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    • 4. 发明申请
    • 2-ARYL-5-HETEROCYCLYL-CYCLOHEXANE-1,3-DIONE COMPOUNDS AND THEIR USE AS HERBICIDES
    • 2-芳基-5-杂环基环己烷-1,3-二酮化合物及其作为除草剂的用途
    • WO2008110307A1
    • 2008-09-18
    • PCT/EP2008/001840
    • 2008-03-07
    • SYNGENTA PARTICIPATIONS AGMATHEWS, Christopher, JohnFINNEY, JohnROBINSON, LouisaTYTE, MelloneyMUEHLEBACH, MichelWENGER, Jean
    • MATHEWS, Christopher, JohnFINNEY, JohnROBINSON, LouisaTYTE, MelloneyMUEHLEBACH, MichelWENGER, Jean
    • C07D309/06A01N43/16C07D305/06C07D307/12C07D309/22C07D313/04C07D333/16C07D333/48C07D335/02C07D405/10C07D409/10A01N43/08A01N43/10A01N43/18A01N43/22
    • C07D309/06C07D305/06C07D307/12C07D309/22C07D313/04C07D333/16C07D333/48C07D335/02C07D405/10C07D409/10
    • Cyclohexanedione compounds of Formula (I) wherein R 1 is methyl, ethyl, n -propyl, iso -propyl, cyclopropyl, halomethyl, haloethyl, halogen, vinyl, ethynyl, methoxy, ethoxy, halomethoxy or haloethoxy, R 2 and R 3 are, independently hydrogen, halogen, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 3 -C 6 alkenyloxy, C 3 -C 6 haloalkenyloxy, C 3 -C 6 alkynyloxy, C 3 -C 6 cycloalkyl, C 1 -C 6 alkylthio, C 1 -C 6 alkylsulfinyl, C 1 -C 6 alkylsulfonyl, C 1 -C 6 alkylsulfonyloxy, C 1 -C 6 haloalkylsulfonyloxy, cyano, nitro, phenyl, phenyl substituted by C 1 -C 4 alkyl, C 1 -C 3 Cahaloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, cyano, nitro, halogen, C 1 -C 3 alkylthio, C 1 -C 3 alkylsulfιnyl or C 1 -C 3 alkylsulfonyl, or heteroaryl or heteroaryl substituted by C 1 -C 3 Calkyl, d.Cahaloalkyl, C 1 -C 3 aIkoxy, C 1 -C 3 haloalkoxy, cyano, nitro, halogen, C 1 -C 3 alkylthio, C 1 -C 3 alkylsulfinyl or C 1 -C 3 alkylsulfonyl, R 4 is hydrogen, methyl, ethyl, n -propyl, iso -propyl, halomethyl, haloethyl, halogen, vinyl, ethynyl, methoxy, ethoxy, halomethoxy or haloethoxy, X is O, S, S(O) or S(O) 2 , R 5 is hydrogen or methyl, R 6 is hydrogen, methyl or ethyl, or forms a double bond, which links the carbon atom, to which R 6 is attached, with the adjacent carbon atom of R 7 or R 8 , R 7 and R 8 are independently of each other C 1 -C 5 alkylene, which is unsubstituted or substituted by methyl or ethyl, or C 2 -C 5 alkenylene, which is unsubstituted or substituted by methyl or ethyl, and G is hydrogen, an alkali metal, alkaline earth metal, sulfoniυm, ammonium or a latentiating group, are suitable for use as herbicides.
    • 乙基,正丙基,异丙基,环丙基,卤代甲基,卤代乙基,卤素,乙烯基,乙炔基,甲氧基,乙氧基,卤代甲氧基或卤代乙氧基的环己二酮化合物,其中R 1是甲基, R 2和R 3独立地是氢,卤素,C 1 -C 6烷基,C 3 C 1 -C 6卤代烷基,C 1 -C 6烷氧基,C 1 -C 6烷基,C 1 -C 6烷基,C 1 -C 6烷基,C 1 -C 6 - C 6 -C 6卤代烷氧基,C 2 -C 6亚烯基,C 2 -C 6亚烷基,C 2 -C 6亚烷基, 卤代链烯基,C 2 -C 6炔基,C 3 -C 6链烯氧基,C 3 - C 3 -C 6卤代链烯氧基,C 3 -C 6炔氧基,C 3 -C 3 - C 6烷基亚磺酰基,C 1 -C 6烷基亚磺酰基,C 1 -C 6烷基亚磺酰基,C 1 -C 6烷基亚磺酰基,C 1 -C 6烷基亚磺酰基,C 1 -C 6烷基亚磺酰基,C C 1 -C 6烷基磺酰基,C 1 -C 6烷基磺酰氧基,C 1 -C 6烷基磺酰基,C 1 -C 6烷基磺酰基,C 1 -C 6烷基磺酰基, -C 6卤代烷基磺酰氧基,氰基,硝基,苯基,被C 1 -C 4烷基取代的苯基,C 1〜 卤代烷基,C 1 -C 3烷氧基,C 1 -C 3烷基,C 1 -C 3烷氧基,C 1 -C 3烷氧基,C 1 -C 3烷氧基,C 1 -C 3烷氧基, 卤代烷氧基,氰基,硝基,卤素,C 1 -C 3烷硫基,C 1 -C 3烷基, 或C 1 -C 3烷基磺酰基,或被C 1 -C 3烷基取代的杂芳基或杂芳基, C 1 -C 4烷基,C 1 -C 5烷氧基,C 1 -C 3烷氧基,C 1 -C 3烷氧基,C 1 -C 3烷氧基, 氰基,硝基,卤素,C 1 -C 3烷硫基,C 1 -C 3烷基亚磺酰基或C 1 -C 3烷基亚磺酰基, C 1 -C 3烷基磺酰基,R 4是氢,甲基,乙基,正丙基,异丙基,卤代甲基,卤代乙基,卤素,乙烯基 ,乙炔基,甲氧基,乙氧基,卤代甲氧基或卤代乙氧基,X是O,S,S(O)或S(O)2,R 5是氢或甲基,R 6是氢,甲基或乙基,或形成连接R 6连接的碳原子与R SUP的相邻碳原子的双键。 > 7 或R 8,R 7 R 8和R 8彼此独立地是未取代的或被甲基或乙基取代的C 1 -C 5亚烷基, 或C 2 -C 5亚烷基,其未被取代或被甲基或乙基取代,G为氢,碱金属,碱土金属,磺酰胺,铵 或潜伏组,适用于除草剂。
    • 7. 发明申请
    • PHENOXYPROPENYLPHENYL DERIVATIVES AND THEIR USE AS HERBICIDES
    • 苯氧基苯酚衍生物及其作为除草剂的用途
    • WO2004002947A1
    • 2004-01-08
    • PCT/EP2003/006945
    • 2003-06-30
    • SYNGENTA PARTICIPATIONS AGNEBEL, KurtSCHAETZER, JürgenSTOLLER, AndréHALL, Roger, GrahamWENGER, JeanBONDY, Steven, ScottCOMER, Daniel, DennisPENZOTTI, Julie, ElizabethGROOTENHUIS, Peter, Diederik, Jan
    • NEBEL, KurtSCHAETZER, JürgenSTOLLER, AndréHALL, Roger, GrahamWENGER, JeanBONDY, Steven, ScottCOMER, Daniel, DennisPENZOTTI, Julie, ElizabethGROOTENHUIS, Peter, Diederik, Jan
    • C07C255/37
    • C07C255/54A01N37/38C07C39/19C07C39/24C07C39/27C07C43/23C07C47/575C07C59/68C07C59/74C07C65/28C07C67/31C07C69/92C07C205/34C07C205/38C07C205/56C07C217/76C07C217/84C07C225/10C07C233/25C07C235/46C07C251/48C07C255/37
    • Compounds of formula (I), wherein R 01 is hydrogen, C 1 -C 8 alkyl, C 3 -C 8 alkenyl or C 3 -C 8 alkynyl; or R 01 is phenyl or phenyl-C 1 -C 6 alkyl, it being possible for the phenyl rings in turn to be mono- to penta-substituted by halogen and/or mono-, di- or tri-substituted by C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy, -CN, -NO 2 , C 1 -C 8 alkylthio, C 1 -C 8 alkylsulfinyl or C 1 -C 8 alkylsulfonyl; or R 01 is C 1 -C 8 alkyl mono- to penta-substituted by halogen or mono-, di- or tri-substituted by -CN, C 1 -C 6 alkylamino, di(C 1 -C 6 alkyl)amino or C 1 -C 4 alkoxy; n is 0, 1, 2, 3 or 4; each R 1 independently is halogen, -CN, -SCN, -SF 5 , -NO 2 , -NH 2 , -C0 2 R 7 , -CONR 8 R 9 , -C(S)NH 2 , -C(R 10 )=NOR 11 , -COR 12 , -OR 13 , -SR 14 , -SOR 15 , -SO 2 R 16 , -OSO 2 R 17 , C 1 -C 8 alkyl, C 2 -C 8 alkenyl, C 2 -C 8 alkynyl or C 3 -C 6 cycloalkyl; or C 1 -C 8 alkyl, C 2 -C 8 alkenyl or C 2 -C 8 alkynyl mono- to penta-substituted by halogen and/or mono-, di- or tri-substituted by -CN, -NO 2 , -NR 18 R 19 , -CO 2 R 20 , -CONR 21 R 22 , -COR 23 , -C(R 24 )=NOR 25 , -C(S)NR 26 R 27 , -C(C 1 -C 4 alkylthio)=NR 28 , -OR 29 , -SR 30 , -SOR 31 , -SO 2 R 32 or C 3 -C 6 cycloalkyl; and/or each R 1 independently is C 3 -C 6 cycloalkyl mono- to penta-substituted by halogen and/or mono-, di- or tri-substituted by -CN, -NO 2 , -NR 18 R 19 , -CO 2 R 20 , -CONR 21 R 22 , -COR 23 , -C(R 24 )=NOR 25 , -C(S)NR 26 R 27 , -C(C 1 -C 4 alkylthio)=NR 28 , -SR 30 , -SOR 31 , -SO 2 R 32 or C 3 C 6 cycloalkyl; and/or each R 1 independently is phenyl, which in turn can be mono- to penta-substituted by halogen and/or mono-, di- or tri-substituted by C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy, -CN, -NO 2 , C 1 -C 4 alkylthio, C 1 -C 4 alkylsulfinyl or C 1 -C 4 alkylsulfonyl; and/or two adjacent R 1 together form a C 1 -C 7 alkylene bridge, which can be interrupted by from 1 to 3 hetero atoms selected from oxygen, nitrogen and sulfur and which can be mono- to penta-substituted by halogen and/or mono-, di- or tri-substituted by C 1 -C 6 alkyl or C 1 -C 6 alkoxy, the total number of ring atoms being at least 5 and at most 9; and/or two adjacent R 1 together form a C 2 -C 7 alkenylene bridge, which can be interrupted by from 1 to 3 hetero atoms selected from oxygen, nitrogen and sulfur and which can be mono- to penta-substituted by halogen and/or mono-, di- or tri-substituted by C 1 -C 6 alkyl or C 1 -C 6 alkoxy, the total number of ring atoms being at least 5 and at most 9; R 3 and R 4 are each independently of the other hydrogen, halogen, -CN, C 1 -C 4 alkyl or C 1 -C 4 alkoxy; or R 3 and R 4 together are C 2 -C 5 alkylene; m is 1, 2, 3, 4 or 5; and R 2 , R 7 to R 32 , X 1 and X 2 are as defined in claim 1, and the agrochemically acceptable salts, N-oxides and a
    • 式(I)的化合物,其中R01是氢,C1-C8烷基,C3-C8链烯基或C3-C8炔基; 或R 01是苯基或苯基-C 1 -C 6烷基,苯环可以被卤素单取代和五取代,和/或被C1-C4烷基,C1-C4卤代烷基, ,C 1 -C 4烷氧基,-CN,-NO 2,C 1 -C 8烷硫基,C 1 -C 8烷基亚磺酰基或C 1 -C 8烷基磺酰基; 或R01为被卤素单取代或五取代或被-CN,C 1 -C 6烷基氨基,二(C 1 -C 6烷基)氨基或C 1 -C 4烷氧基单 - ,二 - 或三 - 取代的C 1 -C 8烷基; n为0,1,2,3或4; 每个R 1独立地是卤素,-CN,-SSCN,-SF 5,-NO 2,-NH 2,-CO 2 R 7,-CONR 8 R 9,-C(S)NH 2,-C(R 10)= NOR 11,-COR 12,-OR 13,-SR 14 ,-SOR 15,-SO 2 R 16,-OSO 2 R 17,C 1 -C 8烷基,C 2 -C 8烯基,C 2 -C 8炔基或C 3 -C 6环烷基; 或C 1 -C 8烷基,C 2 -C 8链烯基或被卤素单取代至五取代的C 2 -C 8炔基和/或被-CN,-NO 2,-NR 18 R 19,-CO 2 R 20,-CONR 21 R 22,-COR 23单 - ,二 - 或三 - 取代 ,-C(R 24)= NOR 25,-C(S)NR 26 R 27,-C(C 1 -C 4烷硫基)= NR 28,-OR 29,-SR 30,-SOR 31,-SO 2 R 32或C 3 -C 6环烷基; 和/或每个R 1独立地是被卤素单取代和/或被 - 或 - 被-CN,-NO 2,-NR 18 R 19,-CO 2 R 20,-CONR 21 R 22,-COR 23 - 取代的C 3 -C 6环烷基, C(R 24)= NOR 25,-C(S)NR 26 R 27,-C(C 1 -C 4烷硫基)= NR 28,-SR 30,-SOR 31,-SO 2 R 32或C 3 C 6环烷基; 和/或每个R 1独立地是苯基,其又可以被卤素单取代和五取代,和/或被C1-C4烷基,C1-C4卤代烷基,C1-C4烷氧基,-CN, -NO 2,C 1 -C 4烷硫基,C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基; 和/或两个相邻的R 1一起形成C 1 -C 7亚烷基桥,其可以被1至3个选自氧,氮和硫的杂原子中断,并且可以被卤素和/或单 - 被C1-C6烷基或C1-C6烷氧基二取代或三取代,环原子总数至少为5,最多为9; 和/或两个相邻的R1一起形成C 2 -C 7亚烯基桥,其可以被1至3个选自氧化的杂原子