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1. 发明申请

WO2005105718A3 PROCESS FOR THE PRODUCTION OF CYCLIC DIKETONES 审中-公开
标题翻译：生产循环二氧化碳的方法
公开(公告)号：WO2005105718A3
公开(公告)日：2006-05-04
申请号：PCT/EP2005004680
申请日：2005-04-29
申请人： SYNGENTA PARTICIPATIONS AG , SYNGENTA LTD , JACKSON DAVID ANTHONY , EDMUNDS ANDREW , BOWDEN MARTIN CHARLES , BROCKBANK BEN
发明人： JACKSON DAVID ANTHONY , EDMUNDS ANDREW , BOWDEN MARTIN CHARLES , BROCKBANK BEN
IPC分类号： C07C17/10 , C07C17/23 , C07C23/32 , C07C45/45 , C07C45/71 , C07C67/11 , C07C315/04 , C07C317/44 , C07D213/50 , C07D213/80 , C07C49/403 , C07C49/603 , C07C49/733
CPC分类号： C07D213/80 , C07C17/10 , C07C17/23 , C07C23/32 , C07C67/11 , C07C315/04 , C07D213/50 , C07C69/78 , C07C69/76 , C07C317/44
摘要： The present invention relates to a process for the preparation of compounds of formula (I), wherein the substituents are as defined in claim 1, by reacting a compound of formula (II), with a bromine or chlorine source to form a compound of formula (III), wherein X is chlorine or bromine; reacting that compound with water to form the compound of formula (IV), converting that compound, using a compound of formula (V), wherein M + is the hydrogen cation or an alkali metal ion, alkaline earth metal ion or ammonium ion, into the compound of formula (VI), and treating that compound with a cyanide source in the presence of a base.
摘要翻译：本发明涉及制备式（I）化合物的方法，其中取代基如权利要求1所定义，通过使式（II）化合物与溴或氯源反应形成式（III），其中X为氯或溴; 使该化合物与水反应以形成式（IV）化合物，使用其中M +为氢阳离子或碱金属离子，碱土金属的式（Ⅴ）化合物转化该化合物金属离子或铵离子转化成式（VI）的化合物，并在碱的存在下用氰化物源处理该化合物。

2. 发明申请

WO2009000442A8 PROCESSES FOR THE PREPARATION OF PYRAZOLES 审中-公开
标题翻译：制备吡唑的方法
公开(公告)号：WO2009000442A8
公开(公告)日：2010-01-21
申请号：PCT/EP2008004830
申请日：2008-06-16
申请人： SYNGENTA PARTICIPATIONS AG , SYNGENTA LTD , BOWDEN MARTIN CHARLES , GOTT BRIAN DAVID , JACKSON DAVID ANTHONY
发明人： BOWDEN MARTIN CHARLES , GOTT BRIAN DAVID , JACKSON DAVID ANTHONY
IPC分类号： C07D231/12 , C07D231/14 , C07D231/16
CPC分类号： C07C251/76 , C07D231/12 , C07D231/14
摘要： The present invention relates to novel processes for the production of compounds of formula (I) wherein Hal and Hal' are independently Cl or F, and R1 is H, Cl or F.
摘要翻译：本发明涉及制备式（I）化合物的新方法，其中Hal和Hal'独立地为Cl或F，且R 1为H，Cl或F.

3. 发明申请

WO2009000441A8 PROCESSES FOR THE PREPARATION OF PYRAZOLES 审中-公开
标题翻译：制备吡唑的方法
公开(公告)号：WO2009000441A8
公开(公告)日：2010-01-14
申请号：PCT/EP2008004829
申请日：2008-06-16
申请人： SYNGENTA PARTICIPATIONS AG , SYNGENTA LTD , BOWDEN MARTIN CHARLES , GOTT BRIAN DAVID , JACKSON DAVID ANTHONY , GUTSU IACOB EREMIA
发明人： BOWDEN MARTIN CHARLES , GOTT BRIAN DAVID , JACKSON DAVID ANTHONY , GUTSU IACOB EREMIA
IPC分类号： C07C251/76 , C07D231/12 , C07D231/14
CPC分类号： C07C251/76 , C07D231/12 , C07D231/14
摘要： The present invention relates to novel processes for the production of compounds of formula (I) wherein Hal and Hal' are independently selected from Cl and F, and R1 is selected from Cl, F and H.
摘要翻译：本发明涉及制备式（I）化合物的新方法，其中Hal和Hal'独立地选自Cl和F，R 1选自Cl，F和H.

4. 发明申请

WO2009138373A3 PROCESSES FOR THE PREPARATION OF ESTERS 审中-公开
标题翻译： ESTERS的制备方法
公开(公告)号：WO2009138373A3
公开(公告)日：2010-02-25
申请号：PCT/EP2009055649
申请日：2009-05-11
申请人： SYNGENTA LTD , SYNGENTA PARTICIPATIONS AG , BOWDEN MARTIN CHARLES , JACKSON DAVID ANTHONY , SAINT-DIZIER ALEXANDRE CHRISTI
发明人： BOWDEN MARTIN CHARLES , JACKSON DAVID ANTHONY , SAINT-DIZIER ALEXANDRE CHRISTIAN
IPC分类号： C07C67/08 , C07C69/747
CPC分类号： C07C253/30 , C07C67/08 , C07C2601/02 , C07C69/743 , C07C255/37
摘要： The invention relates to a process for the preparation of synthetic pyrethroid insecticides. The process involves coupling of carboxylic acid (IV) with an alcohol (V) in the presence of a catalyst wherein R1, R2, R3 and Ar are defined in the specification.
摘要翻译：本发明涉及制备合成拟除虫菊酯类杀虫剂的方法。该方法包括在催化剂的存在下羧酸（IV）与醇（V）的偶联，其中R1，R2，R3和Ar在说明书中定义。

5. 发明申请

WO2009000442A3 PROCESSES FOR THE PREPARATION OF PYRAZOLES 审中-公开
标题翻译：制备吡唑的方法
公开(公告)号：WO2009000442A3
公开(公告)日：2009-07-23
申请号：PCT/EP2008004830
申请日：2008-06-16
申请人： SYNGENTA PARTICIPATIONS AG , SYNGENTA LTD , BOWDEN MARTIN CHARLES , GOTT BRIAN DAVID , JACKSON DAVID ANTHONY
发明人： BOWDEN MARTIN CHARLES , GOTT BRIAN DAVID , JACKSON DAVID ANTHONY
IPC分类号： C07D231/12 , C07D231/14 , C07D231/16
CPC分类号： C07C251/76 , C07D231/12 , C07D231/14
摘要： The present invention relates to novel processes for the production of compounds of formula (I) wherein Hal and Hal' are independently Cl or F, and R1 is H, Cl or F.
摘要翻译：本发明涉及制备式（I）化合物的新方法，其中Hal和Hal'独立地为Cl或F，且R 1为H，Cl或F.

6. 发明申请

WO2007020381A3 PROCESS FOR THE SYNTHESIS OF MANDIPROPAMID AND DERIVATIVES THEREOF 审中-公开
标题翻译：合成麦芽苦苷及其衍生物的方法
公开(公告)号：WO2007020381A3
公开(公告)日：2007-05-03
申请号：PCT/GB2006002946
申请日：2006-08-08
申请人： SYNGENTA PARTICIPATIONS AG , BOWDEN MARTIN CHARLES , CLARK THOMAS AITCHESON , GIORDANO FANNY DELPHINE BRIGTT , JAU BEAT , SCHNEIDER HANS-DIETER , SEIFERT GOTTFRIED , WISS JUERG , ZELLER MARTIN , FABER DOMINIK
发明人： BOWDEN MARTIN CHARLES , CLARK THOMAS AITCHESON , GIORDANO FANNY DELPHINE BRIGTT , JAU BEAT , SCHNEIDER HANS-DIETER , SEIFERT GOTTFRIED , WISS JUERG , ZELLER MARTIN , FABER DOMINIK
IPC分类号： C07C231/02 , C07C33/46 , C07C43/174 , C07C43/313 , C07C59/70 , C07C69/734 , C07C213/02 , C07C231/12 , C07C235/34 , C07C251/16 , C07C255/37 , C07C315/04 , C07C317/46 , C07C319/20 , C07C323/62
CPC分类号： C07C231/12 , C07C33/46 , C07C59/70 , C07C69/734 , C07C213/02 , C07C235/34 , C07C251/16 , C07C255/37 , C07C315/04 , C07C319/20 , C07C317/46 , C07C323/62
摘要： A process for the preparation of a compound of formula (I) wherein: R is an alkynyl group; R 1 is alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkyl-alkyl, phenyl and phenylalkyl, it being possible in turn for all of the receding groups to carry one or more identical or different halogen atoms; alkoxy; alkenyloxy; alkynyloxy; alkoxyalkyl; haloalkoxy; alkylthio; haloalkylthio; alkysulfonyl; formyl; alkanoyl; hydroxy; halogen; cyano; nitro; amino; alkylamino; dialkylamino; carboxyl; alkoxycarbonyl; alkenyloxycarbonyl; or alkynyloxycarbonyl; and n is an integer from 0 to 3, said process comprising: (i) the reaction of a compound of formula (III) wherein R, R 1 and n are as hereinbefore defined; m and m' are independently 0 or 1; when m and m' are both 0, A is an alkyl, alkenyl or alkynyl group (suitably having up to eight carbon atoms), optionally substituted by one or more groups independently selected from halogen, hydroxy, alkoxy, C 1-4 dialkylamino or cyano; when one of m and m' is 0 and the other is 1, A is an alkanediyl, alkenediyl or alkynediyl group containing at least two carbon atoms (and suitably having up to eight carbon atoms), optionally substituted by one or more groups independently selected from halogen, hydroxy, alkoxy, C 1-4 dialkylamino or cyano; when m and m' are both 1, A is an alkanetriyl, alkenetriyl or alkynetriyl group containing at least three carbon atoms (and suitably having up to eight carbon atoms), optionally substituted by one or more groups independently selected from halogen, hydroxy, alkoxy, C 1-4 dialkylamino or cyano; and wherein if the group A contains three or more carbon atoms, one or more of the carbon atoms may each optionally be replaced with an oxygen atom, provided that there is at least one carbon atom between any two oxygen atoms in the molecule, with a compound of formula (IV) to give a compound of formula (II) wherein R, R 1 and n are as hereinbefore defined, and (ii) the reaction of a compound of formula (II) with , wherein L is a leaving group, to give the compound of formula (I) as hereinbefore defined, is disclosed.
摘要翻译：一种制备式（I）化合物的方法，其中：R是炔基; R 1是烷基，烯基，炔基，环烷基，环烷基 - 烷基，苯基和苯基烷基，所有后退基团依次可以携带一个或多个相同或不同的卤素原子; 烷氧基; 烯; 炔; 烷氧基; 卤代烷氧基; 烷; 卤代烷; alkysulfonyl; 甲酰基; 烷; 羟基; 卤素; 氰基; 硝基; 氨基; 烷基; 二烷基; 羧基; 烷; 链烯基氧基; 或炔氧基羰基; 并且n为0至3的整数，所述方法包括：（i）其中R，R 1和N 2如上定义的式（III）化合物的反应; m和m'独立地为0或1; 当m和m'均为0时，A为任选被一个或多个独立地选自卤素，羟基，烷氧基，C 1 -C 6烷氧基的烷基，烯基或炔基（适宜地具有至多8个碳原子） 4个二烷基氨基或氰基; 当m和m'中的一个是0而另一个是1时，A是含有至少两个碳原子（并且合适地具有至多8个碳原子）的烷二基，亚烯基或炔二基，任选被一个或多个独立选择的基团取代卤素，羟基，烷氧基，C 1-4烷基氨基或氰基; 当m和m'均为1时，A是含有至少三个碳原子（并且合适地具有至多8个碳原子）的烷三基，亚烷基三炔或炔三基，任选地被一个或多个独立地选自卤素，羟基，烷氧基 C 1-4烷基氨基或氰基; 并且其中如果基团A含有三个或更多个碳原子，一个或多个碳原子可以各自任选被氧原子替代，条件是分子中任何两个氧原子之间至少有一个碳原子，得到式（II）化合物，其中R，R 1和n如上所定义，和（ii）式（II）化合物与式其中L是离去基团，得到如上文所定义的式（I）化合物。

7. 发明申请

WO0105766A2 CHEMICAL PROCESS 审中-公开
标题翻译：化学工艺
公开(公告)号：WO0105766A2
公开(公告)日：2001-01-25
申请号：PCT/GB0002613
申请日：2000-07-07
申请人： ZENECA LTD , BROWN STEPHEN MARTIN , WILLIAMS ALFRED GLYN , BOWDEN MARTIN CHARLES
发明人： BROWN STEPHEN MARTIN , WILLIAMS ALFRED GLYN , BOWDEN MARTIN CHARLES
IPC分类号： C07D213/61 , C07D213/00
CPC分类号： C07D213/61
摘要： A process for the preparation of 3,5-dichloropyridine comprising reacting a trichloropyridine, a tetrachloropyridine or pentachloropyridine with zinc metal, in the presence of an acidic compound and at a temperature in the range 50-120 DEG C.
摘要翻译：一种制备3,5-二氯吡啶的方法，包括使三氯吡啶，四氯吡啶或五氯吡啶与锌金属在酸性化合物的存在下，在50-120℃的温度下反应。

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