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    • 4. 发明申请
    • PREPARATION OF PURIFIED FLUOROSUBSTITUTED ORGANIC CARBONATES
    • 纯化氟化物有机碳酸盐的制备
    • WO2014056936A1
    • 2014-04-17
    • PCT/EP2013/070973
    • 2013-10-08
    • SOLVAY SA
    • BOMKAMP, MartinLAMBERT, Alain
    • C07D317/42
    • C07D317/42
    • A process for the preparation of purified fluorosubstituted organic carbonates, especially of fluoroethylene carbonate, difluoroethylene carbonate, fluoromethyl methyl carbonate and difluorinated dimethyl carbonate from ethylene carbonate and dimethyl carbonate and F 2 is described. After fluorination, and preferably after performing a step of hydrogen fluoride depletion, the impure fluorosubstituted organic carbonates are subjected to a treatment with an agent of formula (I), R-H, wherein R is a nucleophilic group, and a subsequent step of distillation in at least one distillation column. Alcohols and amines, for example, are suitable as agent of formula (I). Methanol is especially preferred.
    • 描述了从碳酸亚乙酯和碳酸二甲酯和F2制备纯化的氟取代的有机碳酸酯,特别是氟代亚乙基碳酸酯,二氟亚乙基碳酸酯,氟甲基甲基碳酸酯和二氟化碳酸二甲酯的方法。 在氟化后,优选在进行氟化氢消耗的步骤之后,将不纯的氟代取代的有机碳酸酯用式(I),RH(其中R是亲核基团)的试剂进行处理,随后在 至少一个蒸馏塔。 醇和胺例如适合作为式(I)的试剂。 甲醇是特别优选的。