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1. 发明申请

WO2012084745A1 PROCESS FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS 审中-公开
标题翻译：生产氟化有机化合物的方法
公开(公告)号：WO2012084745A1
公开(公告)日：2012-06-28
申请号：PCT/EP2011/073138
申请日：2011-12-16
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , TORTELLI, Vito , GALIMBERTI, Marco , MONZANI, Cristiano , GAVEZOTTI, Piero
发明人： TORTELLI, Vito , GALIMBERTI, Marco , MONZANI, Cristiano , GAVEZOTTI, Piero
IPC分类号： C07C41/22 , C07C43/12 , C08G65/00 , C08G65/323
CPC分类号： C07C41/22 , C07C41/48 , C08G65/007 , C08G65/3236 , C09K5/00 , C07C43/126 , C07C43/315
摘要： A process for fluorinating hydrocarbon compounds, which comprises: A. providing a compound selected from the group consisting of straight-chain, branched-chain and cyclic alkanes, straight-chain, branched-chain and cyclic ethers, said compound comprising at least one carbon-hydrogen bond and being free from -C(O)- functional groups; B. reacting said compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a compound wherein at least one carbon-hydrogen bond has been replaced by a carbon-fluorine bond. Compositions of partially fluorinated compounds obtained with the process are also disclosed.
摘要翻译：一种氟化烃化合物的方法，其包括：A.提供选自直链，支链和环烷烃，直链，支链和环醚的化合物，所述化合物包含至少一个碳 - 氢键并且不含-C（O） - 官能团; 在至少一种包含至少一个碳 - 碳双键并且在所述双键的碳原子上具有至少一个氟或氯原子的（全）卤代烯烃存在下，使所述化合物与氟反应，得到其中至少一个碳 - 氢键已被碳 - 氟键取代的化合物。还公开了通过该方法获得的部分氟化化合物的组合物。

2. 发明申请

WO2013000735A1 NOVEL FLUORINATED UNSATURATED COMPOUND AND POLYMERS OBTAINABLE THEREFROM 审中-公开
标题翻译：新型氟化不饱和化合物和可获得的聚合物
公开(公告)号：WO2013000735A1
公开(公告)日：2013-01-03
申请号：PCT/EP2012/061432
申请日：2012-06-15
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.p.A. , MONZANI, Cristiano , TORTELLI, Vito
发明人： MONZANI, Cristiano , TORTELLI, Vito
IPC分类号： C07C381/00 , C08F216/14
CPC分类号： C08F14/28 , C07C313/10 , C07C381/00 , C08F2/22 , C08F14/18 , C08F14/22 , C08F14/26 , C08F214/18 , C08F214/186 , C08F216/1408
摘要： A compound of formula CF 2 =CFCF 2 OSF 5 and polymers comprising recurring units deriving from CF 2 =CFCF 2 OSF 5 are disclosed as well as processes for their preparation.
摘要翻译：公开了式CF 2 = CFCF 2 OSF 5的化合物和衍生自CF 2 = CFCF 2 OSF 5的重复单元的聚合物及其制备方法。

3. 发明申请

WO2012062602A1 PROCESS FOR THE PREPARATION OF DIFLUOROACETIC ACID 审中-公开
标题翻译：制备二油酸的方法
公开(公告)号：WO2012062602A1
公开(公告)日：2012-05-18
申请号：PCT/EP2011/068946
申请日：2011-10-28
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , TORTELLI, Vito , MONZANI, Cristiano , WLASSICS, Ivan
发明人： TORTELLI, Vito , MONZANI, Cristiano , WLASSICS, Ivan
IPC分类号： C07C51/00 , C07C51/41 , C07C53/18
CPC分类号： C07C51/41 , C07C51/00 , C07C51/02 , C07C51/412 , C07C53/18
摘要： A process is provided for the preparation of difluoroacetic acid from tetrafluoroethylene. The process comprises reacting tetrafluoroethylene with an aqueous solution of an inorganic base, optionally in the presence of an organic solvent.
摘要翻译：提供了从四氟乙烯制备二氟乙酸的方法。该方法包括任选地在有机溶剂存在下使四氟乙烯与无机碱的水溶液反应。

4. 发明申请

WO2012160135A1 HYDRO-FLUOROCOMPOUNDS 审中-公开
标题翻译： HYDRO氟化合物
公开(公告)号：WO2012160135A1
公开(公告)日：2012-11-29
申请号：PCT/EP2012/059702
申请日：2012-05-24
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.p.A. , TORTELLI, Vito , WLASSICS, Ivan , MONZANI, Cristiano , KENT, Bradley Lane , VENERONI, Alessandro
发明人： TORTELLI, Vito , WLASSICS, Ivan , MONZANI, Cristiano , KENT, Bradley Lane , VENERONI, Alessandro
IPC分类号： C07C51/00 , C07C51/41 , C07C59/115
CPC分类号： C07C59/135 , C07C51/00 , C07C51/377 , C07C51/41 , C07C59/115 , C08K3/20
摘要： The invention pertains to certain hydro-fluorocompounds of the following formula (I): R f O-R H -O-(CH2) m -[CF(X)] n -COOX a wherein: - X a is H, a monovalent metal (preferably an alkaline metal) or an ammonium group of formula -N(R' n ) 4 , wherein each of R' n , equal to or different from each other, independently represents a hydrogen atom or a C 1-6 hydrocarbon group (preferably an alkyl group); - R f is a C 1 -C 6 (per)fluoroalkyl optionally comprising one or more catenary oxygen atoms, preferably R f is a group of formula R 'f -CH 2 -, wherein R' f is a C 1 -C 5 perfluorinated group, possibly comprising one or more ethereal oxygens, preferably a C 1 -C 3 perfluorinated group, possibly comprising one or more ethereal oxygens; - R H is a fluorine-free hydrocarbon group optionally comprising one or more catenary oxygen atoms; - X is F or CF 3 , preferably X is F; - m is 0 or 1; - n is 1 to 3, to a process for the manufacture of said hydro-fluorocompounds, to a method of making fluoropolymers in the presence of said hydro-fluorocompounds, and to fluoropolymer dispersions comprising said hydro-fluorocompound.
摘要翻译：本发明涉及以下式（I）的某些含氟化合物：RfO-RH-O-（CH2）m- [CF（X）] n-COOXa其中：-Xa为H，一价金属（优选碱金属）或式-N（R'n）4的铵基，其中R'n彼此相同或不同，各自独立地表示氢原子或C1-6烃基（优选烷基） ; -R f是任选地包含一个或多个链状氧原子的C 1 -C 6（全）氟烷基，优选地，Rf是式R'f-CH 2 - 的基团，其中R'f是C1-C5全氟化基团，可能包含一个或多个更多的醚氧，优选C1-C3全氟化基团，可能包含一个或多个醚类氧; - RH是任选地包含一个或多个链状氧原子的无氟烃基; - X是F或CF 3，优选X是F; - m为0或1; n为1至3，涉及制备所述含氟化合物的方法，涉及在所述含氟化合物存在下制备含氟聚合物的方法，以及包含所述氢氟化合物的含氟聚合物分散体。

5. 发明申请

WO2012069364A1 PROCESS FOR PRODUCING PERFLUORINATED ORGANIC COMPOUNDS 审中-公开
标题翻译：生产富含有机化合物的方法
公开(公告)号：WO2012069364A1
公开(公告)日：2012-05-31
申请号：PCT/EP2011/070400
申请日：2011-11-17
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.p.A. , TORTELLI, Vito , GALIMBERTI, Marco
发明人： TORTELLI, Vito , GALIMBERTI, Marco
IPC分类号： C07C67/14 , C07C67/287 , C07C67/307 , C07C69/708 , C07C69/63 , C07D317/42
CPC分类号： C07C67/287 , C07C51/58 , C07C51/60 , C07C67/14 , C07C2601/14 , C07D317/14 , C07D317/34 , C07D317/42 , C07C69/63 , C07C53/50
摘要： A process for producing a perfluorinated functional compound is disclosed, which comprises: A. converting an at least partially hydrogenated alcohol into an at least partially hydrogenated ester compound; B. reacting said at least partially hydrogenated ester compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a perfluorinated ester compound.
摘要翻译：公开了一种制备全氟化官能化合物的方法，其包括：A.将至少部分氢化的醇转化为至少部分氢化的酯化合物; 在至少一种包含至少一个碳 - 碳双键的（全）卤代烯烃存在下，使所述至少部分氢化的酯化合物与氟反应，并且在所述的碳 - 碳双键的碳原子上具有至少一个氟或氯原子双键，得到全氟化酯化合物。

6. 发明申请

WO2012104365A2 METHOD FOR MANUFACTURING PERFLUOROVINYLETHERS 审中-公开
标题翻译：制备全氟尿嘧啶的方法
公开(公告)号：WO2012104365A2
公开(公告)日：2012-08-09
申请号：PCT/EP2012/051730
申请日：2012-02-02
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.p.A. , MILLEFANTI, Stefano , TORTELLI, Vito , MARCHIONNI, Giuseppe , ALBONETTI, Stefania , GREGORI, Manuel , FORNASARI, Giuseppe
发明人： MILLEFANTI, Stefano , TORTELLI, Vito , MARCHIONNI, Giuseppe , ALBONETTI, Stefania , GREGORI, Manuel , FORNASARI, Giuseppe
IPC分类号： C07C41/42
CPC分类号： C07C41/24 , C07C43/17
摘要： The invention pertains to a process for the manufacture of a perfluorovinylether by hydrodehalogenation of a halofluoroether (HFE) having general formula (l-A) or (l-B): R f O-CR f 'X-CR f "R f "'X' (l-A) wherein Rf represents a C 1 -C 6 perfluoro(oxy)alkyl group; R f ', R f " and R f '", equal or different from each other, independently represent fluorine atoms or C 1 -C 5 perfluoro(oxy)alkyl groups; X and X', equal or different from each other, are independently chosen among CI, Br or I; wherein R f * and R f *', equal or different from each other, independently represent fluorine atoms or C 1 -C 3 perfluoro(oxy)alkyl groups; Y 1 and Y 2 , equal or different from each other, independently represent fluorine atoms or C 1 -C 3 perfluoroalkyl groups; X and X' are as above defined; said process comprising contacting said halofluoroether (HFE) with hydrogen in the presence of a catalyst comprising palladium and at least one transition metal (M) selected from the group consisting of the metals of group VIIIB, other than palladium, and of group IB.
摘要翻译：本发明涉及通过具有通式（1A）或（1B）的卤代氟醚（HFE）的加氢脱卤制备全氟乙烯基醚的方法：RfO-CRf'X-CRf“Rf”'X'（1A）其中Rf代表 C1-C6全氟（氧）烷基; Rf'，Rf“和Rf”“彼此相同或不同，独立地表示氟原子或C1-C5全氟（氧）烷基; X和X'彼此相同或不同，独立地选自CI，Br或I; 其中Rf *和Rf *'彼此相同或不同，独立地表示氟原子或C1-C3全氟（氧）烷基; Y1和Y2彼此相同或不同，独立地表示氟原子或C1-C3全氟烷基; X和X'如上所定义; 所述方法包括在催化剂存在下使所述卤代氟醚（HFE）与氢气接触，所述催化剂包含钯和至少一种选自除钯以外的第VIIIB族金属和IB族的过渡金属（M）。

7. 发明申请

WO2011003575A1 PROCESS FOR PRODUCING PERFLUORINATED ORGANIC COMPOUNDS 审中-公开
标题翻译：生产富含有机化合物的方法
公开(公告)号：WO2011003575A1
公开(公告)日：2011-01-13
申请号：PCT/EP2010/004081
申请日：2010-07-06
申请人： SOLVAY SOLEXIS S.p.A. , GALIMBERTI, Marco , TORTELLI, Vito
发明人： GALIMBERTI, Marco , TORTELLI, Vito
IPC分类号： C07D317/42 , C07B39/00
CPC分类号： C07D317/42
摘要： A process for producing a perfluorinated functional compound is disclosed, which comprises: A. converting an at least partially hydrogenated alcohol into an at least partially hydrogenated fluoroformate compound; B. reacting said at least partially hydrogenated fluoroformate compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a perfluorinated fluoroformate compound.
摘要翻译：公开了一种制备全氟化官能化合物的方法，其包括：A.将至少部分氢化的醇转化为至少部分氢化的氟甲酸酯化合物; B.在至少一种包含至少一个碳 - 碳双键的（全）卤代烯烃存在下，使所述至少部分氢化的氟甲酸酯化合物与氟反应，并在所述的碳 - 碳双键的碳原子上具有至少一个氟或氯原子双键，得到全氟化氟甲酸酯化合物。

8. 发明申请

WO2012007310A1 PROCESS FOR THE FLUORINATION OF HALOOLEFINS 审中-公开
标题翻译：胡萝卜素的荧光过程
公开(公告)号：WO2012007310A1
公开(公告)日：2012-01-19
申请号：PCT/EP2011/061264
申请日：2011-07-05
申请人： SOLVAY SOLEXIS S.p.A. , TORTELLI, Vito , GALIMBERTI, Marco
发明人： TORTELLI, Vito , GALIMBERTI, Marco
IPC分类号： C07C17/04 , C07C19/12 , C07C41/22
CPC分类号： C07C17/04 , C07C41/22 , C07C19/12 , C07C43/123
摘要： A process for the fluorination of haloolefins with elemental fluorine in the presence of anhydrous HF proceeds with high yield and selectivity in the product deriving from the addition of fluorine to the carbon-carbon double bond.
摘要翻译：在无水HF存在下用元素氟氟化氟代烯烃的方法在从碳 - 碳双键中加入氟的产物中产生高产率和选择性。

9. 发明申请

WO2015049239A1 PROCESS FOR THE SYNTHESIS OF FLUORALKYL SULFONATE SALTS 审中-公开
标题翻译：氟磺酸钠合成方法
公开(公告)号：WO2015049239A1
公开(公告)日：2015-04-09
申请号：PCT/EP2014/070952
申请日：2014-09-30
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
发明人： MONZANI, Cristiano , TORTELLI, Vito
IPC分类号： C07C277/08 , C07D487/04 , C07D213/20 , C07C303/32 , C07C209/12
CPC分类号： C07C303/32 , C07C209/00 , C07C211/63 , C07C277/08 , C07C279/06 , C07C309/06 , C07D213/20 , C07D487/04 , C07C279/04 , C07C309/10
摘要： A process for the preparation of the fluoroalkyl sulfonate salt of a nitrogen-based organic base said process comprising the step of reacting a fluoroalkyl sulfonyl halide with an organic base selected from the group consisting of tertiary amines, pyridines, amidines and guanidines.
摘要翻译：一种制备氮基有机碱的氟烷基磺酸盐的方法，所述方法包括使氟烷基磺酰卤与选自叔胺，吡啶，脒和胍的有机碱反应的步骤。

10. 发明申请

WO2019202079A1 METHOD OF MAKING MIXTURE OF POLYMERS 审中-公开
公开(公告)号：WO2019202079A1
公开(公告)日：2019-10-24
申请号：PCT/EP2019/060085
申请日：2019-04-18
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
发明人： FONTANA, Giovanni , GALIMBERTI, Marco , TORTELLI, Vito
IPC分类号： C08G65/00 , C08G65/323
摘要： The present invention relates to a process for the synthesis of partially and fully fluorinated polyether (PFPE) polymers, to PFPE polymers obtained therefrom and to the use of said PFPE polymers as intermediate compounds for the manufacture of additives for plastic and glass coating.

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