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    • 5. 发明申请
    • 3-CARBONYLAMINOTHIOPHENES AND THEIR USE AS FUNGICIDES
    • 3-羰基苯甲酸和它们作为防腐剂使用
    • WO2004099195A1
    • 2004-11-18
    • PCT/EP2004/004194
    • 2004-04-21
    • SYNGENTA PARTICIPATIONS AGEHRENFREUND, JosefWALTER, HaraldTOBLER, HansLAMBERTH, Clemens
    • EHRENFREUND, JosefWALTER, HaraldTOBLER, HansLAMBERTH, Clemens
    • C07D409/12
    • C07D409/12A01N55/00C07D333/28C07D333/36C07D411/12C07D413/12C07D417/12
    • The invention also relates to novel compounds of formula (1) where Het is a 5- or 6-membered heterocyclic ring containing one to three heteroatoms, each independently selected from oxygen, nitrogen and sulphur, the ring being substituted by one to three groups R 4 ; R 1 is hydrogen, optionally substituted (C 1 - 4 )alkyl, formyl, optionally substituted (C 1 - 4 )alkylC(=0), optionally substituted (C 1 - 4 )alkylC(=0)0, optionally substituted (C 1 - 4 )alkoxy(C 1 - 4 )alkyl, optionally substituted allyl, optionally substittited propargyl or optionally substituted allenyl; each R 2 is, independently, halogen, optionally substituted (C 1 - 4 )alkyl, optionally substituted (C 1 - 4 )alkoxy or optionally substituted (C 1 - 4 )alkoxy(C 1 - 4 )alkyl; R 3 is either at position 2 or at position 4 of the thiophene ring and is an organie group containing three to thirteen carbon atoms and al least one silicon atom and, optionally, one to three heteroatoms, each independently selected from oxygen, nitrogen and sulphur, and is optionally substituted by one to four independently selected halogen atoms; each R 4 is, independently, halogen, C 1 - 3 alkyl, C 1 - 3 haloalkyl, C 1 - 3 alkoxy(C 1 - 3 )alkyl or cyano; r is 0, 1 or 2; and X is 0 or S; or an N-oxide thereof, to novel intermediates used in the preparation of these compounds, to agrochernical compositions which comprise at least one of the novel compounds as an active ingredient and to the use of the active ingredients or compositions in agriculture or horticulture for controlling or preventing infestation of plants by phytopathogenic microorganisms, preferably fungi.
    • 本发明还涉及式(1)的新化合物,其中Het是含有一至三个杂原子的5-或6-元杂环,各自独立地选自氧,氮和硫,该环被一至三个基团R <4>; 任选取代的(C 1-4)烷基C(= O),任选取代的(C 1-4)烷基C(= O) 4)烷氧基(C 1-4)烷基,任选取代的烯丙基,任选取代的炔丙基或任选取代的烯丙基; 每个R 2独立地是卤素,任选取代的(C 1-4)烷基,任选取代的(C 1-4)烷氧基或任选取代的(C 1-4)烷氧基(C 1-4)烷基; R 3在噻吩环的位置2或位置4处,并且是含有三至十三个碳原子和至少一个硅原子和任选地一至三个杂原子的有机基团,各自独立地选自氧,氮 和硫,并且任选被一至四个独立选择的卤素原子取代; 每个R 4独立地是卤素,C 1-3烷基,C 1-3卤代烷基,C 1-3烷氧基(C 1-3)烷基或氰基; r为0,1或2; X为0或S; 或其N-氧化物,用于制备这些化合物的新中间体,包含至少一种新化合物作为活性成分的农业组合物以及农业或园艺中的活性成分或组合物用于控制 或通过植物病原微生物,优选真菌来防止植物侵染。