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1. 发明申请

WO2011048053A1 METHOD FOR THE MANUFACTURE OF FLUORINATED ETHYLENE CARBONATES 审中-公开
标题翻译：氟化乙烯碳酸盐的制备方法
公开(公告)号：WO2011048053A1
公开(公告)日：2011-04-28
申请号：PCT/EP2010/065642
申请日：2010-10-18
申请人： SOLVAY FLUOR GmbH , BOMKAMP, Martin , OLSCHIMKE, Jens , EICHER, Johannes
发明人： BOMKAMP, Martin , OLSCHIMKE, Jens , EICHER, Johannes
IPC分类号： C07D317/46
CPC分类号： C07D317/46
摘要： Difluoroethylene carbonate, trifluoroethylene carbonate and tetrafluoroethylene carbonate are synthesized from dichloroethylene carbonate, trichloroethylene carbonate and tetrachloroethylene carbonate with fluorinating agents, e.g. alkali metal fluorides, antimony fluorides and especially the HF adducts of amines. The fluorinated carbonates are suitable as additives in lithium ion batteries.
摘要翻译：二氟乙烯碳酸酯，三氟乙烯碳酸酯和四氟乙烯碳酸酯由二氯乙烯碳酸酯，三氯乙烯碳酸酯和四氯乙烯碳酸酯与氟化剂合成。碱金属氟化物，氟化锑，特别是胺的HF加合物。氟化碳酸酯适合用作锂离子电池中的添加剂。

2. 发明申请

WO2011051275A1 LITHIUM SULFUR BATTERY 审中-公开
标题翻译：锂硫电池
公开(公告)号：WO2011051275A1
公开(公告)日：2011-05-05
申请号：PCT/EP2010/066143
申请日：2010-10-26
申请人： SOLVAY FLUOR GmbH , OLSCHIMKE, Jens , BOMKAMP, Martin , EICHER, Johannes
发明人： OLSCHIMKE, Jens , BOMKAMP, Martin , EICHER, Johannes
IPC分类号： H01M12/08 , H01M10/052 , H01M10/0569 , H01M10/0568 , H01M10/05
CPC分类号： H01M12/08 , H01M4/134 , H01M4/38 , H01M4/381 , H01M4/382 , H01M10/05 , H01M10/052 , H01M10/0568 , H01M10/0569 , H01M2300/0025 , H01M2300/0068 , Y02E60/128 , Y02T10/7011
摘要： A lithium sulfur battery comprising at least one fluorosubstituted compound is described. Preferred fluorosubstituted compounds which are predominantly solvents are notably selected from the group consisting of fluorosubstituted carboxylic acid esters, fluorosubstituted carboxylic acid amides, fluorosubstituted fluorinated ethers, fluorosubstituted carbamates, fluorosubstituted cyclic carbonates, and fluorosubstituted acyclic carbonates fluorosubstituted ethers, perfluoroalkyl phosphoranes, fluorosubstituted phosphites, fluorosubstituted phosphates, fluorosubstituted phosphonates and fluorosubstituted heterocycles. Monofluoroethylene carbonate, cis-difluoroethylene carbonate, trans- difluoroethylene carbonate, 4,4- difluoroethylene carbonate, trifluoroethylene carbonate, tetrafluoroethylene carbonate, 4-fluoro-4-methyl-l,3-dioxolane-2-one, 4-fluoro-4-ethyl- 1,3-dioxolane-2-one, 2,2,2-trifluoroethyl-methyl carbonate, 2,2,2-trifluoroethyl-fluoromethyl carbonate are preferred. The solvent my further comprise non-fluorinated solvents, e.g. ethylene carbonate, a dialkyl carbonate or propylene carbonate. The invention also concerns the use of fluorinated compounds as additive for such batteries and specific electrolyte solutions.
摘要翻译：描述了包含至少一种氟取代的化合物的锂硫电池。主要是溶剂的优选氟取代的化合物特别选自氟取代的羧酸酯，氟取代的羧酸酰胺，氟取代的氟代醚，氟取代的氨基甲酸酯，氟取代的环状碳酸酯和氟取代的无环碳酸酯氟取代的醚，全氟烷基磷，氟取代的亚磷酸酯，氟取代的磷酸酯，氟取代的膦酸酯和氟取代的杂环。单氟代碳酸亚乙酯，顺式二氟亚乙基碳酸酯，反式二氟亚乙基碳酸酯，4,4-二氟亚乙基碳酸酯，三氟乙烯碳酸酯，四氟乙烯碳酸酯，4-氟-4-甲基-1,3-二氧戊环-2-酮，4-氟-4- 乙基-1,3-二氧戊环-2-酮，2,2,2-三氟乙基 - 甲基碳酸酯，2,2,2-三氟乙基 - 氟甲基碳酸酯。溶剂我还包括非氟化溶剂，例如碳酸亚乙酯，碳酸二烷基酯或碳酸亚丙酯。本发明还涉及氟化化合物作为这种电池和特定电解质溶液的添加剂的用途。

3. 发明申请

WO2012146525A1 LITHIUM AIR BATTERY CELL 审中-公开
标题翻译：锂离子电池
公开(公告)号：WO2012146525A1
公开(公告)日：2012-11-01
申请号：PCT/EP2012/057169
申请日：2012-04-19
申请人： SOLVAY SA , EICHER, Johannes , OLSCHIMKE, Jens , BOMKAMP, Martin , GARCIA-JUAN, Placido
发明人： EICHER, Johannes , OLSCHIMKE, Jens , BOMKAMP, Martin , GARCIA-JUAN, Placido
IPC分类号： H01M10/0567 , H01M10/052
CPC分类号： H01M8/22 , H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M12/08 , H01M2220/20 , H01M2300/0028 , H01M2300/0034 , Y02E60/122 , Y02E60/128 , Y02T10/7011
摘要： A lithium-air battery cell with an electrolyte composition comprising LiPO 2 F 2 is described. The electrolyte composition comprises an electrolyte solvent, for example, one or more non-fluorinated solvents, e.g. ethylene carbonate, a dialkyl carbonate or propylene carbonate, and/or one or more fluorinated organic solvents, e.g. fluoroethylene carbonate, cis-difluoroethylene carbonate, trans-difluoroethylene carbonate, 4,4-difluoroethylene carbonate, trifluoroethylene carbonate, tetrafluoroethylene carbonate, 4-fluoro-4-methyl-1,3-dioxolane-2-one, 4-fluoro-4-ethyl-1,3-dioxolane-2-one, 2,2,2-trifluoroethyl-methyl carbonate, 2,2,2-trifluoroethyl-fluoromethyl carbonate are preferred. The solvent may further comprise other additives. Also described is a vehicle battery, especially a car battery constituted of a multitude of lithium-air battery cells of the invention. The battery can be used to provide electrical energy to consumers for electric current including an electric motor driving the vehicle.
摘要翻译：描述了具有包含LiPO2F2的电解质组成的锂空气电池单元。电解质组合物包含电解质溶剂，例如一种或多种非氟化溶剂，例如，碳酸亚乙酯，碳酸二烷基酯或碳酸亚丙酯，和/或一种或多种氟化有机溶剂，例如，氟代碳酸亚乙酯，顺式二氟亚乙基碳酸酯，反式二氟亚乙基碳酸酯，4,4-二氟亚乙基碳酸酯，三氟乙烯碳酸酯，四氟乙烯碳酸酯，4-氟-4-甲基-1,3-二氧戊环-2-酮，4-氟-4- 乙基-1,3-二氧戊环-2-酮，2,2,2-三氟乙基 - 甲基碳酸酯，2,2,2-三氟乙基 - 氟甲基碳酸酯。溶剂可以进一步包含其它添加剂。还描述了一种车辆电池，特别是由本发明的多个锂空气电池单元构成的汽车电池。电池可以用于为消费者提供电能，包括驱动车辆的电动机的电流。

4. 发明申请

WO2010026079A1 PROCESS FOR THE ELECTROCHEMICAL MANUFACTURE OF HALOGENS USING CONDUCTIVE METAL DERIVATIVES 审中-公开
标题翻译：使用导电金属衍生物的卤化物电化学制备方法
公开(公告)号：WO2010026079A1
公开(公告)日：2010-03-11
申请号：PCT/EP2009/060935
申请日：2009-08-25
申请人： SOLVAY FLUOR GmbH , EICHER, Johannes , SOMMER, Christoph , HERKELMANN, Ralf , PERNICE, Holger , SCHWERDT, Phillip
发明人： EICHER, Johannes , SOMMER, Christoph , HERKELMANN, Ralf , PERNICE, Holger , SCHWERDT, Phillip
IPC分类号： C25B1/24 , C25B11/04
CPC分类号： C25B1/245 , C25B1/24 , C25B11/04 , C25B11/0442
摘要： Fluorine is prepared by electrolysis of precursors, generally of fluoride salts in molten form, e.g. in the form of molten KF-2HF. An anode is applied which is fully constituted of or coated with nitrides, diborides or carbides of metals of the 4 th to 6 th sub group of the periodical system of the elements or boron-doped silicon carbide; alternatively, it contains them in a conductive or non-conductive matrix. Preferably, diborides of titanium, zirconium, hafnium or tungsten, or mixtures of two or three of them, are applied.
摘要翻译：氟通过电解电解制备，前体通常为熔融形式的氟化物盐，例如以熔融的KF-2HF的形式。施加阳极，其完全由元素或硼掺杂碳化硅的周期性系统的第4至第6子组的金属氮化物，二硼化物或碳化物完全构成或涂覆; 或者，它将它们包含在导电或非导电基质中。优选地，应用钛，锆，铪或钨的二硼化物，或其中两种或三种的混合物。

5. 发明申请

WO2009013198A1 PROCESS FOR OBTAINING A PURIFIED HYDROFLUOROALKANE 审中-公开
标题翻译：获得纯化氢氟烷的方法
公开(公告)号：WO2009013198A1
公开(公告)日：2009-01-29
申请号：PCT/EP2008/059285
申请日：2008-07-16
申请人： SOLVAY FLUOR GmbH , UENVEREN, Ercan , HAUSMANN, Eckhard , EICHER, Johannes , EICHHOLZ, Kerstin
发明人： UENVEREN, Ercan , HAUSMANN, Eckhard , EICHER, Johannes , EICHHOLZ, Kerstin
IPC分类号： C07C17/395 , C07C19/08 , C07C51/58 , C07C53/48
CPC分类号： C07C17/395 , C07C51/58 , C07C19/08 , C07C53/46 , C07C53/48
摘要： The invention consequently relates, in one aspect, to a process for obtaining a hydrofluoroalkane comprising at least two carbon atoms, which is purified of unsaturated organic impurities, according to which the hydrofluoroalkane containing organic impurities including (chloro)fluoro olefins is subjected to at least one purification treatment with bromine or BrCl, preferably in the presence of an initiator. The process is suitable, for example, to purify 1,1,1,2-tetrafluoroethane. A further aspect concerns the application of LEDs or OLEDs to support chemical reactions of the gas-gas, liquid-liquid or gas-liquid type, and a respective reactor.
摘要翻译：因此，本发明在一方面涉及一种获得含有至少两个碳原子的氢氟烷烃的方法，该方法是不饱和有机杂质的纯化，根据该方法，含有（氯）氟烯烃的有机杂质的含氟氟烷烃至少经受用溴或BrCl进行一次净化处理，优选在引发剂存在下进行。该方法例如用于纯化1,1,1,2-四氟乙烷是合适的。另一方面涉及LED或OLED的应用以支持气体，液体或气液型以及相应的反应器的化学反应。

6. 发明申请

WO2005085129A2 HERSTELLUNG VON CARBONYLFLUORID 审中-公开
标题翻译：羰基的生产
公开(公告)号：WO2005085129A2
公开(公告)日：2005-09-15
申请号：PCT/EP2005/001281
申请日：2005-02-09
申请人： SOLVAY FLUOR GMBH , BRAUN, Max , EICHER, Johannes
发明人： BRAUN, Max , EICHER, Johannes
IPC分类号： C01B31/00
CPC分类号： C01B32/80
摘要： Carbonylfluorid, das auch als Ätzgas verwendet werden kann, lässt sich durch photochemische Oxidation von Chlordifluormethan oder Trifluormethan mit Licht, beispielsweise mit Licht einer Wellenlänge ≥ 280 nm in Anwesenheit von Chlor herstellen.
摘要翻译：羰基氟化物，其也可以用作蚀刻气体可通过氯二氟甲烷，三氟甲烷，或与光的光化学氧化，例如光> =的波长来产生在氯的存在280纳米。

7. 发明申请

WO2010026082A1 PROCESS FOR THE ELECTROCHEMICAL MANUFACTURE OF HALOGENS USING A MATRIX ANODE 审中-公开
标题翻译：使用矩阵阳极的电解质制备方法
公开(公告)号：WO2010026082A1
公开(公告)日：2010-03-11
申请号：PCT/EP2009/060940
申请日：2009-08-25
申请人： SOLVAY FLUOR GMBH , EICHER, Johannes , HERKELMANN, Ralf , PERNICE, Holger , SCHWERDT, Phillip , SOMMER, Christoph
发明人： EICHER, Johannes , HERKELMANN, Ralf , PERNICE, Holger , SCHWERDT, Phillip , SOMMER, Christoph
IPC分类号： C25B1/24 , C25B11/04
CPC分类号： C25B1/245 , C25B1/24 , C25B11/04
摘要： Fluorine is prepared by electrolysis of precursors, generally of fluoride salts in molten form or dissolved in HF. An anode is applied which is based on matrices made of AI 2 O 3 , SiC and Si x N y and conductive ceramics. Especially borides, nitrides and carbides of metals of sub-groups 4 to 6 of the periodic system of elements, boron-doped silicon carbide and boron-doped diamond are conductive and can be applied in the construction of anodes for the electrochemical production of fluorine. Chlorine can be produced from chlorides.
摘要翻译：氟通过电解电解制备，前体通常为熔融形式的氟化物盐或溶于HF中。应用基于由Al2O3，SiC和SixNy制成的基体和导电陶瓷的阳极。特别是元素周期性系统的4至6族金属的硼化物，氮化物和碳化物，硼掺杂的碳化硅和硼掺杂的金刚石是导电的，并且可以用于构建用于氟的电化学生产的阳极。氯可以由氯化物生产。

8. 发明申请

WO2009130224A1 PREPARATION OF HYDROGEN FLUORIDE FROM FLUORSPAR OR CALCIUM FLUORIDE CONTAINING WASTE MATERIAL 审中-公开
标题翻译：含有氟化物的氟化物或含有氟化钙的废弃物的制备
公开(公告)号：WO2009130224A1
公开(公告)日：2009-10-29
申请号：PCT/EP2009/054752
申请日：2009-04-21
申请人： SOLVAY FLUOR GMBH , GRASS, Helmut , HENGST, Matthias , EICHER, Johannes
发明人： GRASS, Helmut , HENGST, Matthias , EICHER, Johannes
IPC分类号： C01B7/19
CPC分类号： C01B7/192
摘要： The invention concerns a process for the preparation of HF and anhydrite from calcium fluoride in the form of fines and sulfuric acid. The content of sulfuric acid is kept in a range where no agglomeration occurs. In the process of the invention, dust originating from natural fluorspar can be reacted, as well as synthetic calcium fluoride, e.g. from calcium fluoride and optionally calcium carbonate containing solids from treating waste gas or waste water with basic calcium compounds to remove contained HF.
摘要翻译：本发明涉及一种以微细和硫酸的形式从氟化钙制备HF和无水石膏的方法。硫酸的含量保持在不发生凝聚的范围内。在本发明的方法中，来自天然氟石的粉尘可以与合成的氟化钙反应，例如合成的氟化钙。来自氟化钙和任选的含碳酸钙的固体，用碱性钙化合物处理废气或废水以除去含有的HF。

9. 发明申请

WO2007074148A1 PURIFICATION OF ALKENONE ETHERS 审中-公开
标题翻译：碱性酮的纯化
公开(公告)号：WO2007074148A1
公开(公告)日：2007-07-05
申请号：PCT/EP2006/070191
申请日：2006-12-22
申请人： SOLVAY FLUOR GmbH , WIESENHÖFER, Wolfgang , KALBREYER, Wolfgang , EICHER, Johannes
发明人： WIESENHÖFER, Wolfgang , KALBREYER, Wolfgang , EICHER, Johannes
IPC分类号： C07C45/78
CPC分类号： C07C45/81 , C07C45/455 , C07C49/255
摘要： Alkenone ethers, especially haloalkenone ethers are intermediates in chemical synthesis. By-products are formed during storage and these can be removed by freezing-out.
摘要翻译：烯酮醚，特别是卤代烯酮醚是化学合成中的中间体。在储存期间形成副产物，并且可以通过冷冻除去副产物。

10. 发明申请

WO2011045338A1 HIGH-PURITY FLUORINE GAS, THE PRODUCTION AND USE THEREOF, AND A METHOD FOR MONITORING IMPURITIES IN A FLUORINE GAS 审中-公开
标题翻译：高纯度氟气，其生产和使用方法，以及监测氟气中污染物的方法
公开(公告)号：WO2011045338A1
公开(公告)日：2011-04-21
申请号：PCT/EP2010/065334
申请日：2010-10-13
申请人： SOLVAY FLUOR GmbH , PERNICE, Holger , EICHER, Johannes , FEYS, Francis , BALTHASART, Dominique , SOMMER, Christoph , KRUEGER, Harald
发明人： PERNICE, Holger , EICHER, Johannes , FEYS, Francis , BALTHASART, Dominique , SOMMER, Christoph , KRUEGER, Harald
IPC分类号： C01B7/20 , G01N21/01
CPC分类号： G01N21/3504 , C01B7/20 , G01N21/33 , G01N21/39 , G01N21/72 , G01N21/94 , G01N2021/399
摘要： An apparatus for producing a fluorine gas, comprising at least one fluorine generating cell, and at least one fluorine generating cell detector for detecting components of products obtained by the fluorine generating cell, wherein at least one of the fluorine generating cells is connected with the fluorine generating cell detector.
摘要翻译：一种氟气的制造装置，其特征在于，具有至少一个氟发生电池，以及至少一个氟发生电池检测器，用于检测由氟发生电池获得的产物的成分，其中至少一个氟发生电池与氟生成细胞检测器。

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