J31/14 , C07C2/20 , C10M107/10
CPC分类号： C08F110/14 , B01J31/0249 , B01J31/143 , B01J2231/20 , B01J2531/31 , B01J2531/32 , C07C2/32 , C07C2/36 , C07C2531/22 , C07C2531/24 , C10M107/10 , C10M2205/0285 , C10N2220/022 , C10N2220/023 , C10N2230/02 , C10N2270/00 , C07C11/02
摘要： This invention relates to base oils for lubricating compositions. In particular, the present invention provides a process for the selective oligomerisation of C 5 to C 20 alpha-olefins to produce polyalphaolefin oligomers with a molecular weight distribution that is suitable for use in lubricant base oils.
摘要翻译：本发明涉及润滑组合物的基础油。特别地，本发明提供了选择性低聚C5至C20α-烯烃以产生具有适用于润滑油基础油的分子量分布的聚α-烯烃低聚物的方法。

7. 发明申请

WO2015079262A1 REMOVAL OF FREE FATTY ACIDS FROM GLYCERIDE OILS 审中-公开
标题翻译：从甘油油中去除免费的脂肪酸
公开(公告)号：WO2015079262A1
公开(公告)日：2015-06-04
申请号：PCT/GB2014/053553
申请日：2014-11-28
申请人： THE QUEEN'S UNIVERSITY OF BELFAST , ATKINS, Martin , COLEMAN, Fergal , GOODRICH, Peter
发明人： ATKINS, Martin , COLEMAN, Fergal , GOODRICH, Peter
IPC分类号： C11B3/02 , C11B3/06
CPC分类号： C11B3/06 , A23D9/007 , A23L5/27 , A23V2002/00 , C11B3/02 , C11C3/003
摘要： The present invention relates to deacidification of glyceride oils. The present invention provides a process for removing free fatty acids from glyceride oil, preferably palm oil, containing free fatty acids, said process comprising the steps of: (i) contacting the glyceride oil containing free fatty acids with the basic ionic liquid; wherein the basic ionic liquid has a basic anion selected from hydroxide, alkoxide, alkylcarbonate, hydrogen carbonate, serinate, prolinate, histidinate, threoninate, valinate, asparaginate, taurinate and lysinate; and a cation selected from: [N(R a )(R b )(R c )(R d )] + , wherein: R a , R b , R c and R d are each independently selected from hydrogen, a C 1 to C 8 , straight chain or branched alkyl group or a C 3 to C 6 cycloalkyl group, wherein said alkyl or cycloalkyl groups are unsubstituted or may be substituted by one to three groups selected from: C 1 to C 4 alkoxy, C 2 to C 8 alkoxyalkoxy, C 3 to C 6 cycloalkyl, -OH, -SH, - CO 2 (C 1 to C 6 )alkyl, -OC(O)(C 1 to C 6 )alkyl, or any two of R a , R b , R c and R d combine to form an alkylene chain -(CH 2 ) q - wherein q is from 3 to 6; and (ii) obtaining a treated glyceride oil having a reduced content of free fatty acid compared to the glyceride oil feed of step (i).
摘要翻译：本发明涉及甘油酯油的脱酸。本发明提供了一种从含有游离脂肪酸的甘油酯油，优选棕榈油中除去游离脂肪酸的方法，所述方法包括以下步骤：（i）使含有游离脂肪酸的甘油酯油与碱性离子液体接触; 其中所述碱性离子液体具有选自氢氧化物，醇盐，烷基碳酸盐，碳酸氢盐，丝氨酸盐，脯氨酸盐，组氨酸盐，苏氨酸盐，缬氨酸盐，天冬酰胺酸盐，牛磺酸盐和赖氨酸盐的碱性阴离子; 和选自：[N（Ra）（Rb）（Rc）（Rd）] +的阳离子，其中：Ra，Rb，Rc和Rd各自独立地选自氢，C1至C8，直链或支链烷基或C 3至C 6环烷基，其中所述烷基或环烷基是未取代的或可被一至三个选自以下的基团取代：C 1至C 4烷氧基，C 2至C 8烷氧基烷氧基，C 3至C 6环烷基，-OH，-SH， CO 2（C 1至C 6）烷基，-OC（O）（C 1至C 6）烷基或R a，R b，R c和R d中的任何两个结合形成亚烷基链 - （CH 2）q-，其中q为3至6 ; 和（ii）与步骤（i）的甘油酯油进料相比，获得游离脂肪酸含量降低的经处理的甘油酯油。

8. 发明申请

WO2017168164A1 PROCESS FOR THE PREPARATION OF A LUBRICANT BASE STOCK COMPRISING THE SELECTIVE THERMAL DECOMPOSITION OF PLASTIC POLYOLEFIN POLYMER 审中-公开
标题翻译：包含塑性聚烯烃聚合物的选择性热分解的润滑油基料的制备方法
公开(公告)号：WO2017168164A1
公开(公告)日：2017-10-05
申请号：PCT/GB2017/050907
申请日：2017-03-30
申请人： TRIFOL RESOURCES LIMITED , ATKINS, Martin Philip , COLEMAN, Fergal
发明人： ATKINS, Martin Philip , COLEMAN, Fergal
IPC分类号： C10B53/07 , C10G1/10
摘要： The present invention relates to a process for the preparation of a lubricant base stock from the thermal decomposition of plastic polymer. The present invention provides a process for preparing a lubricant base stock from the thermal decomposition of plastic polyolefin polymer, the method comprising the steps of: i) introducing plastic polyolefin polymer into a thermal reaction zone of a vacuum pyrolysis reactor; ii) heating the plastic polyolefin polymer at sub-atmospheric pressure, wherein the temperature in the thermal reaction zone of the reactor is from 500 °C to 750 °C, to induce thermal decomposition of the plastic polyolefin polymer and to form a thermal decomposition product effluent which comprises a major portion by weight of a C 20 to C 60 wax fraction; iii) condensing a vapour component of the thermal decomposition product effluent from the vacuum pyrolysis reactor; and iv) subjecting the C 20 to C 60 wax fraction of the thermal decomposition product to catalytic hydroisomerization in a hydroisomerization reactor in the presence of hydrogen to form the lubricant base stock; wherein the plastic polyolefin polymer comprises polyethylene and polypropylene in a polyethylene to polypropylene weight ratio of from 60:40 to 90:10.
摘要翻译：本发明涉及由塑料聚合物的热分解制备润滑剂基料的方法。本发明提供了由塑料聚烯烃聚合物的热分解制备润滑剂基料的方法，该方法包括以下步骤：i）将塑性聚烯烃聚合物引入真空热解反应器的热反应区; ii）在亚大气压下加热塑料聚烯烃聚合物，其中反应器的热反应区中的温度为500℃至750℃，以引发塑料聚烯烃聚合物的热分解并形成热分解产物流出物，其包含主要重量份的C 20至C 60蜡馏分; iii）冷凝来自真空热解反应器的热分解产物流出物的蒸气组分; 和iv）在氢存在下在加氢异构化反应器中使C 20到C 60馏分的热分解产物进行催化加氢异构化以形成润滑剂基料; 其中所述塑料聚烯烃聚合物包含聚乙烯与聚丙烯的重量比为60:40至90:10的聚乙烯和聚丙烯。

9. 发明申请

WO2017168160A1 PROCESS FOR THE PREPARATION OF A C20 to C60 WAX FROM THE SELECTIVE THERMAL DECOMPOSITION OF PLASTIC POLYOLEFIN POLYMER 审中-公开
标题翻译：从塑性聚烯烃聚合物的选择性热分解制备C20至C60蜡的方法
公开(公告)号：WO2017168160A1
公开(公告)日：2017-10-05
申请号：PCT/GB2017/050900
申请日：2017-03-30
申请人： TRIFOL RESOURCES LIMITED , ATKINS, Martin Philip , COLEMAN, Fergal
发明人： ATKINS, Martin Philip , COLEMAN, Fergal
IPC分类号： C10B53/07 , C10G1/10
摘要： The present invention relates to a process for the preparation of a C 20 to C 60 wax from the thermal decomposition of plastic polymer. The present invention provides a vacuum pyrolysis process for preparing a C 20 to C 60 wax from the thermal decomposition of plastic polyolefin polymer, the method comprising the steps of: i) introducing plastic polyolefin polymer into a thermal reaction zone of a vacuum pyrolysis reactor; ii) heating the plastic polyolefin polymer at sub-atmospheric pressure, wherein the temperature in the thermal reaction zone of the reactor is from 500 °C to 750 °C, to induce thermal decomposition of the plastic polyolefin polymer and to form a thermal decomposition product effluent which comprises a major portion by weight of a C 20 to C 60 wax fraction; and iii) condensing a vapour component of the thermal decomposition product effluent from the vacuum pyrolysis reactor in a multistage condensation comprising a plurality of condensation stages connected in series.
摘要翻译：本发明涉及由塑料聚合物的热分解制备C20至C60蜡的方法。本发明涉及由塑料聚合物的热分解制备C20至C60蜡的方法。本发明提供了用于由塑料聚烯烃聚合物的热分解制备C20至C60蜡的真空热解方法，该方法包括以下步骤：i）引入塑料聚烯烃聚合物加入到真空热解反应器的热反应区中; ii）在亚大气压下加热塑料聚烯烃聚合物，其中反应器的热反应区中的温度为500℃至750℃，以引发塑料聚烯烃聚合物的热分解并形成热分解产物流出物，其包含主要重量份的C 20至C 60蜡馏分; 和iii）将来自真空热解反应器的热分解产物流出物的蒸汽组分在包含多个串联连接的冷凝级的多级冷凝中冷凝。

10. 发明申请

WO2017168165A1 PROCESS FOR THE PREPARATION OF A LUBRICANT BASE STOCK COMPRISING THE SELECTIVE THERMAL DECOMPOSITION OF PLASTIC POLYOLEFIN POLYMER 审中-公开
标题翻译：包含塑性聚烯烃聚合物的选择性热分解的润滑油基料的制备方法
公开(公告)号：WO2017168165A1
公开(公告)日：2017-10-05
申请号：PCT/GB2017/050908
申请日：2017-03-30
申请人： TRIFOL RESOURCES LIMITED , ATKINS, Martin Philip , COLEMAN, Fergal
发明人： ATKINS, Martin Philip , COLEMAN, Fergal
IPC分类号： C10B53/07 , C10G1/10
摘要： The present invention relates to a process for the preparation of a lubricant base stock from the thermal decomposition of plastic polymer. The present invention provides a process for preparing a lubricant base stock from the thermal decomposition of plastic polyolefin polymer, the method comprising the steps of: i) introducing plastic polyolefin polymer into a thermal reaction zone of a vacuum pyrolysis reactor; ii) heating the plastic polyolefin polymer at sub-atmospheric pressure, wherein the temperature in the thermal reaction zone of the reactor is from 500 °C to 750 °C, to induce thermal decomposition of the plastic polyolefin polymer and to form a thermal decomposition product effluent which comprises a major portion by weight of a C 20 to C 60 wax fraction; iii) condensing a vapour component of the thermal decomposition product effluent from the vacuum pyrolysis reactor in a multistage condensation comprising a plurality of condensation stages connected in series; and iv) subjecting the C 20 to C 60 wax fraction of the thermal decomposition product to catalytic hydroisomerization in a hydroisomerization reactor in the presence of hydrogen to form the lubricant base stock.
摘要翻译：本发明涉及由塑料聚合物的热分解制备润滑剂基料的方法。本发明提供了由塑料聚烯烃聚合物的热分解制备润滑剂基料的方法，该方法包括以下步骤：i）将塑性聚烯烃聚合物引入真空热解反应器的热反应区; ii）在亚大气压下加热塑料聚烯烃聚合物，其中反应器的热反应区中的温度为500℃至750℃，以引发塑料聚烯烃聚合物的热分解并形成热分解产物流出物，其包含主要重量份的C 20至C 60蜡馏分; iii）将来自真空热解反应器的热分解产物流出物的蒸气组分冷凝成包含串联连接的多个冷凝级的多级冷凝; 和iv）在氢存在下在加氢异构化反应器中使C 20到C 60馏分的热分解产物进行催化加氢异构化以形成润滑剂基料。

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