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1. 发明申请

WO2007003449A1 COMPOSITE MATERIAL 审中-公开
标题翻译：复合材料
公开(公告)号：WO2007003449A1
公开(公告)日：2007-01-11
申请号：PCT/EP2006/060914
申请日：2006-03-21
申请人： STABILIMENTI TESSILI OZELLA S.p.A. , GAIO, Andrea , MEZZO, Luca
发明人： GAIO, Andrea , MEZZO, Luca
IPC分类号： C08J5/04
CPC分类号： C08J5/04 , C08J2363/00
摘要： The composite material comprises a fibrous support and a thermosetting resin having a glass transition temperature of no less than 30°C which impregnates the support. The support comprises a plurality of assembled thread-like first and second elements. The first thread-like elements are based on or coated by a thermoplastic phenoxy polymer having a glass transition temperature (Tg) of no less than 20°C and the formula (I), (II), or (III), in which R 1 and R 2 are mutually independently selected from among H, C 1 -C 10 alkyl and optionally substituted phenyl, R 3 is selected from among H, C 1 -C 10 alkyl, C 1 -C 10 car- boxyethyl and COR 4 where R 4 denotes H or a C 1 -C 9 alkyl, and n is an integer of between 30 and 200. The second thread-like elements are fibres selected from the group consisting of carbon, glass, basalt, p-aramid and polyphenylenebenzobisoxazole (PBO) fibres and mixtures thereof.
摘要翻译：复合材料包括玻璃化转变温度不低于30℃的纤维状载体和热固性树脂，其浸渍载体。支撑件包括多个组装的螺纹状的第一和第二元件。第一线状元件基于玻璃化转变温度（Tg）不低于20℃，式（I），（II）或（III））的热塑性苯氧基聚合物或其涂层，其中R R 1和R 2彼此独立地选自H，C 1 -C 10烷基和任选取代的苯基 R 3选自H，C 1 -C 10烷基，C 1 -C 10亚烷基，C 1 -C 3 其中R 4表示H或C 1 -C 9烷基，其中R 4表示H或C 1 -C 9烷基，并且n是30至200的整数。第二线状元件是选自由碳，玻璃，玄武岩，对芳族聚酰胺和聚亚苯基苯并双恶唑（PBO）纤维及其混合物组成的组的纤维。

2. 发明申请

WO2007043007A1 SYNTHESIS OF CARBON NANOTUBES AND/OR NANOFIBRES ON A POLYMER SUBSTRATE 审中-公开
标题翻译：聚合物基体上碳纳米管和/或纳米纤维的合成
公开(公告)号：WO2007043007A1
公开(公告)日：2007-04-19
申请号：PCT/IB2006/053712
申请日：2006-10-10
申请人： STABILIMENTI TESSILI OZELLA S.p.A. , MEZZO, Luca , GAIO, Andrea , CESANO, Federico , SCARANO, Domenica , ZECCHINA, Adriano
发明人： MEZZO, Luca , GAIO, Andrea , CESANO, Federico , SCARANO, Domenica , ZECCHINA, Adriano
IPC分类号： C01B31/02 , C08K7/24 , C08K3/04 , B01J31/06 , B01J31/28
CPC分类号： B82Y40/00 , B01J23/755 , B01J31/06 , B82Y30/00 , C01B32/162 , D01F9/127 , D01F9/1273
摘要： The method provides for the synthesis of carbon nanotubes and/or nanofibres on the surface of a polymer substrate selected from the group consisting of polybenzoxazoles, polybenzimidazoles, polyimides, polyaramides and mixtures thereof. The method comprises the steps of: depositing on the surface of the substrate at least one metal belonging to one of groups Ib to VIIIb of the Periodic Table of Elements, which metal has catalytic properties- with respect to the formation and development of the carbon nanotubes and/or nanofibres, and placing the substrate in contact with a gas comprising a component the molecule of which contains at least one carbon atom, at a temperature of between 400 and 900°C, so as to bring about the synthesis of the carbon nanotubes and/or nanofibres on the surface of the polymer substrate.
摘要翻译：该方法提供了在选自聚苯并恶唑，聚苯并咪唑，聚酰亚胺，聚酰胺及其混合物的聚合物基材的表面上合成碳纳米管和/或纳米纤维。该方法包括以下步骤：在基材的表面上沉积至少一种属于元素周期表的Ib至VIIIb族之一的金属，该金属具有催化性能 - 关于碳纳米管的形成和发展和/或纳米纤维，并且将底物与包含其分子含有至少一个碳原子的组分的气体在400-9000℃的温度下接触，以使碳纳米管和/ 或聚合物基材表面上的纳米纤维。

3. 发明申请

WO2011069743A1 ELECTROCHEMICAL SENSING METHOD 审中-公开
标题翻译：电化学传感方法
公开(公告)号：WO2011069743A1
公开(公告)日：2011-06-16
申请号：PCT/EP2010/066169
申请日：2010-10-26
申请人： NANOCYL S.A. , UNIVERSITE DE BRETAGNE SUD , LUIZI, Frederic , MEZZO, Luca , FELLER, Jean-Fançois , CASTRO, Mickaël
发明人： LUIZI, Frederic , MEZZO, Luca , FELLER, Jean-Fançois , CASTRO, Mickaël
IPC分类号： G01N33/00 , G01N27/12
CPC分类号： G01N27/308 , B82Y15/00 , G01N33/0047
摘要： The present invention is related to a method for detecting at least one chemical analyte vapour in a gaseous environment comprising the steps of: - providing a fibre-based electrochemical sensor, said fibre-based sensor comprising at least one type of composite fibres, said type of composite fibres comprising a co-continuous phase blend comprising a first and a second continuous polymer phase, the first polymer phase being sensitive to the chemical analyte vapour to be detected in use, wherein said first polymer phase comprises a dispersion of carbon nanotubes at a concentration above the percolation threshold and wherein the chemical analyte is soluble in said first polymer phase; - measuring the initial electrical conductivity of the fibre-based sensor; - bringing said fibre-based sensor into contact with at least one chemical analyte to induce a modification of the electrical conductivity of the fibres; - measuring the modification of the resulting electrical conductivity of said fibre-based sensor and correlating said modification with the identification of the chemical analyte to be detected.
摘要翻译：本发明涉及一种用于在气体环境中检测至少一种化学分析物蒸汽的方法，包括以下步骤： - 提供基于纤维的电化学传感器，所述基于纤维的传感器包括至少一种类型的复合纤维，所述类型的复合纤维，其包含包含第一和第二连续聚合物相的共连续相共混物，所述第一聚合物相对待使用的待检测的化学分析物蒸气敏感，其中所述第一聚合物相包含碳纳米管在浓度高于渗滤阈值，其中化学分析物可溶于所述第一聚合物相中; - 测量基于光纤的传感器的初始电导率; - 使所述基于纤维的传感器与至少一种化学分析物接触以引起纤维的电导率的改变; - 测量所述基于光纤的传感器的所得电导率的修改，并将所述修改与要检测的化学分析物的识别相关联。

4. 发明申请

WO2011069742A1 PTC RESISTOR 审中-公开
标题翻译： PTC电阻器
公开(公告)号：WO2011069742A1
公开(公告)日：2011-06-16
申请号：PCT/EP2010/066164
申请日：2010-10-26
申请人： NANOCYL S.A. , UNIVERSITE DE BRETAGNE SUD , LUIZI, Frederic , MEZZO, Luca , FELLER, Jean-François , CASTRO, Mickaël
发明人： LUIZI, Frederic , MEZZO, Luca , FELLER, Jean-François , CASTRO, Mickaël
IPC分类号： H01C7/02 , H01C17/065
CPC分类号： H01C7/027 , H01C17/06586
摘要： The present invention is related to a polymer fibre-based PTC resistor comprising a co-continuous polymer phase blend, said blend comprising a first and a second continuous polymer phase, wherein the first polymer phase comprises a dispersion of carbon nanotubes at a concentration above the percolation threshold, said first polymer phase presenting a softening temperature lower than the softening temperature of the second polymer phase.
摘要翻译：本发明涉及包含共连续聚合物相共混物的聚合物纤维基PTC电阻器，所述共混物包含第一和第二连续聚合物相，其中第一聚合物相包含浓度高于渗透阈值，所述第一聚合物相呈现软化温度低于第二聚合物相的软化温度。

5. 发明申请

WO2011134864A1 SHEAR SENSOR 审中-公开
标题翻译：剪刀传感器
公开(公告)号：WO2011134864A1
公开(公告)日：2011-11-03
申请号：PCT/EP2011/056333
申请日：2011-04-20
申请人： NANOCYL S.A. , MEZZO, Luca , LUIZI, Frédéric , LUSSEY, David , DEVAUX, Eric , CAMPAGNE, Christine , ROCHERY, Maryline , CAYLA, Aurélie
发明人： MEZZO, Luca , LUIZI, Frédéric , LUSSEY, David , DEVAUX, Eric , CAMPAGNE, Christine , ROCHERY, Maryline , CAYLA, Aurélie
IPC分类号： G01L1/20 , D02G3/44 , D01F1/09
CPC分类号： G01L1/20 , D01F1/09 , D02G3/441
摘要： The present invention is related to a shear sensor comprising two or more electrodes and an electrically conductive textile, said sensor being adapted to measure a resistivity variation in response to a shear deformation, said textile comprising conductive multifilament fibres having a resistivity comprised between 10 2 Ohm.cm and 10 7 Ohm.cm and said fibres comprising a polymer matrix and a conductive filler.
摘要翻译：本发明涉及包括两个或多个电极和导电织物的剪切传感器，所述传感器适于测量响应于剪切变形的电阻率变化，所述纺织品包含导电复丝纤维，其电阻率为102Ohm·cm 和107欧姆·厘米，并且所述纤维包含聚合物基质和导电填料。

6. 发明申请

WO2010007163A1 METHOD FOR THE PREPARATION OF A REINFORCED THERMOSET POLYMER COMPOSITE 审中-公开
标题翻译：制备增强型热固性聚合物复合材料的方法
公开(公告)号：WO2010007163A1
公开(公告)日：2010-01-21
申请号：PCT/EP2009/059247
申请日：2009-07-17
申请人： NANOCYL S.A. , KATHOLIEKE UNIVERSITEIT LEUVEN , MEZZO, Luca , GODARA, Ajay , ROCHEZ, Olivier , LUIZI, Frédéric , WARRIER, Ashish , VERPOEST, Ignaas , LOMOV, Stepan
发明人： MEZZO, Luca , GODARA, Ajay , ROCHEZ, Olivier , LUIZI, Frédéric , WARRIER, Ashish , VERPOEST, Ignaas , LOMOV, Stepan
IPC分类号： C08J5/06 , C08J5/10 , C08J5/24 , C09D171/10 , D06M11/74 , D06M13/513 , D06M15/53 , D06M15/643
CPC分类号： D01F11/00 , B82Y30/00 , C08G2650/56 , C08J5/06 , C08J5/10 , C08L63/00 , C09D163/00 , C09D171/00 , D06M11/74 , D06M13/513 , D06M15/53 , D06M15/643 , Y10T428/292 , C08L2666/22 , C08K3/041 , C08L71/00 , C08K3/04
摘要： The present invention refers to a method for the preparation of a reinforced thermoset polymer composite, said thermoset polymer composite comprising coated fibres, the coating being used as a vehicle for the introduction of carbon nanotubes into the thermoset polymer, the preparation of said reinforced thermoset polymer composite comprising the following steps: - providing fibres; - preparing a coating comprising carbon nanotubes and a polymeric binder; - applying said coating to said fibres to obtain coated fibres; - impregnating said coated fibres with a precursor of a thermoset polymer and letting part of the carbon nanotubes transfer from the coating into the precursor of the thermoset polymer; - curing said precursor containing the coated fibres and the transferred carbon nanotubes to achieve the reinforced thermoset polymer composite.
摘要翻译：本发明涉及一种制备增强的热固性聚合物复合材料的方法，所述热固性聚合物复合材料包括涂覆的纤维，该涂层用作将碳纳米管引入热固性聚合物中的载体，所述增强的热固性聚合物的制备复合材料包括以下步骤： - 提供纤维; - 制备包含碳纳米管和聚合物粘合剂的涂层; - 将所述涂层施加到所述纤维上以获得涂覆的纤维; - 用热固性聚合物的前体浸渍所述涂覆的纤维，并使部分碳纳米管从涂层转移到热固性聚合物的前体中; - 固化含有涂覆纤维和转移的碳纳米管的所述前体以实现增强的热固性聚合物复合材料。

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