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1. 发明申请

WO2012146525A1 LITHIUM AIR BATTERY CELL 审中-公开
标题翻译：锂离子电池
公开(公告)号：WO2012146525A1
公开(公告)日：2012-11-01
申请号：PCT/EP2012/057169
申请日：2012-04-19
申请人： SOLVAY SA , EICHER, Johannes , OLSCHIMKE, Jens , BOMKAMP, Martin , GARCIA-JUAN, Placido
发明人： EICHER, Johannes , OLSCHIMKE, Jens , BOMKAMP, Martin , GARCIA-JUAN, Placido
IPC分类号： H01M10/0567 , H01M10/052
CPC分类号： H01M8/22 , H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M12/08 , H01M2220/20 , H01M2300/0028 , H01M2300/0034 , Y02E60/122 , Y02E60/128 , Y02T10/7011
摘要： A lithium-air battery cell with an electrolyte composition comprising LiPO 2 F 2 is described. The electrolyte composition comprises an electrolyte solvent, for example, one or more non-fluorinated solvents, e.g. ethylene carbonate, a dialkyl carbonate or propylene carbonate, and/or one or more fluorinated organic solvents, e.g. fluoroethylene carbonate, cis-difluoroethylene carbonate, trans-difluoroethylene carbonate, 4,4-difluoroethylene carbonate, trifluoroethylene carbonate, tetrafluoroethylene carbonate, 4-fluoro-4-methyl-1,3-dioxolane-2-one, 4-fluoro-4-ethyl-1,3-dioxolane-2-one, 2,2,2-trifluoroethyl-methyl carbonate, 2,2,2-trifluoroethyl-fluoromethyl carbonate are preferred. The solvent may further comprise other additives. Also described is a vehicle battery, especially a car battery constituted of a multitude of lithium-air battery cells of the invention. The battery can be used to provide electrical energy to consumers for electric current including an electric motor driving the vehicle.
摘要翻译：描述了具有包含LiPO2F2的电解质组成的锂空气电池单元。电解质组合物包含电解质溶剂，例如一种或多种非氟化溶剂，例如，碳酸亚乙酯，碳酸二烷基酯或碳酸亚丙酯，和/或一种或多种氟化有机溶剂，例如，氟代碳酸亚乙酯，顺式二氟亚乙基碳酸酯，反式二氟亚乙基碳酸酯，4,4-二氟亚乙基碳酸酯，三氟乙烯碳酸酯，四氟乙烯碳酸酯，4-氟-4-甲基-1,3-二氧戊环-2-酮，4-氟-4- 乙基-1,3-二氧戊环-2-酮，2,2,2-三氟乙基 - 甲基碳酸酯，2,2,2-三氟乙基 - 氟甲基碳酸酯。溶剂可以进一步包含其它添加剂。还描述了一种车辆电池，特别是由本发明的多个锂空气电池单元构成的汽车电池。电池可以用于为消费者提供电能，包括驱动车辆的电动机的电流。

2. 发明申请

WO2011036293A2 COMPOSITION OF A FLUORINATED ORGANIC CARBONATE AND A LEWIS ACID 审中-公开
标题翻译：氟化有机碳酸酯和乳酸的组成
公开(公告)号：WO2011036293A2
公开(公告)日：2011-03-31
申请号：PCT/EP2010/064269
申请日：2010-09-27
申请人： SOLVAY SA , OLSCHIMKE, Jens , BOMKAMP, Martin , GROSSMANN, Andreas
发明人： OLSCHIMKE, Jens , BOMKAMP, Martin , GROSSMANN, Andreas
IPC分类号： C07D317/36 , C07D317/42
CPC分类号： C07D317/36 , C07D317/42
摘要： The present invention provides inter alia a method for handling fluorinated organic carbonates such that degradation reactions are minimized or even completely suppressed and hence initial purity of fluorinated organic carbonatesis essentially maintained during handling. The invention further provides compositions comprising a fluorinated organic carbonate with improved stability against degradation reactions. The compositions comprise equal to or less than 500 ppm of a Lewis acid.
摘要翻译：本发明尤其提供一种处理氟化有机碳酸酯的方法，使得降解反应最小化或甚至完全抑制，因此氟化有机碳酸酯的初始纯度在处理过程中基本保持。本发明进一步提供包含具有改进的降解反应稳定性的氟化有机碳酸酯的组合物。组合物包含等于或小于500ppm的路易斯酸。

3. 发明申请

WO2016016319A1 FLUORINATED CARBONATES COMPRISING TWO OXYGEN BEARING FUNCTIONAL GROUPS 审中-公开
标题翻译：包含两个氧气轴承功能组的氟化碳酸盐
公开(公告)号：WO2016016319A1
公开(公告)日：2016-02-04
申请号：PCT/EP2015/067408
申请日：2015-07-29
申请人： SOLVAY SA
发明人： BOMKAMP, Martin , SEFFER, Dirk
IPC分类号： C07C69/96 , H01G11/60 , H01M10/0567
CPC分类号： H01M10/0567 , B61L3/006 , B61L3/008 , C07C68/00 , C07C69/96 , H01G11/58 , H01G11/60 , H01G11/62 , H01G11/64 , H01M10/052 , H01M10/0525 , H01M10/0569 , H01M12/08 , H01M2300/0034 , Y02E60/13
摘要： Fluorinated carbonates comprising two oxygen bearing functional groups, methods for the preparation thereof, and their use as solvent or solvent additive for lithium ion batteries and supercapacitors are disclosed.
摘要翻译：公开了包含两个含氧官能团的氟化碳酸酯，其制备方法及其作为锂离子电池和超级电容器的溶剂或溶剂添加剂的用途。

4. 发明申请

WO2014009377A1 FLUORINATED CARBONYL COMPOUNDS COMPRISING A TRIPLE BOND, METHODS FOR THEIR MANUFACTURE AND USES THEREOF 审中-公开
标题翻译：包含三重键的氟化碳化合物，其制造方法及其用途
公开(公告)号：WO2014009377A1
公开(公告)日：2014-01-16
申请号：PCT/EP2013/064504
申请日：2013-07-09
申请人： SOLVAY SA
发明人： BOMKAMP, Martin , SEFFER, Dirk
IPC分类号： H01M10/0567 , C07C68/02 , C07C69/04 , C07C69/96 , H01M10/0569 , H01G11/60 , H01G11/64 , H01M10/052
CPC分类号： C07C255/03 , C07C69/96 , C07C253/30 , C07C255/14 , H01G11/60 , H01G11/62 , H01G11/64 , H01M10/052 , H01M10/0567 , H01M10/0569 , H01M12/08 , H01M2300/0034 , Y02E60/13
摘要： Fluorinated carbonyl compounds comprising a triple bond were prepared and their use as solvent additives or solvents in lithium ion batteries, lithium air batteries, lithium sulphur batteries and supercapacitors is described. Preferred compounds contain at least one nitrile or at least one alkynyl group.
摘要翻译：制备包含三键的氟化羰基化合物，并描述它们在锂离子电池，锂空气电池，锂硫电池和超级电容器中作为溶剂添加剂或溶剂的用途。优选的化合物含有至少一个腈或至少一个炔基。

5. 发明申请

WO2018073124A1 METHOD FOR PRODUCING FLUOROFORMATE COMPOUNDS 审中-公开
标题翻译：生产氟塑料化合物的方法
公开(公告)号：WO2018073124A1
公开(公告)日：2018-04-26
申请号：PCT/EP2017/076205
申请日：2017-10-13
申请人： SOLVAY SA
发明人： BUISINE, Olivier , KASUBKE, Michael , SEFFER, Dirk , BOMKAMP, Martin
IPC分类号： C07C269/04 , C07C68/02 , C07C51/58 , C07C55/40 , C07C69/96 , C07C271/12 , C07C271/20
CPC分类号： C07C269/04 , C07C51/58 , C07C68/02 , C07C55/40 , C07C69/96 , C07C271/12 , C07C271/20
摘要： The invention relates to the preparation of fluorosubstituted fluoroformate from halosubstituted haloformate by reaction with at least one fluorinating agent in the presence of a catalyst. The further preparation of fluorosubstituted (fluoro)alkyl carbonates, fluorosubstituted (fluoro)alkyl polycarbonates, fluorosubstituted (fluoro)alkyl carbamates and fluorosubstituted (fluoro)alkyl polycarbamates is disclosed.
摘要翻译：本发明涉及通过在催化剂存在下与至少一种氟化剂反应由卤代甲酸酯制备氟取代的氟甲酸酯。披露了氟取代的（氟代）烷基碳酸酯，氟取代的（氟代）烷基聚碳酸酯，氟取代的（氟代）烷基氨基甲酸酯和氟取代的（氟代）烷基聚氨基甲酸酯的进一步制备。

6. 发明申请

WO2015004195A1 FLUORINATED CARBONATES COMPRISING DOUBLE BOND-CONTAINING GROUPS, METHODS FOR THEIR MANUFACTURE AND USES THEREOF 审中-公开
标题翻译：包含双重含粘结剂组的氟化碳酸盐，其制造方法及其用途
公开(公告)号：WO2015004195A1
公开(公告)日：2015-01-15
申请号：PCT/EP2014/064734
申请日：2014-07-09
申请人： SOLVAY SA
发明人： BOMKAMP, Martin , KIM, Hag-Soo
IPC分类号： C07C68/02 , C07C69/96 , H01M6/16
CPC分类号： C07C69/96 , C07C68/02 , H01G11/60 , H01G11/64 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/0569 , H01M12/02 , H01M12/06 , H01M12/08 , H01M2300/0025 , H01M2300/0034 , Y02E60/128 , Y02E60/13
摘要： Fluorinated carbonates comprising double-bond containing groups were prepared and their use as solvent additives or solvents in lithium ion batteries, lithium air batteries, lithium sulphur batteries and supercapacitors is described. Preferred compounds contain at least one alkenyl or at least one (hetero)aryl group.
摘要翻译：制备含有双键的基团的氟化碳酸酯，并描述它们在锂离子电池，锂空气电池，锂硫电池和超级电容器中作为溶剂添加剂或溶剂的用途。优选的化合物含有至少一个烯基或至少一个（杂）芳基。

7. 发明申请

WO2013026777A9 FLUOROALKYL S-(FLUORO)ALKYL THIOCARBONATES, A METHOD FOR THE PREPARATION OF FLUOROALKYL S-(FLUORO)ALKYL THIOCARBONATES, AND THEIR USE 审中-公开
公开(公告)号：WO2013026777A9
公开(公告)日：2013-02-28
申请号：PCT/EP2012/066045
申请日：2012-08-16
申请人： SOLVAY SA , BOMKAMP, Martin
发明人： BOMKAMP, Martin
IPC分类号： H01M10/0525 , H01M10/0567 , H01M10/0569 , H01M10/42 , C07C329/06
摘要： Fluoroalkyl S-alkyl thiocarbonates and fluoroalkyl S-fluoroalkylthiocarbonates which are suitable as additives or solvents in lithium ion batteries are prepared from fluoroalkyl fluoroformates and the respective thioalcohol. Methanethiol, allyl thiol and 2,2,2-trifluorothiol are the preferred thioalcohol. Fluoromethyl S-methyl thiocarbonate, fluoromethyl S-allyl thiocarbonate, fluoromethyl S-2,2,2-trifluoroethyl thiocarbonate and fluoromethyl S-allyl thiocarbonate are the preferred compound to be produced.

8. 发明申请

WO2017017210A1 METHOD FOR THE MANUFACTURE OF FLUORINATED CYCLIC CARBONATES AND THEIR USE FOR LITHIUM ION BATTERIES 审中-公开
标题翻译：氟化循环碳酸盐的制造方法及其用于锂离子电池的方法
公开(公告)号：WO2017017210A1
公开(公告)日：2017-02-02
申请号：PCT/EP2016/068056
申请日：2016-07-28
申请人： SOLVAY SA
发明人： LEE, Ji-Hun , CHOI, Ji-Ae , HWANG, Hyung-Kwon , BOMKAMP, Martin , TVERDOMED, Sergey , SHEVCHUK, Mykhailo , KALINOVICH, Nataliya , RÖSCHENTHALER, Gerd-Volker
IPC分类号： C07D317/22
CPC分类号： C07D317/22
摘要： The present invention concerns methods for the manufacture of ethylene carbonate substituted with a fluorinated alkoxy group, certain ethylene carbonates substituted with a fluorinated alkoxy group as well as their use as solvent or solvent additive for lithium ion batteries and supercapacitors.
摘要翻译：本发明涉及用氟化烷氧基取代的碳酸亚乙酯的制造方法，由氟化烷氧基取代的某些乙烯碳酸酯以及它们作为锂离子电池和超级电容器的溶剂或溶剂添加剂的用途。

9. 发明申请

WO2014056936A1 PREPARATION OF PURIFIED FLUOROSUBSTITUTED ORGANIC CARBONATES 审中-公开
标题翻译：纯化氟化物有机碳酸盐的制备
公开(公告)号：WO2014056936A1
公开(公告)日：2014-04-17
申请号：PCT/EP2013/070973
申请日：2013-10-08
申请人： SOLVAY SA
发明人： BOMKAMP, Martin , LAMBERT, Alain
IPC分类号： C07D317/42
CPC分类号： C07D317/42
摘要： A process for the preparation of purified fluorosubstituted organic carbonates, especially of fluoroethylene carbonate, difluoroethylene carbonate, fluoromethyl methyl carbonate and difluorinated dimethyl carbonate from ethylene carbonate and dimethyl carbonate and F 2 is described. After fluorination, and preferably after performing a step of hydrogen fluoride depletion, the impure fluorosubstituted organic carbonates are subjected to a treatment with an agent of formula (I), R-H, wherein R is a nucleophilic group, and a subsequent step of distillation in at least one distillation column. Alcohols and amines, for example, are suitable as agent of formula (I). Methanol is especially preferred.
摘要翻译：描述了从碳酸亚乙酯和碳酸二甲酯和F2制备纯化的氟取代的有机碳酸酯，特别是氟代亚乙基碳酸酯，二氟亚乙基碳酸酯，氟甲基甲基碳酸酯和二氟化碳酸二甲酯的方法。在氟化后，优选在进行氟化氢消耗的步骤之后，将不纯的氟代取代的有机碳酸酯用式（I），RH（其中R是亲核基团）的试剂进行处理，随后在至少一个蒸馏塔。醇和胺例如适合作为式（I）的试剂。甲醇是特别优选的。

10. 发明申请

WO2013110741A1 FLUORINATED CARBONATES IN HYBRID SUPERCAPACITORS 审中-公开
标题翻译：混合超滤器中的氟化碳酸盐
公开(公告)号：WO2013110741A1
公开(公告)日：2013-08-01
申请号：PCT/EP2013/051399
申请日：2013-01-25
申请人： SOLVAY SA , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , UNIVERSITE D'ORLEANS
发明人： BÉGUIN, François , BOMKAMP, Martin , GAUTHY, Fernand , RAYMUNDO-PIÑERO, Encarnación
IPC分类号： H01G9/022 , H01G11/60
CPC分类号： H01G11/60 , Y02E60/13
摘要： A hybrid supercapacitor device comprising at least one positive electrode, at least one negative electrode, a separator and an electrolyte based on one or more organic solvents wherein the electrolyte comprises from 0.1 to 100 percent by weight, based on the entire weight of the solvent(s) in the electrolyte, of at least one fluorinated carbonate of formula I or II wherein R 1 to R 4 , which may be the same or different, are independently selected from hydrogen, fluorine, C 1 to C 8 -alkyl and C 1 to C 8 haloalkyl which the proviso that at least one of R 1 to R 4 is a fluorine atom or comprises a fluorine atom and R 5 to R 6 , independently of one another are selected from hydrogen, C 1 to C 8 alkyl or C 1 -C 8 haloalkyl.
摘要翻译：一种混合超级电容器装置，包括至少一个正电极，至少一个负极，隔板和基于一种或多种有机溶剂的电解质，其中所述电解质占所述溶剂的总重量的0.1至100重量％ s）在至少一种式I或II的氟化碳酸酯中，其中可以相同或不同的R 1至R 4独立地选自氢，氟，C 1至C 8 - 烷基和C 1至C 8卤代烷基，其中条件是R 1至R 4中的至少一个为氟原子或包含氟原子，R 5至R 6彼此独立地选自氢，C 1至C 8烷基或C 1 -C 8卤代烷基。

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