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1. 发明申请

WO2012175418A1 PROCESS FOR MANUFACTURING BATTERY COMPONENTS 审中-公开
标题翻译：制造电池组件的方法
公开(公告)号：WO2012175418A1
公开(公告)日：2012-12-27
申请号：PCT/EP2012/061424
申请日：2012-06-15
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.p.A. , ABUSLEME, Julio A. , PIERI, Riccardo , FOSSATI, Paolo
发明人： ABUSLEME, Julio A. , PIERI, Riccardo , FOSSATI, Paolo
IPC分类号： H01M2/16 , H01M2/14
CPC分类号： H01M10/04 , C08K5/07 , C08K5/151 , H01M2/145 , H01M2/1653 , H01M2/1686 , C08L27/16
摘要： The present invention pertains to a process for manufacturing a component of a secondary battery, said process comprising the following steps: (i) preparing a liquid composition comprising: - a liquid medium selected from the group consisting of aliphatic ketones, cycloaliphatic ketones, cycloaliphatic esters and mixtures thereof, and - at least one fluorinated polymer [polymer (F)] comprising recurring units derived from vinylidene fluoride (VDF), hexafluoropropylene (HFP) and at least one (meth)acrylic monomer (MA) having formula (I), wherein: - R 1 , R 2 and R 3 , equal to or different from each other, are independently selected from a hydrogen atom and a C 1 -C 3 hydrocarbon group, and - R x is a hydrogen atom or a C 1 -C 5 hydrocarbon moiety comprising at least one functional group selected from a hydroxyl, a carboxyl, an epoxide, an ester and an ether group; and (ii) processing said liquid composition to provide a film.
摘要翻译：本发明涉及制造二次电池组件的方法，所述方法包括以下步骤：（i）制备液体组合物，其包含： - 液体介质，其选自脂族酮，脂环族酮，脂环族酯以及至少一种含有衍生自偏二氟乙烯（VDF），六氟丙烯（HFP）和至少一种具有式（I）的（甲基）丙烯酸单体（MA））的重复单元的氟化聚合物[聚合物（F）其中：-R 1，R 2和R 3彼此相同或不同，独立地选自氢原子和C 1 -C 3烃基，且-R x是氢原子或包含至少一个选自羟基，羧基，环氧化物，酯和醚基的官能团; 和（ii）处理所述液体组合物以提供膜。

2. 发明申请

WO2012175417A1 SECONDARY BATTERIES 审中-公开
标题翻译：二次电池
公开(公告)号：WO2012175417A1
公开(公告)日：2012-12-27
申请号：PCT/EP2012/061423
申请日：2012-06-15
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.p.A. , ABUSLEME, Julio A. , FAIG, Régis , PIERI, Riccardo
发明人： ABUSLEME, Julio A. , FAIG, Régis , PIERI, Riccardo
IPC分类号： H01M2/16 , H01M6/06 , H01M10/0565
CPC分类号： H01M2/162 , H01M2/1653 , H01M6/06 , H01M10/0565 , H01M2300/0085
摘要： The present invention pertains to a secondary battery comprising at least one separator, said separator comprising at least one fluorinated polymer [polymer (F)], said polymer (F) comprising recurring units derived from vinylidene fluoride (VDF), hexafluoropropylene (HFP) and at least one (meth)acrylic monomer (MA) having formula (I) here below, wherein: - R 1 , R 2 and R 3 , equal to or different from each other, are independently selected from a hydrogen atom and a C 1 -C 3 hydrocarbon group, and - R OH is a C 1 -C 5 hydrocarbon moiety comprising at least one hydroxyl group.
摘要翻译：本发明涉及包含至少一个分离器的二次电池，所述分离器包含至少一种氟化聚合物[聚合物（F）]，所述聚合物（F）包含衍生自偏二氟乙烯（VDF），六氟丙烯（HFP）和至少一种具有式（I）的下述的（甲基）丙烯酸单体（MA），其中：-R 1，R 2和R 3彼此相同或不同，独立地选自氢原子和C 1 -C 3烃基，和-ROH是包含至少一个羟基的C 1 -C 5烃部分。

3. 发明申请

WO2011073344A1 METHOD FOR MANUFACTURING FLUOROELASTOMERS 审中-公开
标题翻译：制造荧光体的方法
公开(公告)号：WO2011073344A1
公开(公告)日：2011-06-23
申请号：PCT/EP2010/069964
申请日：2010-12-16
申请人： SOLVAY SOLEXIS S.P.A. , APOSTOLO, Marco , PIERI, Riccardo , CHERNYSHEVA, Liubov
发明人： APOSTOLO, Marco , PIERI, Riccardo , CHERNYSHEVA, Liubov
IPC分类号： C08F14/18
CPC分类号： C08F14/18 , C08F2/16 , C08F2/22 , C08F2/26 , C08F2/24
摘要： The invention pertains to a process for manufacturing a (per)fluoroelastomer having a heat of fusion of less than 5 J/g as measured by ASTM D-3418-08, said process comprising polymerizing at least one fluorinated monomer in the presence of at least one initiator in a polymerization medium comprising: (A) water; (B) at least one fluorinated surfactant [surfactant (FS)] having formula (I) here below: wherein: - X 1 , X 2 and X 3 , equal to or different from each other, are independently selected from H, F and C 1 -C 6 (per)fluoroalkyl groups, optionally comprising one or more catenary or non-catenary oxygen atoms, - Rp represents a divalent perfluorinated C 1 -C 3 bridging group, - L represents a bond or a divalent group and - Y represents a hydrophilic functionality selected from anionic functionalities, cationic functionalities and non-ionic functionalities; (C) at least one fluorinated compound [compound (F)] different from surfactant (FS); wherein said polymerization medium has a pH value of less than 7.
摘要翻译：本发明涉及通过ASTM D-3418-08测定的具有小于5J / g的熔化热的（全）含氟弹性体的方法，所述方法包括在至少存在下聚合至少一种氟化单体聚合介质中的一种引发剂，包括：（A）水; （B）至少一种具有式（I）的氟化表面活性剂[表面活性剂（FS）]：其中：-X 1，X 2和X 3彼此相同或不同，独立地选自H，F和C 1 -C 6 （全）氟烷基，任选地包含一个或多个链或非链状氧原子，-Rp表示二价全氟化C1-C3桥连基团，-L表示键或二价基团，-Y表示选自阴离子功能性，阳离子官能度和非离子官能度; （C）与表面活性剂（FS）不同的至少一种氟化化合物[化合物（F）]; 其中所述聚合介质的pH值小于7。

4. 发明申请

WO2008129041A1 VINYLIDENE FLUORIDE COPOLYMERS 审中-公开
标题翻译：乙烯基氟化物共聚物
公开(公告)号：WO2008129041A1
公开(公告)日：2008-10-30
申请号：PCT/EP2008/054831
申请日：2008-04-22
申请人： SOLVAY SOLEXIS S.p.A. , ABUSLEME, Julio , PIERI, Riccardo , BARCHIESI, Emma
发明人： ABUSLEME, Julio , PIERI, Riccardo , BARCHIESI, Emma
IPC分类号： C08F214/22 , B01D71/34 , H01M4/62
CPC分类号： C08F214/22 , B01D69/02 , B01D71/34 , B01D71/40 , B01D71/76 , B01D2325/36 , C08F214/225 , C08J5/2237 , C08J2327/16 , H01M4/621
摘要： The present invention pertains to a linear semi-crystalline copolymer [polymer (A)] comprising recurring units derived from vinylidene fluoride (VDF) monomer and at least one hydrophilic (meth)acrylic monomer (MA) of formula (I) wherein each of R1, R2, R3, equal or different from each other, is independently an hydrogen atom or a C 1 -C 3 hydrocarbon group, and R OH is a hydrogen or a C 1 -C 5 hydrocarbon moiety comprising at least one hydroxyl group, said polymer (A) comprising from 0.05 to 10 % by moles of recurring units derived from said hydrophilic (meth)acrylic monomer (MA) and being characterized by a fraction of randomly distributed units (MA) of at least 40 %, having improved thermal stability, to a process for its manufacture, to a composition comprising the same, and to its use as binder in batteries or for the manufacture of hydrophilic membranes.
摘要翻译：本发明涉及包含衍生自偏氟乙烯（VDF）单体和至少一种式（I）的亲水（甲基）丙烯酸单体（MA））的重复单元的线性半结晶共聚物[聚合物（A）]，其中R1 R 2，R 3彼此相同或不同，独立地为氢原子或C 1 -C 3烃基，R 1 OH / >是包含至少一个羟基的氢或C 1 -C 5 -C 5烃部分，所述聚合物（A）包含0.05至10摩尔％的重复单元衍生自所述亲水性（甲基）丙烯酸单体（MA），并且其特征在于具有至少40％的随机分布单元（MA）的一部分，其制备方法具有改善的热稳定性，包含该组合物的组合物，并且其用作电池中的粘合剂或用于制造亲水膜。

5. 发明申请

WO2013037692A1 ELECTRODE-FORMING COMPOSITION 审中-公开
标题翻译：电极成型组合物
公开(公告)号：WO2013037692A1
公开(公告)日：2013-03-21
申请号：PCT/EP2012/067408
申请日：2012-09-06
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.p.A. , COJOCARU, Paula , PIERI, Riccardo , APOSTOLO, Marco
发明人： COJOCARU, Paula , PIERI, Riccardo , APOSTOLO, Marco
IPC分类号： H01M4/36 , H01M4/38 , H01M4/62 , H01M4/485
CPC分类号： H01M4/623 , H01G9/0029 , H01G11/22 , H01G11/58 , H01M4/0409 , H01M4/0414 , H01M4/0419 , H01M4/36 , H01M4/366 , H01M4/38 , H01M4/485 , H01M4/62 , H01M4/621 , Y10T29/417 , Y10T29/49115
摘要： The invention pertains to an aqueous electrode-forming composition comprising: - at least one fluoropolymer [polymer (F)]; - particles of at least one powdery active electrode material [particles (P)], said particles (P) comprising a core of an active electrode compound [compound (E)] and an outer layer of a metallic compound [compound (M)] different from Lithium, said outer layer at least partially surrounding said core; and - water, to a process for its manufacture, to a process for manufacturing an electrode structure using the same, to an electrode structure made from the same and to an electrochemical device comprising said electrode structure.
摘要翻译：本发明涉及含水电极形成组合物，其包含： - 至少一种含氟聚合物[聚合物（F）]; - 至少一种粉状活性电极材料颗粒[颗粒（P）]，所述颗粒（P）包含活性电极化合物[化合物（E）]的核心和金属化合物[化合物（M）]的外层不同于锂，所述外层至少部分地围绕所述芯; 和水，其制造方法，使用该方法制造电极结构的方法，由其制造的电极结构和包括所述电极结构的电化学装置。

6. 发明申请

WO2011121078A1 FLUOROPOLYMER-BASED HYBRID ORGANIC/INORGANIC COMPOSITES 审中-公开
标题翻译：基于荧光聚合物的混合有机/无机复合材料
公开(公告)号：WO2011121078A1
公开(公告)日：2011-10-06
申请号：PCT/EP2011/055019
申请日：2011-03-31
申请人： SOLVAY SOLEXIS S.P.A. , ABUSLEME, Julio A. , PIERI, Riccardo , PAGIN, Ivan
发明人： ABUSLEME, Julio A. , PIERI, Riccardo , PAGIN, Ivan
IPC分类号： C08F214/18
CPC分类号： C08F214/18 , B01D67/0079 , B01D69/148 , B01D71/022 , B01D71/027 , B01D71/34 , B01D71/70 , B01D2323/38 , B82Y30/00 , C08F8/00 , C08F214/182 , C08F214/186 , C08F214/225 , C08F214/245 , C08F220/06 , C08F220/20 , C08F2800/10 , C08F2810/20 , C08F2810/50 , C08J5/005 , C08J5/2281 , C08J2333/10 , C08K3/346 , C09D127/16 , H01M2/145 , H01M2/166 , H01M8/1046 , Y02P70/56 , C08F8/12 , C08F8/42 , C08F210/02 , C08K3/36
摘要： The invention pertains to a process for manufacturing a fluoropolymer hybrid organic/inorganic composite, said process comprising: (i) providing a mixture of: - at least one fluoropolymer comprising recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] of formula: wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C 1 -C 3 hydrocarbon group, and R OH is a hydrogen atom or a C 1-C 5 hydrocarbon moiety comprising at least one hydroxyl group [polymer (F)]; and - at least one metal compound [compound (M)] of formula: X 4-m AY m wherein m is an integer from 1 to 4, and, according to certain embodiments, from 1 to 3, A is a metal selected from the group consisting of Si, Ti and Zr, Y is a hydrolysable group, X is a hydrocarbon group, optionally comprising one or more functional groups; - reacting at least a fraction of hydroxyl groups of the ROH groups of said monomer (MA) of said polymer (F) with at least a fraction of said compound (M), so as to obtain a grafted polymer comprising pendant -Y m-1 AX 4-m groups, with m, Y, A and X having same meaning as above detailed; - hydrolyzing and/or polycondensing compound (M) and/or pendant -Y m-1 AX 4-m groups, as above detailed to yield a fluoropolymer hybrid organic/inorganic composite comprising inorganic domains, to fluoropolymer hybrid organic/inorganic composites obtained therefrom and to the use of the same in several fields of use.
摘要翻译：本发明涉及一种制备含氟聚合物杂化有机/无机复合材料的方法，所述方法包括：（i）提供以下混合物： - 至少一种含有至少一种（甲基）丙烯酸单体衍生的重复单元的含氟聚合物[单体（MA ）]，其中R 1，R 2，R 3彼此相同或不同，各自独立地为氢原子或C1-C3烃基，ROH为氢原子或C 1 -C 5烃部分，其包含在至少一个羟基[聚合物（F）]; 和 - 至少一种式：X4-mAYm的金属化合物[化合物（M）]，其中m是1至4的整数，并且根据某些实施方案，从1至3，A是选自以下的金属：的Si，Ti和Zr，Y是可水解基团，X是烃基，任选地包含一个或多个官能团; - 将所述聚合物（F）的所述单体（MA）的ROH基团的至少一部分羟基与至少一部分所述化合物（M）反应，以获得包含侧基-Ym-1AX4的接枝聚合物 -m组，m，Y，A和X具有与上述相同的含义; - 水解和/或缩聚化合物（M）和/或侧基-Ym-1AX4-m基团，如上所述，以产生含有无机结构域的含氟聚合物杂化有机/无机复合材料，由其获得的含氟聚合物杂化有机/无机复合材料和在几个使用领域使用相同。

7. 发明申请

WO2013010936A1 AQUEOUS VINYLIDENE FLUORIDE POLYMER LATEX 审中-公开
标题翻译：水性乙烯基氟化物聚合物
公开(公告)号：WO2013010936A1
公开(公告)日：2013-01-24
申请号：PCT/EP2012/063778
申请日：2012-07-13
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , STANGA, Milena , PIERI, Riccardo , BERTASA, Anna Maria , KENT, Bradley Lane , BRINATI, Giulio
发明人： STANGA, Milena , PIERI, Riccardo , BERTASA, Anna Maria , KENT, Bradley Lane , BRINATI, Giulio
IPC分类号： C08L27/16 , C09D127/16 , C08K3/04 , H01M4/04 , H01M10/0525
CPC分类号： H01M4/623 , C08L27/16 , C09D127/16 , H01M4/0402 , H01M4/0404 , H01M4/133 , H01M4/1393 , H01M4/622 , H01M10/0525
摘要： The present invention pertains to an aqueous composition comprising: (A) an aqueous latex comprising at least one vinylidene fluoride (VDF) polymer [polymer (F)] comprising recurring units derived from vinylidene fluoride (VDF) and at least one (meth)acrylic monomer (MA) having formula (I) here below: wherein: - R 1 , R 2 and R 3 , equal to or different from each other, are independently selected from a hydrogen atom and a C 1 -C 3 hydrocarbon group, and - R OH is a hydrogen atom or a C 1 -C 5 hydrocarbon moiety comprising at least one hydroxyl group, (B) at least one powdery electrode material, and (C) optionally, less than 10% by weight, based on the total weight of the aqueous composition, of at least one organic solvent (S), wherein the polymer (F) in the aqueous latex is under the form of primary particles having an average primary particle size of less than 1 μm, as measured according to ISO 13321. The present invention also pertains to a process for manufacturing an electrode using said aqueous composition, to an electrode comprising a metal substrate coated on at least one surface with said aqueous composition and to use of said electrode for manufacturing a non-aqueous-type electrochemical device.
摘要翻译：本发明涉及一种水性组合物，其包含：（A）包含至少一种含偏二氯乙烯（VDF）的重复单元和至少一种（甲基）丙烯酸酯的偏二氟乙烯（VDF）聚合物[聚合物（F）具有式（I）的单体（MA）如下：其中：-R 1，R 2和R 3彼此相同或不同，独立地选自氢原子和C1-C3烃基，和-ROH是氢原子或包含至少一个羟基的C 1 -C 5烃部分，（B）至少一种粉末状电极材料，和（C）任选地，基于水性组合物的总重量，小于10重量％至少一种有机溶剂（S），其中根据ISO 13321测量，水性胶乳中的聚合物（F）是平均一次粒径小于1μm的初级颗粒的形式。本发明还涉及一种使用所述水溶液制造电极的方法涉及包含涂覆在至少一个表面上的金属基材与所述水性组合物的电极，并且使用所述电极来制造非水型电化学装置。

8. 发明申请

WO2011073337A1 METHOD FOR MANUFACTURING FLUOROPOLYMERS 审中-公开
标题翻译：制造荧光体的方法
公开(公告)号：WO2011073337A1
公开(公告)日：2011-06-23
申请号：PCT/EP2010/069955
申请日：2010-12-16
申请人： SOLVAY SOLEXIS S.P.A. , PIERI, Riccardo , KAPELIOUCHKO, Valeri , CHERNYSHEVA, Liubov
发明人： PIERI, Riccardo , KAPELIOUCHKO, Valeri , CHERNYSHEVA, Liubov
IPC分类号： C08F14/18 , B01F17/00 , C08F6/14 , C08J3/03
CPC分类号： C08F6/14 , C08F14/18 , C08L27/12 , C08F2/24 , C08F2/32
摘要： The invention pertains to a process for manufacturing a (per)fluoropolymer, said process comprising polymerizing one or more fluorinated monomers in the presence of a multi-phase medium, said medium comprising: (A) a water phase [phase (W)]; (B) at least one fluorinated surfactant [surfactant (FS)] having formula (I) here below: R f -(OCF 2 CF 2 ) K-1 -O-CF 2 -COOX a (I) wherein R f is a C 1 -C 3 perfluoroalkyl group comprising, optionally, one or more ether oxygen atoms, k is 2 or 3 and X a is a selected from a monovalent metal and an ammonium group of formula NRN4, wherein R N , equal or different at each occurrence, is a hydrogen atom or a C 1 -C 3 alkyl group; (C) an oil phase [phase (O)] comprising: - at least one non-functional (per)fluoropolyether (non-functional PFPE) comprising at least one (per)fluoropolyoxyalkylene chain [chain (Rp)] and - at least one functional (per)fluoropolyether (functional PFPE) comprising at least one (per)fluoropolyoxyalkylene chain [chain (R' F )] and having a number average molecular weight of at least 1000 and a solubility of less than 1% by weight in water at 25°C.
摘要翻译：本发明涉及制备（全）含氟聚合物的方法，所述方法包括在多相介质存在下聚合一种或多种氟化单体，所述介质包括：（A）水相[相（W）]; （B）至少一种式（I）的氟化表面活性剂（表面活性剂（FS））如下：Rf-（OCF2CF2）K-1-O-CF2-COOXa（Ⅰ）其中Rf是C1-C3全氟烷基，任选地，一个或多个醚氧原子，k为2或3，Xa为选自式NRN4的一价金属和铵基团，其中每次出现时相同或不同的RN为氢原子或C1-C3 烷基; （C）油相[相（O）]，其包含：至少一种包含至少一个（全）氟聚氧亚烷基链[链（Rp）]的至少一个非官能（全）氟聚醚（非官能PFPE）包含至少一种（全）氟聚氧亚烷基链[链（R'F）]并且数均分子量至少为1000且在水中的溶解度小于1重量％的功能性（全）氟聚醚（功能性PFPE）在25°C。

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