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    • 3. 发明申请
    • HYDRO-FLUOROCOMPOUNDS
    • HYDRO氟化合物
    • WO2012160135A1
    • 2012-11-29
    • PCT/EP2012/059702
    • 2012-05-24
    • SOLVAY SPECIALTY POLYMERS ITALY S.p.A.TORTELLI, VitoWLASSICS, IvanMONZANI, CristianoKENT, Bradley LaneVENERONI, Alessandro
    • TORTELLI, VitoWLASSICS, IvanMONZANI, CristianoKENT, Bradley LaneVENERONI, Alessandro
    • C07C51/00C07C51/41C07C59/115
    • C07C59/135C07C51/00C07C51/377C07C51/41C07C59/115C08K3/20
    • The invention pertains to certain hydro-fluorocompounds of the following formula (I): R f O-R H -O-(CH2) m -[CF(X)] n -COOX a wherein: - X a is H, a monovalent metal (preferably an alkaline metal) or an ammonium group of formula -N(R' n ) 4 , wherein each of R' n , equal to or different from each other, independently represents a hydrogen atom or a C 1-6 hydrocarbon group (preferably an alkyl group); - R f is a C 1 -C 6 (per)fluoroalkyl optionally comprising one or more catenary oxygen atoms, preferably R f is a group of formula R 'f -CH 2 -, wherein R' f is a C 1 -C 5 perfluorinated group, possibly comprising one or more ethereal oxygens, preferably a C 1 -C 3 perfluorinated group, possibly comprising one or more ethereal oxygens; - R H is a fluorine-free hydrocarbon group optionally comprising one or more catenary oxygen atoms; - X is F or CF 3 , preferably X is F; - m is 0 or 1; - n is 1 to 3, to a process for the manufacture of said hydro-fluorocompounds, to a method of making fluoropolymers in the presence of said hydro-fluorocompounds, and to fluoropolymer dispersions comprising said hydro-fluorocompound.
    • 本发明涉及以下式(I)的某些含氟化合物:RfO-RH-O-(CH2)m- [CF(X)] n-COOXa其中:-Xa为H,一价金属(优选碱 金属)或式-N(R'n)4的铵基,其中R'n彼此相同或不同,各自独立地表示氢原子或C1-6烃基(优选烷基) ; -R f是任选地包含一个或多个链状氧原子的C 1 -C 6(全)氟烷基,优选地,Rf是式R'f-CH 2 - 的基团,其中R'f是C1-C5全氟化基团,可能包含一个或多个 更多的醚氧,优选C1-C3全氟化基团,可能包含一个或多个醚类氧; - RH是任选地包含一个或多个链状氧原子的无氟烃基; - X是F或CF 3,优选X是F; - m为0或1; n为1至3,涉及制备所述含氟化合物的方法,涉及在所述含氟化合物存在下制备含氟聚合物的方法,以及包含所述氢氟化合物的含氟聚合物分散体。