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1. 发明申请

WO2012150253A1 METHOD FOR MANUFACTURING FLUOROELASTOMERS 审中-公开
标题翻译：制造荧光体的方法
公开(公告)号：WO2012150253A1
公开(公告)日：2012-11-08
申请号：PCT/EP2012/058011
申请日：2012-05-02
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.p.A. , KENT, Bradley Lane , APOSTOLO, Marco , CHERNYSHEVA, Liubov , COMINO, Giovanni
发明人： KENT, Bradley Lane , APOSTOLO, Marco , CHERNYSHEVA, Liubov , COMINO, Giovanni
IPC分类号： C08F214/22
CPC分类号： C08F214/28 , C08F214/22 , C08F214/222 , C08F214/225
摘要： The invention pertains to a process for manufacturing a fluoroelastomer [fluoroelastomer (A)] having a heat of fusion of less than 5 J/g as measured by ASTM D-3418-08, said method comprising emulsion polymerizing vinylidene fluoride (VDF) in the presence of at least one additional fluorinated monomer, in an aqueous polymerization medium, said method comprising polymerizing VDF and said additional fluorinated monomer(s) in the presence of a redox radical initiator system comprising: - at least one organic oxidizing agent [agent (O)]; - at least one organic reducing agent [agent (R)]; and - at least one transition metal catalyst [agent (P)]; wherein agent (O) is fed to said polymerization medium separately from agent (R) and agent (P), so that agent (O) comes in contact with agent (R) and agent (P) exclusively in said polymerization medium comprising VDF and optional additional monomer(s), to fluoroelastomers having low amount of chain defects and low amount of polar end groups, notably obtainable from said process, and to curable compositions therefrom.
摘要翻译：本发明涉及通过ASTM D-3418-08测定的具有小于5J / g的熔化热的含氟弹性体（含氟弹性体（A）]的制造方法，所述方法包括：将聚偏二氟乙烯在水性聚合介质中存在至少一种另外的氟化单体，所述方法包括在氧化还原自由基引发剂体系存在下聚合VDF和所述另外的氟化单体，其包含： - 至少一种有机氧化剂）]; - 至少一种有机还原剂[agent（R）]; 和 - 至少一种过渡金属催化剂[试剂（P）]; 其中将试剂（O）与试剂（R）和试剂（P）分开地进料到所述聚合介质中，使得试剂（O）仅在包含VDF的聚合介质中与试剂（R）和试剂（P））接触，具有少量链缺陷和少量极性端基的含氟弹性体，特别是可从所述方法得到的含氟弹性体及其可固化组合物。

2. 发明申请

WO2012049093A1 FLUOROELASTOMERS 审中-公开
标题翻译：氟
公开(公告)号：WO2012049093A1
公开(公告)日：2012-04-19
申请号：PCT/EP2011/067575
申请日：2011-10-07
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , APOSTOLO, Marco , CHERNYSHEVA, Liubov
发明人： APOSTOLO, Marco , CHERNYSHEVA, Liubov
IPC分类号： C08F214/22 , C08F214/28 , C08K5/14 , C09K8/00 , C08F2/00 , C08F2/30 , C08F2/38 , C08F236/20
CPC分类号： C08F214/282 , C08F214/22 , C08F214/222 , C08F214/225 , C08F214/26 , C08F214/28 , C08F236/20
摘要： The invention pertains to peroxide-curable fluoroelastomers which can meet the requirements for the oil and gas industry, including explosive decompression, and which can be easily processed to yield cured parts in standard machineries at reasonable throughput rates, said fluoroelastomers comprising: - recurring units derived from vinylidene fluoride (VDF); - recurring units derived from hexafluoropropylene (HFP); - recurring units derived from at least one bis-olefin [bis-olefin (OF)] having general formula : wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 , equal or different from each other, are H, a halogen, or a C 1 -C 5 optionally halogenated group, possibly comprising one or more oxygen group; Z is a linear or branched C 1 -C 18 optionally halogenated alkylene or cycloalkylene radical, optionally containing oxygen atoms, or a (per)fluoropolyoxyalkylene radical; and - iodine or bromine cure-sites; said fluoroelastomers further possessing a Mooney viscosity (ML) of at least 85 MU (1+10@121 °C), when measured according to ASTM D1646. The Applicant has surprisingly found that fluoroelastomers as above detailed, despite their high molecular weight and thus their Mooney viscosities values, can be effectively processed to yield cured parts which possess outstanding sealing and mechanical properties in particular at high temperature and/or after exposure to hostile environments (e.g. to chemicals at high temperature) so as to provide for outstanding behaviour (substantially no failure) in explosive decompression conditions.
摘要翻译：本发明涉及可满足石油和天然气工业的要求的过氧化物固化的含氟弹性体，包括爆炸性减压，并且可以容易地以合理的通过速率在标准机械中加工产生固化部分，所述含氟弹性体包括： - 衍生单元偏氟乙烯（VDF）; - 衍生自六氟丙烯（HFP）的重复单元; - 衍生自具有以下通式的至少一种双烯烃[双烯烃（OF）]的重复单元：其中R 1，R 2，R 3，R 4，R 5和R 6彼此相同或不同，为H，卤素或可能包含一个或多个氧基团的C 1 -C 5任选卤代基团; Z是任选含有氧原子的直链或支链C 1 -C 18任选卤代亚烷基或亚环烷基，或（全）氟聚氧亚烷基; 和 - 碘或溴固化位点; 当根据ASTM D1646测量时，所述含氟弹性体还具有至少85MU（1 + 10 @ 121℃）的门尼粘度（ML）。申请人惊奇地发现，尽管具有高分子量，因此其门尼粘度值，上述含氟弹性体可以被有效地加工以产生具有优异的密封性和机械性能的固化部分，特别是在高温和/或暴露于敌对之后环境（例如，在高温下的化学品），以便在爆炸性减压条件下提供突出的行为（基本上没有故障）。

3. 发明申请

WO2012168351A1 HYPERBRANCHED FLUOROELASTOMER ADDITIVE 审中-公开
标题翻译：超滤荧光增容剂添加剂
公开(公告)号：WO2012168351A1
公开(公告)日：2012-12-13
申请号：PCT/EP2012/060786
申请日：2012-06-07
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , FANTONI, Matteo , COMINO, Giovanni , APOSTOLO, Marco
发明人： FANTONI, Matteo , COMINO, Giovanni , APOSTOLO, Marco
IPC分类号： C08F214/26
CPC分类号： C08F14/26 , C08F214/26 , C08F214/262 , C08F214/265
摘要： The invention pertains to a hyperbranched (per)fluoroelastomer [fluoroelastomer (B)] comprising recurring units derived from a bis-olefin [bis-olefin (OF)] having general formula (I): wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 , equal or different from each other, are H or C 1 -C 5 alkyl; Z is a linear or branched C 1 -C 18 alkylene or cycloalkylene radical, optionally containing oxygen atoms, preferably at least partially fluorinated, or a (per)fluoropolyoxyalkylene radical, said fluoroelastomer (B) having a slope in G' curve such that the ratio: G' 100 /G' 0.01 is of less than 10, when determined at 260°C according to ASTM D4440 standard, wherein G'100 is the storage modulus at a shear rate of 100 rad/sec and G' 0.01 is the storage modulus at a shear rate of 0.01 rad/sec, to compositions comprising the same, and to a process for their manufacture.
摘要翻译：本发明涉及含有通式（I）的双烯烃[双烯烃（OF）]的重复单元的超支化（全）含氟弹性体（含氟弹性体（B））：其中R1，R2，R3，R4，R5 和R 6相同或不同，为H或C 1 -C 5烷基; Z是直链或支链的C 1 -C 18亚烷基或亚环烷基，任选地含有氧原子，优选至少部分氟化的，或（全）氟聚氧亚烷基，所述含氟弹性体（B）具有G'曲线的斜率，当根据ASTM D4440标准在260℃下测定时，G'100 / G'0.01小于10，其中G'100是剪切速率为100rad / sec的储能模量，G'0.01为储能模量以0.01rad / sec的剪切速率加入包含该组合物的组合物，以及其制备方法。

4. 发明申请

WO2012084587A1 LOW VISCOSITY FLUOROELASTOMERS 审中-公开
标题翻译：低粘度荧光物质
公开(公告)号：WO2012084587A1
公开(公告)日：2012-06-28
申请号：PCT/EP2011/072520
申请日：2011-12-13
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , APOSTOLO, Marco , COMINO, Giovanni , CRISTINI, Marco
发明人： APOSTOLO, Marco , COMINO, Giovanni , CRISTINI, Marco
IPC分类号： C08F14/18 , C08F214/18 , C08F214/22
CPC分类号： C08F216/1408 , C08F2/38 , C08F14/18 , C08F214/18 , C08F214/184 , C08F214/222 , C09D129/10
摘要： The invention pertains to a low viscosity curable (per)fluoroelastomer [fluoroelastomer (A)] having a number-averaged molecular weight of 3 000 to 45 000, said (per)fluoroelastomer comprising at least 1 % moles, with respect to the total moles of recurring units, of recurring units derived from at least one (per)fluoromethoxyalkylvinylether of formula (I): CFX'=CX"OCF 2 OR f formula (I) wherein X' and X", equal to or different from each other, are independently H or F; and R f is selected from the group consisting of C 1 -C 6 (per)fluoroalkyls, linear or branched; C 5 -C 6 cyclic (per)fluoroalkyls; and C 2 -C 6 (per)fluorooxyalkyls, linear or branched, comprising from 1 to 3 catenary ethereal oxygen atoms [monomer (M)].
摘要翻译：本发明涉及数均分子量为3 000至45 000的低粘度可固化（全）含氟弹性体（含氟弹性体（A）]，相对于总摩尔数，所述（全）含氟弹性体包含至少1摩尔％衍生自式（I）的至少一个（全）氟代甲氧基烷基乙烯基醚的重复单元：CFX'= CX“OCF 2 OR f其中X'和X”彼此相同或不同的式（I）独立地为H 或F; 并且R f选自直链或支链的C 1 -C 6（全）氟代烷基; C5-C6环状（全）氟烷基; 和直链或支链的C2-C6（全）氧代烷基，其包含1至3个悬链烯醚氧原子[单体（M）]。

5. 发明申请

WO2013037692A1 ELECTRODE-FORMING COMPOSITION 审中-公开
标题翻译：电极成型组合物
公开(公告)号：WO2013037692A1
公开(公告)日：2013-03-21
申请号：PCT/EP2012/067408
申请日：2012-09-06
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.p.A. , COJOCARU, Paula , PIERI, Riccardo , APOSTOLO, Marco
发明人： COJOCARU, Paula , PIERI, Riccardo , APOSTOLO, Marco
IPC分类号： H01M4/36 , H01M4/38 , H01M4/62 , H01M4/485
CPC分类号： H01M4/623 , H01G9/0029 , H01G11/22 , H01G11/58 , H01M4/0409 , H01M4/0414 , H01M4/0419 , H01M4/36 , H01M4/366 , H01M4/38 , H01M4/485 , H01M4/62 , H01M4/621 , Y10T29/417 , Y10T29/49115
摘要： The invention pertains to an aqueous electrode-forming composition comprising: - at least one fluoropolymer [polymer (F)]; - particles of at least one powdery active electrode material [particles (P)], said particles (P) comprising a core of an active electrode compound [compound (E)] and an outer layer of a metallic compound [compound (M)] different from Lithium, said outer layer at least partially surrounding said core; and - water, to a process for its manufacture, to a process for manufacturing an electrode structure using the same, to an electrode structure made from the same and to an electrochemical device comprising said electrode structure.
摘要翻译：本发明涉及含水电极形成组合物，其包含： - 至少一种含氟聚合物[聚合物（F）]; - 至少一种粉状活性电极材料颗粒[颗粒（P）]，所述颗粒（P）包含活性电极化合物[化合物（E）]的核心和金属化合物[化合物（M）]的外层不同于锂，所述外层至少部分地围绕所述芯; 和水，其制造方法，使用该方法制造电极结构的方法，由其制造的电极结构和包括所述电极结构的电化学装置。

6. 发明申请

WO2011073344A1 METHOD FOR MANUFACTURING FLUOROELASTOMERS 审中-公开
标题翻译：制造荧光体的方法
公开(公告)号：WO2011073344A1
公开(公告)日：2011-06-23
申请号：PCT/EP2010/069964
申请日：2010-12-16
申请人： SOLVAY SOLEXIS S.P.A. , APOSTOLO, Marco , PIERI, Riccardo , CHERNYSHEVA, Liubov
发明人： APOSTOLO, Marco , PIERI, Riccardo , CHERNYSHEVA, Liubov
IPC分类号： C08F14/18
CPC分类号： C08F14/18 , C08F2/16 , C08F2/22 , C08F2/26 , C08F2/24
摘要： The invention pertains to a process for manufacturing a (per)fluoroelastomer having a heat of fusion of less than 5 J/g as measured by ASTM D-3418-08, said process comprising polymerizing at least one fluorinated monomer in the presence of at least one initiator in a polymerization medium comprising: (A) water; (B) at least one fluorinated surfactant [surfactant (FS)] having formula (I) here below: wherein: - X 1 , X 2 and X 3 , equal to or different from each other, are independently selected from H, F and C 1 -C 6 (per)fluoroalkyl groups, optionally comprising one or more catenary or non-catenary oxygen atoms, - Rp represents a divalent perfluorinated C 1 -C 3 bridging group, - L represents a bond or a divalent group and - Y represents a hydrophilic functionality selected from anionic functionalities, cationic functionalities and non-ionic functionalities; (C) at least one fluorinated compound [compound (F)] different from surfactant (FS); wherein said polymerization medium has a pH value of less than 7.
摘要翻译：本发明涉及通过ASTM D-3418-08测定的具有小于5J / g的熔化热的（全）含氟弹性体的方法，所述方法包括在至少存在下聚合至少一种氟化单体聚合介质中的一种引发剂，包括：（A）水; （B）至少一种具有式（I）的氟化表面活性剂[表面活性剂（FS）]：其中：-X 1，X 2和X 3彼此相同或不同，独立地选自H，F和C 1 -C 6 （全）氟烷基，任选地包含一个或多个链或非链状氧原子，-Rp表示二价全氟化C1-C3桥连基团，-L表示键或二价基团，-Y表示选自阴离子功能性，阳离子官能度和非离子官能度; （C）与表面活性剂（FS）不同的至少一种氟化化合物[化合物（F）]; 其中所述聚合介质的pH值小于7。

7. 发明申请

WO2012010495A1 FLUOROELASTOMER COMPOSITION 审中-公开
标题翻译：荧光体组合物
公开(公告)号：WO2012010495A1
公开(公告)日：2012-01-26
申请号：PCT/EP2011/062069
申请日：2011-07-14
申请人： SOLVAY SOLEXIS S.P.A. , FANTONI, Matteo , APOSTOLO, Marco , COMINO, Giovanni
发明人： FANTONI, Matteo , APOSTOLO, Marco , COMINO, Giovanni
IPC分类号： C08K9/02 , C08L27/12
CPC分类号： C08L29/10 , C08K7/00 , C08K9/02 , C08L27/12
摘要： The invention pertains to a (per)fluoroelastomer composition having improved plasma resistance, said composition comprising: - at least one (per)fluoroelastomer [fluoroelastomer (A)]; and - from 0.1 to 50 weight parts, per 100 parts by weight of said fluoroelastomer (A) of alkaline-earth metal carbonate particles [particles (P)], each particle comprising : (a) a core consisting essentially of at least one alkaline-earth metal carbonate; and (b) a shell consisting essentially of at least one Group IV transition metal compound.
摘要翻译：本发明涉及具有改善的耐等离子体性的（全）含氟弹性体组合物，所述组合物包含： - 至少一种（全）含氟弹性体[含氟弹性体（A）]]。和0.1至50重量份的每100重量份的所述含氟弹性体（A）的碱土金属碳酸盐颗粒[颗粒（P）]，每个颗粒包含：（a）主要由至少一种碱 - 地下金属碳酸盐; 和（b）基本上由至少一种IV族过渡金属化合物组成的壳。

8. 发明申请

WO2016079230A1 MULTI-LAYERED ELASTOMER ARTICLE AND METHOD FOR MAKING THE SAME 审中-公开
标题翻译：多层弹性体制品及其制造方法
公开(公告)号：WO2016079230A1
公开(公告)日：2016-05-26
申请号：PCT/EP2015/077077
申请日：2015-11-19
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
发明人： COJOCARU, Paula , TRIULZI, Francesco Maria , APOSTOLO, Marco , ORIANI, Andrea Vittorio , SPREAFICO, Marco Alberto
IPC分类号： C23C18/16 , C23C18/20 , C23C18/30
CPC分类号： C23C18/1687 , C23C18/1633 , C23C18/1653 , C23C18/2006 , C23C18/206 , C23C18/30
摘要： The present invention relates to a multi-layered elastomer article and to a method for its manufacturing. The multi-layered article made of an elastomeric composition [composition (C)] comprising at least one elastomer, said article having at least one surface [surface (S)] comprising: - nitrogen-containing groups [groups (N)] and - at least one layer [layer (L1)] adhered to said surface (S) comprising at least one metal compound [compound (M)].
摘要翻译：本发明涉及一种多层弹性体制品及其制造方法。由包含至少一种弹性体的弹性体组合物[组合物（C）]制成的多层制品，所述制品具有至少一个表面[S（S）]，其包含： - 含氮基团（基团（N）]和 - 粘附到包含至少一种金属化合物[化合物（M）]的所述表面（S）的至少一层[层（L1）]。

9. 发明申请

WO2018219790A1 SHIELDED CABLES 审中-公开
公开(公告)号：WO2018219790A1
公开(公告)日：2018-12-06
申请号：PCT/EP2018/063728
申请日：2018-05-24
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
发明人： GENONI, Massimo , MAURI, Stefano , BASSI, Mattia , APOSTOLO, Marco , AVATANEO, Marco
IPC分类号： H01B3/44 , H01B7/30 , H01B11/10 , B32B15/082 , B32B15/085 , C23C18/16 , C23C18/20 , C23C18/38 , C23C18/32
摘要： The present invention relates to a cable, suitable for both electrical and data transmission, comprising at least one shield layer, comprising a metal layer directly adhering onto the polymeric layer.

10. 发明申请

WO2015128339A1 CROSSLINKABLE FLUOROPOLYMERS 审中-公开
标题翻译：可交联氟聚合物
公开(公告)号：WO2015128339A1
公开(公告)日：2015-09-03
申请号：PCT/EP2015/053873
申请日：2015-02-25
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
发明人： APOSTOLO, Marco , TRIULZI, Francesco Maria , COJOCARU, Paula , WLASSICS, Ivan , MARCHIONNI, Giuseppe , TONELLI, Claudio Adolfo Pietro
IPC分类号： C08F214/24 , C08F214/26 , C08F214/18 , C08F214/22
CPC分类号： C08F214/225 , C08F214/18 , C08F214/186 , C08F214/22 , C08J3/24 , C08J3/28 , C08J5/18 , C08J2327/08 , H01L31/0481 , Y02E10/50
摘要： The present invention pertains to a process for the manufacture of a crosslinkable fluoropolynner, to said crosslinkable fluoropolynner and the crosslinked fluoropolynner obtainable therefrom, to a film comprising said crosslinkable fluoropolymer or said crosslinked fluoropolymer and to uses of said crosslinked fluoropolymer film in various applications.
摘要翻译：本发明涉及将可交联氟聚合物，所述交联性氟聚合物和由其获得的交联氟聚合物制造到包含所述可交联含氟聚合物或所述交联的含氟聚合物的膜以及所述交联的氟聚合物膜在各种应用中的用途的方法。

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